經濟部中央梯準局—工消费合作社印製 320655 A7 B7 五、發明説明（1 ) 本發明係有關分散染料時於9 5 °C以下可染色之同時 ，特別在配合各種染料之混合染料下，各種染料充份且均 勻染於纖維後，於染色前所期待之染料（特別是黑色染料 )之發色性極佳之聚酯纖維。 本發明更有關具優異之耐洗性*耐光性，熱特性，力 學性特性，且生產性極佳之聚酯纖維。 本發明係有關上述聚酯纖維與選由纖維素纖維*羊毛 *絲，拉伸繊維，聚醯胺纖維及醋酸酯中至少1種與之混 合後，具優異之發色性，堅固性及觸感佳之混用布料染色 物《本發明之聚酯織維及混用布料適用於內裏*婦女裡， 外均宜。 近來，衣料用纖維之功能被多樣化需求著，單純之繊 維可被滿足乃十足困難。因此，複合化素材被極髙之期待 β聚酯嫌維亦同樣以各種纖維素材，例如與纖維素纖維， 羊毛，絲，拉伸嫌維，聚醯胺織維，醋酸酯纖維等與之進 行複合化。惟，此些混用布料之製造中*各種組成繊維之 物性差異極大，產生各種問題》特別是，染色性差異之問 題極爲重大·> 例如由聚酯纖維與纖維索纖維所組成之混合布料之染 色即有極大問題點。聚酯繊維之染色通常使用分散染料β 而織維素纖維之染色則以直接染料或反應染料》特別是近 年來爲提昇堅固性使用反應染料之機會大增。聚酯繊維與 繊維素繅維所組成之混用布料染色時，由於各纖維所使用 之染色有別，因此通常以各別染浴之二段二浴染色方法β 本紙張尺度逋用中國國家梯準（CNS ) Α4规格（210X297公釐） ， -4 - (請先閲讀1之注^項再填寫本頁) 訂 Γ 320655 B7 經濟部中央標準局身工消費合作社印装 五、發明説明 (^ ) 1 ' 1 惟 既 存 聚 酯 纖 維 染 色 所 使 用 之 分 散 染 料 之 染 色 溫 度 爲 1 1； 1« 1 1 0 °C 以 上 9 — 般 爲 1 3 0 °c 左 右 〇 若 於 1 1 0 P »"； | 1 3 0 °c 之 溫 度 下 欲 將 此 混 用 布料 以 — 浴 染 色 時 則 反 應 染 料 產 生 熱 分 解 無 法 與 聚 酯 纖 維 成 同 色 性 0 又 Ϊ ιΐιιίιϊ^ 抑 止 研 先 閲 1 反 應染 料 引 起 熱 分 解 則 務 必 使 溫 度 於 9 5 °C 以 下 染 色 時 f Tf 1 之 注 :1 I 則 聚 酯 嫌 維 之 染 色 性 不 足 而 色 索 濃 度 雛 法 呈 現 • 因 此 > 只 1 I 好 以 1 3 0 °C 下 使 用 分 散 染 料 進 行 聚 酯纖 維 之 染 色 後 再 Ψ 項 再 % 1 1 Λ 於 9 5 °C 以 下 之 溫 度 使 用 反 應染料 進 行 嫌 維 素 織 維 之 染 色 寫 本 %. I 方 法 〇 倘 若 可 將 2 種 染 料 於 —' 染 浴 中 以 9 5 °c 以 下 之 溫 頁 1 1 1 度 進 行 染 色 ， 則 由 低 感 染 色 成 本 簡 化 操 作 性 之 面 觀 之 不 1 1 失 爲 一 效 率 性 之 方 法 0 1 * I 於 公 知 之 聚 酯 繊維與繊 維 素 繊維 之 混 用 布 料 ， 其 各 個 訂 -| 嫌 維 染色 溫 度仍 有極 有 差 距 i 因 此 一 段 — 浴 染 色 之 進 行仍 1 | 極 困 難 〇 1 1 | 另 外 聚 酯 織維 與羊 毛 ΐ 或 絲 所 組 成 之 混 用 布 料 之 染 1 1 色 同 樣亦有極 大 問 題 點 θ 羊 毛 ΐ 絲 所組成 之 布 料 其 尺 寸 安 1 定 性 * 力 學 強 度 * 增 最 後 爲 降低 成 本 聚 酯 織維與 之 混 用： 1 布 料 爲 理 想 考 量 0 惟 既 存 聚 酯 織維 染 色 時 其 染色 溫 度 必 1 1 爲 1 1 0 °c 以 上 ， 而 ft 溫 度 於 羊 毛 或 時 因 過 熱 而使 其 願 維 1 I 白 體 脆 化 1 不 但 未能 與 聚 酯 織 維 成 同 色 性 * 且 羊 毛 9 絲 之. ( ^ 1 強 度 低 減 1 觸 感 顯 著 惡 化 因 此 i 此 混 用 布 料 至 今 尙 無 法 1 1 | 染 色 〇 先 行 技 術 中 > 此 些 混 合 布 料 染 色 時 先 染 聚 酯 娜 糴 維 1 U 1 後 » 交 織 交 編 後 t 再 以 酸 性 染 料 將 絲 或 羊 毛 染 色 之 方 法 1 I ζ 惟 利 用 此 法 Ϊ 當 多 數 色 時 權 爲 煩 雜 ϊ 生 産 性 Ϊ 成 本 均 1 1 本紙張尺度適用中國國家梂率（CNS ) A4^格（210X297公釐） A7 B7 五、發明説明（3 ) 爲極大問題點。再由羊毛V絲之熱安定性不良面考置，常 壓下染色時，則先行聚酯纖維之染色性變爲不良，無法染 出聚酯纖維之染色漢度。 又，既存之聚酯織維與拉伸纖維所組成之混用布料的 染色亦出現極大問題。先行技術中，聚醯胺纖維由於觸感 .柔軟，常壓可染性，代表聚胺酯纖維之拉伸纖維與之混用 後，應用於針織運動服婦人用內裡中之裡地，泳裝，襪子 等。惟，聚醯胺纖維易受氣體，光之影響變黃，包線時完 成拉伸纖維力道弱而易引起脫絲，缺乏尺寸安定性，形狀 安定性等缺點。因此，爲使上述缺點消失*而進行聚酯纖 維與拉伸纖維之混用》 以聚酯纖維取代聚醯胺纖維後，則可解決聚醯胺纖維 有關之上述問題。惟，造成染色性之新問題出現。亦即* 聚酯織維之染色溫度高之問題產生。既存之聚酯纖維與聚 胺酯纖維之混用布料中，爲染色至某濃度，因而務必達至 少1 1 0°C以上之染色溫度，此溫度條件下聚胺酯織維受 熱惡化而強度大幅低下，變黃等重大問題產生。爲防止聚 經濟部中央梂準局貞工消費合作社印裝 k--ΊΜ..---Π------^ 取-- (請先閲讀背#之注意事項再填寫本頁) f 胺酯繊維之熱惡化而於常壓下進行染色則先行技術中之聚 酯織維之染色性不良，聚酯纖維無法染至一定濃度。 ' 又，聚酯纖維與聚醯胺纖維所組成之混用布料之染色 上亦有極大問題點出現9聚醯胺纖維以酸性染料爲常壓可 染性，具高強度等之優點，惟易變黃，熱安定性，尺寸安 定性均不良等問題存在。因此，爲解決此些缺點而與聚酯 繊維之混用被考量*惟，一般與聚酯繊維混用後，由於染 尺度適用中國®家橾率（CNS > A4規格（210X297公釐） 320655 A7 B7 經濟部中央揉率局負工消費合作杜印裂 五、發明説明（4 ) 色溫度極髙，因此，產生聚醯胺著色，觸慼不良等問題。 爲考置聚醯胺之熱安定性，若於常壓下染色則仍造成先行 技術中之聚酯纖維之染色性不良，聚酯嫌維無法達其染色 瀵度。 又 > 聚醋織維與醋酸酯繊維所組成之混用布料之染色 亦有極大問題點。醋酸酯嫌維係纖維素分子之氫氧基經乙 醯化後之纖維素系嫌維，因此，基本分子結構與繊維素類 似，但，對於直接染料，反應染料並非可染性，通常，.利 用分散染料於常壓下進行染色。若超越1 〇 o°c之高壓染 色進行後，則此乙醣基經水解後易起熱惡化·*維維出現白 濁。特別是，此乃公知之易成二醋酸酯纈維者•混用乙酸 酯纖維後求布料其尺寸安定性，強力提髙，製造成本低減 ，因此，與聚酯纖維之混用被選定考置。惟，一般與聚酯 嫌維混用後，由於染色溫度過髙，造成醋酸酯嫌維之白濁 ，觸感太硬等問題出現。爲考量醋酸酯嫌維之熱安定性於 常壓下染色則先行技術中之聚酯纖維染色性不良，無法使 聚酯織維達欲染色之濃度。 又，雖分散染料可提昇染色性之聚酯纖維爲公知者， 惟，仍存極多問題點。 做爲易染性聚酯纖維者1公知者以共聚聚酯做爲原料 者* 先行技術中對於分散染料可提昇染色性之聚酯織維對 於特定之單獨染料亦顯示易染性 > 對於各種染料被混合之 染料之某些染料完全抽空，某些染料抽空不全，造成抽空 — - ___ 本紙張尺度適用中圈國家樣準（CMS ) A4規格（210X297公釐） fcr — J—;--Η-----策------訂------， (請先閲讀背册之注^項再填窝本頁) 裡濟部中央標率局f工消费合作社印装 「"-)，ν A7 __B7 五、發明説明（5 ) 率不齊，各混合染料之混合比於染色前後預期結果不一之 S大問《產生《特別於黑色染料之問題顯著，先行技術之 易r染性聚酯織維之黑色發色性，於染色前所預期相比極大 差異問題產生* 做爲易染性聚酯繊維者，公知者以共聚聚酯爲原料者 *其中有與聚環氧乙二醇，己二酸共聚者爲公知者β 與聚環氣乙二酵共聚之聚對苯二甲酸乙二醇酯纖維者 *例如：特開平3—40880號公報，特開平3_17 4076號公報’特賭平4 — 41732號公報，特開平 4-4 1 7 3 8號公報等所示者。此纖維爲與6〜1 0重 置％之聚環氧乙烯對苯二甲酸鹽織維共聚之聚簾嫌維，達 成9 8 °C可染性。惟，本發明者調査過纖維之特性後發現 、由於聚環氧乙二醇之共聚比率熱髙，因此造成耐光性、 耐乾洗性均降低>.另外，雖於98°C達可染，而9 5°C卻 無法達成可染性&亦即，此9 8°C與9 5°C之可染差異於 工業上極大影響。此乃，常壓用染色鍋於沸賸狀態下進行 染色時*染色溫度出現9 5〜9 8°C之不定數*染色溫度 3 t之差別下，出現批料間不同染色群之重大缺陷。若， 9 5 °C爲可染時則此問題自然消失•更者，聚乙二酵之共 聚比率變髙則引起原絲白度低滅，淺色系則難有均勻色染 之問題點，又，此種共聚組成其聚合之真空狀態下易引起 突沸現象，嚴重時突沸之聚合物阻塞於真空管造成末能分 解解除狀態。又，5重量％以上之聚乙二醇共聚後之聚酯 嫌維其紡紗性不充份。亦即，離開紡口後，溶融聚合物接 本紙張尺度遥用中困國家捸準（CNS ) A4规格（2丨0X297公嫠） ~ flu 1^1 imi In ^^1 ^^1 ^^1 : . 一 s (f閲讀背Φ之注$項再瑱寫本頁) 訂 Γ 經濟部中央操準局f工消費合作社印褽 320655 A7 _B7__ 五、發明说明（6 ) 受冷卻時絲易卷曲；造成斷絲，起毛等問題。又，由於紡 絲性不良欲製成單絲旦尼爾爲1旦尼爾左右之細旦尼爾之 絲極爲困難。細旦尼爾化於柔軟觸感係絕對必要者，於裡 地，婦女外衣等之觸感均爲必要要求範園，而此種共聚組 成，使難以細旦尼爾化其用途亦極限•如上述此些先行技 .術中之易染絲其染色性，耐牢性，白度，聚合性，紡紗性 均有缺點。 又，聚乙二醇與己二醇與之共聚之聚酯嫌維亦爲公知 者（例如，特開昭6 3 — 851 1 1號公報，特開昭63 —235536號公報）*特開昭63 — 8 5111號公 報中公開有聚醚單位0. 5〜10重置％，二羧酸單位 0. 5〜10重童％與之共聚之聚酿繊維，其實施例中公 開有聚乙二醇4重量％與己二醇4重置％與之共聚之聚酯 纖維。 此纖維若以Μ醌系之單獨染料予與染色時，則可達最 髙吸收率。惟，由於此染料於分散染料中分子量較小（分 子量349)，易染於纖維β因此，儘管此染料可達高抽. 空率卻不代所有染料均爲髙抽空率°更且，此織維之己二 酸重置/聚乙二醇重量小’各種染料之混合染料不易染色 ，特別是黑色染料之發色性有不良傾向°又*此織維由纖 維之非晶部份之分子密度所示之動態粘彈性測定求出之損 失正切最髙溫度（以下，T max〔°C〕稱之）較髙，因此 對各種染料之混合染料顯示不出易染性’僅限於單獨染料 爲易染性，因此汎用性有極大間題點。 本紙張尺度適用中國興家揉率（CNS ) A4规格（210X297公釐） ;|--r----If 裝 1 — (請先閔讀背面之注f項再填寫本頁) 訂 f 鍾濟部中央梂準局貞工消費合作社印製 320655 A? B7 五、發明说明（7 ) 特開昭6 3_2 3 5 5 3 6號公報中公開聚乙二酵6 重置％與己二醇5.1重量％與之聚之聚對苯二甲酸乙二 醉酯繊維，此纖維亦與上述相同單獨染料之髙抽空率’聚 乙二醇可達成之共聚比率髙，T aax亦髙，對耐乾洗性’ 耐光性，白度，聚合性，配合染料之染色性，紡紗性等均 .有問題。 做爲其他共聚聚酯繊維之方法者，公知者如四甲基二 醉，1，4 —環己二醇等之二酵與之共聚之聚酯纖維（特 開昭 58— 120815 號公報），2，2 —雙〔4-( 2-氫化乙氣基）苯基〕丙烷與之共聚後，經髙速紡紗法 ‘之聚酯繊維（特開昭5 9 — 1 9 9 8 1 4公報）等等•惟 ，此法取得聚酯纖維可改善染色性，而9 5 °C爲不可染性 。又，公知者有碳數8以上之脂肪族二羧酸共聚之後，經 高速紡紗爲易染性聚酯纖維者（特開平5-9 85 1 2號 公報）。此聚酯纖錐確實具髙染色性，惟耐乾洗性極不佳 ，熱應力低因此取得布料之觸感極不良等問題出現。又* _ 公知之金颶酸酸酿共聚之聚酯髙速紡紗後易染化之方法（ 特公昭60— 10126號公報惟，此嫌維強度低， 其結果造成布料之破裂強度低之缺黏，實質上未能用於本 發明之目的》更且，金屬硫酸酯共聚之聚酯含多量金展硫 酸酯變性後之不融物，因此，紡紗時間變長後，紡口袋阻 塞*紡紗變不能爲。 公知者有爲提髙染色性之5 -硫代異苯二甲酸鹽與己 二酸共聚後，經常法取得之聚龍纖維（特開昭5 1 — 1 3 本紙張尺度適用中«Η家梂準（CNS ) A4規格（2丨0X297公釐} ^n· 1· - - n ml tuf tv (請先閲讀背面之注#^項再填寫本頁) 訂 經濟部中夬棵準局舅工消费合作社印簟 Α7 Β7 五、發明説明（8 ) 3529號公報，特開昭55-158325號公報，特 開昭61 — 239015猇公報）·惟，此聚酯織維亦於 9 5 ΐ下染色性不足*因此無法達成本發明之目的。 做爲染色方法，後處理方法之改良方法者，公知者如 :載體染色•惟，載體染色之染浴中用以苯殷衍生物，芳 .香族鹵化物，聯苯基衍生物等髙沸點有機化合物，因此， 造成廢液處理，作業惟顯著不良之缺點•又，提高染色性 之公知者如經髙速紡紗後取得之聚酯織維於1 8 o°c〜 300 °C下做濕熱處理之方法（特開昭58 — 13682 5號公報，特公昭63-73650號公報）。唯，雖濕 熱處理後可提髙染色性，卻缺乏均染性，且，經過一次髙 速紡妙取得之嫌維，再次熱處理後，無法產生有效提高高 速紡紗之生產性之缺點》 諸如上述，截至目前倚未能於9 5 °C以下之溫度下具 髙分散染料性，且各種分散染料之混合配合染料可具有優 異染色性之聚酯纖維於工業上被生產者。另外，公知者有 改善某種程度之聚酯繊維中，其耐乾洗性，耐光性*熱特 性，紡紗性等問題點不斷β 本發明之目的係提供分散染料於9 5 °C以下時染色可 能，且各種分散染料之混合配合染料具優異染色性，更且 ，耐乾洗性，耐光性，熱特性，力學特性以及染色加工上 由具優異生產性之聚酯繊維與其繊維及繊維素戡維*羊毛 ，絲，拉伸織維，聚藤胺織維中選出至少一種織維使用後 ，具優異之發色性，耐牢性，觸感性之混用布料染色物者 本紙張尺度逍用中國國家標準（CNS > Μ規格（210X297公釐） -* I I ^^1 ^ I -I I -^ _ (請先閎讀背面之注項再填寫本頁) 訂 320655 A7 B7 Μ濟部中央棣準局—工消費合作社印製 五、發明説明（9 ) σ 本發明者發現，使用聚乙二醇與二羧酸共聚之聚對苯 二甲酸乙二醇酯之聚酯纖維中，特別選由二羧酸中之己二 酸後，其共聚比率設定於極限範函，由纖維非晶部扮之分 子密度所示之動態粘弾性測定求出所使用之被設定於特定 範圍之T max之聚對苯二甲酸乙二醇酯繊維可解決上述課 題者，進而完成本發明》 亦即本發明第1特徵係將平均分子置5 0 0〜 4000之聚乙二醇1. 5〜4, 5重置％，己二酸9〜 6重置％共聚後之聚對苯二甲酸乙二醇酯，滿足於1. 3 S己二醇之重量聚乙二酵之重量％^ 6後*損失正切 之最高溫度爲9 0〜10 8 °C者之聚酯纖維》 本發明之第2特徵係使用該聚酯織維與纖維素繊維之 混用布料染色物，本發明之第3特徽係使用該聚酯繅維與 羊毛或絲之混用布料染色物，本發明第4特徵係使用該聚 酯纖維與拉伸織維之混用布料染色物，本發明第5特徵係 使用該聚酯纖維與聚醯胺纖維之混用布料染色物，本發明 第6特徵係使用該聚酯織維與醋酸酯織維之混用布料染色 構成本發明之聚酯纖維聚合物係平均分子量5 0 0〜 4000之聚乙二酵1. 5〜4. 5重量％，己二醇9〜 6重最％共聚後，滿足於1. 3 ή己二酸之重量聚乙 二醇之重置6之聚對苯二甲酸乙二醇酯所組成之共聚 聚酯者。爲取得於9 5 °C下具充份染色性，耐牢性則聚乙 (請先閎讀^^之注^^項再填窝本頁) 蒗 訂 f 本紙張尺度適用中阃®家揉準（CNS > A4规格（210X297公釐） -12 - 經濟部中央樣準局貝工消费合作社印製 A7 ____B7___ 五、發明说明（10 ) 二醇與己二酸之2共聚成份爲不可缺者•單爲平均分子置 500〜4000之聚乙二醇1. 5〜4. 5重擞％之共 聚對苯二甲酸乙二醇酯，或，單爲己二酸6〜9重惫％之 共聚聚對苯二甲酸乙二醇酯則於9 5 °C下無法顯示充扮之 染色性β 所謂染色性即指染料可充份染色於織維上，具有出現 某澳度染色之織維之性能者，最簡單即可以後述實施例所 示含染料之浴中染料抽空率之大小做判定* 做爲共聚成份之聚乙二醇對於提高染色性爲極具效率 之共聚成份者。當平均分子量不足5 0 0時，則由於含極 低分子置之聚乙二醇因此，於高真空下聚合時被減壓留去 ，取得含聚合物之聚乙二醇置難以固定。因此，原絲之強 伸展特性，染色性，熱特性等無法均一，製品之特性分岐 不一。反之，若平均分子置超出4000時，由於不被共 聚於聚合物內之髙分子量之聚乙二醇過多，造成染色性， 耐乾洗性•耐光性均低減。 做爲共聚成份之己二酸由於可引起繊維之非晶結構逋 當混亂而有提昇染色性之優點》除做爲引起非晶結構混亂 提昇染色性之共聚單體之己二酸（碳數6 )之外，脂肪族 二羧酸成份亦有其效果。惟，碳數5以下之脂肪族二羧酸 其聚合物之熟安定性變低，產生自度低減。由於熱安定低 減爲鄰接於羧基之亞甲基之莫耳分子數成正比，因而造® 此結果•另外，若爲碳數7以上之脂肪族二羧酸成份則非 晶部份之混亂過大，因此，耐牢性，特別是耐乾洗性顯著 表紙浪尺度遑用中两國家棣準（CNS ) Μ规格（210Χ297公釐） 一 13 - J-I J-----f 裝------订------， (請先閲讀背潘之注f项再填寫本ί) 320655 經濟部中央揉率局I工消费合作社印裝 A7 B7 五、發明説明（11 ) 降低。然而，在己二酸方面，此些問題點等特別小。也因 此，己二酸被限於狹小範豳中選出，爲極優異之共聚成份 者*雖然並非經此理由而定論，但，可由以下推定之•亦 即，己二酸雖具4個亞甲基，但，此長度幾乎相當於對苯 二甲酸之苯環之長度》因此，本發明所使用之聚酯嫌維因 .彎曲性基混亂非晶部結構者，其混亂程度停留於必要之最 小限，因此，成爲熱特性等最接近聚對苯二甲酸乙二酵酯 嫌維之改質聚酯織維β 用以分散染料爲確保於9 5 °C下具充份的染色性，耐 牢性，紡紗性，聚乙二醇之置應爲1. 5〜4. 5重量％ 若聚乙二醇之量不足1. 5重暈％則染色性變差。若超 過4. 5重量％則不僅耐光性變差*且易引起聚合物之聚 合階段之染色，高真空聚合中，顯著出現突沸，起泡，不 易達成細且旦尼爾化等之紡紗性問題染色性，耐牢性， 聚合性，紡紗性之最佳均衡暈爲2〜4重量％。 另外，己二酸之最適當置隨聚乙二醇量而異，一般爲 9〜6重置％。若己二酸置不足6重量％則9 5 °C之染色 性不足。反之，超過9重置％則耐熱性低減，只能取得觸 感不佳堅硬布料。 若不選擇均衡之染色性與耐牢性，以及聚合性，紡絲 性佳之共聚比率則無實用性。爲提高染色性1儘量使聚乙 二醇之多量共聚較佳。惟，聚乙二醇置多則易使耐光性’ 耐乾洗性大幅降低，且，聚合性，紡紗性亦減低。因此’ 以適量之己二酸代替多量之聚乙二醇使共聚後，可防止耐 本紙張尺度適用中國躅家揉準（CNS ) A4规格（2丨OX297公羞〉 (請先閲讀f之注f項再填寫本頁) Λ裝 訂 320655 A7 B7 娌濟部中央揉準局貞工消費合作社印装 五、發明说明（i2) 光性，耐乾洗性，聚合性，紡紗性之低下。 另外，不僅對於單獨染料，各種分散染料之混合配合 染料爲提髙染色性，此聚乙二醇與己二酸之比率爲極重要 之條件•爲取得此種共聚組成，務必滿足1. 3S己二酸 之重置聚己二醇之重置％ (以下，此值爲R值）S 6 者。若R值小於1. 3時，聚乙二醇之共聚比率變髙，達 成常壓可染性之置之聚乙二醇，己二醇與之共聚後則耐光 性，耐乾洗性低減。 又，經各種分散材料之混合後之配合染料下染色時， 產生各種染料之抽空性之差，染色後之發色性與染色前所 預期者相異。特別是黑色染料下染色時之染色性變差· 另外，R值若大於6則，己二醇之共聚比率變髙，達 成常壓可染性之盘之聚乙二醇，己二醇共聚後，則耐熱性 低減，熱裝置等：t.程中織維變硬，造成觸感不佳•且，即 使滿足1. 3SR值6之組成，而R值變大則取得之混用 布料製品之觸慼變硬而不良，爲使達柔軟觸感·此值以4 以下，特別是3以下爲最理想又，於配合染料下染色時 爲能取得優異之發色性則理想R值應爲1. 7〜6,更佳 者爲1 . 7〜4 β 又，本發明所使用之聚酿纖維中，含1 〇重量％以下 ，較佳爲5%以下之其他二醇，醇酸等之聚酯形成能之共 聚成份亦可。惟，務必以不妨害耐牢性變化程度之共聚成 份者。 更且因應所需，各種添加劑，例如：消光劑，熱安定 (讀先閲讀背面之注f項再填寫本頁) Γ裝- 訂 本紙張尺度逍用中®國家樣率（CNS ) A4规格（210X297公釐） 15 經汫部中央梂率局貝工消費合作社印製 320655 A7 B7 五、發明説明（is) 劑，消泡劑，整色劑，難燃劑，氧化防止劑，紫外線吸收 劑，紅外線吸收劑，晶核剤，螢光增白劑等與之共聚，或 混合均可。 構成本發明所使用之聚酯纖維之聚合物一般製造聚對 苯二甲酸乙二醇酯之工程中，於縮聚終了前之任意階段下 ，以聚乙二醇，己二酸，或單甲酯，二甲酯，二乙酯，雙 (羥乙基）酯等之做爲低級烷基酯者添加於反應系中與之 共聚後製造出。此時，此些共聚成份可照原來或分散於乙 二醇等適當溶劑中，溶解或加熱處理後再加入。 典型的聚合方法由下所示》將對苯二甲酸二甲酯與己 二醇二甲酯於乙二醇中，於催化量之醋酸錳，醋酸鈣，醋 酸鈷等之存在下，2 0 0〜2 4 0°C下進行酯交換反應， 使對苯二甲酸與己二酵之兩末端羥乙基化此時，反應終 點以理論置之甲醇出現爲準。其後，加入聚乙二醇與縮聚 催化劑之三氧化銻，於2 6 0〜2 9 0 °C下進行減壓下聚 合- 本發明之聚酯繊維務必由動態粘弾性測定求出之損失 正切最高溫度爲90〜1 08 °C者。此仍於此範園下方可 確保本發明所番之優異染色性。T max與非晶部份之分子 密度成正比，因此，此值變小則非晶部之分子密度愈小， 造成侵入染料之空隙變大愈易進入染料·，抽空率變髙。 將T max設定於此範園內後，本發明之聚酯緻維不僅 單獨染料時可達成9 5 eC可染性，且各種分散染料之混合 配合染料下染色時，對於各種分散染料均顯示優異染色性 本紙張尺ϋΜ中興國家揉準（CNS > A4规格（21〇X25>7公嫠> ' JII.-----71- (請先W讀^e之注f項再填寫本頁) 訂 A7 320655 B7 五、發明説明（W〉 ，結果，可達成染色前出現所預設之發色性•特別黑色染 料之染色時，其黑色發色性更是極爲優異。 此T max係繊維之結構因子，即使具相同的共聚組成 之共聚物，卻因紡紗溫度，紡紗速度，延展倍率，熱處理 溫度，精煉條件，強鹸減量條件，染色條件等之紡紗條件 ，後加工條件之不同而出示不同之值者。特別是設定熱之 溫度，其值之變化極大，因此，控制熱設定溫度，使 T max維持於上述範圍內爲極大之要點。若未謹慎考慮熱 處理溫度則於本發明所規定之共聚聚酯時，熱處理溫度由 室溫至1 6 0°C時T max漸漸昇髙，當超過1 6 0°C又大 幅低減。此些變化比例，因各共聚組成有所相異，因此， 熱處理溫度與T fflax之關係務必精密。本發明中，超過 1 0 81則染色性改善效果變小* 9 5°C可染性無法出現 。且，並非愈低愈.佳，易使非晶部份變太粗，造成染料容 易進入同時易脫落之缺點β亦即，耐牢性，特別是耐乾洗 性，耐濕磨擦性，耐洗性等降低β又，熱處理時之硬化後 ，觸感變差，尺寸安定性減低等問題一一出現。因此，雖 實用性爲90〜1 1 0°C，最好以9 5〜1 0 5°C者爲宜 〇 本發明聚酯纖維之融點爲2 3 0〜2 4 5°C。未達 2 3 0 °C時，聚酯織維於熱處理之加工，熨斗等使用階段 下出現熱變性，使物性，觸感引起變化》融點超過2 4 5 °C則紡紗性降低。構成本發明聚酯纖維之聚合物者係爲特 殊組成者•因此 > 爲達良好紡紗之紡紗溫度•若以紡口表 本紙織逋用中困瞒準（cnsM娜（應贈釐）一 π _ (請先K讀^8之注^>項再填寫本I ) 袭 訂 經濟部中央裸準局貞工消費合作社印策 320655 A7 B7 五、發明説明（15 ) 面溫度表示，務必達2 5 5〜2 7 0左右者。因此，聚合 物之融點超過2 4 5 °C後，將熔融聚合物，使得擠壓機溫 度不能設定太高，造成難以維持此紡口表面溫度之困難點 〇 本發明之聚酯纖維維可以卷取速度1 5 0 Om/ mi η下未延展絲之2〜3. 5倍，經延撓一般法，或聯 機紡紗一延撓工程直延法取得。雖於5 0 Om/m i η以 上之卷取速度之高速紡紗方法亦無不可，但，非晶部份之 配向性變得太低（T max太小），耐牢性低減，故非良好 紡紗方法。紡紗條件並無特定限制，只要公知之條件者即 可紡紗。惟，務必進行紡口表面溫度之管理。亦即，紡口 表面溫度務必於2 5 5〜2 7 0°C者》若不足2 5 5 °C則 溫度不夠，易出現塊狀，造成大量斷絲。另外，270〜 3 00 °C亦可紡紗，惟，卷絲太多，出現斷絲，脫毛現象 頻率極大。 經濟部中央標準局貝工消費合作社印袋 (請先閲讀背面之注意事項再填寫本頁) 本發明聚酯纖維中，9 5°C下染色時，深色度之K/ S爲2 0以上。K/S之測定方法由實施例記載方法取得 。評定染色性之染料由於具有的分子結構（分子量爲 518)，因此，此染料若可取得高染色性者，則使用任 何種類之分散染料均可確保取得高染色性者。此高染色性 係指K/S爲20以上者。因此，95 °C下染色時，若K /S爲2 0以上者，則可如同一般聚酯纖維於1 3 0°C染 色時之同等發色性出現之。此發色性一般可達約7 5 %以 上之抽空率。 本紙張尺度適用中國國家標準（CNS)A4規格（ 210X297公釐）_ 18 _ 320655 Α7 Β7 五、發明説明（16 ) 如此被染色之染色物爲顯示髙耐牢性，則耐乾洗性務 必爲3級以上。本發明之耐乾洗性係評定液污染者》此評 定方法戴於實施例中•另外，耐牢性之評定項目有耐水性 ，耐洗性，耐昇華性，耐磨擦性等，本發明者之研討中若 達耐乾洗性3級以上者，本發明之聚酯纖維中除耐光性之 外，實用上必要之耐水性，耐洗性，耐昇華性，耐磨性等 各種耐牢性於工業上均達一定的水準•因此，耐乾洗性成 爲本發明聚酯繅維全體染色牢固性之指標•因而，此耐牢 性爲3級以上則取得染色物之實用性牢固性亦佳。又*爲 可用於外裝，本發明之染色條件務必爲3〜4級以上，最 好以4級以上之耐光性者。 經濟部中央揉準局貝工消费合作社印裝 (請先閲讀背面之注f項再填窝本頁) 本發明之混用布料染色物之特徵係上述本發明聚酯纈 維與由纖維素纖維，羊毛，絲，拉伸纖維，聚醯胺纖維， 醋酸酯嫌維選出至少一種嫌維與之混合布料染色物者。此 些混用布料中，有關本發明之聚酯織維形態，混用方法， 並無特別限定，公知之方法者即可。例如：做爲混用方法 者以經絲或緯絲之交織織物，兩面兼用織物等編織物， tricot, Russeli等編織物，其他如交撓，合絲，混染亦 可〇 本發明所使用之繊維素繊維並無特別限定，可以棉， 麻等天然繊維，銅銨人造絲，人造絲，高濕模量粘膠纖維 混用布料之聚酯繊維含率並無特別限定，但，爲使嫌維素 織維之觸慼佳，吸濕性，吸水性，制電性佳以2 5〜7 5 %者爲宜。 