TW394789B - Process for the demetallation of residual oils - Google Patents

Process for the demetallation of residual oils Download PDF

Info

Publication number: TW394789B
Authority: TW; Taiwan
Prior art keywords: oil; aluminum; please; gold; catalyst
Prior art date: 1995-02-24

Application number

TW085101764A

Other languages

English (en)

Chinese (zh)

Inventor

Jesper Bartholdy

Original Assignee

Haldor Topsoe As

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-02-24

Filing date

1996-02-13

Publication date

2000-06-21

1996-02-13 Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As

2000-06-21 Application granted granted Critical

2000-06-21 Publication of TW394789B publication Critical patent/TW394789B/zh

Links

238000000034 method Methods 0.000 title claims abstract description 19
239000003921 oil Substances 0.000 title abstract description 17
238000007324 demetalation reaction Methods 0.000 title abstract 2
229910052782 aluminium Inorganic materials 0.000 claims description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
230000002079 cooperative effect Effects 0.000 claims description 7
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 7
239000010931 gold Substances 0.000 claims description 7
229910052737 gold Inorganic materials 0.000 claims description 7
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
229910052750 molybdenum Inorganic materials 0.000 claims description 5
239000011733 molybdenum Substances 0.000 claims description 5
238000009835 boiling Methods 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 4
239000001301 oxygen Substances 0.000 claims 4
229910052760 oxygen Inorganic materials 0.000 claims 4
YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 2
239000007789 gas Substances 0.000 claims 2
239000004576 sand Substances 0.000 claims 2
239000009728 shiwei Substances 0.000 claims 2
239000004575 stone Substances 0.000 claims 2
239000003054 catalyst Substances 0.000 abstract description 41
229910052751 metal Inorganic materials 0.000 abstract description 18
239000002184 metal Substances 0.000 abstract description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
239000010779 crude oil Substances 0.000 abstract description 7
239000010457 zeolite Substances 0.000 abstract description 7
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 6
229910052739 hydrogen Inorganic materials 0.000 abstract description 6
239000001257 hydrogen Substances 0.000 abstract description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 5
229910021536 Zeolite Inorganic materials 0.000 abstract description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 5
235000012239 silicon dioxide Nutrition 0.000 abstract description 4
239000000377 silicon dioxide Substances 0.000 abstract description 4
239000011149 active material Substances 0.000 abstract description 2
150000001875 compounds Chemical class 0.000 abstract description 2
230000000737 periodic effect Effects 0.000 abstract description 2
229910052681 coesite Inorganic materials 0.000 abstract 1
229910052593 corundum Inorganic materials 0.000 abstract 1
229910052906 cristobalite Inorganic materials 0.000 abstract 1
239000003208 petroleum Substances 0.000 abstract 1
229910052682 stishovite Inorganic materials 0.000 abstract 1
229910052905 tridymite Inorganic materials 0.000 abstract 1
229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
150000002739 metals Chemical class 0.000 description 9
238000011049 filling Methods 0.000 description 7
229910052759 nickel Inorganic materials 0.000 description 6
229910001182 Mo alloy Inorganic materials 0.000 description 3
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 3
238000005470 impregnation Methods 0.000 description 3
150000002736 metal compounds Chemical class 0.000 description 3
229910052720 vanadium Inorganic materials 0.000 description 3
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
238000001354 calcination Methods 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
239000000463 material Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000010426 asphalt Substances 0.000 description 1
XUFUCDNVOXXQQC-UHFFFAOYSA-L azane;hydroxy-(hydroxy(dioxo)molybdenio)oxy-dioxomolybdenum Chemical compound N.N.O[Mo](=O)(=O)O[Mo](O)(=O)=O XUFUCDNVOXXQQC-UHFFFAOYSA-L 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
230000009194 climbing Effects 0.000 description 1
USZLJXMWEKEFIN-UHFFFAOYSA-L cobalt(2+) dinitrite hexahydrate Chemical compound O.O.O.O.O.O.N(=O)[O-].[Co+2].N(=O)[O-] USZLJXMWEKEFIN-UHFFFAOYSA-L 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000003292 glue Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
JCCNYMKQOSZNPW-UHFFFAOYSA-N loratadine Chemical compound C1CN(C(=O)OCC)CCC1=C1C2=NC=CC=C2CCC2=CC(Cl)=CC=C21 JCCNYMKQOSZNPW-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000011017 operating method Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
238000012856 packing Methods 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

