TW304860B - - Google Patents

Description

V. Description of the invention (/ A7 B7 The present invention resembles a novel compound of formula I with killing II activity C3 Η

A R3 compound 1 and R mixed <Ν configuration or · Xiehe 1 丨 its son 1 and 丨, the original R H R compound nitrogen ο C ο is configured to be hetero X γ ΧΥ its}) and a b of 2

R or —I- n— ^^^^ 1 nn ^ 1. ^ 1 ^^^^ 1 ^^ 1 (please read the precautions on the back before filling in this page)

R is

C

, 1T R and

Based on 4 R N or 子, the original hydrogen CSI gas is 1 is 1 R A R

C C / | \; or the base hydrogen is} Li 4 K C white I 0

Alkyl \ 1/4 C

Base 粝 基 Prosperyl base Alkyl \ «/ 4 C Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

Hydrogen to 2 R

C

D

C C

Alkane \ — / 6 C

C-line plain halogen is the same or not in the same phase as f; it is the base phen D or

Alkane 4 CI 1 C This paper scale is applicable to the Chinese National Standard (CNS) M specifications (210X297 mm) 5. Description of the invention (work) A7 B7 Printed base 9 (C 1 1 C 4) for the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Hospital gas group 9 (C 1 — CZ) Binyl group 9 (C 1 — CZ) Halo group gas group »(C 3 — C 6) Alkenyl group (C 3 — C 6) Alkynyl group • (C 1 — C 4) secondary house base two gas base »Radon or nitro 1 η is 0 * 1 2 $ 3 or 4 * ZO is — 0 — • — 0 one (C 1 — C 4) hospital base —» — ( C 1 — C 4) Alkyl 0-0 9 — S (0)-(C! -C 4) Alkyl — S (〇)-~ 9 -S (Ο) S — (C 1 — C 4) Alkyl Base — »m is 0 • 1 9 or 2 t B is (C 1 — C 6) hospital base • halogen one (C 1 — C 6) hospital base 9 (C 3 — C 6) Hunyuan base • or is ( CZ — C 6) Alkenyl or (C 2 — C 4) Alkynyl — (C 1 — C 2) Alkyl »Each is unsubstituted or substituted by 1 to 3 halogens Substituted, or aryl or heteroalkenyl, its white is independently unsubstituted or (C 1 — C 6) alkyl »halogen — (C — C 6) alkyl &gt; halogen» (C 1 — C 6 ) Yuan «radical or halogen — (C 1 — C 6) Yuan oxy mono-substituted to penta-substituted • or R5 .r7 — (CH) -A &lt; 1 Λ, r8 or trimethylsilyl» R 5 $ R 6 $ R 7 9 R 8 and R 9 are white and stand for hydrogen $ (c — C 4) Yuan or halogen $ and P are 0 9 1 9 2 or 3 1 -8- — ^ ---- --AI 装 ------ 定 ----- ί line (please read the precautions on the back before filling in this page) This paper scale is applicable to China National Standard (CNS) 84 specifications (210Χ297mm) Economy A7 ______B7_ printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Education. 5. Description of invention (j) R3 is hydrogen, (Ci _C6) alkyl, (C, -ce) haloalkyl containing 1 to 5 halogen atoms, (Ci- C4) Alkane-based (Ci — C2) hospital base, (Cz — C *) suspected-based (Ci — C2) hospital base It is like unsubstituted or substituted by 1 to 3 yttrium atoms, (C2 — C4) alkynyl mono (Ci _C2) alkyl, unsubstituted or substituted by 1 to 4 halo atoms (C3 _Ce) Chen alkyl , Unsubstituted or substituted by 1 to 4 halogen atoms (C3 — C6), alkynyl (Ci -C4), alkynyl (Cl — C4) halide; (Cl — C4) burned gas Carbonyl- (Ci- (: 2) alkyl, (Ci-c4) alkylaminocarbamate-(Cl-C2) yalkenyl "phenyl- (Ci-C3) courtyard group • Its image is unsubstituted or substituted Halogen, (Cl-c3) alkyl, (Ci _C4) alkane, (Ci -c4) haloalkyl, trityl, nitro or (Ci _C4) subalkyl di-air, their phenyl groups are the same Or different substituents are mono-substituted to tri-substituted; unsubstituted phenyl group or by a self-contained (C! -C4) alkyl group, (Ci -C4) alkane group, halogen, containing 1 to 3 halo Atomic (Ci —C2) haloalkyl, nitro or phenyl monosubstituted or disubstituted phenyl, or unsubstituted pyridyl or independently substituted (Ci _C4) alkyl, (Ci _C4) alkyl Oxygen, halogen, (Ci 〇2) containing 1 to 3 decanolin atoms Alkyl, nitro or pyridyl mono- or di-substituted; R4 is (Ci-C4) alkyl, phenyl, or R3 and R4-together with the nitrogen atom to which they are bonded to form a saturated or unsaturated From 5 to 7 members, this paper is not replaced or is (Ci _C4) alkyl. The paper standard is applicable to China National Standard (CNS) Α4 specification (210X297 mm) ------ Μ 1 装 ----- -Subscribe ----- (Line (please read the notes on the back before filling in this page) A7 B7 printed by the Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs V. Invention description (&gt;) Substituent substitution, may contain 1 To 3 hire extra gas, gas and sulfur heteroatoms. The compound of the present invention possesses the characteristics of killing poems, killing niches and killing codlings. It is suitable as an active ingredient in the fields of agriculture, gardening and physiology. The present invention further includes a method for preparing the compound of the present invention, as well as a composition for killing microbes, killing cockroaches and killing Kundian, the composition containing the compound as an active ingredient, and both the compound and the composition In the control of phytopathogenic emblem bacteria, Chi Yan and Kun niches and prevent such attacks. If the compound of formula I contains an asymmetric sulfon atom, the compound exists in an optically active form. In any case, this compound exists in the form of [E] and / or [Z], only because of the presence of fatty bars, glucosamine and hydrazono double bonds. Furthermore, atropisoieris (atropisoieris ·) may also be present. Formula I is intended to include all possible isomeric forms and mixtures thereof, such as racemic mixtures and any [E / Z] mixtures. Unless specifically defined, the definitions of the terms used above and below are as follows: halogen is fluorine, atmosphere, bromine or iodine, and it is fluorine, chlorine or bromine, and more particularly fluorine or gas. Alkyl is straight chain, such as methyl, ethyl, n-propyl, n-butyl, n-hexyl, n-octyl, n-decyl, n-dodecyl, n-hexadecyl or n-octadecyl, or branched , Such as isopropyl, isobutyl, secondary butyl, tertiary butyl, isopentyl, neopentyl or isohexyl. The alkenyl group is a straight chain or branched carp alkenyl group, such as vinyl, 1_methylvinyl-10-This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm) I: ------ Jkl installation ------ order ----- (line (please read the precautions on the back before filling in this page) 304860 _ ^ ___ 5. Description of the invention (gray) base, allyl, ι_butene Group, isopropenyl, especially propyl. Alkynyl is, for example, ethynyl, 1-propynyl or 1-butynyl • especially propynyl. It should be understood that cycloalkyl is propyl, butyl , Pentyl or quasi-hexyl substituents such as haloalkyl and haloalkyl gas groups may be partially or completely substituted with the same or different chemical radicals. Examples of haloalkyl groups are gas, ammonia and / or o Mono-substituted to tri-methyl group, such as CHF2, CFs or CHCU; mono-substituted with fluorine, ammonia and / or bromine to penta-substituted ethyl • For example, Cli2 CF3 'CF2 CF3. CF2 CCI3, CF2 CHC12, CF2 CCI3, CF2 CHC1 2. CF 2 CHF e, CF z CFClz, CH2 CHz Cl, CFz CHBr2 · CFz CHC1F, CF2 CHBrF or CC1FCHC1F; trifluoromethyl is preferred. Direct bond (Ci-C4) Subalkyldioxy KHz -O- CH2 CH2 -O-CH2 CHZ CHZ -0- or -O-CH2 CH2 CH2 ch2 -〇〇Aryl is, for example, phenyl or naphthyl, especially benzene #. Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please Read the precautions on the back and then fill out this page.) Zachenji is a 5 to 7 member with 1 to 3 values selected from the group consisting of nitrogen, gas and sulfur groups of heteroatoms of aromatic or non-aromatic fan. Preferably It is a 5th and 6th member of Fenbiao containing bait atoms as heteroatoms, suitable ones contain other heteroatoms, preferably nitrogen or sulfur, especially nitrogen. It is formed by R3 and the radon atom bonded to it The term 5 to 7 Yuanchen especially includes pyrrolidine, piperidine, morpholine, sulfur, and oxoline, six times. This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm). Employee consumption of the Central Standard Falcon Bureau of the Ministry of Economic Affairs Printed by the cooperative A7 B7 V. Description of the invention (έ) Methylamine, zirconium, pyrazole, pyrrole, 1, 2, 4-triazole, 1, 2, 3-triazole, tetrazolium • isoxazole, oxazole Azole, isoxazoline, oxazolidine, oxazole, isoxazole and isoxazolidine. Preferred in the scope of the present invention are (1) compounds of formula I, in which a) X is a nitrogen atom and Y Is 0CH3 or NHCH3 or b) X is C Η and Υ is 0 C Η 3, where: Α is a gas atom or NR4 group;

Ri is hydrogen · (Ci-C4) courtyard group, window element one (Ci-c4) alkyl group, propyl group, m group or methylthio group;

Rz is hydrogen, (Ci -C6) alkyl (C3-C6) Chenane

η or thienyl; D is the same or different, which is halogen · (Ci _C4) alkyl, (Ci-C4) alkoxy, (Ci-c2) haloalkyl, ((: 1 1 (: 2 ) Binane gas group, (〇3-(: 6) alkene gas group, (C3-C6) alkynyl gas group, (Cl-C4) hypoalkylene gas group, cyano or nitro; -12- this paper The standard is applicable to China National Standard Falcon (CNS) A4 specification (210X297 mm) I 1 · ~ 丨 binding (line (please read the precautions on the back before filling in this page) ^ 4860 _ &quot; l V. Description of invention (Ί) η Is 〇, 1, 2, 3 or 4; redundant is _〇 one, a 0 — (Ci one (: 4) alkyl one,-(c ^ — C4) yard group one — — S (Ο) B -,-(Cl-C 4) alkyl mono S (0)-,-S (Ο) B- (Cl-C 4) alkyl mono &quot; · m is 0, 1 »or 2, B is (C ! _C6) alkyl • Ci_C6) alkyl, (C3 _C6) eunyl, or (Cz-C6) alkenyl or (C2 — C4) alkynyl- (Ci —C2) alkyl, each The tungsten is unsubstituted or substituted with a halogen atom of 1 to 3, or is an aryl group or a heteroalkenyl group, and its base is unsubstituted or substituted by (Ci —Ce) alkyl · halogen mono (Ci -c6) alkyl ,halogen , (Ci one (: 6) alkoxy or if element one (

Ci-Cs) alkyl mono to five substitutions, or

(Please read the precautions on the back and then fill out this page) R / r8 R 5, R 6, R 7, Rs and R9 Sisi stand up as Hyena, (Ci

Printed by the Immigration and Consumer Cooperative of the Central Ministry of Economic Affairs

Subalkane 4 original ί &gt; I to 歯 I Z 2 1 partial group c C is 5 gas I ί or to alkane 1, generation 1} C is substituted with 4 ί taken, CI is not based on I base. Alkyl -Alkenyl group} C _ «alkane 6 (43); c, C to 2 and 3 I group I 1 C, or-alkane 2 is halogenated by I element 2 C or -a, ί &gt; &lt; instead of C or 1 * 6. Take {group, hydrogen C group is burnt by I ο 1 alkyl group> 3 1} You are fast 4 p RC 2 its} c (C · 4 1 of a base C This paper size is suitable for China Standard (CNS) Α4 specification (210 × 297 mm) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of the Invention (Party) (C3 — (: 6)) alkyl substituted by a halogen atom • Not substituted or (C3-C6) alkyl (Ci-C 0: 4) alkyl substituted with 1 to 4 halogen atoms, «Ci- (Ci-C *) alkyl; (Ci-Ci) alkanoylcarbonyl- (Ci-Cz) alkyl. Phenyl- (Cl_C3) alkyl, which is unsubstituted or substituted by element, (Ci—C3) alkyl, (Ci—C4) alkyl, (Ci—c4) halogen Alkyl, gas, nitro or (Ci —c4) hypoalkyl digas, the phenyl group is the same or different Substituted groups are mono- to tri-substituted; unsubstituted phenyl groups or "self-supported (Ci-C *) alkyl groups, (Ci_C4) alkanoyl groups • halogens, containing 1 to 3 ammonium halide atoms (Ci _C2) Phenyl, nitro or phenyl mono- or di-substituted phenyl, or unsubstituted pyridyl or (Ci-C4) alkyl, (Ci-C *) alkane Group, bismuth, (Ci _C2) haloalkyl containing 1 to 3 americium halogen atoms, nitro or gas-based mono- or di-substituted pyridyl; R4 is (C!-04) alkyl, phenyl, or R3 and R4 together form a saturated or unsaturated 5- to 7-membered ring with the nitrogen atom to which they are bonded. This is unsubstituted or substituted with a (Ci -C4) alkyl substituent, which may contain 1 to 3 additional It is a heteroatom of nitrogen, gas and sulfur. (2) Compound of formula I, where X is nitrogen · Y is 〇CH3; (3) Compound of formula I, where X is CH; (4) Compound of formula I, where X is N, Y is NHCH3, H, CH3, cyclopropyl or CN; -14- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) I, ------ Jk-installed- ---- order ----- &lt; line (please read the notes on the back before filling this page) 30 4860 A7 B7 5. Description of the invention (? ) (5) Compound of formula I, where A is gas, NCH3 or n-C6 Hs • Especially gas or NCHs, not to mention gas; (6) Compound of formula I, where Ri is hydrogen, methyl • cyclopropyl Or protyl, which is otherwise methyl; (7) The compound of formula I, wherein R2 is (Ci-C4) alkyl or propyl, especially methyl or propyl; 2 is 8) The compound of formula I, wherein R2 is mono / ~ ^> and the D group is kojirin, (Ci_CU) alkyl, (Ci_C4) alkanoyl, (Ci-02) alkyl substituted with 1 to 5 halogen atoms, C2) 豳Alkoxy, (C3-Ce) alkenyl, (C3

(C -Ce) alkynyloxy · (Ci -C4) alkylidene dioxy, phenyl or nitro, or trypanyl; D is especially fluorine, chlorine, bromine

Ci_C4) alkyl or one CF3

ZB (9) Compound of formula I, where R2 is IJ ------ {, I loaded ------ ordered ----- f line (please read the notes on the back before filling this page) Economy Printed by the Beigong Consumer Cooperative of the Ministry of Central Standards (D) ZO is — 0 — f — 0 — (C 1 — C 4) courtyard — 9 — (C — C 4) courtyard — 0 one, -S (0 ) AZ —,-(C 1 — C 4 alkyl—S (〇) 2 one.—S (〇) ZO— (C!-C 4) alkyl— 9 Wait until it is — 0 — • — C Η 2 — 0 — or _ 0-C Η 2 — • More specifically — 0 — C Η ζ; (1 0) Compounds of formula I, where R 2 is &lt; 5 ZO- Β 15- This paper scale is applicable to Chinese national standards ( CNS) A4 specification (210X297mm) A7

Du Printing Co., Ltd. Employee Consumption Cooperation of Central Bureau of Standards of the Ministry of Economic Affairs

Fifth, the description of the invention (/.) B is the (Ci-C4) hospital base, consisting of (Ci-C4) hospital base or (C2-C4) alkenyl or (C2_C4) alkynyl_ (Ci-C2) Alkyl, β is unsubstituted or substituted by 1 to 3 atoms by atoms, or is aryl or voluntarily, unsubstituted or substituted by (Ci _c2) alkyl. Halogen one (Ci -Cz) alkyl · bin Cable, (Ci-C2) alkoxy or halogen mono- (c1-Cz) alkyl mono- to di-substituted, or

R 5, R 6, R 7, Re and R9® are selected from hydrogen to hydrogen, (Ci-C2) alkyl or halogen, and P is 0, 1, 2 or 3; B to be (Ci-〇2) Alkyl • Halogen (Ci _C3) alkyl, or allyl or propargyl, which is unsubstituted. Or in all cases substituted by 1 or 2 halogen atoms or 1 or 2 methyl groups, or Phenyl, substituted by a substituent selected from fluorine, cyanide, bromine and CF3, or — (CH) 2 (11) compound of formula I, where Rz is a phenyl substituted at the 4-position by a Z—B (12) The compound of formula I, wherein R3 is hydrogen, (Ci-C6) alkyl, (Ci-C4) window alkyl containing 1 to 3 partial halogen atoms, (Ci _C2) alkane group (_ 1 6 _ This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) I; {I binding f line (please read the precautions on the back before filling this page) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards V. Description of Invention (M)

Ci— C2) alkyl, (C ^ -CU) alkylcarbonylcarbonyl mono (C, —CZ) alkyl, propenyl, allyl, unsubstituted or substituted by 1 to 3 amino atoms, (C3- Ce) Chen alkyl, unsubstituted or substituted with 1 to 2 slap halogen atom, propylmethyl, fluoro-CZ) alkyl, unsubstituted or halogen, methyl, methyl group or containing 1 To the phenyl mono (Ci — C2) alkyl substituted by 3 halogen atoms, the phenyl group may be unsubstituted or substituted by the same or different substituents; the unsubstituted phenyl group may be substituted by quaternity (C! — C4) Alkyl (Ci- 匚 4) alkane, halogen, (Ci — C2) haloalkyl containing 1 to 3 mesitine atoms, nitro or phenyl mono- or di-substituted phenyl, or Unsubstituted pyridinyl or sulfonated (C! — C4) alkyl, (C! _C4) alkane, halogen, (C1 -C2) haloalkyl containing 1 to 3 tilt halogen atoms , Nitro or cyano mono- or di-substituted pyridyl; or R3 and R4 together with the nitrogen atom to which they are bound to form a saturated or unsaturated 5 to 7 member, the Chen is not substituted or (Ci _C4 ) Alkyl substitution, may contain 1 to 3 additional nitrogen Heteroatoms of oxygen and sulfur; R3 is preferably radium, (〇1-06) alkyl, (Ci-C4) containing 1 to 3 halogen atoms to form a hospital group, (Ci-Cz) halomethyl, Unsubstituted or substituted with 1 to 3® halogen atoms propa-2-en-1-yl, allyl, (C3-C6) alkyl, unsubstituted or substituted with 1 to 2 fluorine or chlorine atoms Cyclopropylmethyl, propyl- (Ci _CZ) alkyl, unsubstituted or substituted by halogen, methyl, methyl, or halogenated methyl substituted with halogen atoms containing 1 to 3 halogen atoms —C2 ) Alkyl, Benzene-17- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297mm) 丨: ------ &lt; I installed ------ ordered ----- f line (please read the precautions on the back before filling in this page) A7 ____B7_ printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention description (/ work) The group may not be substituted or be replaced by the same or different substituents. Disubstituted; unsubstituted phenyl or thiophene is substituted by halogen, methyl, mesyl, halomethyl containing 1 to 3 dysprosium atoms, phenyl or nitro; unsubstituted ttPyridyl or be called alone Substituted pyridine by halogen, methyl, methyl group, halomethyl containing 1 to 3 bow tooth atoms, radon or nitro; or r3 and R4 together with it is 1, 2, 4-triazole Group, 4— «Ilinyl · 1 azepine, 1 piperidinyl or 1 pyrrolidinyl, R 3 is particularly preferably methyl; (13) The compound of formula I, wherein R 4 is methyl or benzene Group, especially methyl; (14) Compound of formula I, wherein X is CH; Y is OCH3; Ri is CH3; A is gas; R2 is 4-methylphenyl or 4-allylaminophenyl or 4- (3 monotrifluoromethyl monobenzyl) phenyl or 4- (2, 2-difluoromethylpropyl) phenyl and R 3 is C Η 3; (15) The compound of formula I, wherein a) X is a nitrogen atom and Y is 0CH3 or NHCH3 or b) X is C Η and Υ is 0 C Η 3. Among them: Α is a gas atom or NR4 group; -18- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 17 n people &quot; &quot; binding (line (please read the precautions on the back before filling out this page) A7 B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (丨 3)

Ri is hydrogen, (Ci 104) alkyl · propyl, propyl or methylthio;