本紙張又度適用中繭國家棣準（CNS > Α4规格（210X297公釐） -19 -Printed 320655 A7 B7 by the Central Bureau of Industry and Economics of the Ministry of Economic Affairs and Industry Co., Ltd. V. Description of the invention (1) The present invention relates to disperse dyes that can be dyed below 95 ° C, especially when mixed with various dyes. Polyester fiber with excellent color development of dyes (especially black dyes) expected before dyeing after various dyes are adequately and evenly dyed on the fiber. The present invention is more concerned with polyester fibers having excellent washing resistance, light resistance, thermal characteristics, mechanical characteristics, and excellent productivity. The present invention relates to the above-mentioned polyester fiber and cellulose fiber * wool * silk, stretched fiber, polyamide fiber and acetate mixed with at least one of them, has excellent color development, firmness and touch The mixed fabric dyeing with good feeling "The polyester woven fabric and mixed fabric of the present invention are suitable for inner and inner * women's interior and exterior. Recently, the functions of fabric fibers have been diversified, and it is very difficult to satisfy the simple dimension. Therefore, the composite material is expected to be extremely high. Beta polyester is also similar to various fiber materials, such as cellulose fiber, wool, silk, stretched fiber, polyamide fiber, acetate fiber, etc. Compounding. However, in the manufacture of these mixed fabrics, the physical properties of the various components are extremely different, causing various problems. In particular, the problem of the difference in dyeability is extremely significant. ≫ For example, mixed fabrics composed of polyester fibers and fiber cord fibers Dyeing has a huge problem. Disperse dyes β are commonly used for dyeing polyester polyester and direct dyes or reactive dyes are used for dyeing of cellulose fibers. Especially in recent years, the opportunities for using reactive dyes to enhance robustness have increased greatly. When dyeing mixed fabrics composed of polyester and polyester fabrics, due to the different dyeing of each fiber, the two-stage and two-bath dyeing method of each dyeing bath is usually used. Β The paper scale is based on the Chinese National Standard. (CNS) Α4 specification (210X297 mm), -4-(please read the note ^ of item 1 before filling in this page) Order Γ 320655 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Workers and Consumers Cooperatives V. Invention Instructions (^) 1 '1 However, the dyeing temperature of the disperse dyes used for the dyeing of the existing polyester fiber is 1 1; 1 «1 1 0 ° C above 9-generally around 1 3 0 ° C. If it is below 1 1 0 P» "; | 1 3 0 ° c If you want to use this mixed fabric in-bath dyeing, the reactive dye will decompose thermally and cannot be homochromic with polyester fiber. 0 Ϊ ιΙιιίιϊ ^ Inhibition of research first 1 must be thermally decomposed by reactive dyes Note on f Tf 1 when dyeing at a temperature below 95 ° C: 1 I means that the polyester has insufficient dyeability and the chromatographic concentration Presentation of the embryonic method • Therefore, only 1 I is better to use disperse dyes to dye polyester fibers at 1 3 0 ° C and then item Ψ and then% 1 1 Λ to use reactive dyes at temperatures below 9 5 ° C Suzhiwei's dyeing text%. I Method 〇 If two dyes can be dyed in a dyeing bath at a temperature of 9 5 ° C below 1 1 1 degree, the operability aspect is simplified by the low infection color cost Viewing is not 1 1 The method of losing efficiency is 0 1 * I is used in the mixture of the known polyester and polyester fabrics, and its individual order- | The dyeing temperature of the dimension is still very different. Therefore, one section-bath dyeing The progress is still 1 | Very difficult 〇1 1 | In addition, the dyeing of mixed fabrics composed of polyester woven fabric and wool l or silk 1 1 color also has great problems θ The fabric composed of wool l silk has a stable size 1 * Mechanical strength * Increased most In order to reduce the cost, the polyester fabric is mixed with it: 1 The fabric is an ideal consideration. However, when the existing polyester fabric is dyed, the dyeing temperature must be 1 1 to 1 1 0 ° C, and the ft temperature is too high due to wool or when it is overheated. Make it willing to dimension 1 I white body embrittlement 1 not only failed to form the same color with polyester woven dimension * and wool 9 silk. (^ 1 Reduced strength 1 The touch is significantly deteriorated so i this mixed fabric has so far not been able to 1 1 | Dyeing ○ Advanced technology > These dyed mixed fabrics are dyed with polyester navy 1U 1 after interlacing »After weaving and interweaving t and then dyeing silk or wool with acid dyes 1 I ζ But using this method Ϊ When The majority of the color time rights are complicated. Productive Ϊ Costs are all 1 1 This paper scale is applicable to the Chinese National Frame Rate (CNS) A4 ^ grid (210X297mm) A7 B7 5. The invention description (3) is a major problem. Then, the thermal stability of the wool V silk is poor. When dyeing under normal pressure, the dyeability of the first polyester fiber becomes poor, and the dyeing degree of the polyester fiber cannot be dyed. In addition, the dyeing of mixed fabrics consisting of existing polyester woven fabrics and drawn fibers also poses great problems. In the prior art, polyamide fiber is soft, atmospheric and dyeable due to its soft touch. It is a representative of polyurethane fiber. It is used in knitted sportswear for women, swimwear, and socks. However, the polyamide fiber is susceptible to gas and yellowing due to the influence of light. The strength of the finished drawn fiber when the wire is covered is weak and it is easy to cause spinning. It lacks dimensional stability, shape stability and other shortcomings. Therefore, in order to eliminate the above-mentioned shortcomings *, the mixed use of polyester fiber and drawn fiber is carried out. After replacing the polyamide fiber with the polyester fiber, the above problems related to the polyamide fiber can be solved. However, new problems that cause dyeability appear. That is to say, the problem of high dyeing temperature of polyester fabric is caused. In the existing mixed fabric of polyester fiber and polyurethane fiber, in order to dye to a certain concentration, it is necessary to reach a dyeing temperature of at least 110 ° C. Under this temperature condition, the polyurethane fabric is deteriorated by heat and the strength is greatly reduced, yellowing, etc. Major problems arise. In order to prevent the Central Economic Development Bureau of the Ministry of Economic Affairs from printing and printing k--ΊΜ ..--- Π ------ ^ Take-- (please read the notes on back # before filling out this page) f When the heat of urethane is deteriorated and the dyeing under normal pressure is carried out, the dyeability of the polyester fabric in the prior art is poor, and the polyester fiber cannot be dyed to a certain concentration. 'Also, there is a great problem in the dyeing of mixed fabrics composed of polyester fibers and polyamide fibers. 9 Polyamide fibers are dyeable with acid dyes at normal pressure and have the advantages of high strength, but are subject to change. Yellow, thermal stability, poor dimensional stability and other problems exist. Therefore, in order to solve these shortcomings, the mixed use of polyester and polyester is considered. However, after the mixed use of polyester and polyester, it is applicable to the China® household rate (CNS> A4 specification (210X297 mm) 320655 A7 B7 The Ministry of Economic Affairs, Central Bureau of Rubbing and Consumption, Du Yinying. 5. Description of the invention (4) The color temperature is extremely high, therefore, the problems of polyamine coloring and poor touch are generated. In order to examine the thermal stability of polyamide, If it is dyed under normal pressure, it still causes the poor dyeability of the polyester fiber in the prior art, and the polyester is not able to achieve its dyeing degree. Also > Dyeing of mixed fabrics composed of polyester woven fabric and acetate ester fabric There is also a great problem. Acetate is a kind of cellulose, which is a kind of cellulose. The basic molecular structure is similar to that of vitamin A. However, for direct dyes, reactive dyes are not acceptable. Dyeing property, usually, dyeing with disperse dyes under normal pressure. If the high-pressure dyeing exceeding 1 〇o ° C is carried out, this ethyl sugar group is prone to heat deterioration after hydrolysis. * Weiwei appears white and turbid. Especially , This is known Those who form diacetate and valerian • After mixing with acetate fiber, the size stability of the fabric is sought, the strength is improved, and the manufacturing cost is reduced. Therefore, the mixed use with polyester fiber is selected for consideration. However, it is generally considered to be dimensional with polyester. After mixing, the dyeing temperature is too high, causing problems such as whiteness and turbidity of the acetate, and too hard to touch. In order to consider the thermal stability of the acetate, the polyester fiber dyeability in the prior art is dyed at normal pressure. Poor, can not make the density of polyester woven Vida to be dyed. Also, although polyester fibers with disperse dyes that can improve the dyeability are well known, there are still many problems. As a dyeable polyester fiber 1 It is well-known that the copolymer polyester is used as the raw material * The polyester weave which can improve the dyeability of the disperse dyes in the prior art also shows easy dyeability for specific individual dyes> Some dyes of the dyes in which various dyes are mixed are completely Pumping down, some dyes are not pumped down completely, resulting in pumping down--___ The paper size is applicable to the middle circle national sample standard (CMS) A4 specification (210X297mm) fcr — J—; --Η ----- 策 ---- --Subscribe ------, (please read first (Note ^ Item and fill in this page on the back of the booklet) The ""-) printed by the Fonggong Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economy and Economy, ν A7 __B7 V. Description of the invention (5) The rate is not uniform, the mixture of various dyes is mixed Compared with the expected results before and after dyeing, S asked "The problem of producing" especially black dyes is significant, and the advanced technology is easy to dye polyester fabrics. The black hair colorability is very different from the expected before dyeing. Produced * As the easily dyeable polyester, it is known to use copolymerized polyester as the raw material * Among them, it is known to be copolymerized with polyethylene glycol and adipic acid. Beta is copolymerized with polycyclic gas glyoxalase Polyethylene terephthalate fiber * For example: Japanese Patent Laid-Open No. 3-40880, Japanese Patent Laid-open No. 3_17 4076 'Japanese Patent Laid-Open No. 4-41732, Japanese Patent Laid-open No. 4-4 1 7 3 8 etc. As shown. This fiber is a poly-curtain with 6 ~ 10% resetting ratio of polyethylene oxide terephthalate woven to achieve a dyeability of 98 ° C. However, after investigating the characteristics of the fiber, the inventors found that the copolymerization ratio of polyethylene oxide is hot, which results in a reduction in light resistance and dry cleaning resistance. In addition, although it can be dyed at 98 ° C, However, the dyeability at 95 ° C cannot be achieved & that is, the difference in dyeability between 98 ° C and 95 ° C has a great industrial impact. This is because when the dyeing pot for atmospheric pressure is used for dyeing in a boiling state, the dyeing temperature appears to be an indefinite number of 9 5 to 9 8 ° C. * The dyeing temperature is 3 t, and there are major defects in different dyeing groups between batches. If 9 5 ° C is dyeable, this problem will disappear naturally. Furthermore, if the copolymerization ratio of glyphosate becomes high, the whiteness of the raw silk will be low, and the light color system will hardly have the problem of uniform color dyeing. In addition, this copolymer composition easily causes bumping under the vacuum state of its polymerization. In severe cases, the bumping polymer is blocked in the vacuum tube and causes the state of decomposition and release. In addition, polyesters copolymerized with polyethylene glycol of 5 wt% or more are considered to have insufficient spinnability. That is to say, after leaving the spinning mouth, the melted polymer will be used on the paper scale for remote use. The national standard (CNS) A4 specification (2 丨 0X297 gong) ~ flu 1 ^ 1 imi In ^^ 1 ^^ 1 ^^ 1 : .1 s (f read the note on the back Φ $ item and then write this page) Order Γ The Central Business Administration of the Ministry of Economy f Gong Consumer Cooperative Printed 320320 A7 _B7__ 5. Description of the invention (6) The silk is easy to curl when cooled; Causes broken wires, fluff and other problems. Moreover, it is extremely difficult to produce fine denier filaments having a single filament denier of about 1 denier due to poor spinnability. Fine denier is absolutely necessary for soft touch. In the land, the touch of women's outerwear is a necessary requirement, and this kind of copolymer composition makes it difficult to fine denier. The above-mentioned advanced techniques. The dyeable silk in operation has shortcomings in dyeing, fastness, whiteness, polymerizability and spinning. In addition, polyesters copolymerized with polyethylene glycol and hexylene glycol are also known (for example, Japanese Patent Laid-Open No. 6 3-851 11 and Japanese Patent Laid-Open No. 63-235536) * Japanese Patent Laid-Open 63 — 8 5111 Gazette discloses polyether units 0. 