TW085101764A 1995-02-24 1996-02-13 Process for the demetallation of residual oils TW394789B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DK020095A DK20095A (da)	1995-02-24	1995-02-24	Fremgangsmåde til afmetallisering af residualolie

Publications (1)

Publication Number	Publication Date
TW394789B true TW394789B (en)	2000-06-21

Family

ID=8090881

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW085101764A TW394789B (en)	1995-02-24	1996-02-13	Process for the demetallation of residual oils

Country Status (10)

Country	Link
EP (1)	EP0728832A1 (da)
JP (1)	JPH08245967A (da)
AU (1)	AU4567896A (da)
BR (1)	BR9600797A (da)
CA (1)	CA2170219A1 (da)
DK (1)	DK20095A (da)
NO (1)	NO960739L (da)
NZ (1)	NZ286000A (da)
TW (1)	TW394789B (da)
ZA (1)	ZA961475B (da)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6520286B1 (en)	1996-09-30	2003-02-18	Silentor Holding A/S	Silencer and a method of operating a vehicle
US6332510B1 (en)	1996-09-30	2001-12-25	Silentor Holding A/S	Gas flow silencer
CN103801378B (zh) *	2012-11-13	2016-01-20	中国石油化工股份有限公司	含分子筛和氧化铝的加氢催化剂
CN103801380B (zh) *	2012-11-13	2015-12-16	中国石油化工股份有限公司	含分子筛的加氢催化剂组合物的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0109064A3 (en) *	1982-11-16	1985-06-19	W.R. Grace & Co.	Hydrocarbon conversion catalysts
JPS59206048A (ja) *	1983-05-10	1984-11-21	Shokubai Kasei Kogyo Kk	重質油水素化処理触媒
US4789654A (en) *	1985-03-29	1988-12-06	Catalysts & Chemicals Industries Co., Ltd.	Hydrotreating catalysts
US5183561A (en) *	1990-01-25	1993-02-02	Mobil Oil Corp.	Demetallation of hydrocarbon feedstocks with a synthetic mesoporous crystalline material
JP2547115B2 (ja) *	1990-03-30	1996-10-23	財団法人石油産業活性化センター	炭化水素油用水素化処理触媒組成物ならびにそれを用いる水素化処理方法

1995
- 1995-02-24 DK DK020095A patent/DK20095A/da not_active Application Discontinuation
1996
- 1996-02-12 EP EP96101974A patent/EP0728832A1/en not_active Withdrawn
- 1996-02-13 TW TW085101764A patent/TW394789B/zh not_active IP Right Cessation
- 1996-02-16 NZ NZ286000A patent/NZ286000A/en unknown
- 1996-02-22 AU AU45678/96A patent/AU4567896A/en not_active Abandoned
- 1996-02-23 NO NO960739A patent/NO960739L/no not_active Application Discontinuation
- 1996-02-23 CA CA002170219A patent/CA2170219A1/en not_active Abandoned
- 1996-02-23 JP JP8036414A patent/JPH08245967A/ja not_active Withdrawn
- 1996-02-23 BR BR9600797A patent/BR9600797A/pt active Search and Examination
- 1996-02-23 ZA ZA961475A patent/ZA961475B/xx unknown

Also Published As

Publication number	Publication date
EP0728832A1 (en)	1996-08-28
AU4567896A (en)	1996-09-05
JPH08245967A (ja)	1996-09-24
NZ286000A (en)	1997-02-24
NO960739D0 (no)	1996-02-23
ZA961475B (en)	1996-11-27
CA2170219A1 (en)	1996-08-25
NO960739L (no)	1996-08-26
DK20095A (da)	1996-10-04
BR9600797A (pt)	1997-12-23

Legal Events

Date	Code	Title	Description
2000-11-10	GD4A	Issue of patent certificate for granted invention patent
2003-03-21	MM4A	Annulment or lapse of patent due to non-payment of fees

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