Rz is hydrogen; (Cj—Ce) alkyl; (C3-C6) alkyl; unsubstituted phenyl or benzoxine, (CI -C4) alkyl, (Ci—C *) Alkyl group, (Ci-Cz) trekyl group, (Ct-Cz) haloalkane group · (C3-C6) alkenyloxy group, (C3-Ce) alkenyl group, (Ci_C4) sub-gas group Gas group, nitro group or gas group mono- or di-substituted phenyl group; or β phenyl group; R 3 is hydrogen, ((: 1 a 0: 6) alkyl group, containing 1 to 5 Yuqu atoms (Ci — Ce ) Dental hospital group · (Ci — C4) hospital gas group one (Ci — C2) alkyl, (C2 _C4) alkenyl one (Ci _c2) alkyl, which you are not substituted or substituted by 1 to 3 «halogen atoms , (C2-C4) alkynyl mono (Ci-C2) alkyl, (Cs _C6) cycloalkyl unsubstituted or substituted by 1 to 4 hydrogen atoms, unsubstituted or substituted by 1 to 4 halide halogen atoms (C3-Ce) Chen-alkyl (Ci-C4) alkyl, gas-Ci-C ^ alkyl; (Ci-C4) alkanecarbonyl-(Ci-C2) alkyl, phenyl A (Cl _C3) group, which is unsubstituted or halogenated, (Ci_C3) alkyl, (Ci _C4) alkane, (Ci-C4) haloalkyl, atmosphere, nitro (Ci _C4) Subalkyl diamino group, the phenyl group of which is mono- to tri-substituted by the same or different substituents; the unsubstituted phenyl group is or is substituted by (Ci-C4) alkyl, (Ci -C *) alkoxy. Kojirin, (Ci -C2) kojitan.nitro or nitrogen group containing 1 to 3 halogen atoms -19- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297 Mm) ------ {, I installed ------ ordered ----- ^ line (please read the notes on the back before filling this page) A7 B7 3〇486〇 ^ --- ---- V. Description of the invention (w) Mono-substituted or di-substituted phenyl, or unsubstituted pyridyl or independently (Ci — C4) alkyl, (C! — C4) alkane , Halogen, (Ci-CZ) haloalkyl containing 1 to 3 germanium halogen atoms, nitro or phenyl mono- or di-substituted pyridyl; R4 is (Ci-C4) alkyl, phenyl, or R3 and R4-form a saturated or unfilled nitrogen atom with the nitrogen atom to which it forms 5 to 7 members, which is unsubstituted or substituted with (C ^ _C4) alkyl substituent 1, which may contain 1 to 3 additional A heteroatom from nitrogen, gas and sulfur 〇 (16) Compound of formula I, where X is C Η or N Υ is 0 C 3 Α is 0 or N-R4 Ri is methyl, cyclopropyl or methylthio;

Rz is a methyl group; a propyl group; an unsubstituted phenyl group or a halogen group. (Ci-C4) group, (Ci-C4) group gas group, 1 to 5 halogen atoms substituted (Ci _c2) Alkyl, (Ci-c2 &gt; ϋ alkynyl · (〇3- (: 6) alkenyloxy, (c3-c6) alkynyl, (Ci-Ci) hypoalkylene dioxy, radon or Nitro mono-substituted to di-substituted phenyl, or molenyl; wherein R 3 is defined as formula I and R 4 is methyl or phenyl, or the nitrogen atom bonded to R 3 and R 4 is pyrrolidine, piper Dian-20- This paper scale is applicable to the Chinese National Standard (CNS) 84 specifications (210X297mm) —.I ------ People Packing ------ Order ----- f line (please Read the precautions on the back first and then fill out this page) Printed by the Ministry of Economy Central Standards Bureau Employee Consumer Cooperatives Printed by the Ministry of Economic Affairs Central Standards Bureau Beigong Consumer Cooperatives A7 B7 Fifth, the invention description (ο, Pyroline, Thiomeline, six Methylimine, azole, pyrazole, pyrrole, 1, 2, 4-triazole or 1, 2, 3-triazole. (17) Compounds of formula I, where X is Ν, Υ is NHC Η 3 · Α Is 0 or N—R4,

Ri is methyl, propyl or methylthio; R2 is methyl; propyl; unsubstituted phenyl or halide is halogen, (Ci-C *) alkyl, (Ci-C4) alkyl Gas group, (Ci — C2) alkyl substituted with 1 to 5 tungsten halogen atoms, (Ci -CZ) haloalkane group, (C3-Ce) alkenyl group, (C3-Ce) alkynyl group. (Ci— C *) Dialkyl diamino, mono- or nitro mono-substituted to di-substituted phenyl, or thienyl; wherein R 3 is defined as formula I and R 4 is methyl or stupyl, or R 3 and R 4 — "The atom is pyrrolidine, piperidine, oxoline, thioxoline, hexamethyleneamine, imidazole • pyrazole. Pyrrole, 1, 2, 4-triazole or 1, 2, 3-Triazole. (18) The compound of formula I, wherein A is gas, R i is methyl, is methyl; unsubstituted phenyl or halide is halogen, (Ci -C4) alkyl, (Ct -C4) alkyl gas · 1 to 5 values for Atomic-2 1- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------ f I installed ------ ordered ---- -f line (please read the precautions on the back before filling in this page) A7 B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economy V. Description of the invention (丨 Replaced (Cl -C2) Hospital Base · (Cl — C2 ) Hospital gas group (C3-ce) alkenyl gas group, (C3-ce> alkynyl gas group, (Ci-c4) hypoalkylene gas group, mono- to di-substituted phenyl group or nitro group, or Tsaipan group; R3 and R3 are (Ci — Ce) group; X and Y are defined as formula I 〇 (19) Formula I compound, wherein R i is methyl, R 2 is methyl, and R 3 is as described , R4 is methyl or phenyl, or R3 and R4-together with the nitrogen atom to which they are bound to form europium and or an unsaturated 5- to 7-membered ring, which is not substituted or substituted by (Ci _C4) alkyl , May contain 1 to 3 extra S heteroatoms from nitrogen, gas and sulfur; and A, X and Y are as shown in formula I (20) The compound of formula I, wherein R3 is hydrogen; (Ci —C4) alkyl; (Cl —C4) alkyl group containing 1 to 3 lanthanide atoms; (Cl — C2) hospital gas group one (_C2 ) Alkyl; unsubstituted or substituted with 1 to 3 halogen atoms; allyl; (C3_C6) cycloalkyl; unsubstituted or substituted with 1 to 2® halogen atoms ; Cyano one (Ci _C2) courtyard group; (Ci — C2) yin gas base group (Cl — C2) courtyard group; unsubstituted or halogenated, methyl, methyl group or containing 1 to 3 ammonium halide Original-22- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) ΙΛ ------ f I installed ------ order ----- f line (please read the back first (Notes to fill out this page again) ^ 04860 g ^ 04860 g Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (Π), «Base, Nitro or (Ci 〇2) Subalkyl Digas Phenyl- (Ci-Cz) alkyl substituted by phenyl, phenyl may be unsubstituted or mono- to di-substituted by the same or different substituents; unsubstituted phenyl or by "halogenated by halogen, methyl , A gas group, containing 1 to 3 halogen Phenylmethyl, propyl or nitro mono- or di-substituted phenyl; or unsubstituted pyridinyl or partially substituted by halogen, methyl, methyl group, containing 1 to 3 halogen Atom's halomethyl, gas or nitro mono- or di-substituted pyridinyl; R4 is methyl or phenyl; or R3 and R4 together with the nitrogen atom to which they are bound form abalone or unsaturated 5 to 7 Beichen, which is unsubstituted or substituted with (Ci _C4) alkyl, may contain 1 to 3 additional heteroatoms selected from nitrogen, gas and sulfur; and A, X, Y, as in formula I As defined. (21) In the compound of formula I mentioned in (20), the nitrogen atom to which Rs and R4 are bonded together is triazolyl, thoracolinyl, 2,6-dimethyl thoracolinyl, aza Leather base, only pyridyl or pyrrolidinyl. (22) The compound of formula I, wherein A is gas, R ^ is methyl. R 2 is methyl; unsubstituted phenyl or oligotropin, (C, a C4) alkyl, (C!- C4) Alkyl, (Ci -C2) alkyl substituted with 1 to 5 atoms, (C: -C2) haloalkane, (C3-Ce) alkenyl, (C3-C6) alkynyl , (Ci -C4) dialkyl, dialkyl, chloro or nitro mono-substituted to di-substituted benzene-23- This paper A degree is applicable to the Chinese National Standard (CNS) A4 ^ grid (210X297 mm) I:- ----- '—installed ------ order ----- f line (please read the precautions on the back before filling in this page) A7 B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Indicate (α) group, or thienyl group; and R3 is hydrogen; (Ci _C4) alkyl group; (Ci _C4) haloalkyl group containing 1 to 3 halogen atoms; (Ci —C2) alkane group (C : -Cz) alkyl; propenyl which is unsubstituted or substituted with 1 to 3 halogen atoms; allyl; (C3-C6) alkyl; unsubstituted or substituted with 1 to 2 halogen atoms Propylmethyl; chloro- (C i -C2) alkyl; (Ci-〇2) alkanoylcarbonyl- (Ci_C2) alkyl; unsubstituted or substituted Element, methyl group, methyl group or containing 1 to 3 tooth atoms, phenyl group, nitro group or (Ct _C2) secondary group diamino substituted phenyl mono (Ci _C2) alkyl group, phenyl group may not be Substituted or mono-substituted to di-substituted with the same or different substituents; unsubstituted phenyl or thiophene; halogen, methyl, mesyl, halomethyl containing 1 to 3 halogen atoms, propyl Or nitro substituted or di-substituted phenyl; or unsubstituted pyridyl or halogen-containing methyl, methoxy, halomethyl containing 1 to 3 healthy atoms, cyano or Nitro mono- or di-substituted pyridyl; and X and Y are as defined in formula I. (23) The compound of formula I mentioned in (22), wherein: A is gas, R i is methyl,

Rz is methyl; unsubstituted phenyl or monophenyl substituted by halogen, methyl, methy, trifluoromethyl or trifluoromethan to disubstituted phenyl; and R 3 is methyl. -24- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) ^ Binding (line (please read the precautions on the back before filling this page) Central Bureau of Standards of the Ministry of Economic Affairs-Industrial and Consumer Cooperation Du Printed A7 B7 5. Description of the invention W) (24) The compound of formula I, wherein: A is NC Η 3, RX is methyl, R2 is methyl; unsubstituted phenyl or thiol A, methyl, methyl gas Radicals, trimethyl or tricyanomethoxy mono-substituted to di-substituted phenyl; and R3 is methyl; unsubstituted phenyl or halogenated by methyl, methyl, methyl, containing Halomethyl of 1 to 3 halogen atom, mono- or di-substituted phenyl of propyl or nitro; or unsubstituted pyridyl or self-propagated halogen, methyl, methy, containing 1 Halomethyl to 3 slap halogen atoms, cyano or nitro mono- or di-substituted pyridyl groups; and X and Y are as defined in formula I 〇 (25) Formula I compounds, wherein X is a nitrogen atom; Y is 0 R i X;

Ri 1 is (Ci-C4) alkyl; wherein A, Rt, R2 and R3 are defined as in formula I. (26) (25) In the mentioned compounds, A is a gas atom; R i and R 2 are methyl;

Rs is hydrogen; (C! -C4) alkyl; (Ci _C4) alkyl containing 1 to 3 partial halogen atoms; (Ci -CZ) alkanoyl (Ci _C2) alkyl; unsubstituted or substituted 1 to 3 Atomic substitution of -25- This paper scale is applicable to Chinese National Standard (CNS) A4 ^ # · (210X297mm) 丨; ------ {I 装 ------ 定- --- f line (please read the precautions on the back before filling in this page) Ministry of Economic Affairs Central Bureau of Industry and Fisheries Consumer Cooperation Du Printing A7 B7 V. Description of Invention (π) Propylene; Allyl; (c3_ce) C-alkyl; C-propyl methyl unsubstituted or substituted by 1 to 2 halogen atoms; Amino- (Ci -C2) alkyl; (Ci _CZ) alkylcarbonyl- (Ci-02) alkyl ; Unsubstituted or substituted by dentyl, methyl, mesyl or containing 1 to 3 he β atoms, phenyl, nitro or (Ct — C2) hypoalkyldioxy substituted phenyl one (Ci _C2) Alkyl and phenyl groups may be unsubstituted or mono- to di-substituted with the same or different substituents; unsubstituted phenyl groups may be substituted by halogen, methyl or methoxy. Contains 1 to 3 halogens Atom halomethyl, «group or nitro mono- or di-substituted phenyl A substituted or unsubstituted piperidinyl or border Li Luo is poured from halogen, methyl, group A gas containing halomethyl 1 to 3 halogen atoms crane, chloro or nitro-substituted mono or di-substituted pyridyl. (2 7) The compound of formula I mentioned in (26), wherein: R3 is hydrogen; ((: 1-(: 4) alkyl or (Cl-C4) Quyuan group containing 1 to 3 halogen atoms). (28) The compound of formula I, wherein X is a nitrogen atom; Y is N (R 1 2) R! 3;

Ri 2 and Chi ^ 3 are self-promoted as hydrogen or (Ci-C4) alkyl; where A, Ri, Rz and R3 are as defined in formula I. (2 9) The compound of formula I mentioned in (28), wherein: Y is NHz, N (CH3) 2 or NHCz Hs; A is a gas atom; R 1 and R 2 are methyl; * 28 &quot; Applicable to Chinese National Standard (CNS) A4 specification (210X297mm) I: ------ 《I installed ------ order ----- f line (please read the notes on the back before filling (This page) A7 B7 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (vl) R3 is hydrogen; (Ci _C4) alkyl; (Ci —C4) haloalkyl containing 1 to 3 atoms; ( Ci-Cz) Alkyl-mono (Ci-C2) alkyl; propenyl unsubstituted or substituted by 1 to 3 quaternary atoms; allyl; (c3_ce) cycloalkyl; unsubstituted or substituted by 1 Cyclopropylmethyl substituted with halogen atoms up to 2; tri- (c, _C2) alkyl; (Ci-C2) alkanoylcarbonyl- (Ci-c2) alkyl; unsubstituted or derivatized, Methyl, methyl group or containing 1 to 3 halogen atoms, cyano, nitro or (Ci _c2) hypoalkyl substituted phenyl mono (Ci _CZ) alkyl, phenyl may not be substituted or Mono- to di-substituted by interphase or different substituents; unsubstituted phenyl Prompted self-assured dentate • methyl, methoxy, halomethyl containing 1 to 3 halogen atoms, phenyl mono- or di-substituted phenyl or nitro; or unsubstituted pyridinyl Or it may be independently substituted by halogen, methyl, methoxy, halomethyl containing 1 to 3 halogen atoms, cyano or nitro mono- or di-substituted pyridyl. (30) Among the compounds mentioned in (29): R3 is hydrogen; (Ci _C4) alkyl or (Cl -C4) cryptic group containing 1 to 3 hydrogen atoms. (31) The compound of formula I, wherein the X = C double bond is in the E form. The preparation of the compound of formula I is as follows: (A) In order to prepare the compound of formula I with Y being N (Ri 2) Ri 3, the compound of formula I with Y being ORi i is reacted with HN (Ri z) Ri 3. This reaction is advantageously carried out in an inert organic dilution, for example, in the fermentation of ethyl yeast, the ethers of tetrazofuran, the ethyl esters of ethyl alcohol, dimethyl-27- This paper size is applicable to China Standard (CNS) A4 specification (210X297mm) I ^ ^ I binding (line (please read the precautions on the back before filling this page)

30486C A7 B7 Fifth, the description of the invention (7) Grinding sub-class, dimethyl formamide amide or methyl isobutyl ketone. Methylamine can be used in gaseous or dissolved form, such as in solution in ethanol. The traditional method of performing the process is from 0 to 401C, preferably at room temperature. (B) In order to prepare the compounds of formula I X, Y, octa and 111-R3 as defined in formula I (where R3 is not radium),

R ·: HON

A Ri

Among them, A and R R3 are defined as above, and are reacted with the compound of the following formula.

X and Y are as defined above, and U is a leaving group. This reaction is a nucleophilic substitution reaction and can be carried out under conventional reaction conditions in such cases. The leaving group U is preferably cyanogen, bromine, iodine, methanesulfonyl chloride-2 8-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) I ^ I binding ^ line (please read the back first Note: Please fill out this page) A7 B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of invention (7 &gt;) or tosylate. The reaction is advantageously in an inert organic diluent, such as cyclic ethers, such as tetrahydrofuran or dioxane, ketones. For example, acetone, amines, such as dimethylformamide, sub-class, such as dimethyl Sub- ", and in halogen such as sodium hydride, sodium sulfate, beryllium sulfonate, europium, tertiary amine, such as trialkylamine, especially diazabicyclononane or diazabicycloundecane , Or in the presence of vaporized silver, and a ffi degree between 20 * 0 and 8 0¾, preferably from Ot: to 50t. Alternatively, the reaction can be carried out at room temperature with a phase transfer catalyst in the presence of an organic solvent such as methine chloride and in a sickle aqueous solution, such as an oxirane solution, and a phase transfer catalyst such as tetrabutylammonium sulfate. . The resulting compound of formula I can be isolated and passivated by conventional methods. In other words, the resulting isomer mixture, for example, the E / Z isomer mixture, can be separated by a conventional method to obtain a passive isomer, such as M-chromatographic analysis or crystallization. The oximes of the general formula II as starting materials are known or can be prepared by conventional methods (J · Che ·. Soc., Perkin Trans II 537 (1990); Ber. Deutsch. Che ·. Ges. 62, 866 (1929); Gazz. Chi .. Ital. 37 II, 147 (1907); Liebigs Ann. Che. 262, 305 (1891). In other words, the starting material of formula III can be prepared by conventional methods, such as European Patent Publication EP-A-203 6 0 6 (BASF) and the documents cited therein or those described in Angeli ». Che .. 7 1, 3 4 9- 3 6 5 (1 95 9). -29- The size of this paper Applicable to China National Standard (CNS) A4 specification (2 丨 0X297mm) — 1 ------ Into—install ------ order ----- {line (please read the precautions on the back first (Fill in this page) ^ 〇486〇A7 _________B7 V. Description of the invention (W) (C) In order to prepare the compound of formula I where a is radon, X, γ and r The compound defined by formula I:

0H

IV. Printed by the Employees Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economics where X · Y, Ri and 1? 2 have the same definition as above, and the following compounds react u-R 3 V R3 has the same definition as Formula I and U has the same definition as Formula III (R3 is neither Hydrogen, nor phenyl or ftt). This reaction is a nucleophilic substitution reaction as described in (B). (D) In order to prepare X, Y, R! In Formula IV and only 2 compounds as defined in Formula 1, the following procedure is carried out: The compound of formula 〇

〇

VI I ： Person-installation-order line (please read the precautions on the back before filling in this page) 30- This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs system

A7 _B7 V. Description of the invention (π) where X, Y, Ri and only 2 are as defined above. Hydroxylamine or its reaction such as hydrocyanide. This reaction is beneficial to use pyridine or formazan as the solvent, between -201C and + 80¾, or at the boiling point of formazan, preferably between Ot: to 5 Ot, if you use methanol, you must use _, for example with _ (Metal master salt, such as potassium silicate, tertiary amine, such as triethylamine or diazabicyclononane, pyridine or silver vapor. The ketone of formula VI is prepared in a manner similar to that described in (B). Formula VI and its preparation method are described in, for example, EP-3 7-6 2 9, EP-5 0 6 14 9, EP-403 618, EP-414 513, EP-463 488, EP-472 300, EP-4 6 0 5 7 5, W0-9 2/184 94 and other publications. (E) In order to prepare A, X, Y and Y in formula I! ^^ — R3 is as defined in formula I, but R3 is not hydrogen Compounds, perform the following procedure, for example

&quot; A \ d VII N R3 where A, X, Y and ^ _R3 are as defined above, and methylation test _ such as methyl acetate, dimethyl sulfate or dicyanomethane reaction. This reaction is favorable -31- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 丨; ------ {— 装 ------ 定 ----- {线 (PLEASE Read the precautions on the back before filling in this page) S〇486〇A7 B7 i. The description of the invention (“) is carried out in the presence of sulfonic acid or hydrogenated pins in a suitable solution and a suitable reaction degree (for example HS Ankerund HT Clarke; Organi Synthesis, Coll. 3, 172). (F) In order to prepare compounds of formula I where A, X, Y and Ri_R3 define the same formula I, it is advantageous to carry out the following procedure:

A vm Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy where A, Y and Ri _R3 are defined as above. In the presence of sickle, a method similar to that described in EP-A-178 826 is used to react with formate, or with nitrous acid Carry out a nitration reaction, or use a method similar to that described in EP-A-254 426 and a nitrile reaction in the presence of saltiness. Another possible way to synthesize the compound of formula VII is the following trans * compound of formula 0

A

IX IJ ------- ί I installed ------ order ----- f line (please read the precautions on the back before filling in this page) 32- This paper size is applicable to China National Standards (CNS ) A4 specification (210X297 mm) A7 B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of invention (Μ) Among which A, Y and Rt up to only 3 are defined as above, similar to EP-A-178 8 2 6 What is the method described with trimethylphosphine? Reaction, or using a method similar to that described in EP-A-2 54 4 2 6 with gas monomethylhydroxylamine (or its salt). The invention also provides novel compounds of formula VI I, VI I I and IX. It has been found that compounds of formula I possess microbicidal properties for controlling plant-providing pathogenic microorganisms, especially Anhui, which is also the most in line with actual needs. The compound has very favorable therapeutic, preventive and, in general, general properties, and can be used to protect a large number of agricultural plants. Using the active ingredients of formula I, all kinds of sandalwood found in crops of useful plants or some plants (fruits, flowers, leaves, stems, nodules, roots) can be broken through the soil, and can even be processed in the absence of plants. The pathogenic part of the plant formed later in the biological time. The compound of formula I can be further used as a seed dressing test for the treatment of seeds (fruit, nodules, seeds) and seedling plants that are protected from the infection of the Anhui strain and resistant to the pathogenic microorganisms of soil plants. Compounds of formula I are active against the following plant pathogenic emblems, such as partridge inperfecti (especially H. punctatus, also including Pyricularia, Helninthosporiun, Clostridium spp., S eptoria, dermatoglyphics, Cercosporella and Alternaria); 03 genus (eg, Rhizobium, Henileia, Puccinia); sac smelling (eg Venturis and

Erysiphe, Podosphaera, Beaded Hair Uncinula); 0〇Bycetes (-33- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 丨: ------ 'I installed ---- --Subscribe ----- ^ Line (please read the precautions on the back before filling in this page) A7 B7 printed by the consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (β) For example Phytophthora, Peronospora, Breia , Py thiu ·, Plasoopara) 〇The compound of formula I is also a useful active ingredient against Kun Dian and Chi Yan often appear in useful plants and agriculture and garden decoration, especially in rice, persimmon, vegetables and fruits, and forests, At the same time, warm-blooded varieties, fish and plants have better compatibility. The compound of formula I is suitable for controlling Kunxin, cereals, fruits and vegetables, especially Kunding, which can control soil-breaking plants. . Other fields in which the active ingredients of the present invention can be applied are the protection of key-stored goods and materials, as well as the field of health-care plaques, except for the protection of domestic animals and production of live animals. Compounds of formula I are generally sensitive but also resistant to all stages or stages of growth. Its active activity may become apparent, for example, breaking the soil immediately or only after a certain period of time (for example, during the metamorphosis period), harming the borer, or reducing the rate of spawning and / or hatching. Examples of the above-mentioned pests are from Lepidoptera, such as leaf moth reeds, small leaf moth reeds, winged moth deer, ground tiger reeds, Alabama argillaceae, aaylois genus, Trichosperma spp., Leaf moth articles, seed medicine羼, 繼 夜 娥, busseola, powder spotted locust, leaf moth genus, chiloJR, leaf leaf worm moth, grape fruit stupid moth, snail moth roll, leaf moth JR, cochylisJK, sheath moth roll, crocidoloDia binotalis, Cryptophe lebia leucotreta, Cyd ia Genus, corn borer · Diparops is castanea, Associated purple chrysanthemum, locust moth moth, yellow moth. Eupoecilia aabiguella. Tea genus, cut root root moth, small roll moth, suspected small roll moth, ringworm grub Kei, cabbage borer, Meipu white moth, tomato stupid, spiny moth latent moth, fine moth reed, pharmacopoeia, poisonous beetle, -34- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) I; ------ Air-installed ------ Ordered ----- ^ line (please read the precautions on the back first and then fill in this page) Printed 304860 A7 __B7___ by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the Invention (θ) ®ll mothweed, Tianmu Maodiange, Spodoptera exigua, tobacco hawkmoth Inchworms, corn borers, sawdust beetles, leafworm moths, leafworm moths, red chrysanthemum, horse # potato tuber moth, cabbage butterfly, diamondback moth, diamondback moth, mothworm, white borer, noctuid , Coprinus spp., Eriocheirium spp., And Yange 羼; Coleoptera moth bees, such as percussion yang, weevil, stick niche, beet tibia, world jellyfish, weevil stalk, skin stupid 羼, Cucurbita repens, Yan Yan, Qian'e Yi, Potato Jiaxin, Weevil, Sichatou, Tail Bee, Weevil, Little Stupid, Lachatina, Lepidoptera, Genmous, Scarab , Gu Xiang Ke, wheat moth genus, pink genus, Pseudospirulina genus, and Dermatoglyphus; Orthoptera, such as non-Cockroaches, cockroach, 蠼 辄 羼, Madeira Cna • Feihuang, Periplaneta and fried cockroaches; Isoptera, such as termite knots; Oh, insects, such as the genus Pseudomonas spp; lice eyes, such as the genus Haeaatopinus and the long jaw lice, polyphasic knot, Aphis gossypii, and Rhizobium aphid; Trituroptera, such as Daaelinea hurricane and feather louse; Thysanoptera, such as Thrips, Thrips, Thrips, Thrips, Thrips and Thrips; Heterowing For example, the leaf beetle, Distant ie 1 la theobroia, Red Spring Show, Eustusus, Dunchun JR, Spring Recording, Spring Recording JK, Spring Spring, R h 〇dnius Tall, S ah 1 berge 11 asingu 1 aris , Dao Chun Yi and Lu Chun Yi; Homoptera, such as cotton whitefly, whitefly, stag beetle, aphididae, aphid-35- This paper scale is applicable to China National Standard (CNS) A4 specifications (2 丨0X297mm) 丨: ------ <I installed ------ ordered ----- f line (please read the precautions on the back and then fill out this page) Staff of the Central Bureau of the Ministry of Economic Affairs A7 B7 printed by consumer cooperatives V. Description of invention (3. ) 羼, (coccidioides, Paleididae, Pseudococcidae, Pseudococcinea spp., Pterocarya spp., Pseudococcidae, Leafhopper, Phyllostachys aegypti, Spotted hopper, GascardU spp., Plant genus, Pseudococcidae, Burmese coccinea, long-tube aphids, tuft-fronted aphid, echidium, ricehopper, genus Cerambycidae, continuous cotton aphids, mealybugs, white scaleworms, mealybugs, wood louse, peach cotton scales , Coccinella spp., Ytterbium aphid, Helmetidae, Leaf beetle, Aphid spp., Syrup Xingong, Greenhouse powdery mildew, Psyllium, and Orange shield scale; Hymenoptera, such as leaf wasps, Attas羼, wheat stalk bee, sawhorn medicine bee horn, saw horn bee, leaf bee horn, field ant gui, kitchen ants, saw horned minnow, fire ant genus and wasp larvae; diptera, such as Aedes Kei, Anther igona soccata, Mosquito mosquito, Red-headed lizard, Pterocephalus spp., Coccinella spp., Cucurbita ruficollis, Nematode falcon, Rope reed, Chimpanzee Drosophila, Both flies, Erythris spp., Glossa , Leather skin, weevil, latent genus, green genus, latent genus, Musca domestica JR, # 蠼 骅, horn aphid, wheat flies, beet leaf larvae, flea genus, apple flies, yam Mosquito, sting fly, gadfly, night cicada and Mosquito hurricanes; Flea-orders, such as leaf flea and Diptera, such as Western fishes; Tick-eyes, such as thick-footed powder, budding buds, apple spines, flowering worms, beaks Tick, calf tick, hurricane, moss covered, Calipitriaecus spp., Itch full JH, miscellaneous skin full, chicken ear leached oriental medicine spp., Yuanmou JK, Hyaloaia spp., Hard genus. 0 lygonycbus pratensis, 嗛 姆 JR. Red Claw 81, P hy 11 ocoptruta oleivora, Inverted multi-eating squirrel, Manchuria, Fan tick Tick JK, Root Manchu-3-3 * This paper size is applicable to China National Standard (CNS) A4 specification (210X297 gong mai) 丨 一 ------ / 丨 installation ------ order ----- f line (please read the precautions on the back first and then fill out this page) Central Ministry of Economic Affairs Printed by Jubei Consumer Cooperatives * A7 __B7 V. Description of the invention (3> 丨), Shimangong, Fuxianmang and Yaomang. Typical crops suitable as targets are, in particular, cereals such as wheat and barley , Rye, oats, rice, corn or sorghum * beets such as beets or forage beets; fruits such as pears, stone fruits and soft fruits such as apples, pears, Plums, peaches, almonds, cherry blossoms or berries, such as strawberries, raspberries, or blackberries; legumes such as beans, sargasso, peas, or soybeans; oil crops, such as rapeseed, mustard, poppy, olive, Xiangri, Coconut, castor oil, cocoa, or peanuts; cucurbits, such as pumpkin, courgette, or watermelon; fibrous plants, such as cotton, flax, hemp, or jute; citrus plants, such as orange, lime birch, konjac, or tangerine ; Vegetables, such as spinach, lettuce, reeds, cabbage, cabbage, rice, fanga, mala, or pepper; Lauraceae, such as pear, cinnamon, or camphor; and tobacco, pits, kana, eggplant, Sugar cane, tea, pepper, grapes, hops, milkweed plants and suspicion plants. The compositional activity of the I compound includes the ability to be substantially expanded by the addition of other niche and / or tsutsugamushi and to be used in a variety of fields. Suitable additions represent the following types of active ingredients: organophosphorus compounds, nitrophenols and their derivatives, formazan, urea, carbamate, pyrethrum, cyanogenated hydrocarbons and ilthuringiensis preparations. Conventionally, the active ingredient of formula I is used as a composition, and it can be applied to a certain field or plant together with other active ingredients in the same or intermittent form. These other active ingredients may include fertilizers, trace elements, or other preparations that affect the growth of sickle plants. Interesting demixing agents and antidote agents, antimicrobial agents, fungicides, thread killing agents, soft killing animal thinners or a mixture of these preparations-37- This paper scale is applicable to China National Standards (CNS) A4 specifications (210X297mm) &quot; 丨 ^ {I installed ------ ordered ----- f line (please read the precautions on the back before filling this page) ^ 〇486〇a7 B7 5. Description of the invention (Si) compound, may or may not contain other formulation techniques "Fu Tong Zai Qiang, interface activity_ or other enhancement effect additives. Carriers and additives for shoveling can be solid or liquid. They are commonly used in this formulation technique, such as natural or regenerated minerals, dissolving, dispersing, wetting, and thickening bonding_ or fertilizers. The following are suitable solvents: aromatic hydrocarbons, preferably C8 to ^ 2, such as xylene mixtures or substituted Lei, peptidic acid, such as dibutyl peptidate or dioctyl phthalate, fatty strips , Such as hexane or paraffin, enzymes and second enzymes and their esters, such as ethyl fermentation, ethane fermentation, ethane monomethyl ether or ethyl ether, ketones, such as cyclohexyl, strong polar solvents For example, N-methyl-2-pyrrolidone, dimethyl sulfoxide or dimethylformamide, and unvaporized or cyclized vegetable oils, such as coconut gas or soybean oil; or water. Commonly used as a solid carrier for ash and dispersible powders are, for example, ground natural rocks such as calcite, talc, kaolin, montmorillonite or attapuUite. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back first (Fill in this page again) The other beneficial enhancement additives that can greatly reduce the response rate are natural (animal or plant) or synthetic phospholipids (from the list of brain phospholipids and lecithins), which can be obtained from, for example, soybeans. Depending on the nature of the active ingredient of formula I, a suitable interface activity «[compounds are non-male,» male and / or anionic interface active, which has excellent emulsification, dispersibility and grade properties. This understanding is Interfacial active thread also represents interfacial active_mixture. -38- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). The A7 B7 is printed by the Consumer Labor Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs. ) Appropriate interfacial activity of yin and yin can be called water-soluble salts, but also can be called water-soluble synthetic interface-active compounds. Soap is Jin Yi salt, alkaline earth gold exhibition Salts or ammonium salts of substituted or unsubstituted high-number fatty acids (Ci 〇-C2 2), such as noodles or potassium * of oleic acid or stearic acid, or sodium salts or salts of natural fatty acid mixtures, which can be obtained from For example, coconut oil or tall oil. Mention may also be made of fatty acid methyl taurine. Suitable non-ionic surface active agents are mainly fatty strips or fatty acids, saturated or unsaturated fatty acids and alkyl groups. Phenol polydioxygenate derivatives, whose (fatty strips) free radicals may contain 3 to 30 bowel dioxygenate groups and 8 to 20 «sulfon atoms and alkyl phenol alkyl radicals contain 6 to 18 sickle atoms The examples of non-ionic interfacial activity include nonylphenol polyethylene glycol yeast, castor oil polyethylene glycol ether, polyoxygenated propylene / polyoxygenated ethylene adduct, tributylbenzene polyoxyethylene Acetate, polyoxirane and octylbenzene gas-based polyethylenyl acetate. Other suitable substances are fatty acids of polyoxyethylene sorbitan, such as polyoxyethylene sorbitan trioleate. __ The sub-interface activity is mainly quaternary ammonium, which contains at least one alkyl radical of 8 to 22 sulfon atoms as a substituent, which Possesses a low-yielding or free mandrel, benzyl or lower hydroxyalkyl radical as a further substituent. The》 is preferably in the form of a halide, methyl sulfate or ethyl sulfate, such as stearin Ammonium trimethylammonium cyanide or benzyl bis (2-aminoethyl) ammonium bromide. -39- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 丨: ----- -丨 installed ------ order ----- ^ line (please read the notes on the back before filling in this page) A7 _ B7 printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs For example, the agrochemical preparation includes 0.1 to 99%, especially 0.1 to 95% of the active ingredient of formula I. 99.9% to 1%, especially 99.9 to 5% solid or liquid added Use 0 to 25% and wait for 0.1 to 25% interface active rain. Although it is preferable to use a dense composition for a commercial product, a terminal de-energizer may routinely use a diluted composition. The composition may also include other additives, such as diazepam, defoaming agents, viscosity modifiers, binders, tackifiers, fertilizers or other active ingredients for special purposes. Formulations, i.e. compositions, split preparations or mixtures, which include the active ingredients of formula I and with or without solid alcohol or liquid additives, are prepared by conventional methods, such as mixing and / or grinding active ingredients and extensions », For example, solvents (mixtures), solid carriers, and, suitably, interface-active compounds (interactive agents). A preferred method in the field of protecting crops is on plant bushes (leaf applications), the frequency and rate of which depend on the degree of danger of contamination by special hazards. However, the active ingredient can also reach the plant via the root system (systemic action), which is like applying the liquid composition to moisten the plant location or adding the active ingredient in the form of solid brewing to the plant location, such as adding it to the soil, such as Granular form (soil application). For rice, such particles can be metered into a paddy field full of water. Alternatively, the compound of formula I can be applied to the seed stone fruit (coating) by dipping stone fruit in the liquid strontium composition or by coating with a solid composition. In principle, the use of the compound of formula I can protect any type -4 0- This &amp; Zhang scale applies the Chinese national standard (€ Can) 84 specifications (210 father 297 mm) IJ ------- ί I equipment ------ order ----- line (please read the precautions on the back before filling in this page) Α7 Β7 Fifth, the invention description (κ) plant propagation material. The compound of formula I is used as a pure active ingredient or preferably together with auxiliary additives commonly used in this art formula, and then processed in a known manner to obtain, for example, emulsifiable concentrates, directly sprayable or dilutable solutions, diluted emulsions , Wettable powder, soluble powder, dust and granules, there are also capsules containing polymer. Application methods include spraying, spraying, powdering, dispersing or pouring, and the composition are all formulated to meet the purpose and general requirements. A preferred application rate is 1 g to 2 kg of active ingredient / europium, 25 g to 800 g of active ingredient / mu, and 50 g to 40 g of active ingredient / mu. As a seed dressing product, the dosage per kilogram of seed is preferably from 0.001 g to 1.0 g of active ingredient. The following examples are intended to explain the present invention in more detail, and do not limit the present invention in any way. Preparation Example Ben Example Η _ 1: Preparation of IJ ------ 成-装 ------ 訂 ----- {'line (please read the precautions on the back before filling in this page) Printed by the Bureau of Standards and Staff Consumer Cooperative

-4 1- This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X297mm) Β7. Description of the invention (4) 1. 32g of hydroxylamine hydrochloride is added to 5.2g of 3-methoxyl 2 — 〔([3_Amino-2-butyl) imino] amino) o-tolyl] methacrylic acid acrylate (EP-A-3 7 0 6 2 9, Ho. 156) in 20 ml of pyridine In the formed solution. After stirring the mixture at 30 ° C 8I for 6 hours, ice water was added, and the crystal cake 8 formed after several hours was filtered, and the crystal was washed with water. Recrystallized with ethyl yeast / water to obtain 4.8 g of yellow crystals of 3-methan-2--[([3-hydroxylidylene- 2_butyl) imino] oxy) o-tolyl] propene _Formaldehyde (^ 〇.1.73 compound), melted from 1 0 4 to 1 0 7 &quot; C. Example Η 2 Preparation Η Χ '〇

CF, (please read the precautions on the back before filling out this page) Printed in a KK force tube by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, 5 ml of dimethyl methyl sugar is added to 0.2 g of about 65% hydrogenated The nano-suspension was washed with hexane. Then, add 1.6 g of 3-methylamino-2-([([3-pyridylimino-2-butyl) imino] amino) -o-tolyl] acrylic acid methyl ester and 1 g of 2, 2 -42- This paper scale is applicable to the Chinese National Standard (CNS) Α4 ^ 8 · (210X297 Gong ®) A7 B7_5 printed by the Consumers Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs. Invention Instructions (Qiao) • 2 ~ Trifluoroethyl Iodide. When the radon gas is no longer generated, close the housing tube • At 50, it will stir the mixture for 5 hours. Then • Pour the mole solution into ice water and extract with ethyl acetate. The product was analyzed on silica gel with ethyl acetate / hexane (1: 3>) as an eluent. Chromatography was performed to obtain 1.2 g Colorless oil of 3-methylamino-2-([([(3-2, 2, 2 trifluoroethoxyimino--2-butyl) imino] amino] o-tolyl) acrylic acid Methyl ester (Ho. 1.74 compound). 1H NMR (CDCls): Two but imino substituted methyl shift chemical shifts: 1.99 and 2. 04ppm. Example Η-3 Preparation (please read the notes on the back before filling in (This page)

15. The dissolution of 0 g of copper p-methyl propofol and 20 ml of II amyl nitrite S in 30 ml of formazan was added slowly by dropwise addition of 20 ml of sodium methylate (30%, In the enzyme). Stir the mixture for 5 hours-43- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 X297mm) --- I --.-- ^ ------ ^ I installed ----- -Subscribe ----- J. A7 B7 printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. After the description of the invention (^), add 30 ml of water drop by drop, and then acidify the mixture with acetic acid. The mixture was extracted with ethyl acetate, the extract was washed with water, dried with sodium sulfate, and concentrated in vacuo. The residue was recrystallized from diethyl ether / n-hexane to obtain colorless crystals of α-hydroxyimino-4-methylpropanol. The melting point was 1 22 to 1 24. 8. 1 g of the previously prepared compound and 4. 6 g of o-methylhydroxylamine in 40 ml of pyridine were refluxed for 1 hour. After the addition of toluene, the mixture was encapsulated in vacuum and extracted with ethyl acetate in water. Rinse the organic phase with water, dry it on europium sulfate, and entangle it in the smelly air. Recrystallized with diethyl ether / n-hexane to obtain colorless crystals of α-hydroxyimino-4-methylpropanone-gas monomethyloxime, melting point 156 to 157C 0 1.87 g And 2. 58 g of 2- (ot-bromo-o-tolyl) -3-methyl methyl acrylate was added to 0.4 1 g of hydrogenated pin in 25 ml of N, N-dimethylmethyl blue amine The resulting suspension was stirred for 3 hours. It is then acidified with acetic acid, treated with water, and taken with B_B_C. Rinse the shaved phase twice with a planer and sodium bicarbonate, and once with a saturated chlorinated pin solution. After drying with anhydrous sulfuric acid, the solvent was removed in vacuo. The H-3 compound crystallized from diethyl_ / n-hexane as a colorless crystal has a melting point of 98 to 101 t: (No. 1.117 compound). Example Η — 4 Preparation-4 4 _ (please read the precautions on the back before filling in this page)-installed. 4 ° line. The paper size is applicable to China National Standard (CNS) Α4 specification (210X297mm) 304C6C at _____B7 2. Description of Invention (W)

Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 0. 37 grams of approximately 65% hydrogenated «suspension was rinsed with hexane. Add 10 ml of dimethylformamide. Add a mixture of 2.59 grams of 2- (2-O-methylphenyl) diglycolic acid monomethyl oxime and 2.42 grams of 2- (diphenylhydrazine)-3-hydroxyiminebutane to this float In the next step, use a hot air blast furnace to heat the mixture to 40 to 50t! Until the hydrogen is generated. Then mix the mixture for 1 hour under the exclusion of Shanghai gas and pour into ice water. Extracted with ethyl acetate, on silica gel with ethyl acetate / hexane (1: 2) as an extraction solution for color analysis, to obtain 3.7 grams of yellow oil 2-((((3-diphenyl Group M-2-butyl-imino] amino] o-tolyl] dihydroxyacetic acid methyl ester gas monomethyl oxime (No. 2. 19 compound). 1 Η NMR (CDC 1 3): The chemical shifts of the two crane imino substituted methyl groups: 1. 64 and 2. 12 ppm. Example Η — 5 Preparation -45- (please read the precautions on the back side and then fill out this page) The scale is applicable to China National Standard (CNS) Α4 specification (210Χ297mm) A7 B7 5. Description of invention (μ)

1. 9 grams of 2-[({(3-diphenylhydrazine-2-butyl) imino} amino] o-tolyl) methyl dihydroxyacetate gas monomethyloxime at room temperature Stir for 2 hours in 10 «L of 33% methylamine solution (in ethyl fermentation). Evaporation of ethyl yeast and encountering methylamine, absorption of the residue with diethyl yeast, filtration of the solution, and evaporation of the filtrate, the product is still crystalline solid. Rinse with hexane to prepare 1.8 g of 2-[((([3-diphenylhydrazine-2-butyl) -imino} amino] o-tolylyl] o-tolylyl] dihydroxyamide) N-methyl gas monomethyl oxime (No. 3.19 compound), the melting point is 1 3 5-1 3 6 Ό 0 Example Η — 6 Preparation I: (I binding f line (please read the notes on the back before filling in This page) Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

_ 4 6 _ This paper scale adopts Chinese National Standard (CNS) A4 specification (210 X 297 mm) A7 ____B7 V. Description of the invention (called) 1. 74 grams (AA) of 1 one [4 one (2 · 2-Dyanocyanopropylmethanyl) phenyl] propane-1,4-dione 1- (gas-methyloxime) -2-oxime was added with 0.13 g of hydrogenated ((in 25 ml of N, N — Dimethyl methyl Samine) · Then add 1.5 g of formula (BB) of 2- (2-bromomethylphenyl)-3-methyl methyl acrylate · The mixture was stirred for 3 hours in the crude room . This mixture was acidified with acetic acid, and water and ethyl acetate were added. Separate the aqueous phase, rinse the organic matter once with saturated sodium bicarbonate, and dry over anhydrous sodium sulfate. The solvent was evaporated in vacuo, and the resulting residue was purified on silica gel with hexane / ethyl acetate (3: 1). The title compound was obtained as an oil, which was separated by chromatography on silica gel (hexane / ethyl acetate solution 3: 1) to obtain three isomers · isomer A, melting point 86-88P · iso Bilder B: oil, isomer C (No. 5.9 compound). (Please read the precautions on the back before filling out this page) Binding · Order Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) A7 B7 5. Invention description (#) The following compounds can be prepared in a similar manner to the above method: (Compiled: Me is methyl, Et is ethyl. △ is propyl group, Ph is phenyl group, mp is box viscosity) NMR: chemical shift is S (PPm) (in CDCI3) Table 7J \ 〇1 n ^ i nn ^^^^ 1 Β ^ ϋΒ fem- mV nn HI n ^ i-, ml •. ^ I ^ (Please read the precautions on the back before filling in this page) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 48 This paper standard is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 Mm) J04860 V. Description of invention (w Table 1 A7 B7

H, C

A r3 Examples of du printing of consumer cooperation in the Central Bureau of Standards of the Ministry of Economy AR i Rz 83 or nr3 R4 No. 1.1 NMe Me He 6-CF3 -2-at pyridyl 1.2 NHe H Me 6-CF3 -2-llt pyridyl 1. 3 NMe Me △ 6-CF3 -2-pyridyl 1.4 NMe Me H phenyl 1.5 NHe Me Me phenyl 1.6 NMe Δ Me phenyl 1.7 NNe Me Me 4-CF3 -2-¾ pyridyl 1.8 NMe H Me 4-CF3 -2-¾ Pyridinyl 1.9 NMe △ △ Phenyl 1.10 NMe Me Me 5- CF3 -2-Itt Fatigue Physical Data -49 »* .17 / 2.1 2.09 / 2.1 .p 100t 2.17 / 2.18 I ^ ('I binding Line (please read the precautions on the back before filling in this page) This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X29 * 7mm) V. Description of invention Uf) A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards 1.11 NNe H Me 5-CF3 -2-¾ pyridyl 1.12-H Me 4- (1, 2,4-trisyl) 1.13-NMe Me 4- (1, 2, 4-triazolyl) 161-163 ^ 1.14-Me △ 4- (1, 2,4-triazolyl) 1.15-Me △ 4-morpholinyl 1.16-Me Me 4-morpholinyl 113t: 1.17-H Me 4 -Oxolinyl 1.18 NPh «H Me Phenyl 1.19 NPh» Me Me Phenyl 1.74 /2.22 1.20 NPh # Me △ Phenyl 1.21 HPh # △ Me Phenyl 1.22 NMe Me Me 2-Nitrophenyl 1.93 / 2.06 1.23 MMe H Me 2-Nitrophenyl 1.24 0 Me Me Me 76-78¾ 1.25 0 H Me Me 1.97 / 7.68 1.26 0 △ Me Me 1.96 / 2.00 1.27 0 Me △ Me 6 0-6 2 ¾ 1.28 0 Me H Me 1.29 NHe H Me 3-CF3 -2-lft pyridyl 1.30 NMe Me Me 3-CF3- 2-pyridyl 2.06 / 2.18 1.31 NHe △ Me 3-CF3 -2-pyridyl 1.32 NMe △ Me 3-nitro-2-¾-pyridyl 1.33 NMe H Me 3-nitro-2-pyridyl-50-- ^ ------ {—install ------ order ----- line (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 Mm) V. Description of invention (W) A7 B7 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 1.34 NMe Me Me 3-nitro-2-pyridyl 1.94 / 2.26 1.35 NMe Me Me 2-CF3 -phenyl 1.85 / 2.10 1.36 NMe Me △ 2-CF3 -phenyl 1.37 NNe H He 2-CF3 -phenyl 1.38 NMe Me Me 3-CF3 -phenyl 1.39 NNe Me △ 3-CF3 -phenyl 1.40 NHe H Me 4-CF3 -benzene Base 1.41 NMe Me Me 4- CF3 -phenyl 1.42 NMe Me Me 2-chlorobenzene Base 1.73 / 2.13 1.43 NHe Me Me 3-chlorophenyl 2.12.2.17 1.44 NMe H He 4-aminophenyl 1.45 NNe He He 4-cyanophenyl 2.10 / 2.15 1.46 0 Me Me Phenyl 2.14 / 2.22 1.47 0 Me Δ Phenyl 1.48 0 Me Me Benzyl 1 0 6-1 0 8 10 1.49 0 Me Me Ht 1.92 / 1.95 1.50 0 H Me Et 1.51 0 △ Me Et 1.52 0 Me Δ Et 1.53 0 He H Et 1.54 0 H Me Methoxy Methylmethyl 1.55 0 Me He Methylmethyl 83-84 ^ 1.56 0 He Δ Methoxymethyl 51-; (—Install τ mouth ^ line (please read the precautions on the back before filling this page) This The paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297mm) 5. Description of the invention (ui) A7 B7 Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 1.57 0 △ Me Methylmethyl 1.58 0 Me He Methylmethyl 2.04 / 2.04 1.59 0 Me Me Methylmethyl 1.60 0 Me Me Radonyl 2.04 / 2.04 1.61-Δ Me Cyanomethyl 1.62-Me Me Azatriyl 1.63-Me Me Succinylalkyl 1 . 64 0 Me Me pyridinyl 1.65 0 H Me tertiary butyl 1.66 0 Me Me tertiary butyl 1.96 / 2.04 1.67 0 Me Me propargyl 114-115¾ 1.68 0 Δ Me propargyl 1.69 0 Me Δ propargyl 1.70 0 Me Me 2, 2-dichloropropenylmethyl 2.02 / 2.02 1.71 0 △ Me 2, 2-dichlorocyclopropylmethyl 1.72 0 Me Me Η 1.73 0 Me He Η 104-1071 1.74 0 Me Me CF3 CHz 1.99 / 2.04 1.75 0 Δ Me CF3 ch2 1.76 0 Me H CF3 CHz 1.77 0 Me H CF3 CHz CH2 -52- ^^^ 1 ^^ ^ 1 i nn mm ^ i ^^^ 1 ^^ 1 t ^ i ^ 1 ^ 1 r ^ n Hi I i ^^^ 1 1 ^^ 1 1 ^^ 1 I In-J. I m · 1 ^^ 1 ^^^ 1 ^ 1.-•. J Wu i-4 scale (please read the precautions on the back before filling in this page) This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) V. Invention Description (called) A7 B7 Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 1.78 0 Me Me cf3 ch2 ch2 1.79 0 Me Me CF3 CH2 CHz CHz 2.10 / 2.13 1.80 0 Δ Me cf3 ch2 ch2 ch2 1.81 0 NHe Me Me 94- 98¾ 1.82 0 NMe Δ Me 1.83 0 Me Me ch2 -cci = ch2 80¾ 1.84 0 △ He CHz -CC1 = CHZ 1.85 0 Me Me propyl 1.86 0 He Ne butyl 36- 38t: 1.87 0 Me Me hexyl 1.99 / 2.01 1.88 0 He Me Methoxycarbonylmethyl 90- 93 ¾ 1.89 0 H Me Methoxy Methylmethyl 1.90 0 Me Me 3-fluorobenzyl 2.00 / 2.04 1.91 0 Me Ne 4- 氱 benzyl 1.92 0 He Me 2-aminobenzyl 1.93 0 Me Me 2-CFs -benzyl 1.94 0 Me Me 3-CFs -Benzyl 56-58TC 1.95 0 Me Me 4-CF3 -benzyl 1.96 0 Me Me 3,4-diaminobenzyl 1.97 0 Me Ne 2, 4, 6-trimethylbenzyl 1.98 0 Me Me 4-amino- 2-nitrobenzyl 1.99 0 Me Me 3-methoxybenzyl 1.100 0 Me Me 2-phenylpropyl 1.97 / 2.02 -53- (please read the precautions on the back before filling this page) ---- -^ --'------ ^ I installed ------ ordered ---- .Line_ This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) V. Description of invention ( 4) A7 B7 Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 1.10 1 0 Me Me 3-phenylpropyl 1.102 0 Me Me 2- (4-nitrophenyl) ethyl 1.103 0 Me He 2- (2- CF3 -phenyl) ethyl 1.104 0 Me Me 2- (4-methylphenyl) ethyl 1.105 0 Me Me 2-hydrogen-6-flour benzyl 1.106 0 Me He 3, 4-methine digas Benzyl 1.107 0 He Me 2-aminobenzyl 1.108 0 He Me 2- (4-aminophenyl) ethyl 1.109 0 Me Me cyanopropylmethyl 2.01 / 2.01 1.110 0 Me Me 2- (1,3-dioxenyl) methyl 1.111 0 Me Me 2,2,3,3, -tetrafluoroisobutylmethyl 1.112 0 Me Me «-fluoroethylcarbonylcarbonylmethyl 1.113 0 Me 2-andronyl Me 2.06 / 2.10 2 .20 (E / Z) 1.114 0 Me 4-methyl Et 2.12 Phenyl-54- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 1 ^ 1 H — ^ ϋ nn ί t ^ —Λ ί ^^^ 1 ^^^ 1 ^^^ 1 ^ ϋ ^ ϋ I, il ^ i (nn. »S ^« .— ^ ¾., 1-4 ^ (Please read the precautions on the back before filling this page) V. Description of the invention (β) A7 B7 1.115 NMe Me 4-methyl He 2. 1〇 (isomeric phenyl 2.08 (isomeric 1.116 0 Me Me CHZ FCH2 50-5 It: 1.117 0 Me He 2- (4-¾olinyl) ethyl 1.99 / 2.01 1.118 0 Me Me Pyrrolyl 89-9 It: 1.119 0 Me He 2- (1-Reporter) ethyl 1.120 0 Me Me 2-fluorobenzyl 9 3- 9 6 ¾ 1.121 0 Me Me 4-fluorobenzyl 104-106¾ «» R 1 / Rz or R3. P. Or 1 H NMR b_IS. (Please read first (Notes on the back and then fill out this page) Pack.,-° Line Printed by the Central Standards Bureau of the Ministry of Economy-Industrial and Consumer Cooperatives -55- This paper size is suitable for Chinese countries Quasi (CNS) A4 size (210 X 297 mm) 304860 A7 B7 V. invention is described (&gt;) Table 2 N COOCH3

(Please read the precautions on the back before filling in this page) Printed example of AR i Rz R3 physical data or NR3 r4 number 2 1 NMe Me Me 6-CF3 -2 -at -pyridyl 2 . 2 NMe H Me 6-CF3 -2 -at pyridyl 2. 3 NMe Me △ 6-CF3 -2 -at pyridyl 2. 4 NMe Me H phenyl 2.5 NMe Me Me phenyl 87 -88¾ 2. 6 NMe Δ Me phenyl 2. 7 NMe Me Me 4-CF3 -2-¾ pyridyl 2. 8 NMe H Me 4-CF3 -2-¾ pyridyl 2. 9 NMe △ Δ phenyl 2. 10 NMe Me Me 5-CF3 -2 -Pyridyl-56- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) V. Description of the invention (Jr 丨) A7 B7 Printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 2.11 NMe H Me 5-CF 3-2 -pyridyl 2.12 — H Me 4- (1, 2,4-triazolyl) 2.13-NMe He 4- (1, 2, 4-triazolyl) 2.14-He Δ 4- (1, 2,4-triazolyl) 2.15-Me △ 4-morpholinyl 2.16-Me Me 4-oxolinyl 2.17-H He 4-morpholinyl 2.18 NPh # H Me benzene Base 2.19 HPh »Me Me phenyl 1.64 / 2.12 2.20 NPh »Me △ phenyl 2.21 NPh * Δ He phenyl 2.22 NMe Me Me 2-nitrophenyl 2.23 NMe H Me 2-nitrophenyl 2.24 0 Me Me Me 104-106¾ 2.25 0 H Me Me 2.26 0 △ He Me 1.92 / 1.97 2.27 0 Me △ Me 6 7- 7 0 ¾ 2.28 0 Me H Me 2.29 NMe H He 3-CF3 -2-ftt pyridyl 2.30 NMe Me Me 3-CF3 -2- Pyridinyl 2.31 NHe △ Me 3-CF3 -2-ltt pyridyl 2.32 NMe Δ Me 3-nitro-2-pyridyl 2.33 NMe H Me 3-codeyl- 2- lfii yl-57- —.I- ----- · (· I installed ------ ordered ----- ^ line (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification ( 210X297mm) A7 B7 V. Description of invention (j ^) DuPont Printing by Staff Consumption Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs 2.34 NNe Me Me 3-nitro-2-ftt pyridyl 2.35 NMe Me Me 2-CF3 -phenyl 2.36 NMe Me △ 2_CF3 -phenyl 2.37 ΝΗβ H Me 2-CF3 -phenyl 2.38 NMe He Me 3-CF3 -phenyl 2.39 NMe Me Δ 3-CF3 -phenyl 2.40 NNe H Me 4-CF 3 -phenyl 2.41 NMe Me He 4-CF3 -phenyl 2.42 NMe Me Me 2-chlorophenyl 81Ό 2.43 NMe Me Me 3 -chlorophenyl 2.10 / 2.13 2.44 NNe H Me 4-chlorophenyl 2.45 NMe Me Me 4-aminophenyl 2.08 / 2. 13 2.46 0 He Me phenyl 89-9 0Ό 2.47 0 Me Δ phenyl 2.48 0 Me Me benzyl 2.49 0 Me Me Et 2.50 0 H Me Et 2.51 0 Δ Me Et 2.52 0 He Δ Et 2.53 0 Me H Et 2.54 0 H Me Methylmethyl 2.55 0 Me Me Methoxymethyl 87 -88t: 2.56 0 Me △ Methoxymethyl-58- (please read the precautions on the back before filling in this page) ——Installation --- Order ----- {. The size of the paper in line is applicable to Chinese national standards (CNS) A4 specification (210X297 gongnai) 304860 A7 B7 V. Invention description) Printed by the Consumer Standardization Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 2.57 0 △ Me Methylmethyl 2.58 0 Me Me Ethylmethyl 2.59 0 Me Me Cyanomethyl 2.60 0 Me Me Methyl methyl 9 4-95 ¾ 2.61-Δ Me Trimethyl 2.62-Me Me Azalyl 2.63-He Me Piperidinyl 2.64 0 Me He Pyridinyl 2.65 0 H Me tertiary butyl 2.66 0 Me He tertiary butyl 1.93 / 2.02 2.67 0 Me Me propargyl 120-122¾ 2.68 0 △ Me propargyl 2.69 0 Me Δ propargyl 2.7 0 0 Me Me 2, 2-diaminopropylmethyl 1.99 / 1.99 2.71 0 Δ Me 2, 2-diaminopropylmethyl 2.72 0 He Me Η 2.73 0 Me Me Η 114-116¾ 2.74 0 Me Me CF3 CHz 52-53¾ 2.75 0 Δ Me CF3 CHz 2.76 0 He H cf3 ch2 2.77 0 Me H CF3 CH2 CHz -59- (Please read the precautions on the back before filling this page)-1 ^^^ 1--- I 1 ^ 1 — ^ n ^^^ 1 n ^ i ^^^ 1 ^^^ 1 111 1 、 一--1: ^ 1 ^ 1 In _ The size of the linear paper is in accordance with the Chinese National Standard (CNS) A4 specification ( 210X297 mm) A7 B7 V. Description of invention (#) Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 2.78 0 Me Me CF3 CHz CHz 2.79 0 Me Me cf3 ch2 ch2 ch2 86¾ 2.80 0 Δ Me CF3 CHz CHz CHz 2.81 0 NHe Me Me 80-enc 2.82 0 NMe △ He 2.83 0 Me He CHZ -CC1 = ch2 66Ό 2.84 0 △ Me CH2 -CC1 = CHZ 2.85 0 Me Me propyl 2.86 0 Me Me butyl 58- 6 2 TC 2.87 0 Me Me Hexyl 50- 5 3 ¾ 2.88 0 Me Me Methoxycarbonylmethyl 1.96 / 2.04 2.89 0 H Me Methoxycarbonylmethyl 2.90 0 Me Me 3-fluorobenzyl 2.91 0 Me Me 4-nitrobenzyl 2.92 0 Me Me 2-aminobenzyl 2. 93 0 Me He 2-CF3 -benzyl 2.94 0 He Me 3-CF3 -benzyl 87-88¾ 2.95 0 Me Me 4-CF3 -benzyl 2.96 0 Me Me 3,4-dihydroxybenzyl 2.97 0 Me Me 2 , 4,6-trimethylbenzyl 2.98 0 Me Me 4-cyano-2-nitrobenzyl 2.99 0 He Me 3-methoxybenzyl 2.100 0 Me Me 2-phenylpropyl-60- (please Read the precautions on the back first and then fill out this page) Binding ------ Order -----. The size of the line paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) V. Description of the invention (β) A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