5 ~ 10 reset%, dicarboxylic acid units 0. 5 ~ 10 heavy boy% copolymerized with the brewing dimension, its embodiments disclose polyethylene di Polyester fiber copolymerized with 4% by weight of alcohol and 4% by weight of hexanediol. When this fiber is dyed with a single dye of the M quinone series, the highest absorption rate can be achieved. However, because this dye has a small molecular weight (molecular weight 349) in disperse dyes, it is easy to dye on fiber β. Therefore, although this dye can reach a high pumping rate, it does not replace all dyes. It is a high pumping rate. The adipic acid reset / polyethylene glycol weight is small. The mixed dyes of various dyes are not easy to dye, especially the black dye has a bad tendency to develop color. * The molecular density of the non-crystalline portion of the fiber The maximum tangent temperature of the loss tangent determined by the dynamic viscoelasticity measurement shown below (hereinafter referred to as T max [° C]) is higher than that of the high temperature, so it does not show susceptibility to mixed dyes of various dyes. Infectiousness, so universality has a huge problem. The size of this paper is applicable to China's Xingjia rubbing rate (CNS) A4 specification (210X297mm); | --r ---- If Pack 1 — (please read the note f on the back of the Min before filling in this page) Book f bell Printed by the Ministry of Economic Affairs, Central Bureau of Economic Development, Zhengong Consumer Cooperatives 320655 A? B7 V. Description of the invention (7) Japanese Patent Publication No. 6 3_2 3 5 5 3 6 publishes glyoxin 6 reset% and hexylene glycol 5.1 The weight percentage of poly (ethylene terephthalate) copolymerized with this fiber is also the same as that of the same single dye as above. The copolymerization ratio of polyethylene glycol can be achieved, Taax is also high, and it is resistant to dry cleaning. 'Light resistance, whiteness, polymerizability, dyeability with dyes, and spinning properties are all in question. As a method of copolymerizing other polyesters, it is known that polyester fibers copolymerized with two enzymes such as tetramethyl dihydrazine, 1,4-cyclohexanediol, etc. (Japanese Patent Laid-Open No. 58-120815), 2,2-Bis [4- (2-Hydrogenated Ethyl) Phenyl] propane is copolymerized with it, and the polyester is sized by the high-speed spinning method (Japanese Patent Laid-Open No. 5 9-1 9 9 8 1 4 Gazette ) Etc. • However, the polyester fiber obtained by this method can improve the dyeability, and 9 5 ° C is not dyeable. In addition, it is known that after copolymerization of an aliphatic dicarboxylic acid having a carbon number of 8 or more, the polyester fiber is easily dyed by high-speed spinning (Japanese Patent Laid-Open No. 5-9 85 12). This polyester fiber cone does have high dyeability, but the dry cleaning resistance is very poor, and the thermal stress is low. Therefore, the problem of obtaining a bad texture for the fabric occurs. And * _ The well-known method of polyester dyeing and copolymerization of gold hurric acid and acid brewing is easy to dye after spinning (Japanese Patent No. 60-10126) However, the low dimensional strength is the result of the lack of low rupture strength of the fabric Sticky, which could not be used for the purpose of the present invention substantially. Furthermore, the polyester copolymerized with metal sulfate contains a large amount of insoluble matter after the denaturation of the gold sulfate. Therefore, after the spinning time becomes longer, the spinning pocket becomes clogged * spinning It can't be changed. The well-known person has polylong fibers obtained by the common method after copolymerization of 5-thioisophthalate and adipic acid for improving dyeability (Japanese Patent Publication No. 5 1-1 3) Medium «Η 家 梂 准 (CNS) A4 specification (2 丨 0X297mm) ^ n · 1 ·--n ml tuf tv (please read the note # ^ on the back side and fill in this page) Order the Ministry of Economic Affairs The quasi-bureau uncle consumer cooperatives Inmo A7 Β7 V. Description of the invention (8) No. 3529, No. 55-158325, No. 61-239015 Gazette) · However, this polyester weave 5 Insufficient dyeability * and therefore cannot achieve the purpose of the invention. As a dyeing method, an improved method of post-processing method Known such as: carrier dyeing, but, dyeing baths for carrier dyeing use benzine derivatives, aromatic. Aromatic halides, biphenyl derivatives and other high-boiling organic compounds. Therefore, waste liquid treatment results in significant operations Disadvantages and disadvantages • In addition, a well-known person who improves the dyeability, such as a polyester fabric obtained after high-speed spinning, is subjected to a wet heat treatment method at 18 ° C to 300 ° C (Japanese Patent Laid-Open No. 58-13682 5) Bulletin, Japanese Special Publication No. 63-73650). However, although the wet dyeing can improve the dyeability, it lacks even dyeing. Moreover, after a high-speed spinning, the suspected dimension cannot be effectively improved after heat treatment again. The shortcomings of the productivity of high-speed spinning "Such as the above, up to now, it has not been able to disperse dyes at temperatures below 95 ° C, and the mixed dyes of various disperse dyes can have excellent dyeability of polyester fibers. It is a producer in the industry. In addition, the well-known ones have a certain degree of improvement in the polyester fabric, its dry cleaning resistance, light resistance * thermal characteristics, spinning properties and other problems continue to β. The purpose of the present invention is to provide disperse dyes in 9 Below 5 ° C Dyeing is possible, and the mixed dyes of various disperse dyes have excellent dyeability, moreover, dry cleaning resistance, light resistance, thermal characteristics, mechanical properties, and dyeing processing are made of polyester with excellent productivity and its dimensions and vitamins. At least one fabric selected from the group consisting of wool, silk, stretch weave, and polyamine weave has excellent color development, fastness, and touch. It is a mixed fabric dye. This paper size is used in China. National Standards (CNS > M specifications (210X297mm)-* II ^^ 1 ^ I -II-^ _ (please read the remarks on the back before filling in this page) Order 320655 A7 B7 MU Ministry Central Standard Printed by the Bureau-Consumer Cooperative Society V. Description of the invention (9) σ The inventor found that among the polyester fibers of polyethylene terephthalate copolymerized with polyethylene glycol and dicarboxylic acid, especially selected from two After the adipic acid in the carboxylic acid, the copolymerization ratio is set to the limit norm function, and the polymerization pair used to set the T max in a specific range is obtained from the dynamic viscosity measurement shown by the molecular density of the fiber amorphous part. Ethylene phthalate can be solved The subject, and then completed the present invention ", that is, the first feature of the present invention is to set the average molecular weight of 5 0 0 ~ 4000 polyethylene glycol 1. 5 ~ 4, 5 reset%, adipic acid 9 ~ 6 reset% The polyethylene terephthalate after copolymerization is satisfied with the weight of 1.3 S hexylene glycol and the weight% of polyethylene glycol fermentation ^ 6 after * the maximum temperature of loss tangent is 9 0 ~ 10 8 ° C Polyester fiber "The second feature of the present invention is to use the mixed fabric dyeing of the polyester woven and cellulose fibers, and the third feature of the present invention is to use the mixed fabric dyeing of the polyester reel and wool or silk The fourth feature of the present invention is to use the mixed fabric dyeing of the polyester fiber and the stretched fabric, the fifth feature of the present invention is to use the mixed fabric dyeing of the polyester fiber and the polyamide fiber, and the sixth feature of the present invention 5 重量 ％ ， 乙二 The Department of the use of the polyester woven fabric and acetate woven fabric mixed with fabric dyeing constitute the polyester fiber polymer of the present invention an average molecular weight of 5 0 0 ~ 4000 polyethylene glycol 1. 5 ~ 4. 5 wt%, Hexane Alcohol 9 ~ 6 weights after the most% copolymerization, meet the weight of 1.3 3 adipic acid polyethylene glycol reset 6 polyterephthalic acid Those composed of the copolyester glycol. In order to obtain sufficient dyeability at 9 5 ° C, the fastness is polyethylene (please read the ^^ NOTE ^^ item before filling in the nest page) Quasi (CNS > A4 specification (210X297mm) -12-A7 printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs ____B7___ V. Description of invention (10) The copolymerization component of diol and adipic acid is indispensable • Single polyethylene glycol with an average molecular weight of 500 ~ 4000 1. 5 ~ 4. 5 weight percent of copolymerized polyethylene terephthalate, or a single copolymer of 6 ~ 9 weight percent of adipic acid Polyethylene terephthalate does not show full dyeability at 9 5 ° C. The so-called dyeability means that the dye can be fully dyed on the weave, with the performance of a certain degree of dyeing. In the simplest case, the size of the dye evacuation rate in the dye-containing bath shown in the examples described later can be judged * The polyethylene glycol used as a copolymerization component is a highly effective copolymerization component for improving dyeability. When the average molecular weight is insufficient At 500, due to the low molecular weight polyethylene glycol, it is depressurized and left during polymerization under high vacuum. It is difficult to fix the polymer-containing polyethylene glycol. Therefore, the strong stretch properties, dyeability, and thermal properties of the raw yarn cannot be uniform, and the characteristics of the products are different. On the contrary, if the average molecular weight exceeds 4000, the Too much polyethylene glycol with high molecular weight copolymerized in the polymer causes dyeing, dry-cleaning resistance and light fastness to be reduced. Adipic acid as a copolymerization component can cause chaos due to the disordered amorphous structure "Advantages of improving dyeability" In addition to adipic acid (carbon number 6), which is a comonomer that causes chaos in the amorphous structure and improves dyeability, the aliphatic dicarboxylic acid component also has its effect. However, the carbon number is below 5 The aliphatic dicarboxylic acid polymer has a lower stability of the polymer, resulting in a reduction in self-degree. Since the thermal stability is reduced to the number of mole molecules adjacent to the carboxyl group of the methylene group, it creates ® this result. In addition, if The aliphatic dicarboxylic acid component with a carbon number of 7 or more is too chaotic for the amorphous part. Therefore, the fastness, especially the dry-cleaning resistance, is significant and the surface wave scale is not used. The Chinese and Chinese National Standards (CNS) M specifications (210Χ297 Mm) 13-JI J ----- f installed ------ ordered ------, (please read the note f on the back of the pan and then fill in this) 320655, Ministry of Economic Affairs Central Bureau of Industry and Commerce Cooperatives printed A7 B7. 