TW399092B - Layered catalyst system for lube oil hydroconversion - Google Patents

Layered catalyst system for lube oil hydroconversion Download PDF

Info

Publication number: TW399092B
Authority: TW; Taiwan
Prior art keywords: catalyst; patent application; item; oil; hydrogenation
Prior art date: 1996-07-15

Application number

TW087111496A

Other languages

English (en)

Chinese (zh)

Inventor

James N Ziemer

Dennis J O'rear

Donald S Santilli

Original Assignee

Chevron Usa Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-07-15

Filing date

1998-07-15

Publication date

2000-07-21

1998-07-15 Application filed by Chevron Usa Inc filed Critical Chevron Usa Inc

2000-07-21 Application granted granted Critical

2000-07-21 Publication of TW399092B publication Critical patent/TW399092B/zh

Links

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238000000746 purification Methods 0.000 description 1
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230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000011819 refractory material Substances 0.000 description 1
230000002040 relaxant effect Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
239000011435 rock Substances 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229910052624 sepiolite Inorganic materials 0.000 description 1
235000019355 sepiolite Nutrition 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000012748 slip agent Substances 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000000779 smoke Substances 0.000 description 1
235000012217 sodium aluminium silicate Nutrition 0.000 description 1
241000894007 species Species 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
239000013585 weight reducing agent Substances 0.000 description 1
239000011240 wet gel Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Lubricants (AREA)

TW087111496A 1996-07-15 1998-07-15 Layered catalyst system for lube oil hydroconversion TW399092B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US2175396P	1996-07-15	1996-07-15

Publications (1)

Publication Number	Publication Date
TW399092B true TW399092B (en)	2000-07-21

Family

ID=21805944

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW087111496A TW399092B (en)	1996-07-15	1998-07-15	Layered catalyst system for lube oil hydroconversion

Country Status (13)