2.101 0 Me Me 3-phenylpropyl 2.102 0 Me Me 2- (4-nitrophenyl) ethyl 2.103 0 Me Me 2- (2-CF3-phenyl) ethyl 2.104 0 Me Me 2- (4 -Methylphenyl) ethyl 2.105 0 Me Me 2-chloro-6-fluorobenzyl 2.106 0 He He 3,4 -methinedioxybenzyl 2.107 0 Me Me 2-cyanobenzyl 2.108 0 Me Me 2- (4-azaphenyl) ethyl 2.109 η Me Me Cyanopropylmethyl 1.98 / 1.98 2.110 0 Me Me 2- (1,3-dioxenyl) methyl 2.111 0 Me Me 2, 2 , 3, 3, -tetrafluorobutanyl methyl 2.112 0 Me Me Msstsf —J * -ΛΛ- yuj ot ethoxy * glass methyl 2.113 0 He 2-thipanyl Me 83-86 Ό 2.114 0 Me 4-methyl Base Et 9 4-9 6 TC Phenyl-61- This paper scale is applicable to China National Standard (CNS) Α4 specifications (210X 297mm) (please read the precautions on the back before filling this page) ----- ^ I installed ------ order ----- ^-^ A7 B7 V. Description of the invention (0) Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 2.115 NNe Me 4 -methyl Me Phenyl 2.116 0 Me Me CH2 FCHZ 6 2-6 3 TC 2.117 0 Me Me 2- (4-? Porphyrinyl) ethyl 1.97 / 1.99 2.118 0 Me He pyrrolyl 2.119 0 Me Me 2-U-Pyrrolidinyl) ethyl 2.120 0 Me He 2-fluorobenzyl 81-83¾ 2.121 0 Me Me 4-fluorobenzyl Base 116-118¾

.1 NMe Me Me 6-CF3 -2-[ft Dianji. 2 NMe H Me 6-CF3 -2-®i Dianji. 3 NNe Me Δ 6-CF3 τ 2-Ht deeryl. 4 NMe Me H Benzene Base. 5 NHe Me He phenyl. 6 NMe △ Me phenyl. 7 NHe Me He 4-CF3 -2-pyridyl. 8 NMe H Me 4-CF3 -2-pyridyl. 9 NMe Δ Δ phenyl-62 -(Please read the precautions on the back before filling out this page) v ^ f ^ i nn UK— mu n ^ i ml Bm n · — · ^^^^ 1 ί ^^^^ 1 sn ^ i ms,-f洚 i line paper size is applicable to China National Standards (CNS) A4 (210X297mm) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 304860 a? B7 V. Invention description (female η) 3.10 NMe Me He 5-CF3- 2-¾-Pyridyl 3.11 NMe H Me 5-CF3 -2-Bt Syndrome 3.12-H Me 4- (1,2, 4-triazolyl) 3.13-NMe Me 4- (1, 2,4- Triazolyl) 3.14-He △ 4- (1,2,4-triazolyl) 3.15-Me Δ 4-morpholinyl 3.16-He Me 4-_morpholinyl 3.17-H Me 4- Porphyrinyl 3.18 HPh * H Me Phenyl 3.19 NPh * Me Me Phenyl 135-136¾ 3.20 HPh * Me △ Phenyl 3.21 NPh * △ Me Phenyl 3.22 NMe Me Me 2-Nitrophenyl 3.23 NMe H Me 2- Phenyl 3.24 0 He Me Me 9 0-92 1C 3.25 0 H Me Me 1.97 / 7.68 3.26 0 Δ Me Me 1.94 / 1.95 3.27 0 Me Δ He 88- 9 0 t! 3.28 0 Me H Me 3.29 NMe H Me 3 -CF3 -2-pyridyl 3.30 NMe Me Me 3-CF3 -2-pyridyl 3.31 NMe △ Me 3-CF3 -2-pyridyl 3.32 NMe Δ Me 3-nitro-2-pyridyl _ 6 3 _; ^ -Install i (Please read the precautions on the back before filling in this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) V. Invention description (θ) A7 B7 Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Print 3.33 NMe H Me 3-nitro-2-¾-pyridyl 3.34 NMe Me Me 3-nitro-2-¾-pyridyl 3.35 NMe Me Me 2-CF3-phenyl 3.36 NMe Me △ 2-CF3-phenyl 3.37 NMe H Me 2-CF3 -phenyl 3.38 NMe He Me 3-C F3 -phenyl 3.39 NNe Me Δ 3-CFs _phenyl 3.40 NMe H He 4-CF3 -phenyl 3.41 NHe Me Me 4-CF3 -benzene Base 3.42 NMe Me Me 2-cyanophenyl 1.72 / 2.11 3.43 NHe Me He 3-aminophenyl 2.09 / 2.14 3.44 NHe H Me 4-gas phenyl 3.45 NMe Me Me 4-argylphenyl 2.08 / 2.13 3.46 0 Me He Phenyl 3.47 0 Me △ Phenyl 3.48 0 He Me Benzyl 3.49 0 Me He Et 3.50 0 H Me Et 3.51 0 △ Me Et 3.52 0 Me Δ Et 3.53 0 Me H Et 3.54 0 H Me Methylmethyl 3.55 0 Me Me Methylmethyl 2.00 /2.03 1 6 4 _ (Please read the precautions on the back before filling out this page) ^^^ 1 ^^^ 1 n ^ (^^^ 1 n ^ l HI n ^ — ^^^ 1 ^ 1 ^ 1 ^ ^^ 1 1 ^^ 1 1 ^^ 1 mj 'I ml ^ in n ^ i nn · ϋι ^ ϋ a V ^^^ 1 ml n ^ i fl ^ i This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210X297mm) V. Description of invention (silicon) A7 B7 Printed by the Employees ’Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 3.56 0 Me Δ Methylmethyl 3.57 0 △ He Methylmethyl 3.58 0 He Me Base 3.59 0 Me Me Aminomethyl 3.60 0 He Me Trimethyl 2.00 / 2.01 3.61-Δ Me Trimethyl 3.62-Me Me Azalyl 3.63-Me Me Dipyridyl 3.64 0 Me Me Pyridine Base 3.65 0 H He tertiary butyl 3.66 0 Me Me tertiary butyl 1.95 / 2.01 3.67 0 Me Me propargyl 114-115¾ 3.68 0 Δ He propargyl 3.69 0 Me Δ propargyl 3.70 0 Me Me 2, 2-Dichlorohydrazine 1.99 / 1.99 Propyl methyl 3.71 0 △ Me 2, 2-dichlorocyclopropylmethyl 3.72 0 Me Me Η 3.73 0 Me Me Η 3.74 0 Me Me CF3 CHz 94- 9 6 t: 3.75 0 △ Me CF3 CHz 3.76 0 Me H CF3 CHz -65 -(Please read the notes on the back before filling out this page) ^^^ 1 ^^^ 1 nn n ^ imn ^ — nn in ^ i 1 ^ 1 nn urn— nn ^^^ 1 ^ J. n ^^ i In ^^^ 1 &gt; ^ v. · &Gt; 3 ^ *.. ^ 0¾., \ = Tl-4 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 304860 V. Description of invention U. ) A7 B7 Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 3.77 0 Me H cf3 ch2 ch2 3.78 0 Me Me CF3 CHz CH2 3.79 0 Me Me cf3 ch2 ch2 ch2 3.80 0 Δ Me CF3 CHz CH2 CHz 3.81 0 NMe Me Me 90- 9 It: 3.82 0 NNe Δ He 3.83 0 Me Me CH2 -CC1 = CHz 1.97 / 2.02 3.84 0 △ Me CH2 -CC1 = CH2 3.85 0 Me He propyl 3.86 0 Me Me Butyl 9 1-92¾ 3.87 0 Me Me hexyl 84 -86 ¾ 3.88 0 Me Me Methoxycarbonylmethyl 1 2 7-1 2 9 t: 3.89 0 H He Methoxycarbonylmethyl 3.90 0 Me He 3-fluorobenzyl 3.91 0 Me Me 4-chlorobenzyl Base 3.92 0 Me He 2-aminobenzyl 3.93 0 Me Me 2-CF3 -benzyl 3.94 0 Me Me 3-CF3 -benzyl 1.96 / 2.00 3.95 0 Me Me 4-CF3 -benzyl 3.96 0 Me Me 3,4 -Dipropylbenzyl 3.97 0 Me Me 2, 4, 6-trimethylbenzyl 3.98 0 Me Me 4-chloro-2-nitrobenzyl 3.99 0 Me Me 3-methoxybenzyl-66- (please Read the precautions on the back first and then fill out this page)-· ------ ^ 丨 installed ------ ordered ----- The size of the line paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 Mm) Employee consumption of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative A7 B7 5. Description of the invention (έ 丨) 3.100 0 Me Me 2-phenylpropyl 3.101 0 He He 3-phenylpropyl 3.102 0 Me He 2- (4-nitrophenyl) ethyl 3.103 0 He Me 2- (2-CF3-phenyl) ethyl 3.104 0 Me Me 2- (4-methylphenyl) ethyl 3.105 0 Me Me 2-ambient-6-fluorobenzyl 3.106 0 Me Me 3 , 4-Methylenedioxybenzyl 3.107 0 Me Me 2- 気 benzyl 3.108 0 Me Me 2- (4-chlorophenyl) ethyl 3.109 0 Me Me propylpropylmethyl 2.00 / 2.00 3.110 0 Me Me 2- (1, 3-dioxenyl) methyl 3.111 0 Me Me 2, 2, 3, 3, -tetrafluorocyclobutylmethyl 3.112 0 Me Me α -fluoroethoxycarbonylmethyl 3.113 0 Me 2-Sialenyl Me 3.114 0 Me 4-methyl Et 1 0 3-1 04 ¾ -67- (please read the precautions on the back before filling this page) --- f '丨 install ------ Order ----- f 'line paper size is applicable to China National Standard (CNS) Α4 specification (210X297mm) A7 B7 5. Description of invention (h) Phenyl

3.115 NHe Me 4-methyl Me 9 5- 9 7 ^ phenyl 3.116 0 Me Me ch2 fch2 95-9 7 ¾ 3.117 0 Me Me 2- (4-morpholinyl) ethyl 1.98 / 2.06 3.118 0 Me He pyrrole Base 3.119 0 Me Me 2- (1-piperolidinyl) 1.96 / 1.98 ethyl 3.120 0 Me Me 2-fluorobenzyl 90-91 Ό 3.121 0 Me Me 4-cyanobenzyl 130-131¾ 窣 # R 1 / Rz or R3. P. Or 1 H NMR ------- · ------ ^ I loaded ------ ordered ----- ^-^ (please read the back of it first (Notes to fill out this page) Printed paper size of the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is printed in Chinese National Standard (CNS) A4 (210X297mm) ί. A7 B7

Example XYR i Z * n B or D Physical data number Xing "4.1 CH OMe Me-1 3-CF3 1 3 3-1 3 5 ¾ 4.2 CH ONe Me-1 4-gas 1 4 0-1 4 2 Ϊ: 4 . 3 CH OMe Ke-1 3-nitrogen 175- 177 ¾ 4.4 CH OMe Me-1 2-fluoro1 3 6- 1 3 7 * 0 4.5 CH OMe Me-1 4-methyl isomer 1. 98-l 〇nD isomer 2. Oil isomer 3. Oil 4.6 CH OMe Me 0 0 Methyl-104-106¾ 4.7 CH OMe Me-1 4-bromo 126-128¾ 4.8 CH OMe Me-1 4-gas 14 1- 144 t: 4.9 CH OMe Me-2 3-cyano-5-CF3 1 64-1 6 6 10 4.10 CH OHe Me-0 __ 141- 143υ _ 6 9 _ (please read the notes on the back before filling this page) Installation ·-·· This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) V. Description of invention Ut) A7 B7 Printed by the Employees Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs 4.11 CH OMe Me-1 2-A Radix 113-U5t: 4.12 CH OMe Me-1 3-bromo 176-178¾ 4.13 CH OMe Me-2 3,4-methylene 1 4 3- 1 4 5 ¾ Dioxo 4.14 CH OMe Me 0 0 allyl -7 7-80 t: (isomer 2.08 (isomer 2) 4.15 CH OMe SMe-1 4-methyl 2.08 (Isomer 1) 2. 11 (Isomer 2) 4.16 CH OMe E t-1 4-methyl 3.90 (Isomer 1) 3.97 (Isomer 2) 4.17 CH OMe Me-1 4-isobutyl Group-2.11 (isomer 1) 2.08 (isomer 2) 4.18 CH OMe Me 0 0 propenyl 2.06 / 2.11 (E / Z) 4.19 CH OMe He 0 0 2,2,2-trifluoro 2. 11 (isomer 1) ethyl 2.07 (isomer 2) 4.20 CH OMe Me 0 0 ethyl 9 3-95 C (isomer 2.06 (isomer 2) 4.21 CH OMe CN-1 4-methyl 98-133¾ (E / Z) 4.22 CH OMe CN-1 4-gas 106-108¾ 4.23 CH OMe CN-2 3,4-diamine 1 2 8- 1 3 0 t: 1 0 9-1111: (E / Z Z) 4.24 CH OMe CN 0 0 -CFs oil (E / Z) 4.25 CH OMe CN-1 3-CF3 -70- ^ 1 binding ^ line (please read the precautions on the back before filling this page) This paper size is applicable China National Standard (CNS) Α4 specification (210Χ297mm) A7 B7 V. Description of the invention U_r) Printed by the Ministry of Economic Affairs Central Bureau of Standards and Staff ’s Consumer Cooperatives 4.26 CH OHe CN-1 2-chloro 4.27 CH OMe CN-1 4-fluoro 4.28 CH OMe Me 0 0 Phenyl 112-U41C (isomer oil (isomer 2) 4.29 CH OHe Me 0 0 -CHZ CH = CClz 4 .30 CH OMe Me 0 0 ch2 ch = cf2 4.31 CH OMe Me 0 0 -CHz CH = CBrz 4.32 CH OMe Me 0 0 4-chloro-phenyl 4.33 CH OMe He 0 0 4-fluoro-phenyl 4.34 CH OHe Me s 0 phenyl 4.35 CH OMe Me ch2 0-0 phenyl isomer 1: resin isomer 2: resin 4.36 CH OHe Me CHe 0-1 phenyl oil 4.37 N ONe Me-1 3-CF3 4.38 N OMe Me -1 4-atmosphere 4.39 N OMe Me-1 3-cyano 4.40 N OMe Me-1 2- 觎 lll-112t: 4.41 Η OMe Me-1 4-methyl 101-103¾ 4.42 Ν OHe Me 0 0 4-methyl -1 0 4-1 0 6 ¾ 4.43 Ν OHe Me-1 4-bromo1 3 4- 1 3 6 Ό 4.44 Ν OMe Me-1 4-fluoro 4.45 Ν OHe Me-2 3-F-5-CF3 4.46 Ν OMe Me-0--71- (¾ Read the precautions on the back before filling out this page). Binding. Binding-The size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) V. Description of invention (0 ) A7 B7 Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs «/» 4.47 N OHe Me-1 2-methyl 1 05- 1 0 7 1C 4.48 N OMe Me-1 3-bromo 4.49 N OMe Me-2 3 , 4-Methylene Digas 4.50 N OMe Me 0 0 Allyl 74-7 6 10 4.51 N OMe SHe- 1 4-methyl 88-9η〇4.52 N OMe Et-1 4-methyl 4.53 N OMe Me-1 4-isobutyl- 4.54 N OMe Me 0 0 propylene-based oil 4.55 N OHe Me 0 0 2, 2, 2-trifluoroethyl 4.56 N OHe Me 0 0 ethyl oil 4.57 N OMe CN-1 4-methyl 4.58 N OMe CN-1 4-cyano 4.59 N OMe CN-2 3.4-dichloro 4.60 N OMe CN 0 0 -CFs 4.61 N OMe CN-1 3-CF3 4.62 N OMe CN-1 2-chloro 4.63 N OHe CN-1 4-fluoro 4.64 N OMe Ne 0 0 phenyl 4.65 N OMe Me 0 0 -ch2 ch = ci2 4.66 N OMe Me 0 0 ch2 ch = cf2 4.67 N OMe Me 0 0 -CH2 CH = CBr2 4.68 N OMe Me 0 0 4-gas-phenyl 4.69 N OMe Me 0 0 4-fluoro-phenyl-72- (please Read the notes on the back before filling out this page) ^^^^ 1 ^^^^ 1 ^^^^ 1 ^^ i · — · mV ^^^^ 1 1 ^^ 1 ^ in n · ^ — — — ^ n ^^ tmrm I 1 ml nn. ^ m ^^^^ 1 B1 I. · J, 17 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) V. Description of the invention (θ) A7 B7 Printed «··· 4.I071N N ONINe NeMeSCHz 0- Benkiji *» »4.72 N OHe Me OCHz -0 Phenyl》 4.73 N HHC Hs He-1 3-CF3 4.74 N NHCH3 Me-1 4- 氱 4.75 N NHCHa Me-1 3-atmosphere 4.76 N nhch3 Me-1 2-fluoro 2.11 4.77 N nhch3 Me-1 4-methyl 2.10 4.78 N NHCH3 Me 0 0 Methyl- 4.79 N NHCH3 Me 1 4-Bromo 2.09 4 .80 N NHCH3 Me-1 4-Feng 4.81 N nhch3 Ke-2 3-F-5-CF3 4.82 N nhch3 Me-0-4.83 N NHCHa Me- 1 2-methyl 2.05 4.84 N NHCH3 Me-1 3-bromo 4.85 N NHCH3 Me-2 3,4-methylenedioxy 4.86 N NHCH3 Me 0 0 allyl 118-120¾ 4.87 N NHCH3 SMe-1 4 -Methyl 2.06 4.88 N NHCH3 Et-1 4-methyl 4.89 N nhch3 Me-1 4-isobutyl- 4.90 N NHCH3 Me 0 0 propylene-based oil 4.91 N NHCH3 Me 0 0 2,2,2-trifluoroethylene基 -73- I ,, (I binding ^ line (please read the notes on the back before filling in this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 304860 V. Description of invention (“) A7 B7 Printed 4.92 N NHCH3 Me 0 0 ethyl oil 4.93 N NHCH3 CN-1 4-methyl 4.94 N NHCH3 CN-1 4-ammonia 4.95 N NHCH3 CN-1 3,4- Dichloro 4 .96 N NHCH3 CN 0 0 -cf3 4.97 N NHCH3 CN-1 3-CF3 4 .98 N NHCH3 CN-1 2- «4.99 N NHCH3 CN-1 4-fluoro 4.100 N NHCH3 Me 0 0 Phenyl 4.101 N NHCH3 Me 0 0 -CHZ & He 0 0 ch2 ch = 4.103 N NHCH3 Me 0 0 -CH2 CH = CBr2 4.104 N NHCH3 Me 0 0 4-chloro-phenyl 4.105 N NHCH3 Me 0 0 4-fluoro-phenyl 4.106 N NHCH3 Me s 0 phenyl 4.107 N NKCH3 Me -ch2 00 phenyl 4.108 N NHCH3 He 0CH2 0 phenyl * $ 窣 4.109 CH 0CH3 Me 0 0 n-propyl isomer 1: oil isomer 2: oil 4.110 CH 0CH3 Me 0 0 3, 3-dimethylpropenyl 107-110t: (isomer oil (isomer 2) 4.111 CH OCH3 Me 0 0 2-methyl-allyl-74- isomer 1: 9 7 -9 9 t: Isomer 2: Oil (please read the precautions on the back before filling this page) This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Invention description (6? ) Printed by the Employees ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 4.112 CH 0CH3 Me 0 0 3 -methyl-isomer 1: oleyl 4.13 CH 0 ch3 Me 0 0 allyl isomer 1: 7 4-7 6 1C 4.114 CH 0CH3 Me 0 0 C Base oil 4.115 CH NHCH3 Me 0 0 allyl 4.116 CH NHCH3 Me 0 0 propenyl 4.117 CH OCH3 Me 0CH2 -0 3-CF3 -phenyl isomer 1: 83-85¾ «« «Isomer 1: Resin 4.118 CH OCH3 Me 0 0 3-CF3 -phenyl isomer 1: 127-128 Isomer 2: oil 4.119 CH OCH3 Me OCHz -0 C6 Η 1 1 *** Isomer 1: oil isomer 2: Oil 4.120 CH OCH3 Me 0CH2 -0 Phenyl *** Isomer 1: Oil Isomer 2: Oil 4.121 CH OCH3 Me OCHz -0 4-F-Phenyl Isomer 1: Oil «« «Isomer 2: Oil 4.122 CH OCH3 Me s 0 CH3 Isomer 1: 119-121 Isomer 2: Resin 4.123 CH OCH3 Me -S〇2 -0 ch3 Isomer 1: Foam Isomer 2: Resin 4.124 CH OCH3 Me OCHz -0 Phenyl * (iv) Isomer 1: Oil isomer 2: Resin 4.125 CH OCH3 He OCHz -0 4-CF3 V -75- --- 7 ------ f Ί-- (Please Read the precautions on the back and then fill out this page), νβ &quot; This paper standard is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297mm) V. Description of invention (γ) A7 B7 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Control 4.126 CH 0CH3 He OCHz -0 4-bromo-phenyl * »* 4.127 CH 0CH3 Me OCHz -0 4-CH3 -phenyl *** 4.128 CH 0CH3 Me OCHz -0 4-0CH3 -phenyl *** 4.129 CH OCH3 Me 0CH2 -0 2-CF3 -phenyl *** 4.130 CH OCH3 Me OCHz -0 2-F-phenyl *** Isomer 1: oil isomer 2: oil 4.131 CH OCH3 Me 0CH2 -0 2 -C1-Phenyl * (4.132 CH OCH3 Me OCHz -0 2- Br-3f 16 *** 4.133 CH OCH3 Me OCH2 -0 3-F-phenyl Isomer 1: 111-112 Isomer 2: Oil 4.134 CH OCH3 Me OCH2 -0 3-C1-phenyl isomer 1: oil isomer 2: oil 4.135 CH OCH3 Me OCHz -0 3-bromo-phenyl isomer 1: resin isomer 2: Harz 4.136 Ν OCH3 Me 0CH2 -0 allyl 4.137 Ν OCH3 Me OCHz -0 3-CF3 -phenyl ** 4.138 Ν OCH3 Me OCHz -0 3-CF3 -phenyl *** 4.139 Ν OCH3 Me-1 2-CF3 Oil 4.140 Ν OCH3 Me-1 2-CH3 Isomer 1: 105-107 Isomer 2: Resin 4.141 Ν NHCH3 Me-1 2-CF3 Resin 4.142 Ν NHCH3 Me-1 2-CH3 Isomer 1: Oil Isomer Structure 2: Youyi 7 6 _ --7 ------ · installed-- (Please read the precautions on the back before filling in This page) C This paper uses Chinese National Standard (CNS) Α4 specifications (210Χ297mm)