5. The description of invention (11) is reduced. However, in terms of adipic acid, these problems are particularly small. Therefore, adipic acid is selected from a narrow range of Fan Bin and is an excellent copolymerization component. Although * is not conclusive for this reason, it can be inferred from the following. That is, although adipic acid has 4 methylene groups, this length is almost equivalent to the length of the benzene ring of terephthalic acid. Therefore, The polyester suspected to be used in the present invention has a flexible base with disordered amorphous structure, and the degree of disorder stays at the minimum necessary. Therefore, it becomes the closest to polyethylene terephthalate due to thermal characteristics. 5 The modified polyester weave β is used to disperse the dye to ensure sufficient dyeability, fastness, and spinning at 95 ° C. The setting of polyethylene glycol should be 1. 5 ~ 4. 5 % By weight If the amount of polyethylene glycol is less than 1.5% halo%, the dyeability becomes poor. If it exceeds 4.5% by weight, not only the light resistance is deteriorated *, but also the dyeing of the polymer at the polymerization stage is easily caused. In high-vacuum polymerization, bumping and blistering occur remarkably, and it is difficult to achieve fine and denier spinning properties The optimal balance of the problem of dyeability, fastness, polymerizability, and spinnability is 2 to 4% by weight. In addition, the optimal setting of adipic acid varies with the amount of polyethylene glycol, and is generally 9 to 6% reset. If the adipic acid content is less than 6% by weight, the dyeability at 95 ° C will be insufficient. Conversely, if the reset percentage exceeds 9%, the heat resistance is reduced, and only a hard fabric with a poor touch can be obtained. If balanced dyeing and fastness properties and polymerizability are not selected, the copolymerization ratio with good spinnability is not practical. In order to improve the dyeability 1, it is preferable to copolymerize as much polyethylene as possible. However, a large amount of polyethylene glycol tends to greatly reduce the light resistance 'dry-cleaning resistance, and the polymerizability and spinning properties are also reduced. Therefore, after replacing a large amount of polyethylene glycol with an appropriate amount of adipic acid for copolymerization, it can prevent the size of the resistant paper from being applied to the Chinese standard (CNS) A4 specification (2 丨 OX297 public shame) (Please read the note of f first (Further fill in page f) Λ binding 320655 A7 B7 Printed by the Ministry of Economic Affairs, Central Engineering Bureau, Jeonggong Consumer Cooperative Fifth, Invention Description (i2) Lightness, dry-cleaning resistance, polymerizability, and low spinnability. In addition, Not only for single dyes, but also for mixed dyes of various disperse dyes to improve dyeability, the ratio of polyethylene glycol to adipic acid is an extremely important condition. • To obtain this copolymerization composition, it is necessary to satisfy 1. 3S adipic acid The replacement percentage of polyethylene glycol (hereinafter, this value is R value) is S 6. If the R value is less than 1.3, the copolymerization ratio of polyethylene glycol becomes high, and the atmospheric dyeability is achieved. After copolymerization with polyethylene glycol and hexylene glycol, the light resistance and dry cleaning resistance are reduced. Furthermore, when mixed with various dispersing materials and mixed dyes, dyeing results in poor evacuation of various dyes. The color development is different from what was expected before dyeing, especially the black dye Dyeing property becomes worse during down-dyeing. In addition, if the R value is greater than 6, the copolymerization ratio of hexanediol becomes high, and polyethylene glycol that achieves atmospheric dyeability. After copolymerization of hexanediol, heat resistance Low reduction, thermal equipment, etc .: t. The weaving dimension becomes hard during the process, resulting in a poor tactile feel. And, even if the composition of 1.3SR value 6 is met, and the R value becomes larger, the touch of the mixed fabric product obtained becomes harder and Poor, in order to achieve a soft touch · This value is 4 or less, especially 3 or less is the most ideal and, when dyeing with a dye to achieve excellent color development, the ideal R value should be 1. 7 ~ 6, More preferably, it is 1.7 ~ 4 β. In addition, the polybrown fiber used in the present invention contains less than 10% by weight, preferably less than 5% of other glycols, alkyds, etc. to form copolymerizable polyester Ingredients are also available. However, it is necessary to use copolymerization ingredients that do not hinder the degree of change in fastness. Moreover, according to the needs, various additives, such as matting agent, thermal stability (read the f on the back side and then fill in this page) Γ Loading-National Standard Sample Rate (CNS) A4 Specification (210X297mm) for the standard size of the used paper 15 Printed by Beigong Consumer Cooperatives 320655 A7 B7 V. Description of the invention (is) Agent, defoamer, coloring agent, flame retardant, oxidation inhibitor, ultraviolet absorber, infrared absorber, crystal nucleus, fluorescent whitening It can be copolymerized with or mixed with the agent, etc. The polymer constituting the polyester fiber used in the present invention is generally used in the process of manufacturing polyethylene terephthalate, at any stage before the end of polycondensation. Glycol, adipic acid, or monomethyl ester, dimethyl ester, diethyl ester, bis (hydroxyethyl) ester, etc. as lower alkyl esters are added to the reaction system and copolymerized with them. These copolymerization components can be added to the original or dispersed in an appropriate solvent such as ethylene glycol, dissolved or heated. The typical polymerization method is as follows: "Dimethyl terephthalate and dimethyl hexanediol in ethylene glycol, in the presence of catalytic amounts of manganese acetate, calcium acetate, cobalt acetate, etc. 2 0 0 Carry out the transesterification reaction at ~ 2 4 0 ° C to hydroxyethylate both ends of terephthalic acid and adipic enzyme. At this time, the end point of the reaction is based on the appearance of the theoretical methanol. After that, polyethylene glycol and polycondensation catalyst of antimony trioxide are added, and the polymerization is carried out under reduced pressure at 2 6 0 ~ 2 9 0 ° C-the polyester tangent of the present invention must be the loss tangent determined by the dynamic viscosity measurement The highest temperature is 90 ~ 108 ° C. This is still under the fan garden to ensure the excellent dyeability of the present invention. T max is directly proportional to the molecular density of the amorphous part. Therefore, the smaller the value, the smaller the molecular density of the amorphous part, and the larger the gap of the invading dye becomes, the easier it is to enter the dye. The evacuation rate becomes high. When T max is set in this range, the polyester-based dimension of the present invention not only achieves 95 eC dyeability when used as a single dye, but also exhibits excellent performance for various disperse dyes when mixed with various disperse dyes under dyeing. Dyeing paper size ϋΜ ZTE National Standard (CNS > A4 specification (21〇X25 > 7 Gongyu>) JII .----- 71- (please read the note f of ^ e before filling in this Page) Order A7 320655 B7 Fifth, the description of invention (W>), as a result, it can achieve the preset color development before dyeing. When dyeing with a special black dye, its black color development is extremely excellent. This T max series The structural factors of dimensionality, even with copolymers of the same copolymer composition, are due to the spinning conditions, post-processing conditions due to the spinning temperature, spinning speed, stretch ratio, heat treatment temperature, refining conditions, strong weight reduction conditions, dyeing conditions, etc. Different values are shown. Especially the set heat temperature, the value of which changes greatly, so it is extremely important to control the heat set temperature to maintain T max within the above range. If the heat treatment temperature is not carefully considered, According to the invention When co-polymerizing polyester, the heat treatment temperature increases from room temperature to 160 ° C. T max gradually increases, and when it exceeds 160 ° C, it decreases greatly. The proportion of these changes is different due to the different copolymerization composition, so The relationship between the heat treatment temperature and T fflax must be precise. In the present invention, the effect of improving dyeability becomes smaller than 1 0 81 * 9 5 ° C dyeability does not appear. And, the lower the better, the better, easy to make amorphous The part becomes too thick, which causes the dye to enter and fall off easily. That is, the fastness, especially the dry cleaning resistance, wet friction resistance, and washability decrease β. After hardening during heat treatment, the touch Problems such as deterioration and reduced dimensional stability appear one by one. Therefore, although the practicality is 90 to 110 ° C, it is better to use 9 5 to 105 ° C. The melting point of the polyester fiber of the present invention It is 2 3 0 ~ 2 4 5 ° C. When it does not reach 2 3 0 ° C, the polyester fabric is heat-treated during the heat treatment, and the iron is thermally denatured at the use stage, causing changes in physical properties and touch. Melting point exceeds 2 4 5 ° C will reduce the spinnability. The polymer that constitutes the polyester fiber of the present invention is a special composition • Therefore > The spinning temperature of good spinning • If we use the spinning table paper to weave and use it, we will not be able to use it (cnsM na (preferential gift)) π _ (please read K Note ^ 8 first ^> item and fill in this I) Ordered by the Ministry of Economic Affairs, Central Bureau of Bareness, Zhengong Consumer Cooperative Institution 320655 A7 B7 V. Description of the invention (15) The surface temperature must be around 2 5 5 ~ 2 7 0. Therefore, the melting point of the polymer exceeds 2 4 After 5 ° C, the polymer will be melted, so that the temperature of the extruder cannot be set too high, which makes it difficult to maintain the surface temperature of the spinning mouth. The polyester fiber of the present invention can be wound at a speed of 1 5 0 Om / mi η 2 ~ 3.5 times of the unstretched yarn, obtained by the general method of drawing, or the straight-line method of online spinning-drawing engineering. Although a high-speed spinning method with a winding speed above 50 Om / mi η is also necessary, the orientation of the amorphous portion becomes too low (T max is too small), and the fastness is reduced, so it is not good Spinning method. The spinning conditions are not particularly limited, as long as the known conditions can be spun. However, it is necessary to manage the surface temperature of the spinning mouth. In other words, the surface temperature of the spun yarn must be between 2 5 5 and 2 7 0 ° C. If the temperature is less than 2 5 5 ° C, the temperature is not enough, and agglomeration is likely to occur, resulting in a large number of broken filaments. In addition, it can also be spun at 270 ~ 300 ° C. However, there are too many filament windings, broken filaments, and extremely frequent hair removal. Printed bags of Beigong Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs (please read the precautions on the back before filling out this page) In the polyester fiber of the present invention, when dyeing at 95 ° C, the K / S of the darkness is more than 20 . The measurement method of K / S is obtained by the method described in the examples. The dyes that evaluate dyeability have a molecular structure (molecular weight of 518). Therefore, if this dye can achieve high dyeability, any type of disperse dye can ensure high dyeability. This high dyeability means that the K / S is 20 or more. Therefore, when dyeing at 95 ° C, if the K / S is more than 20, it can appear as the same color as the general polyester fiber when dyeing at 130 ° C. This color development is generally up to about 75% evacuation rate. This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) _ 18 _ 320655 Α7 Β7 V. Description of the invention (16) If the dyed substance so dyed shows high fastness, the dry cleaning resistance must be 3 Above grade. The dry-cleaning resistance of the present invention is the contamination of the evaluation fluid. This evaluation method is worn in the examples. In addition, the evaluation items of fastness include water resistance, washing resistance, sublimation resistance, and abrasion resistance. The inventors In the study, if the dry-cleaning resistance level is 3 or higher, in addition to light resistance, the polyester fiber of the present invention has practically necessary water resistance, washing resistance, sublimation resistance, abrasion resistance and other various fastnesses in The industry has reached a certain level. Therefore, dry cleaning resistance has become an indicator of the overall dyeing fastness of the polyester reel of the present invention. Therefore, if the fastness is above 3, the practical fastness of the dyed product is also good. In addition, for use in exteriors, the dyeing conditions of the present invention must be at least 3 to 4 grades, preferably at least 4 grades of light resistance. Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs (please read note f on the back and fill the page). The characteristics of the mixed fabric dyeing of the present invention are the polyester valvi and cellulose fibers of the present invention. Wool, silk, stretched fiber, polyamide fiber, acetate, etc. at least one kind of fabric mixed with dyes is selected. Among these mixed fabrics, the polyester weave form of the present invention and the method of mixing are not particularly limited, and any known method may be used. For example, as a mixed method, the interwoven fabrics of warp or weft yarns, woven fabrics such as tricot and Russeli on both sides, woven fabrics such as tricot, Russeli, etc., such as interlacing, combined yarns, mixed dyeing, etc. There is no particular restriction on the vitamin dimensions. Natural polyester dimensions such as cotton and hemp, copper ammonium rayon, rayon, and high moisture modulus viscose fiber blended fabrics are not particularly limited. However, in order to prevent The texture of the fabric is very good. It is hygroscopic, water-absorbent, and has good electricity production. This paper is again suitable for China Cocoon National Standard (CNS > Α4 specification (210X297mm) -19-
經涛部中央橾準局属工消费合作社印箪 320655 at __B7 五、發明説明（17 ) 本發明所使用羊毛，絲以原有既存者即可。混用布料 中聚酯纖維含有率並無特別限定，但，爲使羊毛觸感佳， 保暖性佳*容稹密度，絲之觸感佳，磨擦音佳以2 5〜 7 5 %者爲宜· 本發明所使用拉伸織維並無特別限定，乾式紡紗或熔 融紡紗之聚胺酯戡維，聚對苯二甲酸丁酯纖維，聚四亞甲 基二醇酯共聚聚對苯二甲酸丁酯繊維所代表之聚酯系弾性 絲等例》拉伸纖維之混用布料中，聚酯纈維含有率以6 0 〜9 8 %爲佳*聚酯縝維含有率超過7 0%時，可抑制伸 縮特性’因此可用於外裝，輕便服裝等等〃又，不足70 %時，因其具伸縮性而可用於內衣，裡地，泳裝等等· 本發明所使用之聚醯胺纖維者，以具醯胺基之尼龍 6 6，尼龍6等，既存者即可。混合布料中聚酯*維之含 有率並無特別限定，但，爲使聚醯胺纖維之觸感佳，以 25〜75%爲宜。 本發明所使用醋酸酯織維以二醋酸酯，三醋酸酯艤維 均可，惟與熱安定性較差之二醋酸酯織維混用後，可更引 發本發明之效果。醑酸酯纖維之染色亦與聚酯纖維相同用 以分散染料，惟，與本發明聚酯織維混用後，可於9 5 t： 以下之溫度下染色，因此，可達觸感佳，染色成本低之加 工。混用布料中聚酯纖維含有率並未特別限制，惟*爲使 醋酸酯嫌維之觸慼佳，鮮明度，光澤性良好，以2 5〜 7 5 %爲宜。 本發明之混用布料染色物除於本發明所規定之外，只 2〇 _ (請先閲讀背面之注f項再填寫本頁) 訂The industrial and consumer cooperatives of the Ministry of Economic Affairs of the Central Ministry of Economic Affairs and Trade Cooperative Printing Seal 320655 at __B7 V. Description of the invention (17) The wool used in the present invention may be the existing ones. The content of polyester fiber in the mixed fabric is not particularly limited, but in order to make the wool feel good, keep warm * Rong Zhen density, silk feel is good, the friction sound is preferably 2 5 ~ 75% The stretch weaving dimension used in the present invention is not particularly limited, and the polyurethane spinning dimension of dry spinning or melt spinning, polybutylene terephthalate fiber, polytetramethylene glycol copolymer polybutylene terephthalate Examples of polyester-based elastic yarns represented by Kangwei》 In the mixed fabric of stretched fiber, the content of polyester valence is preferably 6 0 ~ 98% * When the content of polyester is more than 70%, it can be suppressed 'Stretching characteristics' can therefore be used for exteriors, lightweight clothing, etc., and when it is less than 70%, it can be used for underwear, lining, swimwear, etc. due to its stretchability. The polyamide fiber used in the present invention, to Nylon 6 6, nylon 6, etc. with an amide group, existing ones are sufficient. The content ratio of the polyester * dimension in the mixed fabric is not particularly limited, but in order to make the polyamide fiber feel better, it is preferably 25 to 75%. The acetate weave used in the present invention can be diacetate or triacetate. However, when mixed with the diacetate weave which has poor thermal stability, the effect of the present invention can be more induced. The dyeing of oleate fiber is the same as that of polyester fiber for dispersing dyes, but it can be dyed at a temperature below 95 t after being mixed with the polyester woven fabric of the present invention, so it can achieve a good touch and dye Low-cost processing. The content of polyester fibers in mixed fabrics is not particularly limited, but * 2 to 7 to 5% should be preferred in order to make the acetates feel as good as they are, with sharpness and good gloss. In addition to the provisions of the present invention, the mixed fabric dyeings of the present invention are only 2〇 _ (please read note f on the back and fill in this page)
Λ, I A7 320655 B7 五、發明説明（1〇 (請先聞讀背面之注項再填寫本頁) 要不妨礙本發明之目的範圍內之纖維均可混用之β與少置 羊毛*棉，絲，人造絲，銅銨人造絲，聚醸胺織維，聚丙 烯基織維，醋酸酯纖維，丙烯基纖維等混用之亦無妨。此 時，亦可附加新混用纖維之特有物性者β 本發明之混用布料染色物編成，製織後，經常法精煉 後取得染色β另外，必要時於精煉後染色前依常法處理強 鹼減最。精煉於6 0〜9 8 °C之溫度下進行之。與拉伸纖‘ 維混用時，使緩和之同時精煉可提髙彈性因此更佳》 經濟部中央標準局員工消费合作社印裝 染色不經載體，9 5°C以下之溫度下，本發明聚酯纖 維以分散染料，纖維素纖維以反應染料或直接染料，醋酸 酯纖維以分散染料，羊毛，絲，聚醯胺繊維以酸性染料使 用後染色。本發明發揮最大效果於9 5 °C以下之溫度下， 以一段一浴染色者爲最佳方法，當然二段一浴染色，二段 二浴染色亦可。染色後以公知方法進行皂洗或還原洗淨。 特別是，與拉伸纖維混用中，拉伸纖維爲聚醯胺嫌維時， 進行還原洗淨，完全去除污染聚酯纖錐之分散染料，但， 以提昇布料之耐牢性爲重點。此些方法以公知之方法者即 可。又*有關染色前後形態固定之進行，以1 4 0〜 1 90 °C之溫度，最好以1 60〜1 80 °C下乾燥固定者 爲宜β 本發明之混用布料染色物，經使用特定之聚酯纖維後 ，於95 °c以下可染色。 因此，不會導致與聚酯纖維混用之羊毛，絲之強度低 減|聚醯胺纖維之黃變，聚胺酯繊維之熱惡化*醋酸酯纖 本紙張尺度逋用中國國家橾準（CNS ) A4规格（210X297公釐） 經濟部中央橾準局貝工消費合作社印製 A7 B7 五、發明说明（19 ) 之白濁化等問題。 更且，由於9 5 °C以下可染色，因此所持染料無分解 ，結果染出光鮮亮魔的色彩。 以下，以實施例做本發明之詳細解說。另外，利用以 下方法測定實施例中主要之測定值。 (1)損失正切最髙溫度（T max)Λ, I A7 320655 B7 V. Description of the invention (1〇 (please read the notes on the back and then fill in this page) To prevent the fibers within the scope of the purpose of the invention from being mixed with β and less wool * cotton, Silk, rayon, copper ammonium rayon, polyamine woven fabric, polypropylene-based woven fabric, acetate fiber, acrylic-based fiber, etc. can be mixed. At this time, the unique physical properties of the new mixed fiber can also be added. The mixed fabric dyeing of the invention is made up, after weaving, the dyeing β is obtained after regular refining. In addition, if necessary, the strong alkali is processed according to the usual method before dyeing after refining. The refining is carried out at a temperature of 6 0 ~ 98 ° .When mixed with the drawn fiber 'dimension, it can be refined while refining can improve the high elasticity, so it is better. "The printing and dyeing of the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs without the carrier, the temperature of the present invention is below 95 ° C. Ester fibers are disperse dyes, cellulose fibers are reactive dyes or direct dyes, acetate fibers are disperse dyes, wool, silk, and polyamidine are dyed with acid dyes. The maximum effect of the present invention is below 95 ° C Under temperature One-bath and one-bath dyeing is the best method. Of course, two-bath and one-bath dyeing is also possible. Two-bath and two-bath dyeing is also possible. After dyeing, it can be washed with soap or reduced by a known method. When the stretch fiber is polyacrylamide, it is reduced and washed to completely remove the disperse dye that contaminates the polyester cone. However, the focus is on improving the durability of the fabric. Those methods can be known methods. * Regarding the fixing of the shape before and after dyeing, it should be dried at a temperature of 1 4 0 ~ 1 90 ° C, preferably at 1 60 ~ 1 80 ° C. Β The mixed fabric dyeing of the present invention is specified after use. After polyester fiber, it can be dyed below 95 ° C. Therefore, it does not cause the wool mixed with polyester fiber, the strength of the silk is reduced | the yellowing of the polyamide fiber, the heat deterioration of the polyurethane fiber * acetate fiber paper The standard uses the Chinese National Standard (CNS) A4 specification (210X297mm). The Ministry of Economic Affairs, Central Bureau of Standardization, Beigong Consumer Cooperative printed A7 B7. 5. The description of the invention (19) White turbidity and other issues. Moreover, due to 9 5 Can be dyed below ° C, so hold Material without decomposition, result dyed light bright magic colors. Hereinafter, embodiments detailed explanation of the present invention. Further, measured by mainly the measured values in the examples the following methods. (1) the loss tangent most Gao temperature (T max)
Olyenteck公司製使用rheo vibron於乾燥空氣中 ，測定周波數1 1 OHz，昇溫速度5°C/分下，測定各 溫度中損失正切（t a η 5 )及動態弾性率。由其結果求 出出損失正切一溫度曲線，求得此曲線上損失正切最.髙溫 度之Traax(°C) •於昇溫速度5 °C / mi η，測定周波 數110Hz下求取之· (2 )融點 利用精工電子公司製D S C，於2 0°C/m i η之昇 溫速度下1 00mj?/m i η之氮氣流下測定之。其中以 熔融之最髙值做爲融點 (3)聚酯纖維之抽空率，深色度（K/S)測定（染色 性之評定） 利用聚酯纖維單位針織質料做爲樣品，以含溫水之 Scoreroll 400 2g/L，7 0°C下精煉處理2 0分鐘，於轉 鼓乾燥器下乾燥之，再以拉幅針進行1 8 0 1，3 0秒之 本紙張又度逋用中國國家揉準（CNS)A4规格（210X297公嫠）_ 22 _ ----^-----「裝------訂------C" (請先閲讀背面之注^^項再填寫本f) 320655 A7 __B7 五、發明説明（2〇 ) 熱安定。抽空率由4 0°c〜9 5。(：舁溫後，再評定維持1 小時後的抽空率《染料使用kayal〇ri聚酯藍—3RSF (曰本化學製藥公司製：分子量5 1 8 ; Colour-index blue-257) ’於6% 0Wf.浴比1 : 5 0下染色*分散劑 以Nik San Salt 70〇〇(日華化學公司製）〇 . 5 g/L .使用後’加入醋0_ 25mj?/L與醋酸鈉lg/L，調 整p Η爲5。 抽空率由分光計求出染料原液之吸光度A，染色後之 染液之吸光度a，代入下式求取。吸光度以採用該染料最 大吸收波長580mm之值β 抽空率=(A— a)/Axl〇〇 (%) 以K / S評定染取濃度深淺代表之深色度·此值，測 定出染色後樣本布料之分光反射率R *由以下所示之 kubelka-Munk 式求出。此值愈大則深度效果愈大，亦即 ，發色性良好之意》R以採用該染料最大吸收波長5 8 〇 η τη之值 K/S = (1-R)2/2R (4 )黑色亮度L值 以聚酯繊維單位針織質料爲樣本’同針織質料3條重 曼，利用Siiga試驗材所製之染料電腦（SM — 4 )測定 本紙張尺度逋用中國«家揉準（CNS ) A4规格（210X297公釐） (請先閱讀背面之注項再填寫本頁 裝 訂 經濟部中夹標準局貝工消费合作社印製 經濟部中央橾準局貝工消费合作社印裝 320655 A7 B7 五、發明説明（21 ) 之。 (5 )染色牢囿性 耐乾洗性以J I S — L — 0860，耐光性以J I S —L — 0842，耐洗性以J I S — L — 0844爲基準 .進行測之。測其聚酯纖維之耐牢性時，以（3)之方法， 利用染色後單位針織質料5 0 Omg進行評定。 (6 )伸縮恢復率 將調整成寬2. 5cm，長16c m之試驗片使固定 軸距離於1 0 cm下張力試驗器固定之，描出延展率.8 0 舛之延展恢復曲線，讀取殘留伸展（L>)，由下式求出 〇其中L爲8 0 %。 延展恢復率（L — L>) X100/L 實施例1 對苯二甲酸乙二酯20重置份，乙二醇714. 7重 置份，己二酸二甲酯（以下略爲DMA) 1. 52重量份 ，做爲酯交換催化劑，置入醋酸錳4水合鹽0. 01重量 份，由150 °C至240 °C漸漸加熱，3小時間留出甲醇 進行酯交換反應。同時加入平均分子量1 0 0 0之聚乙二 醇（以下略爲PEG1000) 0. 44重置份，做爲安 定劑，三甲基磷酸_0. 016重量份及聚合催化劑之三 本紙張尺度逋用中國圃家梂準（CNsTA4洗格（210X297公釐）_以_ ----^----—Λ裝------tr------ " * (請先閲讀ί之注$項再填寫本3r) 經濟部中央揉準局貝工消费合作社印褽 A7 B7 五、發明説明（22) 氣化銻〇. 0 1重量份，消光劑之二氧化鈦0. 1重量份 ，以5 0分鐘進行前聚合<•更且，渐淅減壓，最後於0 . 5To r r275 °C下反應進行2小時過40分鐘，取得 7SP/C=0_ 80之改質聚酯之木片形態》此取得之 聚合物組成經NMR之分析後爲p EG 1 0 0 0，2w t %，D M A 7重量％者。 將取得之聚合物木片於1 3 0°C下1 0 0 L/m i η 之氮氣流下側，2 0小時乾燥後，以具3 6個囲截面之孔 狀紡口，紡紗溫度270°C，紡紗速度1 5 OOm/mi η下製成末延展絲•再將取得之未延展絲經熱滾壓8 0 t： ，熱壓160 延展倍率2. 8倍，延展速度800m /mi η下進行延撓，取得75且尼爾（d) /36燈絲 (f)之延展絲。強度爲5.lg/d，伸展度爲31% * Taiax爲 1 0 3°C 。 本發明之聚酯纖維之染色性可以常法（將未延展絲先 卷後再延展之方法，所諝精梳法）經被紡紗之聚對苯二甲 酸酯纖維（T max: 1 3 6°C)之藍色分散染料後與 1 3 0°C，6 0分鐘染色性比較後評定之。此時，以K/ S做比較，可比較其直接色之濃度故較佳。以kay a Ion聚 酯藍一 3RSF (日本化學製薬公司製）做爲染料，以6 %owf ，浴比1:50做染色，經常法後聚對苯二甲酸 乙酯繅維之1 3 0Ϊ，6 0分鏟染色中，K/S爲2 1 . 4。於本實施例取得之聚酯纖維9 5 °C * 6 0分鐘之Κ/ S爲2 1 . 