, 1T wipe 304860 A7 B7 V. Description of invention (1) Printed by 4.43 CH 0CH3 CN -H oil 4.144 CH 0CH3 CN 0 0 CHs isomers 1: 1 36- 1 38 'isomers Compound 2: Resin 4.145 CH 0CH3 CN 0 1 4- t-butyl oil 4.146 CH 0CH3 CN 0 0 Phenyl oil 4.147 CH 〇CH3 Me 0 0 cf2 CHFz Isomer 1: 80-82¾ 4.148 CH 0CH3 Me 0 0 CF2 CHClz 4.149 CH 0CH3 Me 0 0 CFz CHBr2 4.150 CH 0CH3 Me 0 0 CF2 CHFCF3 4.151 CH 0CH3 NN 0 0 CFZ CHFz 4.152 CH 0CH3 Me 0 0 cf2 CHFCF3 4.153 N NHCH3 Me 0 0 CFz CHFz 4.154 N NHCH3 Me 0 0 cf2 CHFCF3 4.155 CH 0CH3 Me-1 4-ethyl isomer 1: oil isomer 2: oil 4.156 CH 0CH3 Me-1 4- t-butyl isomer 1: resin isomer 2: oil 4.157 CH 0CH3 Me- 1 4-CF3 isomer 1: Resin isomer 2: 101-102 4.158 CH 0CH3 Me 0CH2 -1 4-C1 -phenyl 4.159 CH ONe CN 0 0 phenyl 4.160 N OCH3 Me -S〇2 -0 Et Foam 4.161 N NHCH3 Me -S〇z 0 Et 141-143¾ -77- c (please read the back Please fill in this page if you need to.) 2 The paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm) ^^^ 1 n ^ i nn ml \, 1 ^ 1 · ^ ¾. Ve line A7 B7 5. Description of the invention (I 4 · 162 CH 0CH3 4 · 163 CH OCH3 4 * 164 CH OCHs 4 · 165 CH OCH3 4.166 CH OCH3 4. 167 CH OCH3 4 · 168 CH OCH3 4.169 CH OCH3 4 · 170 CH OCH3 Ministry of Economic Affairs Central Standards Bureau Printed by Beigong Consumer Cooperative

Me OCH2-0 SiNe3 Isomer 1: Resin Isomer 2: Oil Me 〇0 CF2 CHFC1 Isomer 1: 75- 7 6 ¾ Me 0 0 CF2 CHFBr Isomer 1: Resin Me 0 0 CFz CHFCFs Isomer Compound 1: 82-84 t: Me S 0 Et Isomer 1: Oil Isomer 2: Oil Me S 0 n- C3 H 7 Isomer 1: Oil Isomer 2: Oil Me SCH2-° 3 3 -C F3 -Phenyl Me S〇2 CHz 0 3-CFa -Phenyl BD Me SO2 CH2 1 3-C F2 -Phenyl 3-FI 1 Isomer 1: 112-11 . ”Represents that the compound has no substituent—z—B〇: R 1 / R 2 or R 3. P. Or 1 H HHR is C Η I 3, which is consistent with the table title structure. ** · &gt; Z 傈 使The structure # frame is located on the left of the structural element, and the substituent B is located on the right. For example, the substituent Z-B of compound 4.107 is a CH2 Ο-phenyl. ) (Please read the precautions on the back before filling out this page).

V γ -line 304860 V. Description of invention (Table 5 A7 B7 〇

〇

Η R7 Η Ή-: ----- called-installed-- (please read the precautions on the back before filling in this page) Printed example X Υ AR 1 Rs Re R7 P number printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5.1 CH 0CH3 NMe Me Me Cl Cl 1 5.2 CH 0CH3 NMe H He Cl Cl 1 5. 3 CH 0CH3 NMe Me Me FF 1 5.4 CH OCH3 NHe Ke Et FF 1 5.5 CH OCH3 NMe Me Me Br Br 1 5.6 CH OCH3 NPh Me Me Cl Cl 1 5.7 CH OCH3 NPh H Me Cl Cl 1 5.8 CH OCH3 NPh Me Et Cl Cl 1 5.9 CH OCH3 0 Me Me Cl Cl 1 5.10 CH OCH3 0 H Me Cl Cl 1 Isomer 1: 86-isomer 2: Resin isomer 3: Shushu I 79- set

V This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) V. Invention description (#) A7 B7 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5.11 CH 0CH3 0 Me Me FF 1 5.12 CH 0CH3 0 H Me FF 1 5.13 CH OCH3 0 Me HFF 1 5.14 CH OCH3 0 Me C3 H7 Cl Cl 1 5.15 CH 0CH3 0 Me △ Cl Cl 1 5.16 CH 0CH3 0 △ Me Cl Cl 1 5.17 CH OCH3 0 Me Δ Cl Cl 1 5.18 CH OCH3 0 Me Me Br Br 1 5.19 CH OCH3 0 H Me Br Br 1 5.20 CH OCH3 0 Me Me Cl Cl 2 5.21 CH OCH3 0 H He Cl Cl 2 5.22 CH OCH3 0 Me Me FF 2 5.23 N OCH3 NMe Me Me Cl Cl 1 5.24 N OCH3 NNe H Me Cl Cl 1 5.25 N OCH3 NHe Me He FF 1 5.26 N OCH3 NMe Me Et FF 1 5.27 N OCH3 NHe Me Br Br 1 5.28 N OCH3 NPh He Me Cl Cl 1 5.29 N OCH3 NPh H Me Cl Cl 1 5.30 N OCH3 NPh Me Et Cl Cl 1 5.31 N OCH3 0 Me Me Cl Cl 1 5.32 N OCH3 0 H Me Cl Cl 1 5.33 N OCH3 0 Me Me FF 1 -80- ^ Binding (Therefore (please read the back of the first (Notes and then fill out this page) This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 Ο X 297mm) V. Explain clearly (ie 0 A7 B7 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 5.34 Ν OCH3 0 H Me FF 1 5.35 Ν 0CH3 0 He HFF 1 5.36 Ν OCH3 0 Me c3 H7 Cl Cl 1 5.37 Ν OCH3 0 Me Δ Cl Cl 1 5.38 Ν 0CH3 0 Δ Me Cl Cl 1 5.39 Ν OCH3 0 Me △ Cl Cl 1 5.40 Ν OCH3 0 Me Me Br Br 1 5.41 Ν OCH3 0 H Me Br Br 1 5.42 Ν OCH3 0 Me Me Cl Cl 2 5.43 Ν OCH3 0 H Me Cl Cl 2 5.44 Ν OCH3 0 Me Me FF 2 5.45 Ν NHCH3 NMe Me Me Cl Cl 1 5.46 Ν NHCH3 NNe H Me Cl Cl 1 5.47 Ν NHCH3 NMe Me Me FF 1 5.48 Ν NHCH3 NMe Me Et FF 1 5.49 Ν HHCH3 NMe Me Br Br 1 5.50 CH OCHs 0 Me Me HH 1 Isomer 1: Oil Isomer 2: Oil 5.51 Ν OCH3 0 Me Me Cl Cl 1 Isomer 1: Oil 5.52 Ν NHCH3 0 Me Me Cl Cl 1 137 -139 ^ 5.53 Ν HHCH3 0 Me Me Cl Cl 1 5.54 Ν NHCH3 0 H Me Cl Cl 1 5.55 Ν NHCH3 0 Me Me FF 1 -81- -------------- ^ -installed- ----- Subscribe ----- ^ -Line (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard (CNS) Α4 specification (210Χ297mm) Description of the invention (#) A7 B7 5.56 N NHCH3 0 Η Me FF 1 5.57 N NHCH3 0 Me KFF 1 5.58 N NHCH3 0 Me Me Cl Cl 2 5.59 N KHCH3 0 Η Me Cl Cl 2 5.60 N NHCHa 0 Me Me FF 2 and Compound 61

Isomer 1: 113-1151C / Isomer 2: Oil (please read the precautions on the back before filling this page) —------- ^ I 装 ------ 定 ---- -『'..It Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 〇6 2 h3c

Outer Z, CH3

Isomer 1: Oil / Isomer 2: Oil 82 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 304860 A7 B7 V. Description of Invention (Μ) Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs System

1 55-1 6 0 t: (Please read the notes on the back before filling this page)

^^^ 1 — ^ 1 ^^^ 1 n. ^ Ϋ I--II m 1 ^ 1 In-m I nn s I-、 一 (aJ- ^ 1. ^ 1 1—ii (. I This paper size Applicable to China National Standard (CNS) A4 specification (210X 297mm) V. Description of invention (β) .65 5.66 A7 B7

〇 H3C

Br Isomer 1: 109-1101 / Isomer 2: Resin

(Please read the notes on the back before filling this page)

^^ 1 —ii ^^ 1 I 8- II--I— --- I m. I— ^-...... I-----ml-.n in-—... .. — 'I Printed Isomers 1: 13-13310 / Isomer 2: Tree Feet by the Employees ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

** Physical data: ι.Ρ. of Ri / Rz or R3 or 1 H NMR -84- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Invention description (Μ) Table 6

(Please read the precautions on the back before filling out this page)-Pack. Printed example of XY Ri ΤΛ n B or D printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Physical data number 6.1 CH 0CH3 He 0 0 Allyl oil 6. 2 CH 0CH3 Me 1 4-bromo isomer 1: oil isomer 2: oil 6.3 N 0CH3 Me 0 0 alkenyl oil 6.4 N 0CH3 Me-1 4-bromo 131-1321 6.5 N NHCH3 He 0-alkenyl oil 6.6 N NHCH3 Me-1 4-bromo isomer 1 ·. 11 7-1 isomer 2: oil 6.7 CH 0CH3 Me-1 4-methyl- isomer 1: 2. 10 isomer 2: 2 . 08 6.8 N OCH3 He-1 4-methyl- 6. 9 N NHCH3 Me 1 4_methyl- -85-, va line paper size is applicable to China National Standard Falcon (CNS) A4 specification (210X 297 mm) 5. Description of the invention (v A7 B7

〇 H3C

A 'r3 ^ · Install, say (swim (please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-8 6 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 Mm) A7 B7 V. Description of invention (printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs | Example YAR i Rz R3 No. 1 or NR3 R 1 OEt NMe Me Me Me 2 OEt NHe H Me 6-CF3 -2 3 OEt NMe Me Δ 6-CFs -2 4 OEt NMe Me H phenyl 5 OEt NMe Me Me phenyl 6 OEt NMe Δ Me phenyl 7 OEt NMe H Me 4-oxolinyl 8 OEt NPh H Me phenyl 9 OEt NPh Me Me Phenyl 10 OEt NPh Me Δ Phenyl 11 OEt NPh △ Me Phenyl 12 OEt 0 Me Me Me 13 OEt 0 H Me Me 14 OEt 0 Δ Me Me -87- Physical Information ** (Please read the notes on the back first (Fill in this page again) This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 5. Description of the invention (8 2) A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 7.15 OEt 0 Me Δ Ne 7.16 OEt 0 Me H Ne 7.17 OEt 0 Me Me Phenyl 7.18 OEt 0 Me Me Benzyl 7.19 OEt 0 Me Me 3-CF3 -2-¾ pyridyl 7.20 OEt 0 Me Me 3-CF2 -phenyl 7.21 NHZ NMe Me Δ 3-CF3 -phenyl 7.22 NHZ NMe H Me 4-CF3 -phenyl 7.23 NHz NMe Me Me 4-CF3 -Phenyl 7.24 HHZ NMe Me He 2-triphenyl 7.25 NHz NMe Me Me 3-aminophenyl 7.26 nh2 NMe Me Me 4-cyanophenyl 7.27 nh2 0 Me Me phenyl 7.28 nh2 0 Me Me Ne 7.29 NHz 0 Me Me Benzyl 7.30 NHz 0 Me Me Et 7.31 NHz 0 H Me Et 7.32 NHz 0 △ Ne Et 7.33 nh2 0 Me Δ Et 7.34 NHz 0 Me H Et 7.35 NHz 0 Me Me Methoxymethyl 7.36 NHZ 0 Me △ Methane Methyl 7.37 nh2 0 △ Ne Methoxymethyl-88--; ------ 1 -installed ------ ordered-line (please read the precautions on the back first (Fill in this page) This paper scale is applicable to the Chinese National Standard (CNS) A4g (210X297mm) 304860 V. Description of the invention (8)) A7 B7 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics 7.38 KHz 0 Me Me Base 7.39 nh2 0 H Me propenyl 7.40 NHz 0 Me Me gas methyl 7.41 NHz 0 Me Me Η 7.42 NHz 0 Me Me CF3 CHz 7.43 nh2 0 Δ Me cf3 ch2 7.44 NH2 0 Me H CF3 CHz 7.45 NHz 0 Me H CF3 CHz CHz 7.46 nh2 0 Me Me CF3 CHz ch2 7.47 NHz 0 Me Me CF3 CHz ch2 CHz 7.48 NHz 0 Δ Me cf3 ch2 ch2 ch2 7.49 NHEt NMe Me Δ 3-CF3 -phenyl 7.50 NHEt NNe H Me 4-CF3 -phenyl 7.51 NHEt NMe Me Me 4-CF 3 -phenyl 7.52 NHEt NMe He Me 2-chlorophenyl 7.53 NHEt NHe Me He 3-aminophenyl 7.54 NHEt NHe Me He 4-nitrophenyl 7.55 HHEt 0 Me Me phenyl 7.56 NHEt 0 Me Me Me 7.57 NHEt 0 Me Me benzyl 7.58 NHEt 0 Me Me Et 7.59 HHEt 0 H Me Et 7.60 NHEt 0 Δ Me Et-89- (please read the precautions on the back before filling this page) This paper size is applicable China National Standards (CNS) A4g (210X297mm) V. Description of invention (pocket) A7 B7 Printed by the Ministry of Economy Central Standard Falcon Bureau Employee Consumer Cooperative 7.61 NHEt 0 Me △ Et 7.62 NHEt 0 Me H Et 7.63 NHEt 0 Me Me A Aminomethyl 7.64 NHEt 0 Me Δ Methylmethyl 7.65 NHEt 0 △ Ne Methylmethyl 7.66 NHEt 0 Me Me Ethylmethyl 7.67 NHEt 0 H Me Propylene 7.68 NHEt 0 Me Me 氱 methyl 7.69 NHEt 0 Me Me Η 7.70 NHEt 0 Me Me CF3 CH2 7.71 NHE t 0 Δ Me CF3 CHz 7.72 NHEt 0 Me H cf3 ch2 7.73 NHEt 0 Me H CF3 CHz CH2 7.74 NHEt 0 Me Ne CF3 CHz CH2 7.75 NHEt 0 Me Me cf3 ch2 ch2 CHZ 7.76 NHEt 0 △ Me CF3 CHz CH2 ch2 7.77 N (Me) 2 NMe Me △ 3-CF3 -phenyl 7.78 H (Me) z NNe H Me 4-CF3 -phenyl 7.79 N (Me) 2 NMe Me Ne 4-CF3 -phenyl 7.80 N (Me) z NHe Me Me 2-cyanophenyl 7.81 H (Me) 2 NHe Me Me 3-aminophenyl 7.82 N (Me) z NHe Me Me 4-chlorophenyl 7.83 M (Me) z 0 Me Me Phenyl-90- — · Binding call-line (please read the precautions on the back before filling in this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) S0486Q, V. Description of invention (girdle) Central Ministry of Economic Affairs 7.84 H (Me) z 0 Me Me Me 7.85 Η (Μβ) 2 0 Me Me benzyl 7.86 Ν (Μβ) 2 0 Me Me Et 7.87 H (Me) 2 0 H Me Et 7.88 N (Me) 2 0 △ Me Et 7.89 H (Me) 2 0 He △ Et 7.90 N (Me) 2 0 Me H Et 7.91 M (Me) z 0 Me Me Methoxymethyl 7.92 N (Me) 2 0 He Δ Methoxymethyl 7.93 N (Me) z 0 △ Me Methoxymethyl 7.94 N (Me) z 0 Me Me Ethoxymethyl 7.95 M (Me) 2 0 H Me Propylene 7.96 M (Me) z 0 Me He Chloromethyl 7.97 N (Me) z 0 Me Me Η 7.98 N (Me) 2 0 Me Me CF3 CHz 7.99 N (Me) 2 0 △ Me CF3 CHz 7.100 N (Me) z 0 Me H CF3 CHz 7.101 H (Me) z 0 Me H CF3 CHz CHz 7.102 N (Me) z 0 Me Me CF3 CHz ch2 7.103 H (Me) 2 0 Me Me CF3 CHz CH2 ch2 7.104 N (Me) z 0 △ Me CF3 CHz CHz CHz ^ Pack i (^ (Please read the precautions on the back before filling this page) -91-This paper size is applicable China National Standards (CNS) A4 specification (210X297mm) A7 B7 ® 〇486〇 V. Description of invention (0) 2. Formula I of active ingredient formula (% is weight percentage) Case 2: 1: Wettable Powder a) b) c) Table 1-7 Active ingredients 25X 50Z 75 * Sodium lignosulfonate 5X 5X-Sodium lauryl sulfate 3%-5X Sodium diisobutyl sulfonate-6X 102 Octylphenol polyethylene Diester (7-8 · ο1 Ε0)-2%-High-dispersed Di-Volatilized Silicon 52 10X 10% Kaolin 62% 27X-(Please read the precautions on the back before filling this page) Employee consumption of the Central Standards Bureau of the Ministry of Economic Affairs Cooperatives print active ingredients and add them thoroughly Together, milled in a suitable mill mixture was shake bottom to obtain the wettable powder Kuo, water can be thin "into any concentration suspension. Example 2. 2 Emulsions and condensates Table 1-7 Active ingredient 10Χ Octylphenol polyethylene glycol_ (4-5 · ο1 Ε0) 3 * calcium dodecylbenzenesulfonate 3Ϊ hexanone 34Χ xylene mixture 50ί any The desired degree of emulsion can be prepared from any such concentration diluted with water. Example 2.3: Powder should be a) b) Table 1-7 Active ingredient 5% sx talc 95%--92- This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 public daughter) Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Printed A7 B7 V. Description of the invention (Μ) Kaolin-92J; the active ingredient is mixed with the loaded mule • The mixture is ground in a suitable grinder to obtain the available dust of Keli®. Example 2.4: Extrudate pellet Table 1-7 Active Ingredients 102 Sodium Canthylsulfonate 2% Methyl Cellulose Carboxylic Acid IX Naolin 87 * The active ingredients are mixed with additives, the mixture is ground, and the mixture is extruded with water It is dried in an air vapor. Example 2.5 Coated particles Table 1-7 Active ingredients 3Z Polyoxinase (HW 2 0 0) 3X Chilling clay 94X (MW is the molecular weight) The active ingredients of fine particles are removed in the mixer Apply evenly to the kaolin that has been packed with glyphosate to obtain Wuxiang coated particles in this way. Example 2.6: Suspension Concentrate The active ingredients in Table 1-7 are 40 g Polyphenol Glyoxylate (15 · 〇1 EO) SX Sodium Lignosulfonate 10 *