8 ·此結果顯示本發明聚酯繊維9 5 °C，6 0 本紙張尺度適用中國國家標準（CNS ) A4规格（2I0X297公釐） (請先閲讀背面之注f項再填寫本頁) 訂 320655 鯉濟部中央橾率局貝工消費合作社印裝 A7 B7 五、發明説明（23 ) 分鐘之染色性與常法下聚對苯二甲酸乙酯纖維之1 3 0°C ，6 0分鐘之染色性相周。 染色後單位針織質料之耐乾洗性未出現染色物退色現 象，液污染爲4級。另外，耐光性（4級）*乾，濕磨擦 耐性（5級），耐水性（5級），耐洗性（5級），昇華 .耐性（4級）均爲優良者。 實施例2〜4 與實施例1同法下使共聚組成做各種變化後，進行聚 合，紡紗賁驗。其結果列於表1。各種狀態下均顯示良好 之染色性，耐牢性，諸物性。 實施例5 將聚乙二醇之分子置改爲2000，3000， 4 0 0 0後，返復操作實施例1。取得之聚酯織維性質大 致與實施例1相同。K/S爲21. 5〜21. 7*並無 太大差異。另外，耐乾洗性，耐光性均爲4級。 比較例1〜8 製成具表1共聚組成之聚酯織維後*進行各種評定> 由任一不符合本申請發明之共聚組成者，發現染色性或耐 牢性或其他特性均爲不良，且不符實用性。又》比較例2 與5當中偶有於聚合物聚合時之高真空狀態下出現突沸現 象，且有鍋內容物轉入真空管之現象出現*嚴重突沸時則 本紙張尺度適用中國鬮家揉牟（CNS ) Α4规格（210Χ297公t ) id----ίι— ——|訂|-----1 (婧先聞讀背*之注$項再填寫本頁) 320655 A7 __B7__ 五、發明説明（24 ) 造成無法清除裝置之分解。取得之聚合物亦呈黃變。另外 ，比較例2，5 * 6於紡紗中，紡口下出現絲彎曲，造成 斷絲，起毛等等。此種現象即使變換各種條件也無濟於補 1.--:-----(裝--------訂------「 (請先閲讀背面之注$項再填寫本頁) 經濟部中央裸準局貞工消費合作社印裝 本紙張又度適用中國躅家揉準（CNS > Α4规格（210X297公釐） -27 - 經濟部中央梂準局I工消费合作社印装 320655 A7 'B7 五、發明说明（25 ) 第1表 mm mmcsA% m 強度 (β/d) (¾) m CC) Tmx OC) 触率 a) K/S ]級） (級） PEGIOOO DUA 1 2 7 3.5 5.1 31 237 103 75 21.8 4 4 2 2 8 4.0 4.6 34 239 】04 76 21.1 4 4 3 3 7 2.3 5.0 35 238 103 78 21.8 4 4 4 4 7 1.8 5.0 40 238 100 87 21.8 3-4 3 mm 1 0 10 - 4.6 33 240 m 54 17.5 5 4 2 10 0 0.0 4.3 4B m Θ4 m 21.7 2 1 3 5 0 - 4.B 33 249 111 B1 18.1 3 4 4 4 4 1.0 4.8 35 243 109 B5 19.5 3-4 4 5 6.5 0 0.0 4.6 35 253 109 63 19.7 3 3 6 S 5 0.8 4.3 33 243 明 86 21.8 2 2-3 7 4.5 3.5 0.8 4.5 33 246 111 31 18.2 2-3 4 8 3.5 4.5 1.3 4.6 35 243 110 64 19.0 3-4 4 —I,-----r 裝—----—訂叫-----τ (請先閱讀背面之注wi-項再填寫本頁) 本紙法尺度逍用中商辑家梂準（CNS ) A4規格（210X 公釐） A7 B7 320655 五、發明説明（26) 實施例6 將實施例3，4之單位針織質料以Sumi Carone bl-ack S-BF (分散染料，住友化學公司製）5%〇wi ’ pH爲6，浴比1 : 50，於染色助劑，Nik san salt 7 000 (日華化學公司製）之存在下，9 5°C下進行染色》 .取得染色物之L值（亮度）各爲15. 5，15. 3,充 份出現黑色濃度。 爲取得比較，與比較例4，7，8之單位針織質料相 同條件下，染色後，L值各爲18. 8*18. 3， 19. 5,均爲白茶染色物。黑色染料常於4OOnm， 500ητη，580nm附近具吸收最大峰之3種染料與 之混合者^實施例7中，測定染色後染液（殘液）之吸收 光譜後，幾乎未殘留此3個吸收最髙點。惟，與比較例相 較下，進行殘液比色後，均於580nm之吸收各9〇% 以上消失，而4 0 0 ητη，5 0 Ο ητη之吸收爲殘留原液 3 0%以上·此乃本實施例聚酯纖維於配合染料下染色時 ，對於各染料均具有良好之染料抽空性，而不符本#日月範 圍內者，則各染料無法出現高抽空性之雜亂結果出胃β 實施例7 將與實施例1相同製成之7 5 d/7 2 f之聚 於經絲，緯絲上以7 5 d/4 4 f之銅銨人造絲，製成平 織物·此平織物經常法做精煉，絲光處理。絲光A3gjD：[： 爲常溫下，7 5%之氫氧化鈉水溶液中進行β #& 本紙乐尺度逋用中國國家橾準（CNS ) Α4规格（21 ΟΧ297公釐） ill----Af-----—訂J-----Λ. (請先閲讀背φ之注f項再填寫本頁) 經濟部中央標準局貝工消费合作社印策 經濟部中央梂举局貝工消費合作杜印装 Α7 Β7 五、發明说明（27) 3 0秒1 8 0°C中和’水洗之預處理後，無載體經分散染 料與反應染料進行一段一浴染色。分散染料以Kayaron poly ester blue-BRSF(日本化學製藥公司製），反應染 料以Drimarenblue-X-SGN(Sand公司製）。分散劑用 以Disper TL(明成化學公司製）lg/L，硫酸納50 • g/L與碳酸鈉15g/L加入後，pH調製11之水溶 液中加入染料做成染液。於澳度2%owf »浴比1: 50下，9 5°C進行1個小時之染色。染色後，以gran up P (三洋化成公司製）1 g/L於浴比1 : 50，80 °〇下做皂洗1 0分鐘·染色後，依常法進行·精煉。 取得之染色物爲染色均勻，觸慼亦佳。K/S爲 21. 5。耐乾洗性爲4級，，光性爲4級者》 實施例8 以實施例3與4之聚酯_維與實施例7同法進行一段 一浴染色。取得染色物爲染色均勻者，觸感佳，K/S爲 21. 7與22. 0者》又，耐牢性面之耐乾洗性爲3〜 4級，耐光性爲4級者。 比較例9 以比較例4之聚酯繊維，重複實施例7之操作。取得 之染色物爲不均勻者。此乃所持之聚酯纖維之染色性低， 而造成聚酯繊維之發色性偏低之故。 表紙張尺皮逋用中醺鬮家梂丰（CNS ) Α4说格（210X297公釐） (請先聞讀背面之注f項再填寫本頁) 裝 订 A7 B7 320655 五、發明説明（28 ) 比較例1 0 以比較例6之聚酯纖維，重復實施例7之操作。取得 之染色物雖爲均勻者，惟，耐乾洗性，耐光性僅爲2〜3 級·實用上不理想。且，爲7 5 d/7 2 f之細旦尼爾繊 維之故，極易發生起毛現象β 實施例9 將PEG 1000，4重置％，0!^1八7重置％共 聚後之聚對苯二甲酸乙酯纖維以旋轉式做熱處理後取得高 容稹加工絲。加工條件爲熱盤溫度1 9 5 °C·，加工撓數 3400次/ m，輸送率爲一 0. 2%。接著，使取得之 加工絲成1 5 0旦尼爾之雙絲與羊毛4 8號單絲交編後， 製成表面聚酯，裏面羊毛之兩面兼用之交編織物。聚酯織 維混用率爲45重量％，編成條件爲20計（gauge )， 鍋經爲2 0英寸。取得之編織物依常法進行染色。染料以 使用分散染料之 Dianix black BGFS ( 2 0 0 %品，Di» star Japan 公司製）* 酸性染料之 kayaron b 1 ack BGL (日本化學製薬公闻製）》 濃度各爲7%〇wf ，於弱酸性分散劑之存在下， 95°C下進行一段一浴染色。染色後，鹼灰lg/L，非 離子洗淨劑0. 5g/L之弱鹸浴下進行20分 鐘皂洗》取得染色物之L值（亮度）爲11. 8之優良品 者。又*亮度愈低值則黑染愈明顯。染色物之耐乾洗性， 耐光性均爲4級· 本紙張纖用中國國家麟（CNS)娜（職酬）_ 31 _ (請先閲讀f之注項再填寫本I} 裝 訂Olyenteck company uses rheo vibron in dry air, measuring the frequency of 1 1 OHz, heating rate 5 ° C / min, measuring the loss tangent (t a η 5) and the dynamic performance rate at each temperature. From this result, a temperature curve of loss tangent is obtained, and the loss tangent on this curve is obtained. The Traax (° C) of the highest temperature is obtained at a heating rate of 5 ° C / mi η and the measured number of cycles is 110 Hz. 2) The melting point was measured using a DSC manufactured by Seiko Instruments Inc. under a nitrogen flow of 100 mJ · / mi η at a heating rate of 20 ° C / mi η. Among them, the highest melting value is taken as the melting point (3) of the evacuation rate of polyester fiber, the determination of the darkness (K / S) (evaluation of dyeability), using the polyester fiber unit knitted material as the sample, and the temperature Scoreroll 400 2g / L of water, refining treatment at 70 ° C for 20 minutes, drying under a tumble dryer, and then using a tenter pin for 1 801 1, 30 seconds of the original paper and using it in China National Rubbing Standard (CNS) A4 specification (210X297 public daughter) _ 22 _ ---- ^ ----- "installed ------ ordered ------ C " (please read the note on the back first ^^ Fill in this section f) 320655 A7 __B7 V. Description of the invention (2〇) Thermal stability. The evacuation rate is from 4 0 ° C to 95. (: After the temperature is evaluated, the evacuation rate after 1 hour of maintenance is evaluated. Use kayal〇ri polyester blue-3RSF (manufactured by Yoshimoto Chemical Pharmaceutical Co., Ltd .: molecular weight 5 1 8; Colour-index blue-257) 'Dyeing at 6% 0Wf. Bath ratio 1: 5 0 * Dispersant with Nik San Salt 70〇〇 (manufactured by Nichiwa Chemical Co.) 0.5 g / L. After use, add vinegar 0_25mj? / L and sodium acetate lg / L, adjust p Η to 5. The evacuation rate is determined by spectrometer. Absorbance A, absorbance a of dyeing liquor after dyeing, substitute Obtained by the following formula. The absorbance is based on the value of the dye's maximum absorption wavelength of 580 mm. Β evacuation rate = (A-a) / Axl〇〇 (%) K / S is used to evaluate the darkness of the dyeing concentration. This value, The spectral reflectance R of the sample fabric after dyeing is determined by the kubelka-Munk formula shown below. The larger the value, the greater the depth effect, that is, the meaning of good color development. R uses this dye to maximize Absorption wavelength 5 8 〇η τη value K / S = (1-R) 2 / 2R (4) Black brightness L value is based on the polyester knitting unit knitting material as the sample 'same as the knitting material 3 strips, using Siiga test material The dye computer (SM-4) produced by this company is used to determine the paper size. It uses the Chinese «Home Roll Standard (CNS) A4 specification (210X297mm) (Please read the notes on the back and then fill out this page to bind the Ministry of Economic Affairs, China Standard Standards Bureau Printed by Beigong Consumer Cooperatives Printed by Ministry of Economics Central Bureau of Economics and Traders Beigong Consumer Cooperatives 320655 A7 B7 5. Description of invention (21). (5) Dyeing fastness to dry-cleaning resistance to JIS — L — 0860 JIS —L — 0842, wash resistance is measured based on JIS — L — 0844. Test it For the durability of polyester fiber, the method of (3) is used to evaluate the unit knitted material 50 Omg after dyeing. (6) The stretch recovery rate will be adjusted to a width of 2.5 cm and a length of 16 cm. The test piece is fixed The axis distance is fixed at a tensile tester at 10 cm, and the elongation rate is .80. The recovery curve of the extension is read, and the residual extension (L >) is read, which is obtained by the following formula. Where L is 80%. Extended recovery rate (L — L>) X100 / L Example 1 20 replacement parts of ethylene terephthalate, ethylene glycol 714.7 replacement parts, dimethyl adipate (hereinafter abbreviated as DMA) 1 . 52 parts by weight, as a transesterification catalyst, placed 0.01 parts by weight of manganese acetate 4 hydrate salt, gradually heated from 150 ° C to 240 ° C, leaving methanol for 3 hours to transesterify. At the same time, add polyethylene glycol with an average molecular weight of 1000 (hereinafter abbreviated as PEG1000) 0.44 replacement parts, as a stabilizer, trimethylphosphoric acid _0.016 parts by weight and the three paper standards of the polymerization catalyst. Use the Chinese nursery standard (CNsTA4 wash grid (210X297mm) _ 以 _ ---- ^ ----— Λ 装 ------ tr ------ " * (please read first Note 3 of ί and fill in this 3r) The Ministry of Economic Affairs Central Bureau of Accreditation and Printing Co., Ltd. Beigong Cooperative Printing Co., Ltd. A7 B7 5. Description of the invention (22) Gasified antimony 〇. 0 1 parts by weight, matting agent titanium dioxide 0.1 parts by weight ， Pre-polymerization in 50 minutes < • Furthermore, gradually depressurize, and finally the reaction was carried out at 0.5 Torr 275 ° C for 2 hours over 40 minutes, obtained 7SP / C = 0_ 80 modified polyester Morphology of wood chips》 The polymer composition obtained is analyzed by NMR as p EG 1 0 0 0, 2 wt%, DMA 7% by weight. The obtained polymer wood chips are 1 0 0 L / at 1 3 0 ° C At the lower side of the nitrogen flow of mi η, after 20 hours of drying, it is made into a final stretched yarn with a hole shape of 36 holes, a spinning temperature of 270 ° C, and a spinning speed of 1 5 OOm / mi η. Roll the obtained unstretched wire by hot rolling 8 0 t ：, Hot pressing 160, the stretching ratio is 2.8 times, the stretching speed is 800m / mi η, and the stretching wire is obtained with 75 denier (d) / 36 filament (f). The strength is 5.lg / d, stretch Degree is 31% * Taiax is 103 ° C. The dyeability of the polyester fiber of the present invention can be aggregated by spinning by the usual method (the method of rolling the unstretched yarn first and then stretching it, the combing method). The blue disperse dye of terephthalate fiber (T max: 1 3 6 ° C) is evaluated after comparing with the dyeability at 130 ° C for 60 minutes. At this time, K / S is used for comparison. The concentration of the direct color can be compared, so it is better. Kay a Ion Polyester Blue-3RSF (manufactured by Nippon Chemical Co., Ltd.) is used as the dye, dyed at 6% owf and a bath ratio of 1:50, and polyparaphenylene is often used after the process. In the reeling of ethyl dicarboxylate, 1 3 0Ϊ, 60-point shovel dyeing, K / S is 2 1.4. The polyester fiber obtained in this example is 95 ° C * 60 minutes K / S is 2 1.8 · The result shows that the polyester dimension of the present invention is 95 ° C, 60. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (2I0X297mm) (please read note f on the back and fill in this page) Order 320655 Central Department of Lili Ministry HIGHLAND consumer cooperative printing equipment A7 B7 V. Description of the Invention (23) minutes and the dyeing method under ordinary polyethylene terephthalate fibers 1 3 0 ° C, 6 0 minutes circumferential dyeing phase. After dyeing, the dry-cleaning resistance of the unit knitted material did not show the fading of the dyeing, and the liquid contamination was grade 4. In addition, light resistance (level 4) * dry, wet friction resistance (level 5), water resistance (level 5), washing resistance (level 5), sublimation. Resistance (level 4) are all excellent. Examples 2 to 4 After making various changes to the copolymerization composition in the same manner as in Example 1, polymerization and spinning inspection were conducted. The results are shown in Table 1. It shows good dyeability, fastness, and various physical properties in various states. Example 5 After changing the molecular weight of polyethylene glycol to 2000, 3000, and 400, go back to Example 1. The properties of the obtained polyester fabric were substantially the same as in Example 1. K / S is 21. 5 ~ 21. 7 * There is not much difference. In addition, both dry-cleaning resistance and light resistance are grade 4. Comparative Examples 1 to 8 After making polyester woven fabrics having the copolymerization composition of Table 1 * Various evaluations were conducted> From any copolymerization composition that does not conform to the invention of the present application, it is found that the dyeability, fastness, or other characteristics are poor , And does not meet practicality. "Comparative examples 2 and 5 have occasional bumping under high vacuum during polymer polymerization, and there is a phenomenon that the contents of the pot are transferred into the vacuum tube. * In the case of severe bumping, the paper size is applicable to China's home-made rubbing ( CNS) Α4 specification (210Χ297 公 t) id ---- ίι— —— | Subscribe | ----- 1 (Jing first read and read the back * Note $ item and then fill in this page) 320655 A7 __B7__ V. Description of the invention (24) The decomposition of the device cannot be removed. The obtained polymer also turned yellow. In addition, in Comparative Example 2, 5 * 6, the yarn was bent under the spun yarn, resulting in broken yarn, fluff, etc. This phenomenon is not helpful even if you change various conditions. 