Carboxymethyl methionine U-93- This paper scale is applicable to China National Standards (CNS) A4 specification (210X297mm) 7 ^. Install i (chant (please read the precautions on the back before filling this page) 3 〇486〇 V. Description of the invention U ”A7 B7 37J: Formaldehyde aqueous solution 0.2X 75ί silicone oil 0.8Z water 32X water 32X particles of finely mixed active ingredients and additives thoroughly • to obtain a float test liquid. Can be diluted into Any concentration of punishment liquid. 3. Biological example A) Example of microbial activity B-1: The anti-tomato phyt ophthora infes tans (a) therapeutically active tomato plant c V 9 »Ro ter Gno Then, the animal spores in the poems of the emblem «Float f are cultivated indoors at 18 to 201 1C and in the atmosphere of Europium and Lanshui. After 2 4 hours, stop supplying the gas. After the plants have dried up (please read the precautions on the back before filling out this page) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, it is sprayed to include an active ingredient mixture that is formulated into a wettable powder of 20 ppm . After the spray coating has dried, the plants are taken back into the damp chamber and placed for 4 days. The number and size of leaf spots developed after this period of time were used to assess the activity of the test substance. (b) Preventive systemic activity The active ingredient formulated as a wettable powder at a concentration of 60 ppm (relative to soil volume) is administered to the tomato plant cv. "Roter Gnoa" which has been grown for 3 hours in tweezers. After the plant was allowed to stand for 3 days, the bottom of the leaves was sprayed

The spore suspension of Phy tophthora inf estans. The plant was then placed in a sprinkler irrigation room with a saturated humid atmosphere from 18 to 2 Ot: for 5 days. After that, a typical leaf spot was developed, and the number and size of the test specimens were used to evaluate the -94- This paper scale is applicable to the Chinese National Standard Falcon (CNS) A4 specification (210X297 mm) 304860 A7 B7 V. Description of the invention u?) active. The untreated but infected plants in the control group showed a 100% dyeing rate, and those who used one of the active ingredients of formula I in the table, especially made 1. 5 • 1. 24, 1. 117, 2. 24 , 2. 74 and 3. 2 4 compounds, the infection rate of the above two groups of tests was reduced to 20% or less. Example B-2: Plasiopara viticola (Bert. Et C ur t.) (B er 1. et D e T ο ni) activity (a) residual preventive activity «Grape branch cv. &Quot; Chassels” in the greenhouse Medium growth, when it grows into a 10-leaf stage, 3 plants among them_pre-mix (active ingredient of 200p pm). After the coating on the plants is dried, the emblem_spore is evenly implanted on the bottom of the medicine. Float. The plant was then kept in the wet room for 8 days. After that, the control plant had developed disease. The number and size of damaged parts of the treated plant were used to evaluate the activity of the test substance ) Therapeutic activity Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy (please read the precautions on the back and then fill out this page) Grape twigs CV. ”Chassels” grow in the greenhouse, when they grow into 10 leaves, the bottom of the leaves Spray the spore suspension of Plasiopara viticola. After the plant is placed in the humid room for 24 hours, spray the active ingredient mixture (200 ppm of active ingredient). Then keep the plant in the humid room for 7 days. After that, the control plant Already The disease clearly developed. The number and size of the damaged parts of the treated plants were used to evaluate the test -95- This paper scale is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 mm) Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Printed A7 B7__ V. Description of the invention (? Called the activity of the test substance. Compared with the plants in the control group, the dyeing rate of the active ingredients of Formula I is 20% or less. Example B-3: For beets ( B etavu 1 garis) P ythiudebaryanu's active microbes grow on the sterilized oatmeal and add it to the mixture of soil and sand. Put this soil into the flowerpot and plant sugar beets. After planting, immediately The test product formulated as Coba® powder was poured into the soil in the form of water-based floats (20p pm active ingredient, relative to soil mother). The flower pot was placed at a temperature of 20 to 24Ό for 2 to 3 logic. The two stubble sprays water to keep the soil evenly moistened. The evaluation is carried out to calculate the number of beet plant sprouts and the number of healthy and infected plants. (B) Active emblem after seed coating_oats in disinfection Grow on top, add it to the mixture of soil and sand. Fill this planted soil into flower pots and plant it with a seed powder (100 ppm active ingredient, relative to the weight of the seed). Preparation of sugar beet. Flower pots and seeds are placed in a greenhouse at 20-24C for 2 to 3 passes. Gently spray water to keep the soil evenly moist. When evaluating, calculate the number of beet plant buds and key health Number of infected plants. Treated with the active ingredients of formula I, except for the compounds 1. 5, 1. 24, 1. 117, 2. 24, 2. 74 and 3. 24. Over 80% of the plants germinate and have a healthy appearance. Among the flower pots in the control group, only a few plants with unhealthy appearance germinated. -9 6 _ This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) I .------------ 、 玎 ----- ^ (Please read the note on the back first Please fill in this page again) A7 B7 304860 V. Description of the invention (7 /) Example B — 4: Residual protective activity against Cercospora arachidicola of groundnuts 10 to 15 g. The groundnuts separated by the “water-based water-spilling mixture (. 02% active ingredient) until it becomes sticky, and 48 hours later, it is implanted into the spore suspension of the top of the emblem sugar. Plants were bred in 2 1 t: and high tidal flat atmosphere for 72 hours and then placed in the greenhouse until the typical leaf spots appeared. After inoculation, the activity of the active ingredient is evaluated by the number and size of drug spots. The active ingredient of formula I makes the leaf spot occupy less than 10% of the leaf area. In some cases, the disease is almost completely eliminated (0-5% infection). Example B-5: Activity on wheat Puccinia graiinis a) Residual protective activity After 6 days of planting, the wheat plant was sprayed to the dropping point with an aqueous spray yaya compound (0.002 active ingredient). After 24 hours, the emblem was inoculated Zhongzhi 111: 0111〇3? (^ 0 suspension. After 48 hours of cultivation (condition is 2〇10, relative humidity 95 to 100%), the plants are placed in a ffl room at 22 * C, inoculated for 12 days Then evaluate the development of embroidered blisters. B) After 5 days of active planting, pour the water-based sprinkler irrigation mixture (0.006% active ingredient, which is sharper than the soil accretion) into the surrounding wheat plants. Be careful to avoid the subsequent mixture coming into contact with any plants on the ground. After 48 hours, the plants were inoculated with ureidospore suspension suspension. After 48 hours of inoculation (conditions 20TC, relative humidity 95 to 100%), place the plants in a rough room. Twelve days after the inoculation, the development of _blisters was evaluated. -97- The size of this paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 丨 ^ ------ "I installed ------ order ----- ^ line (please read the back first Please pay attention to this page and fill out this page) Printed by the Central Sample Bureau of the Ministry of Economic Affairs of the Beigong Consumer Cooperatives of the Ministry of Economic Affairs Printed by the Central Consumer Agency of the Ministry of Economics A7 ___B7__ 5. Description of the invention) Compounds of formula I, especially 1. in Table 1 , 1.24, 1. 11 7, 2. 74 and other compounds significantly reduced Hui Zhao Qi Ran, in some cases reduced to 10-0%. Example B-6: Activity on rice Pyricularia oryzae a) Residual prevention active rice After the plant grows for 2 encounters, it is sprayed with water-based deer compound (0.02% active ingredient 0 to the dropping point. After 4 to 8 hours, it is inoculated with the floating partridge conidi a to float. After 5 days of inoculation, the infection of the mackerel is evaluated. During this period, the relative intensity is maintained at 95 to 100%, and the temperature is 22 &quot; C. B) The system activity is poured on the water-based water-spraying mixture (0.006% active ingredient, relative to the soil lumps) and grown around the 2 rice. Careful Avoid spraying the mixture with any plants on the ground. Then put the pots in the quantity so that the stem of the rice is the lowest Water into it. 9 After 6 hours, the plants are inoculated with conidi a microbe suspension and kept at a relative humidity of 95 to 100% and a temperature of 241C. In many cases, the compound of formula I prevents infection The condition of the plant deteriorates. Example B-7: Residual retention activity on apple Venturia inaequalis Apple twigs containing fresh tender shoots of 10 to 20 cm are sprayed with _ 狝 mixture (0.022 active ingredient) to the drop point, 24 hours later, inoculated Suspended suspension of anisobacteria conidi a. Plants were first cooked for 5 days at a relative atmospheric temperature of 90 to 100, and then kept in a greenhouse at 20 to 24TC for another 10 days. After 15 days of inoculation, the infection spots were evaluated. Table 1, 2 Or most of the 3 types of I compound-98- This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 mm) I ------ ^ I installed ------ order ---- γ, -line (please read the precautions on the back before filling out this page) A7 304860 B7__ V. Description of the invention (p) The substance has a mosaic activity on spot diseases. (Please read the precautions on the back before filling out this page) Example B-8: Activity against barley Erysiphe graiinis a) Barley plants with residual protective activity of about 8 cm Spray the water-based spray mixture (0.02% active ingredient) to the drop, and after 3 to 4 hours, spray the conidia to withdraw bacteria. The inoculated plants are placed in the 22Ό »room, and the infection is evaluated 10 days after inoculation. B) Systemic activity: Pour the water-based mixture (0.002% active ingredient, relative to soil volume) into the barley plant Siyang about 8 g. Be careful to avoid contact with any sand objects on the ground. After 48 hours • Inoculate plants with conUia microbe suspension. The inoculated plants are placed in a 2 2 * 0 rough room. Ten days after the inoculation, the infection of Huibin was evaluated. Compounds of formula I, especially compounds such as 1.117, 2. 24 and 3. 24, can generally reduce the disease to 20%, and in some cases can be completely avoided. Printed by the Ministry of Economic Affairs of the Central Bureau of Samples of the Jungong Consumer Cooperative 8_9: Compilation of the activity of the fruit twigs Podosphaera leucotricha The apple twigs containing about 15 cm of fresh tender shoots were sprayed with a mixture (0.06% active ingredient), 24 hours Afterwards, the treated plants were inoculated with the suspension of the fungus conidi a and placed under the control of 70% relative humidity and 201C. Twelve days after the inoculation, the infection of the microbes was evaluated. Formula I active ingredients reduce disease to less than 20%. The disease infection rate of plants in the control group was 100%. Example Β — 1 0: Activity on Apple Botrytis cinerea. Residual guarantee -99- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) Printed by the Ministry of Economic Affairs Central Bureau of Industry and Commerce Beigong Consumer Cooperative A7 B7 5. 3. Description of the invention (fa) The spraying mixture for active protection (0.02% active ingredient) is administered to the wound of deliberately breaking apples. The treated apples are then taken up by the suspension of the spores of Corydalis angustifolia. 201 Pei-Yu encounter. The antimicrobial activity of the test sample was determined by the number of decay I in the wound. The active ingredient of formula I can reduce the wound decay _M extension, in some cases it can be completely prevented. Example Β-1 1: Active against Helainthosporiun graiineu · Wheat seeds are contaminated with suspended solids of the spores of the microbe. Let them dry. Contaminated seeds are coated with a suspension of the test substance (600 ppm active ingredient, relative to seed weight). After 2 days, arrange the seeds in a suitable dish containing agar, and after 4 days, evaluate the development of the sugar colonies around the seeds. The test substance was evaluated according to the number and size of Anhui bacteria® colonies. In some cases, certain compounds of formula I show excellent activity, i.e., the activity of inhibiting the colonies of the emblem. Example B-12: Activity against courgettes Colletotrichu · lagenariu · The courgette plants grown in 2 encounters were sprayed with sprinkler irrigation mixture (concentration 0.025). After 2 days, the plant was inoculated with a suspension of anisobacteria spores (1.5 x 10 spores / ml), and the meal was cultivated at 23 t! And high atmospheric humidity for 36 hours. Following the mine under normal atmospheric humidity and 22-231 meals. The development of Hui_Yueran was evaluated 8 days after seeding. The control group of untreated but velvet-stained plants had an infection rate of 100%. In some cases, the compounds of formula I, except for 1.5 and 3.24, can completely inhibit infection. Example Β-1 3: Activity on rye Fusariu · nivale-100- This paper scale uses the Chinese National Standard (CNS) A4 specification (210X297 male daughter)-; ------- ^ .Package- ---- order ----- ball (please read the precautions on the back before filling in this page) 304860 A7 B7 Fifth, the invention description (fjr) Use the mixed roller to kill the test emblem @_ 包装 被 Fusairiu · nivale Naturally dyed rye cv. Tetrahell, and use the following concentrations ... (please read the notes on the back before filling this page) 20 or 6 ppm active ingredient (relative to seed heavy egg). The seeded and treated rye was sown in October using a planter. The planting area was 3 meters, with 6 seeds, and each concentration was repeated 3 times. The test plants were grown under normal cultivated land conditions (preferably plaque fields that could be fully covered in the winter months) until evaluation of the contamination. To assess phytotoxicity, the number of seeds germinated was calculated in the fall, and the number of plants per unit of lentinella per plant was sprouted in the spring. In order to determine the activity of the active ingredient, the percentage of plants infected with Fusariu · wei was determined immediately after melting the snow. For this example, the number of infected plants is less than 5%. Germinated plants have a healthy appearance. Example B-1 4: Activity against wheat Septoria nodoru. Wheat grown to three leaves is prepared from a sprayable mixture of active ingredients (2.8: 1) in a powdery sprayable powder (60 ppm active ingredient) . After printing for 24 hours by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, the treated plant was inoculated with the emblem (: 〇 | ^ | 11 &amp; suspended matter. Then the plant was cultivated under a relative atmospheric humidity of 90-1 00¾ 2 Days, and placed in a greenhouse from 20 to 2424 for 10 days. After 13 days of inoculation, the Hui® is stained, and the proportion of wheat plants affected by the infection is less than 1%. Example B- 1 5: Active protection of rice Rhizoctonia solani Local application of soil for growth Suspended soil is poured around the soil around the rice plants for 10 days (嗔 跃 混 -101- This paper scale adopts the Chinese National Standard (CNS) A4 specification (210X297 mm)) ________B7_ V. Description of the invention (· The love float is for preparation The test substance is matched so that the plants on the ground do not come into contact with floating objects. After 3 days, the stems of Rhizoctonia solani's wheat-growing rice will be inoculated into the rice plant in each flower pot. During the day 2 9t! And nightfall 2 61D and the relative atmospheric suspicion 95% control the food under the Chen block for 6 days to evaluate the infection of the fungus. The result is that less than 5% of rice plants are infected and the appearance of the plant is healthy. The local protective medicine plaque is grown for 12 days Rice plant Suspend the suspension prepared by the test material. After 1 day, place the stems of barley infected with Rhizoctonia solaniii between the rice plants in each partial pot for inoculation. During the day 2 and nightfall 2 6¾ and The plants were cultured for 6 days in a controlled environment at a relative atmospheric temperature of 9 5%, and the plants were evaluated. The control group plants inoculated without treatment had a high infection rate of 100%. In some cases, the compound of formula I would Finished gold inhibits the EC infection of the disease. B. Example of killing Kun Dian activity B — 1 6: Printed on bean aphid (A phiscracciv 〇ra) Active Ministry of Economy Central Standards Bureau employee consumer cooperatives (please read the notes on the back before filling in This page) Pea seedlings were dyed by the bean aphid down, then treated with a spray-emulsion mixture containing 400p pm active ingredient, at 20t: incubation. After 3 days and 6 days were evaluated. In this test, the compounds of Tables 1 to 7 Has excellent activity. Especially the isomer of compound 4.5 has an activity exceeding «80%. Example B-1 7: Diabrotica balteata active young corn plant quilt contains 4 0 0 p pm active ingredients Water-based emulsion spray mixing After the coating is dried, the soybean plant is covered by -102- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm). The consumer cooperation cooperation of the Central Standards Bureau of the Ministry of Economic Affairs is printed by A7 B7. 5. Description of the invention (γ) Cloth plants were scattered in the second stage of the 10th noodles niche and placed in a quail container, and the evaluation was started after 6 days. The percentage reduction in the number of ethnic groups (% of activity) was obtained by comparing the apex that died under treatment and the feed loss with untreated plants. In the test, the compounds of Tables 1 to 7 all had excellent activities. Wait for the compounds 1. 5, 1.24, 2. 24. 3. 24, 4. 5 isomers 1, 414 isomers 1, 4. 14. isomers 1, 4. 117 isomers The activity of Isomer 1 of 4.121. 4. 170 · 5.9 and Isomer 1 of 5.51 are 80%. Example B-18: The active young soybeans of American cotton budworm were sprayed with an aqueous emulsion spraying mixture containing 400 ppm active ingredients. After the spray coating was dried, the soybean plant was scattered on 10 In the larval stage, the American tobacco budworm, placed in a plastic waist container, was evaluated only after 6 days. The percentage of population reduction (activity%), or feed loss, is obtained by comparing acceptance * of the death of untreated plants and feed loss. In the test, the compounds in Tables 1 to 7 all had excellent activities. To be distinguished is the isomer of compound 4.5, the isomer of 1.14, the diisomer of 4.18, 4.117, the isomers of 4.121, 5.9 is 1 and 5. The activity of 52 isomer 1 exceeded 80%. Example B — 19: Active young soybeans of Spodoptera littoralis are sprayed with water-103 containing 40 〇p Pm active ingredient- This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 Mm) I .------ &gt;-* --— install ------ order ----- line (please read the precautions on the back before filling in this page) After the printed layer of the consumer cooperative of the bureau employees was suspected, the soybean plant was spotted and spotted into a plastic waist container. Percentage reduction in the number of ethnic groups (living is obtained by comparison with the treatment and without loss. In the test, Table 1 I. Especially the isomerization of compound 4.5 • 5. 1.24.2.24, the isomer of 5, 5. The heterogeneous activity of 9 is over 80%. The mixture of live spiders (Tetranychus uriticae) is sprayed with water-based emulsified spray mixture after 1 day »Reduced percentage in 2 5 ethnic groups (% activity) of your eggs »Youxiang and Chengxin both have excellent activity. Especially 2 • 2 4 3 • 2 4% 4 • 5 compounds 1 • 4 • 1 1 7 isomers 5 5 2 isomers The activity of the substance 1 is super active on the active PVC board of us licroplus, covered with the wool ball 104-304860 V. Description of the invention (7 $) The emulsion spray mixture is sprayed on the 10th third young Guyang section In other words, the evaluation was not started until 6 days later), or the feed loss, the death of the plant and plant, Jiaxin and the feed loss 7 compounds have excellent actives 1, 4. 14 isomers 1 3 . 24,4. 18,4. Isomer 1 and 5. 52 isomer 1 C. Chiggericidal activity example B— 20: The cotton red spider sex young bean plants are spread with red spiders containing 40 ppm active ingredients for 6 days, and then evaluated. Compare treated and untreated deaths. In the test, Tables 1 to 6 are compound 1. 5, 1. 24, foreign matter 1, 4.14 isomer, 5. 9 isomer 1 and encounter 8 Ο%. Example B-2 1: 11 sex adults full of Boopohil are placed in A7 B7-'^ binding * line (please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297mm) A7 B7 5. Description of the invention (#, the aqueous test solution containing 1 2 5 P pm active ingredient is covered into adult lice. The cotton wool ball is removed, and the meal is prepared for spawning. Whether it is female or not The mortality or survival rate, or the egg-killing activity on eggs, the activity is very obvious. _ 龟 一 / I one,-line (please read the precautions on the back before filling this page) Employee consumption of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative-105- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm)

Claims (1)

A8 C3 Η A R3 compound 1 is mixed with -R mixed (-compound N configuration or, hetero and 1 1 its sons 1 and I, the original RHR compound nitrogen ο C ο is configured to be hetero X Υ X Υ qi) and ab which ( Please read the precautions on the back before filling out this page). F 2 R or the printed version of the Ministry of Economic Affairs Central Bureau of Preservation Consumer Cooperatives; or the base is}) ..- / 4 4 4 single base cC C § 4 _ II R 1 1 1 3 NC 1 or 丨 (R sub., Is and the original hydrogen 1 2 oxygen is 1-is 1 2 RRAR group R thiol hydrogen is C Alkyl Z alkane BC alkyl-SJ / 4 C methyl or cyano cyanopropyl propyl ring η η element halide is ί, 'group of oxygen is the same as alkane} or + the same C phase-is a 1 group C phen D-thio, Or base C This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297 public daughter) C 2 C alkane \ J /, 4 base C alkane I Halogen patent application scope C i — C 2) haloalkoxy C C4 ) Hypoalkyldioxane η is ◦, 1, 2 or 3; ZO is —◦-, a 0 — (Ci — C4) alkyl —, — (Ci — C 4) courtyard group — 0 —, — S (0) 2 — &gt; SB is (Ci _C6) alkyl, halo- (CC 4) alkyl, (C 5-C 6) cycloalkyl, or (C2 _C6) _ group or (C 2-C 4) alkynyl mono (Ci-C 2) alkyl, each unsubstituted or substituted with 1 to 3 halogen atoms, or phenyl, which is unsubstituted or (C 1-C3) alkyl, Halogen- (Ci-C 6) alkyl, substituted with halogen, or R (CH) Rg R8 (Please read the precautions on the back before filling this page) Printed or trimethylsilyl by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs; R 5, Rs and {? 9 are independently hydrogen, (Ci -C4) alkyl, and Rs and R7 are argon or halogen; R 3 is hydrogen, (C! — C s) alkyl> (Ci — Cs) haloalkyl * containing 1 to 5 halogen atoms * ( C 1-C4) alkoxy mono (Ci-C 2) alkyl, (C 2-C 4) alkenyl, which is unsubstituted or substituted by 1 to 3 halogen atoms, (C 2-C 4) alkynyl, un Cyclopropylmethyl substituted or substituted with 1 to 2 halogen atoms, cyano- (Ci-C ^ alkyl; (C! -C4)) alkoxycarbonyl- (C! -C2) alkyl-2 -This paper scale is applicable to China National Standard (CNS) A4 grid (210X297mm) • ▲ Λ Α8 304860 Bd D8 VI. Patent application scope 'phenyl mono (C! — C 2) alkyl, which is not Substituted or halogenated, (Cl-C 4) haloalkyl, unsubstituted phenyl or independently substituted (C 1-C 4) alkyl, (Ci-C 4) alkoxy, halogen, containing (Ci _ C 2) haloalkyl with 1 to 3 halogen atoms, nitro Substituted or disubstituted phenyl, or unsubstituted pyridyl or pyridyl substituted with (C i — C 2) haloalkyl or nitro containing 1 to 3 halogen atoms; R4 is (C!- C 4) alkyl, phenyl, or R3 and R4 together with the nitrogen atom to which they are bonded to form 4 — (1, (please read the precautions on the back before filling this page) 2, 4-triazolyl), 4 A quinolinyl or azepine group; except the following compounds α Printed by Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs 2 · For example, the compound of formula I in item 1 of the patent application, where X is nitrogen and Υ is 0 C Η 3. 3. A compound of formula I as described in item 1 of the patent scope, wherein X is C Η. 4 · For example, the compound of formula I in item 1 of the patent application, where X is nitrogen, Υ is NHC Η 3 and only 1 is only ((幵 3, cyclopropyl or CN. -3- This paper scale is used in China CNS A4 ^ (210Χ297 公 嫠) Printed A8 B8 C8 D8 by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs of the Male Workers ’Cooperatives of the People's Republic of China. 6, Patent application scope 5 · For any of the items 2 to 4 A compound of formula I, wherein A is oxygen, NCH3 or n-C6Hs. 6 A compound of formula I according to any one of claims 2 to 4, wherein Ri is hydrogen, methyl, cyclopropyl or cyano. 7 · As in the patent application, any one of items 2 to 4 of formula I compound, wherein Ri is (C!-C4) alkyl or cyclopropyl. 8 · As in any of the patent application, items 2 to 4 The compound of formula I in the item, wherein R 2 is · and \ = ^ A (d) η D group is a dentin '(Cl _C4) yard group, (Cl — C 4) alkoxy group, is substituted with 1 to 5 halogen atoms Substituted (C!-C 2) alkyl, (Ci-C 2) haloalkoxy, (Ci-C 4) hypoalkyldioxy, fluoro or nitro, or thienyl; and η is 0 , 1, 2, or 3. 9 ♦ If applying for special A compound of formula I according to any one of items 2 to 4, wherein R 2 is Z · B- &lt; 5-(D) η Z is a Ο—, 〇 一 (Ci — C4) courtyard base one, one (Ci-C4) alkyl-101, S (0) 2-. 10. The compound of formula I according to any one of claims 1 to 4, wherein R 2 is -4-(please first Read the notes on the back and fill out this page) The size of this paper adopts China National Standards (CNS) A4 specification (21〇Χ: 297 mm). Six, the scope of patent application A8 B8 C8 D8 The Ministry of Economic Affairs Central Bureau of Industry and Engineering Cooperative Printed B is (C 1 — C 4) Academy ♦ Halo — (C 1 — C 4) Academy is either (C 2 — C 4) alkenyl or (C 2 — C 4) alkynyl — (C — C 2) comprehensive base «each Unsubstituted or substituted with 1 to 3 halogen atoms or independently substituted by (C 1 — C 2) yard group »Halogen — (C 1 — C 2) yard group &gt; halogen &gt; monosubstituted to disubstituted The phenyl group i is R. 5 Rt — (CHf 4 R9 r8 R 5) R a and R 9 are independently hydrogen> (C 1 — C 2) The groups t R 6 and R 7 are argon or 0 1 1 • Compound of formula I as described in any one of items 1 to 4 of the patent application scope> wherein R 2 is a phenyl group substituted by — ZO — Β at the position 4 0 1 2 • As claimed in the patent application scope 1 to 4 Compound 9 of any one of formula I wherein R 4 is methyl or phenyl 〇1 3 • Compound I of formula I as in claim 1 of the patent application t wherein X is C Η; Y is 0 C Η 3 &gt; R 1 It is C Η 3 A is oxygen R 2 is 4-methylphenyl or 4-allyloxyphenyl or 4- (3-difluoromethyl-benzyloxy) phenyl or 4- (2 2 one two Chlorocyclopropylmethoxy) phenyl and R 3 are C Η 3 0 1 4 • Compounds of formula I as claimed in item 1 of the patent scope where a) X is a nitrogen atom and Y is 0 C Η 3 or N Η C Η 3 or b) X is C Η and -5- This paper size is applicable to China National Standards (CNS) Α4 specification (210Χ297mm) -------, ---. 1.-clothing --- --- Order (please read the precautions on the back before filling in this page) Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs, printed by the Male Workers ’Consumer Cooperative, and the scope of patent application Y is ◦ C Η 3, where: Α is oxygen atom or NR # Radical; R! Is hydrogen, (Ci —C4) alkane , Cyclopropyl, cyano or methylthio; R2 is argon; (C i-C 4) alkyl; cyclopropyl; unsubstituted phenyl or is independently halogenated, (C! — C4 ) Alkyl, (Ci—C *) alkoxy, (Ci—C2) haloalkyl, (Ci-C2) haloalkoxy, (Ci-Cs) alkenyloxy, (C3-Cs) alkene Yloxy, (ct —C4) hypooxydioxy mono- or di-substituted phenyl; or thienyl; R3 is hydrogen, (Ci-Cs) alkyl, containing 1 to 5 halogen atoms (C ! — Ce) haloalkyl, (Ci-C 4) alkoxy mono (C! — C 2) alkyl, (C 2 — C 4) alkenyl, which is unsubstituted or substituted by 1 to 3 halo Atomic substitution, (C2-C4) alkynyl, cyclopropylmethyl unsubstituted or substituted by 1 to 2 halogen atoms, cyano- (C! —C4) alkyl; (Ci —C4) alkoxy Carbonyl- (Ci-C2) alkyl, phenyl- (Ci-C2) alkyl, which is unsubstituted or halogenated, _ (Ci-C4) haloalkyl, unsubstituted phenyl or It is independently substituted by (Ci—C4) alkyl, (Ci—Cj) alkoxy, halogen, (Cz _Cz) haloalkyl containing 1 to 3 halogen atoms, or nitro Substituted phenyl, or unsubstituted pyridyl or pyridyl substituted with (C i — C 2) haloalkyl or nitro containing 1 to 3 halogen atoms; -6- This paper scale uses the country of China Standard (CNS) A4 wash grid (210X297mm) (Please read the precautions on the back before filling in this page) 304860 ns8 D8 6. The scope of patent application R4 is (C! —C4) alkyl, phenyl, or R3 and R4- and the nitrogen atom to which it is bonded form 4- (1, 2, 4-triazolyl), 4-morpholinyl or azepine. 1 5 · The compound of formula ί in item 14 of the patent application, wherein A is oxygen, R i is methyl, R 2 is methyl; unsubstituted phenyl or independently halogenated, (C i -C4) alkane Group, (Ci-C4) alkoxy, (Ci-Cz) haloalkyl, (Ci-Cz) -dentate alkoxy, (C3-Ce) alkenyloxy, (C3-C6) alkynyloxy, ( Ci-C *) monoalkyldioxy monosubstituted to disubstituted phenyl, or thienyl; and R3 is (Ci-C6) alkyl. 1 6 · The compound of formula I as claimed in item 14 of the patent scope, wherein R3 is hydrogen; (C! — C4) alkyl; (Ci -C4) haloalkyl containing 1 to 3 halogen atoms; (Ci one C2) Alkoxy 1 (printed by Peking Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs I ------ ·, Yiqu ------ order (please read the notes on the back before filling this page) C i &gt; one C 2) alkyl; unsubstituted or substituted with 1 to 3 halogen atoms propylene: allyl; unsubstituted or substituted with 1 to 2 halogen atoms cyclopropylmethyl; amido A (Cl — C2) alkynyl; (Cl — C2) alkoxycarbonyl one (Ci — c2) alkyl; unsubstituted or halogenated, phenyl containing 1 to 3 halogen atoms; unsubstituted Phenyl is either independently substituted by halogen, methyl, methoxy, halomethyl containing 1 to 3 halogen atoms, or nitro mono- or di-substituted phenyl; or unsubstituted pyridyl or by Halomethyl or nitro monosubstituted pyridyl groups containing 1 to 3 halo atoms; -7-This paper uses the Chinese National Standard (CNS) A4 wash grid (210X297 mm). Consumer Cooperative Printed A8 B8 C8 D8 Sixth, the scope of patent application R4 is methyl or phenyl; or R3 and R4 together with the nitrogen atom to which they are bonded to form 4- (1,2,4-triazolyl), 4-morpholinyl or Azepine. 1 7 · The compound of formula I as claimed in item 14 of the patent scope, wherein A is oxygen * R t is methyl, R2 is methyl; unsubstituted phenyl or independently halogenated, methyl, methoxy, The trifluoromethyl group or trifluoroparent group is mono- to di-substituted phenyl; and-R 3 is methyl. 1 8 · The compound of formula I as in claim 14 of the patent scope, wherein A is NC Η 3, R! Is methyl, Rz is methyl; unsubstituted phenyl or independently halogenated, methyl, methoxy , Trifluoromethyl or trifluoromethoxy mono-substituted to di-substituted phenyl; and R 3 is methyl; unsubstituted phenyl or independently halogenated, methyl, methoxy, containing 1 A phenyl group substituted or disubstituted with a halogenated methyl group or a nitrophosphate of up to 3 halogen atoms; or an unsubstituted pyridyl group or a pyridyl group mono-substituted with a halogenated methyl group or a nitro group containing 1 to 3 halogen atoms. 19, such as the compound of formula I in item 1 of the patent application, where X is a nitrogen atom; Υ is 0 R!!; -8 _ This paper size is applicable to China National Standard (CNS) 84 specifications (210X297 mm) -------- 'd outfit-(please read the precautions on the back before filling in this page) Subscriber A8 B8 C8 ------ D8, patent application scope ν / R 1 1 is (Ci -C4) alkyl; wherein A 'Ri, R2 and R3 are as defined in the patent application item 1 0 2 0. As in the patent application item 1 formula I compound, wherein x is a nitrogen atom; (r12) Rl3; Rl 2 and R! 3 are independently hydrogen or (C!-C 4) alkyl '· # 中 A' R i, R 2 and R 3 are as defined in item 1 of the patent application scope. _ 21 · The compound of formula I as claimed in item 20 of the patent scope, wherein Y is NH2> N (CH3) 2 or NHC2H5; A is an oxygen atom; R 1 and R 2 are methyl groups; R 3 is hydrogen; (C! _C4) alkyl; (C! ~ C4) haloalkyl containing 1 to 3 halogen atoms; (Ct -Cz) alkoxy one (Instigated by the Consumer Labor Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs ----- -¥ γ ^ ------ Order (please read the precautions on the back before filling in this page) C 1-C 2) alkyl; unsubstituted or substituted with 1 to .3 halogen atoms Group; allyl group; cyclopropylmethyl group which is unsubstituted or substituted by 1 to 2 halogen atoms; cyano- (Ci-(: 2) alkyl; — C2) alkyl; unsubstituted or halogen, containing 1 to 3 halogen atoms, nitro substituted phenyl; unsubstituted phenyl or benzyl is independently halogen, methyl, methoxy, containing Halomethyl with 1 to 3 halogen atoms, or phenyl mono- or di-substituted phenyl; or unsubstituted pyridyl or halogenated methyl with 1 to 3 halogen atoms or nitro 1A pyridyl -9- This paper scale adopts China National Standard (CNS) A4 regulation (210X297mm) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, 304860, containing 8: D8. 6. Patent application scope t 2 2 · For example, the compound of formula I in item 21 of the patent application scope, where R3 is hydrogen; (C , — C4) alkyl or (C i — C 4) haloalkyl containing 1 to 3 halogen atoms. 2 3 • The compound of formula I as described in any of items 1 to 4 of the patent application, where X = C Shuangju is in the form of E. 2 4-A method for preparing the compound of formula I as claimed in item 1 of the patent application, which includes (A) in order to obtain the formula I where Y is N (-R i 2) R i 3 Compound, the compound of formula I with Y being 0 R i: reacts with H N (R 1 2) R: 3, the reaction is carried out in a solvent at a temperature of 0 to 40 ° C; (B) in order to obtain the formula X, Y, Ba and Chi 1 in I—R3 is a compound as defined in formula I (where R 3 is not hydrogen), so that the following formula oxime «2 HON ^ A is entered into D Π N R3 Ri where A and Ri — R3 The definition is the same as above, and it reacts with the benzyl derivative of the following formula -10- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) (please read the precautions on the back before filling in this page) Order A I Scope of patent application 〇 u A8 B8 C8 D8 III where X and Y are as defined above, u is a leaving group. The reaction is carried out in an inert organic diluent and alkali, with or without phase transfer catalyst, at Ot: to 50 ° C. (C) In order to prepare the compound in which -A is oxygen, X, Y * Ri — R3 is as defined in the formula I: Y Ν ΟΗ Ν Ri IV ------- ', Ί installed ------ ordered (please read the precautions on the back before filling out this page) Printed by the Zhengong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs Wherein X, Y, Ri and Ruler 2 are as defined above, and the compounds of the formula: U-R 3 V R3 are defined as Formula I, that is, as Formula III (R3 is neither hydrogen nor phenyl or pyridyl) ; This reaction is a nucleophilic substitution reaction as described in (B). -1 1- The size of the paper is used in the Chinese national frame rate (CNS) Μ specification (210X297 mm) 304S60 ABCD 6. Patent application scope (D) For the preparation of X, γ, Ri and R2 in formula IV as defined in formula I The compound of the formula ketone h3c, 〇 VI where X, Y, Ri and 1? 2 are as defined above, and react with hydroxylamine or its salt in the presence of a solvent at a temperature of 0 ° C to 5 ου; (Ε) In order to prepare A, X, Y and only! 1. R3 is as defined in Formula I, but R3 is not a hydrogen compound, so that the following formula is enol or oxime (please read the notes on the back before filling this page) Binding Printed by the Male Workers Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 〇 AN— \ Latch 3 VII where A, X, Y and R 1 — R 3 are as defined above, react with methylating reagents such as methyl iodide, dimethyl sulfate or diazomethane, the reaction is in the presence of alkali Carried out in a suitable solvent. 25 ·-A method for preparing formula VII -1 2- This paper uses the national standard (CNS) Α4 specification (210X297 mm) Λ 36 ^ 860 Α8 Β8 C8 D8 Patent application scope 〇 HO 〇 / Ν &lt; γ / ^ Ν / nr3 Ri VII where A, X, Y and Ri_R3 are defined as formula I, which includes (A) preparing a compound of formula VI I where X is CH, which is a benzene of formula VI II Acetic acid derivatives A vm (Please read the precautions on the back before filling in this page) The Central Sample Bureau of the Ministry of Economic Affairs prints the negative labor consumption cooperative where A — R3 has the same definition as above and reacts with formate in the presence of alkali (B) in Formula VII X is a compound of N, which is a compound of formula VIII in which A, γ, and Chi 1 — Rs have the same definition as above, and the phenylacetic acid derivative reacts with nitrous acid or nitrite in the presence of a base; It is a compound of C Η, which uses the ketoester-13 of formula IX- This paper scale uses the Chinese National Standard (CNS &gt; Α4 wash grid (210X297 mm) 304860 A8 B8 C8 D8 to apply for patent scope. Υ N A Ny NRa Ri IX Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics Among them A, Ya and Chi! _R3 has the same definition as above, and reacts with methoxymethylenetriphenylphosphane; (D) Preparation of the compound of formula VII where X is N, which is like formula A, Y and} ^ 1 in formula IX _R3 has the same definition as Meng ester Reacts with oxygen-methylhydroxylamine or its salts. -2 6 ·-A pest control composition, which includes the compound as the first component of the scope of patent application as the active ingredient, K and a suitable carrier. 2 7 · For the composition of item 26 of the patent application scope, the pests are plant pathogenic microorganisms. 2 8 · For the composition according to item 27 of the patent application scope, the microorganisms are microbes. 29. For the composition according to item 26 of the patent application scope, the pests are insects or chiggers. 3 0 · The compound of formula I as the first item in the scope of patent application is used in the control of pest depletion. 3 1 · A method for controlling and preventing pests, which includes administering a compound such as item 1 of the scope of the patent application to the pests or their living environment. 32. If the method of claim 31 is applied, the pest is a plant pathogenic microorganism. -14 This paper scale is applicable to China National Standards (CNS) A4 Washing (210X297mm) (Please read the precautions on the back before filling in this I) 304860 A8 B8 C8 D8 Patent application scope 3 3 3 The method of item 2, wherein the microorganism is an emblem bacteria. 34. A method such as item 31 of the patent application scope, in which the pest is an insect or a tsutsugamushi. 3 5 · The method as claimed in item 3 1 of the patent application, wherein the seed is treated 0 36 ·-A compound of formula VI I 〇 HO AN R3 VII where A, X, YA and 111 — R3 is defined as in the scope of patent application item 1 37. — Compounds of formula VI II (please read the precautions on the back before filling out this page) Ministry of Economic Affairs Standards and Technology Bureau Printed by consumer cooperatives A ΥΙΠ where A, Υ and R: -R3 is defined as the first item of the patent application range -1 5- This paper size is applicable to China National Standards (CNS) A4 specifications (210X297 mm) 304860 8 888 ABCD VI. Patent application range 38 · a compound of formula IX A 3 RXT · * R and Υ A of the terms 1X, the range of π, and the specific requirements, please specify Ru 3 R (please read the precautions on the back before filling this page) • V clothing-1 1 i Central Ministry of Economic Affairs The bureau's consumer cooperatives printed the cracked paper and used the Chinese standard (CNS) A4 specification (210X297mm)