1.-: ----- (install -------- order -------- "(please read the note $ item on the back before (Fill in this page) The printed paper of the Ministry of Economic Affairs Central Naked Quasi-Zhonggong Consumer Cooperative is again applicable to China's family members (CNS > Α4 specifications (210X297 mm) -27-Ministry of Economic Affairs Central Engagement Bureau I Industrial and Consumer Cooperative Printing 320655 A7 'B7 V. Description of the invention (25) Table 1 mm mmcsA% m Strength (β / d) (¾) m CC) Tmx OC) Touch a) K / S] level) (level) PEGIOOO DUA 1 2 7 3.5 5.1 31 237 103 75 21.8 4 4 2 2 8 4.0 4.6 34 239】 04 76 21.1 4 4 3 3 7 2.3 5.0 35 238 103 78 21.8 4 4 4 4 7 1.8 5.0 40 238 100 87 21.8 3-4 3 mm 1 0 10-4.6 33 240 m 54 17.5 5 4 2 10 0 0.0 4.3 4B m Θ4 m 21.7 2 1 3 5 0-4.B 33 249 111 B1 18.1 3 4 4 4 4 1.0 4.8 35 243 109 B5 19.5 3-4 4 5 6.5 0 0.0 4.6 35 253 109 63 19.7 3 3 6 S 5 0.8 4.3 33 243 Ming 86 21.8 2 2-3 7 4.5 3.5 0.8 4.5 33 246 111 31 18.2 2-3 4 8 3.5 4.5 1.3 4.6 35 243 110 64 19.0 3-4 4 —I, ----- r outfit —----— order ----- τ (please read the back first Note wi-item and then fill out this page) The standard of this paper method is easy to use Chinese business edition standard (CNS) A4 specification (210X mm) A7 B7 320655 5. Description of invention (26) Example 6 Example 3, 4 The unit knitted material is Sumi Carone bl-ack S-BF (disperse dye, manufactured by Sumitomo Chemical Co., Ltd.) 5% 〇wi 'pH is 6, the bath ratio is 1:50, in the dyeing aid, Nik san salt 7 000 (Japan) In the presence of a chemical company), dyeing is carried out at 95 ° C. The L value (brightness) of the dyed product is 15.5 and 15.3, respectively, and the black density appears sufficiently. For comparison, it is compared with Comparative Example 4. ， 7，8 unit knitted material under the same condition, after dyeing, the L value is 18. 8 * 18. 3, 19. 5, are white tea dyes. Black dyes are often mixed at 4OOnm, 500ητη, and 580nm with three absorption peaks ^ In Example 7, after measuring the absorption spectrum of the dye liquor (residual liquid) after dyeing, the three absorption peaks are almost not left. point. However, compared with the comparative example, after the comparison of the residual liquid, the absorption at 580nm each disappeared by more than 90%, and the absorption of 4 0 0 ητη, 5 0 Ο ητη was more than 30% of the residual stock solution. This is In this embodiment, when the polyester fiber is dyed with a compound dye, each dye has good dye evacuation, and if it does not conform to the range of # 日月, then the dyes cannot have a messy result of high evacuation. 7 The 7 5 d / 7 2 f made in the same way as in Example 1 is gathered on the warp and the weft is 7 5 d / 4 4 f copper ammonium rayon to make a flat fabric Do refining and mercerizing. Mercerized A3gjD: [: at room temperature, in a 7 5% aqueous solution of sodium hydroxide β # & This paper music standard uses the Chinese National Standard (CNS) A4 specifications (21 ΟΧ297 mm) ill ---- Af- ----— Subscribe J ----- Λ. (Please read note f on the back of φ before filling in this page) Beigong Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs, Incheon, Ministry of Economy, Central Bureau of Economic Affairs, Beigong Consumer Cooperation Du Printed Α7 Β7 V. Description of the invention (27) 3 0 seconds 1 8 0 ° C After neutralizing 'water washing pretreatment, the carrier-free dyeing with a disperse dye and a reactive dye is carried out in one bath. The disperse dye was Kayaron poly ester blue-BRSF (manufactured by Nippon Chemical & Pharmaceutical Co., Ltd.), and the reaction dye was Drimarenblue-X-SGN (manufactured by Sand). The dispersant was added with Disper TL (manufactured by Mingcheng Chemical Co., Ltd.) lg / L, sodium sulfate 50 • g / L and sodium carbonate 15g / L, and the dye was added to the aqueous solution with a pH of 11 to make the dyeing solution. Dye at 95 ° C for 1 hour at 2% owf »bath ratio 1:50. After dyeing, 1 g / L of gran up P (manufactured by Sanyo Chemical Co., Ltd.) was used for soaping at a bath ratio of 1:50 at 80 ° C for 10 minutes. After dyeing, refining was performed according to the usual method. The dyed material obtained is dyed evenly and has good touch. K / S is 21.5. The dry-cleaning resistance is grade 4, and the gloss is grade 4. "Example 8 The polyester_dimension of Examples 3 and 4 was dyed in the same way as Example 7 in a one-bath one-stage process. If the dyed product is evenly dyed, the touch is good, and the K / S is 21. 7 and 22.0. Furthermore, the dry-cleaning resistance of the fastness surface is 3 to 4 grades, and the light resistance is 4 grades. Comparative Example 9 The operation of Example 7 was repeated using the polyester dimensions of Comparative Example 4. The obtained dyeing is uneven. This is due to the low dyeability of the held polyester fiber, which causes the low color development of the polyester fiber. The table paper ruler is used in the middle of the family home (CNS) Α4 said grid (210X297 mm) (please read the note f on the back and then fill in this page) Binder A7 B7 320655 V. Description of the invention (28) Comparative Example 10 Using the polyester fiber of Comparative Example 6, the operation of Example 7 was repeated. Although the obtained dyeings are uniform, the dry cleaning resistance and light resistance are only grades 2 to 3, which is not practically ideal. Moreover, because of the fine denier of 7 5 d / 7 2 f, the fluffing phenomenon is very likely to occur. Example 9 The PEG 1000, 4 reset%, 0! ^ 1 8 7 reset% polymerization after copolymerization Ethylene terephthalate fiber is processed by rotary heat treatment to obtain high-capacity processed silk. The processing conditions were a hot plate temperature of 195 ° C ·, a processing deflection number of 3400 times / m, and a conveyance rate of 0.2%. Next, the obtained processed yarn was interwoven with a 150-denier twin yarn and a wool No. 4 8 monofilament to make a surface polyester, in which an interwoven fabric of both sides of the wool was used. The blending rate of polyester fabric is 45% by weight, the knitting condition is 20 gauge, and the pan warp is 20 inches. The obtained knitted fabric is dyed according to the usual method. Dianix black BGFS using disperse dyes (200% product, manufactured by Di »star Japan) * acid dyes kayaron b 1 ack BGL (manufactured by Japan Chemical Co., Ltd.) concentration is 7% 〇wf, in In the presence of a weakly acidic dispersant, one-bath dyeing is performed at 95 ° C. After dyeing, alkali ash lg / L, non-ionic detergent 0.5g / L in a weak emperor bath for 20 minutes, soap washing. Obtain the L value (brightness) of the dyed product of 11.8. And * the lower the brightness value, the more obvious the black staining. The dry-cleaning resistance and light-fastness of the dyed products are all 4 grades. This paper fiber is made by China National Liner (CNS) Na (remuneration) _ 31 _ (please read the note of f before filling in this I} binding
趣濟部中央梯準局貝工消费合作社印II 經濟部中央棣準局貝工消費合作社印裝 A7 __B7__ 五、發明说明（29 ) 實施例1 0〜1 2 與實施例9同法下變化各種共聚組成，進行聚合，紡 絲實驗。其結果示於表2 ·均共聚物良好染色性，耐牢性 佳。 比較例1 1〜1 6 製成具表2之共聚組成之聚酯纖維後進行各種評定。 不符本申請發明之共聚組成者，其染色性，耐牢性均出現 問題點。 本紙張尺度適用中國國家梂準（CNS ) Α4规格（210 X 297公釐广 (请先閲讀I之注項再填窝本頁)Printed by the Ministry of Economic Affairs, Central Bureau of Standardization, Beigong Consumer Cooperatives II Printed by the Ministry of Economic Affairs, Central Bureau of Standards, Beigong Consumer Cooperatives A7 __B7__ V. Description of the Invention (29) Example 1 0 ~ 1 2 Variations with Example 9 under the same method Copolymerization composition, polymerization, spinning experiment. The results are shown in Table 2. The homopolymer has good dyeability and good fastness. Comparative Example 1 1 to 16 Polyester fibers having the copolymerization composition of Table 2 were prepared and subjected to various evaluations. Those copolymers that do not conform to the invention of the present application have problems with their dyeability and fastness. The size of this paper is applicable to China National Standards (CNS) Α4 specifications (210 X 297 mm wide (please read the I item before filling in this page)
520655 經濟部中央標準局貝工消費合作社印裂 Α7 Β7 五、發明説明（30 ) 第2表 實施例 組（重量％) R值 L值 耐光性 (級） 耐乾洗性 (級） PEG1000 DMA 9 4 7 1.8 11.8 3-4 4 10 2 8 4. 0 11. 9 4 4 11 3 7 2. 3 11. 9 4 4 . 12 2 7 3. 5 11.8 4 4 比較例 11 0 10 - 13. 0 5 4 12 10 0 0.0 11. 7 3 1 13 5 0 0.0 13. 1 3 4 14 4 4 1.0 12.3 3 4 15 6.5 0 0.0 12.4 3 3 16 6 5 0.8 11.8 2-3 2 14ΊΙΙΊ----Γ 裝-----—訂叫-----^ (請先聞讀背面之注$項再填窝本I ) 本紙張尺度適用中國國家檬準（CNS ) Μ規格（210X297公釐） 經濟部中央標準局貝工消费合作社印褽 320655 A7 B7 五、發明説明（31 ) 實施例1 3 將PEG1 〇〇〇，4重量％ * DMA7重置％共聚 之聚對苯二甲酸乙酯繅維（75d/72i)附與300 T/m之扭轉後，附滾筒糊後，使成經絲’於緯絲上以絹 絲（21d/2f)製成平織物》 染料以使用分散染料之DUnix black BGFS( 2 0 0 %品 ，Di Star Japan 公司製），酸性染料之 Kayaron black BGL(日本化學製藥公司製 漉度各爲7%〇w f於弱酸性，分散劑之存在下’ 9 5乞下進行一段一浴染色。染色後，鹼灰1 g/L ’非 離子洗淨劑0. 5g/L之弱鹼浴，70°C下，進行音洗 20分鐘。取得之染色物Ϊ值（亮度）爲11· 1之優良 品者》另外，亮度愈低，黑染愈明顯•染色物之耐乾洗性 ，耐光性均爲4級.。染色物具獨特之絲之良好鬅感，爲一 佳品。 比較例1 7 除使用聚對苯二甲酸乙酯織維外，重複實施例1 3之 操作。L值爲15. 3,聚酯繅維僅染出淺色。染色溫度 提昇至130 °C進行染色後，L值爲11. 5 9惟’絲之 獨特觸感全無，成堅硬質感° 實施例1 4 PEG1000，4重邏：％’DMA7重量％共聚後 本紙張尺度適用中囲國家揉準（CNS > A4洗格（210X297公釐） (請先聞讀背而之注$項再填寫本頁) - , Lrl i I-»_ I - - 1 1-- 1^1 _ —I— - - n i i Λ 320655 Α7 Β7 M涛部中央標準局—工消費合作社印製 五、發明説明（32) ，以三角截面之聚對苯二甲酸乙顧織維（5 0 d/3 6 f )與2 1 0旦尼爾之聚胺酯系拉伸纖維Leuca (旭化成工 業製）製成經編質料。此時規格爲28G，環線長度常磨 可染紗爲1 080mm/480圈，拉伸纖維爲1 1 2 mm/4 8 0圈，打入配合密度爲9 0圈/英寸。又，聚 酯嫌維之混合率設定爲75. 5%» 所得布料以9 0°C，2分鐘緩和精煉後，1 6 0°C下 乾燦固定 1 分鐘。於 Dianix black BG-FS(Distar Japan公司製）8%〇wf ，染色助劑之Nika San Sal t 1 200 0.5g /文之存在下，以醋酸調整PH爲6，浴 比1:30，95 °C下進行60分鐘染色 取得染色製品之黑色亮度L值爲1 2 . 3，爲充份發 色。伸縮恢復率爲95. 3%，耐洗性爲5級，耐光性爲 4級。另外，柔軟.度佳，具相當優異之觸感珍 實施例15〜17 欒換共聚組成，重複實施例1 4操作β均爲良好的發 色性’耐牢性，伸縮恢復特性•又，具柔軟佳，優異的觸 感。 實施例1 8 將聚乙二醇之分子置改爲2000，4000，重複 實施例1 4之操作·取得之染色製品之性質與實施、例1 4 幾乎相同。其黑色亮度L值均爲12. 3〜12. 4，發 本紙張尺度適用中爾國家樣準< 〇jS >八4规格（210乂297公釐） (請先W讀f之注意事項再填寫本頁) 裝 訂 -35 - A7 B7 五、發明说明（33 ) 色充足&伸縮恢復率爲約9 5% »耐洗性爲5級*耐光性 爲4。又，柔軟度佳，具相當優異的觸慼》 比較例1 8 爲了比較，以常法製成與實施例1 4相同之被紡紗之 .聚對苯二甲酸乙酯與leuca之經編質料，於95°C下進 行60分鐘染色。取得之染色製品之L值爲18. 3，黑 色發色不足》又，於1 3 0°C下染色6 0分鐘後L值爲 12. 4出現充份之黑色發色，惟，破裂強度降爲原布料 之2/3。另外，伸展恢復率降至65%ι 比較例1 9〜2 1 更換共聚組成，將各種染色製品製成與實施例1 4相 同者（表3)。不符本發明之範圍者，其染色性，耐牢性 均爲不足。又，比較例2 0之觸感爲堅硬者。 I-I,-----f裝—— (請先閲讀背*之注$項再填寫本頁) 訂 Λ 經濟部中夬標準局属工消费合作社印製 本紙張尺度適用中國國家標準（CNS > Α4规格（210X297公釐） 爾c:: 320655 A7 B7 鍵濟部中央揉準局負工消費合作社印製 五、發明説明（34) 第3表 實施例 組(重置％) El L值 伸縮回復率 00 (級） 耐錄 (級） PEG1000 DMA 14 4 7 L8 12.3 95.3 5 4 15 2 9 4.5 12.1 96.2 5 4-5 16 3 7 2.3 12.4 95.5 5 4-5 17 2 6 3.0 12.6 94.2 5 4-5 賺例 18 6.5 0 00 1350 94.8 3 2-3 19 0 5 — 16.3 95.3 4 5 20 0 10 — 12.5 &0.3 2-3 5 21 10 0 0.0 12.1 95.6 3 2 (請先閎讀f之注意事項再填寫本頁) 訂 本紙張尺度適用中國®家梂準（CNS > Μ规格（2】OX2W公嫠} 3^0655 經濟部中央橾率局I工消费合作社印製 A7 B7 五、發明説明（35) 實施例1 9 將PEG 100 0，4重量％，DMA7重置％之 共聚物聚對苯二甲酸乙酯纖維（7 5 d/7 2 f )附與 300T/m之回轉，附滾筒糊後’成經紗’於緯紗上使 用5 0 d/9 6 ί之尼龍6 6爲3條雙紗者製成平織物 做爲染料者以使用分散染料之kayaron聚酷藍一3 R S F，酸性染料之 Nylosan BUe-N-GFL(Sand 公司製 )〇 濃度各爲5%〇wf ’於弱酸性，分散劑之存在下’ 9 5°C下做一段一浴染色。染色後，於鹼灰.1 g/L ’非 離子洗淨劑0. 5/L之弱鹸浴下，7〇°C下進行皂洗 20分鐘》所取得染色物之K/S爲21· 0之優良品者 。染色物之耐乾洗性，耐光性均爲4級。觸感柔軟’與尼 龍6 6同色性亦佳.· 實施例2 0 除使用PEG 1 000 * 2重置％ DMA重量％共 聚之聚對苯二甲酸乙酯纖維（75 d/72 f )之外，重 復實施例1 9之操作。取得染色物之K/S爲2 1 . 0， 耐乾洗性爲4級，耐光性均爲5級*觸感柔軟，與尼龍 6 6同色性亦佳。 比較例2 2 1 3 0°C下染色，使用聚對苯二甲酸乙酯嫌維（7 5 本紙張尺度逋用中國國家樣準（CNS ) A4规格（210X297公釐）_收_ (請先聞讀背面之注^^項再填疼本頁) C.装 訂 經潦部中央揉準局貝工消费合作社印製 320655 A7 B7 五、發明説明（36 ) d/72 ί )除外，重復實施例1 9之操作。取得染色物 之K/S雖爲21. 5,而染色物之發色遲鈍，觸慼之柔 軟度亦欠佳。 實施例2 1 將PEG 1000，4重量％，DMA7重置％共 聚之聚對苯二甲酸乙酯纖維（7 5. d/7 2 f )附與 3 0 0 T/m之回轉，附滾筒糊後使成經紗，於緯紗上以 二醋酸酯纖維（1 〇 〇 d)製成平縷物。 做爲染料者使用分散染料之kayaron polyester bl-ue-3RSF’ 分散染料之 kayaron Fast Blue-RD200(日本 化學製藥公司製）。 濃度各爲5%owf ，於弱酸性，分散劑之存在下， 9 0 °C下進行一段一浴染色。染色後，於鹼灰lg/L， 非離子洗淨劑0. 5 g/L之弱鹸浴下7 0 °C下進行皂洗 20分鐘·取得之染色物K/S爲20. 1之優良品者。 染色物之耐乾洗性，耐光性均爲4級。觸感之柔軟性佳， 鮮明度亦佳。 * 實施例2 2 除使用PEG1 000，2重置％，DMA8重童％ 共聚之聚對苯二甲酸乙酯織維（74d/72 f)之外， 重m賁施例21之操作。取得染色物之κ/s爲20. 2 *耐乾洗性爲4級，耐光性均爲5級。觸感柔軟性佳，鮮 本紙張又度適用中國國家梂率（CNS ) A4规格（21〇><297公釐）_ I.·--7“-----Ϊ 戋-- (請先閲讀f之注意事項再填寫本頁)520655 Ministry of Economic Affairs, Central Standards Bureau, Beigong Consumer Cooperatives, printing and cracking Α7 Β7 V. Description of invention (30) Table 2 Example group (weight%) R value L value Light resistance (level) Dry cleaning resistance (level) PEG1000 DMA 9 4 7 1.8 11.8 3-4 4 10 2 8 4. 0 11. 9 4 4 11 3 7 2. 3 11. 9 4 4. 12 2 7 3. 5 11.8 4 4 Comparative example 11 0 10-13. 0 5 4 12 10 0 0.0 11. 7 3 1 13 5 0 0.0 13. 1 3 4 14 4 4 1.0 12.3 3 4 15 6.5 0 0.0 12.4 3 3 16 6 5 0.8 11.8 2-3 2 14ΊΙΙΊ ---- Γ loading-- ---— booking ----- ^ (please read the $ item on the back and fill the nest I) The paper size is applicable to China National Standard (CNS) Μ specification (210X297mm) Central Standard of the Ministry of Economic Affairs Bureau Beigong Consumer Cooperative Printed 320655 A7 B7 V. Description of the invention (31) Example 1 3 Removal of polyethylene terephthalate (75d / 72i) with PEG1, 4% by weight * DMA7 reset% copolymerized ) After twisting with 300 T / m, and after gluing with rollers, the warp yarns are made into weave silk fabrics (21d / 2f) on the weft yarns. Dyes use DUnix black BGFS (2 0 0% product, manufactured by Di Star Japan), Kayaron black BGL (Japanese chemical and pharmaceutical company ’s production degree is 7% each ww in weak acidity, in the presence of dispersing agent, under the presence of dispersing agent '9 5 beg for a one-bath dyeing. After dyeing, alkali gray 1 g / L' Weak alkaline bath of non-ionic detergent 0.5g / L, sound wash at 70 ° C for 20 minutes. The dyed product with a Ϊ value (brightness) of 11.1 is a good product. In addition, the lower the brightness, The black dyeing is more obvious. The dry-cleaning resistance and light resistance of the dyed material are all 4 grades. The dyed material has a unique silk feel and is a good product. Comparative Example 1 7 Except for the use of polyethylene terephthalate woven fabric In addition, the operation of Example 1 3 is repeated. The L value is 15.3, and the polyester reeling only dyes light colors. After the dyeing temperature is raised to 130 ° C for dyeing, the L value is 11. 5 9 but the uniqueness of the silk No touch, hard texture ° Example 1 4 PEG1000, 4 weights:% 'DMA7% by weight After the copolymerization, the paper size is suitable for China National Standard (CNS> A4 wash grid (210X297mm) (please first Read and read the note $ item and then fill out this page)-, Lrl i I-»_ I--1 1-- 1 ^ 1 _ —I—--nii Λ 320655 Α7 Β7 M Tao Ministry Central Standard -Printed by the Industrial and Consumer Cooperatives V. Description of the invention (32). Polyethylene terephthalate with a triangular cross-section (50 d / 3 6 f) and 2 10 denier polyurethane-based stretch fiber Leuca (Manufactured by Asahi Kasei Corporation) Warp-knitted materials. At this time, the specification is 28G, the length of the loop wire is often worn, the dyeable yarn is 1 080mm / 480 turns, the drawn fiber is 1 1 2 mm / 4 8 0 turns, and the drive-in density is 90 turns / in. In addition, the blending ratio of polyester is set at 75.5% »The resulting fabric is gently refined at 90 ° C for 2 minutes, and dried at 160 ° C for 1 minute. In the presence of Dianix black BG-FS (manufactured by Distar Japan) 8% 〇wf, dyeing aid Nika San Salt 1 200 0.5g / article, pH was adjusted to 6 with acetic acid, bath ratio 1:30, 95 ° Carry out dyeing under C for 60 minutes to obtain the black brightness L value of the dyed product of 12.3, which is sufficient color development. The recovery rate of expansion and contraction is 95.3%, the washing resistance is level 5, and the light resistance is level 4. In addition, the softness is good, the touch is very good. Examples 15 to 17 Luan-chang copolymerization composition, repeating Example 14 4 operations are all good color development 'fastness, stretch recovery characteristics Good softness and excellent touch. Example 18 The molecular weight of polyethylene glycol was changed to 2000 and 4000, and the operation of Example 14 was repeated. The properties of the dyed product obtained were almost the same as those of Example 1 and Example 4. The black brightness L value is 12. 3 ~ 12.4, the paper size of the copy is applicable to the national standard of the Seoul National Standard < 〇jS > 8 4 specifications (210 297 mm) (please read the precautions of f first (Fill in this page again) Binding-35-A7 B7 V. Description of the invention (33) The color is sufficient & the recovery rate of expansion and contraction is about 9 5% »Washing resistance is level 5 * light resistance is 4. In addition, the softness is excellent, and it has a quite excellent touch. "Comparative Example 18 For comparison, the same warp-knitted material of polyethylene terephthalate and leuca was prepared by the same method as that of Example 14. And stain at 95 ° C for 60 minutes. The L value of the obtained dyed product is 18.3, and the black hair color is insufficient. Furthermore, the L value is 12.4 after dyeing at 130 ° C for 60 minutes. However, sufficient black hair color appears, but the breaking strength decreases It is 2/3 of the original fabric. In addition, the stretch recovery rate decreased to 65%. Comparative Example 1 9 to 2 1 The copolymer composition was replaced, and various dyed products were made the same as in Example 14 (Table 3). Those that do not conform to the scope of the present invention have insufficient dyeability and fastness. In addition, Comparative Example 20 has a hard feeling. II, ----- f installed—— (please read the note * item on the back * and then fill out this page) Order Λ Printed by the China Consumer Standards Cooperatives of the Ministry of Economic Affairs, the paper standard is applicable to the Chinese National Standard (CNS > Α4 specification (210X297 mm) er c :: 320655 A7 B7 Key Ministry of Central Development and Customs Bureau printed by the consumer labor cooperative V. Invention description (34) Table 3 Example group (reset%) El L value expansion and contraction Response rate 00 (level) Nagre (level) PEG1000 DMA 14 4 7 L8 12.3 95.3 5 4 15 2 9 4.5 12.1 96.2 5 4-5 16 3 7 2.3 12.4 95.5 5 4-5 17 2 6 3.0 12.6 94.2 5 4- 5 Earning example 18 6.5 0 00 1350 94.8 3 2-3 19 0 5 — 16.3 95.3 4 5 20 0 10 — 12.5 & 0.3 2-3 5 21 10 0 0.0 12.1 95.6 3 2 (Please read the precautions of f first (Fill in this page again) The size of the paper for this edition is applicable to the China® Family Design (CNS > Μ specifications (2) OX2W public sister) 3 ^ 0655 Printed by the Ministry of Economic Affairs Central Bureau of Industry and Commerce Cooperative A7 B7 V. Description of invention ( 35) Example 1 9 Copolymer polyethylene terephthalate fiber (7 5 d / 7 2 f) with PEG 100 0,4% by weight and DMA 7% by weight is attached to a 300T / m rotation with roller paste After the 'warp yarn' is used on the weft yarn, the nylon 6 6 of 50 d / 9 6 ί is made of three double yarns to make a flat fabric. As the dye, the kayaron polycool blue 3 RSF using disperse dyes, acid dyes Nylosan BUe-N-GFL (manufactured by Sand Corporation) 〇Concentration is 5% each ww 'weakly acidic, in the presence of dispersing agent' 9 one-bath dyeing at 5 ° C. After dyeing, in alkali gray. 1 g / L 'Non-ionic detergent 0.5 / L in a weak embarrassing bath, soaping at 70 ° C for 20 minutes. The K / S of the dyed product is 21.0. Dry-cleaning resistance and light resistance are all grade 4. Soft touch 'is also the same color as nylon 6 6. Example 2 0 Except the use of PEG 1 000 * 2 reset% DMA weight% copolymerized polyethylene terephthalate Except for the ester fiber (75 d / 72 f), the operation of Example 19 was repeated. The K / S of the dyed product was 2 1.0, the dry-cleaning resistance was level 4, and the light resistance was level 5 * soft touch , Same color with nylon 6 6. Comparative example 2 2 1 3 Dyeing at 0 ° C, using polyethylene terephthalate (7 5 paper size, using China National Standards (CNS) A4 specifications ( 210X297mm) _Receiving_ ( Please read the note ^^ on the back and fill in this page) C. The binding is printed on 320655 A7 B7 by the Beigong Consumer Cooperative of the Central Kneading Bureau of the Ministry of Commerce. 5. Except for the invention description (36) d / 72 ί), The operation of Example 19 was repeated. Although the K / S of the dyed product was 21.5, the color of the dyed product was dull and the softness of the touch was not good. Example 2 1 PEG 1000, 4% by weight, DMA7 reset% copolymerized polyethylene terephthalate fiber (7 5. d / 7 2 f) was attached to 3 0 0 T / m rotation, with roller paste Afterwards, the warp yarns were made into flat strands with diacetate fibers (100 d) on the weft yarns. As the dyestuff, use kayaron polyester bl-ue-3RSF ’of disperse dyes. Kayaron Fast Blue-RD200 of disperse dyes (manufactured by Japan Chemical Pharmaceutical Co., Ltd.). Each concentration is 5% owf, in the presence of weakly acidic, dispersing agent, at 90 ° C for a period of one bath dyeing. 1。 After dyeing, in alkali ash lg / L, non-ionic detergent 0.5 g / L in a weak embarrassing bath at 70 ° C for 20 minutes. The obtained dye K / S is 20.1 Product owner. The dry-cleaning resistance and light resistance of the dyed products are all 4 grades. The softness of touch is good, and the sharpness is also good. * Example 2 2 The operation of Example 21 was repeated except for the use of polyethylene terephthalate (74d / 72 f) copolymerized with PEG1000, 2% reset, DMA8% heavy copolymer. The kappa / s of the dyed product is 20. 2 * The dry-cleaning resistance is 4 grades, and the light resistance is 5 grades. The soft touch is good, and the fresh paper is again suitable for the Chinese National Frame Rate (CNS) A4 specification (21〇 < 297mm) _ I. · --7 "----- Ϊ 戋-( (Please read the notes of f before filling out this page)
τη； · · 參. 3^0655 A7 B7 經濟部中央樣率局貝工消費合作社印製 五、發明説明（37) 明度亦佳》 比較例2 3 1 3 0°C下染色，用以聚對苯二甲酸乙酯繊維（7 5 d/7 2 f )除外，重覆實施例2 1之操作"取得染色物 .之K/S雖爲21. 5,而染色物之發色卻遲鈍，其觸感 .之柔軟度亦欠佳。 本發明之聚酯織維分散染料於9 5 °C以下之溫度下可 取得染成實用染色之漉度，而且，染色物之染色耐牢性例 如耐乾洗性，耐光性，熱特性均達先行技術之聚酯嫌維染 色物之水準，纖維之機械性質亦不低於實質特性· 本發明之聚酯纖維之各種分散染料被配合之配合染料 染色中，組成配合染料之各染料之抽空中未有差數出現， 市販配合染料下可出現預先期待之色彩，濃度如經黑色染 色用染料後可成黑染。 本發明之聚酯纖維與織維素纖維，羊毛，縣，聚醴胺 織維，拉伸纖維與之混用之複合布料可於寅質上混用纖維 之一般實技染色溫度下將混用纖維原料全部染色。因此， 可提供對於不損及缺乏熱安定性纖維特性之聚酯纖維混用 布料染色物之極髙生產性之方法。 -llsf - _ (請先閲讀背面之注f項再填寫本頁) 策 訂 Λ 本紙張尺度適用中繭國家標率（CNS ) Α4見格（210Χ297公釐） -40 -τη; · Ref. 3 ^ 0655 A7 B7 Printed by the Beigong Consumer Cooperative of the Central Sample Bureau of the Ministry of Economy V. Invention description (37) Brightness is also good "Comparative Example 2 3 1 3 3 0 3 ° C dyeing, used to gather Except for ethyl phthalate (7 5 d / 7 2 f), repeat the operation of Example 2 1 " Obtain the dye. Although the K / S is 21. 5, the color of the dye is dull, Its touch. The softness is also not good. The polyester woven disperse dyes of the present invention can achieve practical dyeing at a temperature below 95 ° C, and the dyeing fastness of the dyed products, such as dry-cleaning resistance, light resistance and thermal properties, are all advanced The level of technical polyester dyes and the mechanical properties of the fibers are not lower than the essential characteristics. In the polyester fiber of the present invention, various disperse dyes are dyed by compound dyes. If there is a difference, the expected color will appear under the dyestuffs on the market, and the concentration can be black dyed if the dye is used for black dyeing. The polyester fiber and woven cellulose fiber of the present invention, wool, county, polyacrylamide woven fabric, stretch fiber and the composite fabric mixed therewith can be used at the general practical dyeing temperature of the upper quality mixed fiber dyeing. Therefore, it is possible to provide a highly productive method for dyeing mixed fabrics of polyester fibers that do not impair and lack the characteristics of thermally stable fibers. -llsf-_ (Please read note f on the back and then fill in this page) Planning Λ This paper scale is applicable to China National Cocoon National Standard Rate (CNS) Α4 see grid (210Χ297mm) -40-