Country	Link
EP (1)	EP0912660A1 (cs)
JP (1)	JP2000515185A (cs)
KR (1)	KR20000023803A (cs)
AU (1)	AU724363B2 (cs)
BR (1)	BR9710326A (cs)
CA (1)	CA2259539A1 (cs)
CZ (1)	CZ9699A3 (cs)
EA (1)	EA001619B1 (cs)
HU (1)	HUP0004280A3 (cs)
PL (1)	PL331037A1 (cs)
TR (1)	TR199900097T2 (cs)
TW (1)	TW399092B (cs)
WO (1)	WO1998002503A1 (cs)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6162350A (en) *	1997-07-15	2000-12-19	Exxon Research And Engineering Company	Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
WO2004043594A1 (en) *	2000-11-16	2004-05-27	Exxonmobil Research And Engineering Company	Process for improving basestock low temeperature performance using a combination catalyst system
FR2797270B1 (fr) *	1999-08-02	2003-03-07	Inst Francais Du Petrole	Procede et flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite
DE69932186T2 (de) *	1998-11-06	2006-11-23	Institut Français du Pétrole, Rueil-Malmaison	Anpassungsfähiges verfahren zur herstellung medizinischer öle und gegebenenfalls mitteldestillaten
FR2785616B1 (fr) *	1998-11-06	2000-12-08	Inst Francais Du Petrole	Procede flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite
FR2785617B1 (fr) *	1998-11-06	2001-01-05	Inst Francais Du Petrole	Procede flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite
JP2004500445A (ja)	1999-05-28	2004-01-08	シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ	潤滑基油の製造方法
FR2808028B1 (fr) *	2000-04-21	2003-09-05	Inst Francais Du Petrole	Procede flexible de production de bases huiles avec une zeolithe zsm-48
EP1370633B1 (en)	2001-02-13	2005-08-17	Shell Internationale Researchmaatschappij B.V.	Lubricant composition
AR032941A1 (es) *	2001-03-05	2003-12-03	Shell Int Research	Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones
AR032930A1 (es)	2001-03-05	2003-12-03	Shell Int Research	Procedimiento para preparar un aceite de base lubricante y gas oil
AR032932A1 (es)	2001-03-05	2003-12-03	Shell Int Research	Procedimiento para preparar un aceite de base lubricante y un gas oil
WO2003070857A1 (en) *	2002-02-25	2003-08-28	Shell Internationale Research Maatschappij B.V.	Process to prepare a catalytically dewaxed gas oil or gas oil blending component
EP1534802B1 (en)	2002-07-18	2005-11-16	Shell Internationale Researchmaatschappij B.V.	Process to prepare a microcrystalline wax and a middle distillate fuel
US7198710B2 (en) *	2003-03-10	2007-04-03	Chevron U.S.A. Inc.	Isomerization/dehazing process for base oils from Fischer-Tropsch wax
US7815789B2 (en)	2003-06-23	2010-10-19	Shell Oil Company	Process to prepare a lubricating base oil
US7727379B2 (en)	2004-03-02	2010-06-01	Shell Oil Company	Process to continuously prepare two or more base oil grades and middle distillates
US20050269245A1 (en) *	2004-06-03	2005-12-08	Huve Laurent G	Process for desulphurising and dewaxing a hydrocarbon feedstock boiling in the gasoil boiling range
WO2006067174A1 (en) *	2004-12-23	2006-06-29	Shell Internationale Research Maatschappij B.V.	Process to prepare two iso paraffinic products from a fisher-tropsch derived feed
TWI473652B (zh)	2008-12-26	2015-02-21	Nippon Oil Corp	Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
WO2010142448A2 (en)	2009-06-12	2010-12-16	Albemarle Europe Sprl	Sapo molecular sieve catalysts and their preparation and uses
CN101942321B (zh) *	2009-07-09	2015-01-14	中国石油化工股份有限公司	一种异构脱蜡生产润滑油基础油的方法
JP5290912B2 (ja)	2009-08-18	2013-09-18	Ｊｘ日鉱日石エネルギー株式会社	潤滑油基油の製造方法
US8431014B2 (en)	2009-10-06	2013-04-30	Chevron U.S.A. Inc.	Process and catalyst system for improving dewaxing catalyst stability and lubricant oil yield
US20120000818A1 (en) *	2010-06-30	2012-01-05	Exxonmobil Research And Engineering Company	Process for the preparation of group ii and group iii lube base oils
CN103459563B (zh) *	2011-03-31	2015-06-17	雪佛龙美国公司	用于改进脱蜡催化剂稳定性和润滑油产率的新型方法和催化剂体系
EP2734605B1 (en) *	2011-07-20	2017-10-25	ExxonMobil Research and Engineering Company	Production of lubricating oil basestocks
SG11201400212XA (en) *	2011-09-21	2014-08-28	Exxonmobil Res & Eng Co	Lubricant base oil hydroprocessing and blending
JP6506667B2 (ja) *	2015-09-29	2019-04-24	Ｊｘｔｇエネルギー株式会社	潤滑油基油の製造方法
JP6034479B2 (ja) *	2015-12-11	2016-11-30	シェブロンユー．エス．エー．インコーポレイテッド	脱蝋触媒の安定性及び潤滑油の収率を改良するための新規なプロセス及び触媒システム
JP2024506820A (ja) *	2021-01-26	2024-02-15	シェブロンユー．エス．エー．インコーポレイテッド	重質グレード基油製品を製造するプロセス
CN116790286A (zh) *	2023-07-12	2023-09-22	山东公泉化工股份有限公司	一种加氢裂化方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3579802D1 (de) *	1984-12-21	1990-10-25	Mobil Oil Corp	Kaskadenentwachsungsverfahren.
US4913797A (en) *	1985-11-21	1990-04-03	Mobil Oil Corporation	Catalyst hydrotreating and dewaxing process
US5358628A (en) *	1990-07-05	1994-10-25	Mobil Oil Corporation	Production of high viscosity index lubricants
JP3665069B2 (ja) *	1993-10-08	2005-06-29	アクゾノーベルナムローゼフェンノートシャップ	水素化分解及び水素化脱ロウ方法
US5565086A (en) *	1994-11-01	1996-10-15	Exxon Research And Engineering Company	Catalyst combination for improved wax isomerization

1997
- 1997-07-15 CZ CZ9996A patent/CZ9699A3/cs unknown
- 1997-07-15 CA CA002259539A patent/CA2259539A1/en not_active Abandoned
- 1997-07-15 EA EA199900108A patent/EA001619B1/ru not_active IP Right Cessation
- 1997-07-15 EP EP97933476A patent/EP0912660A1/en not_active Ceased
- 1997-07-15 WO PCT/US1997/012339 patent/WO1998002503A1/en not_active Ceased
- 1997-07-15 TR TR1999/00097T patent/TR199900097T2/xx unknown
- 1997-07-15 JP JP10506261A patent/JP2000515185A/ja active Pending
- 1997-07-15 BR BR9710326A patent/BR9710326A/pt not_active Application Discontinuation
- 1997-07-15 AU AU36649/97A patent/AU724363B2/en not_active Ceased
- 1997-07-15 HU HU0004280A patent/HUP0004280A3/hu unknown
- 1997-07-15 PL PL97331037A patent/PL331037A1/xx unknown
1998
- 1998-07-15 TW TW087111496A patent/TW399092B/zh active
1999
- 1999-01-15 KR KR1019997000287A patent/KR20000023803A/ko not_active Ceased

Also Published As

Publication number	Publication date
EP0912660A1 (en)	1999-05-06
KR20000023803A (ko)	2000-04-25
WO1998002503A1 (en)	1998-01-22
BR9710326A (pt)	1999-08-17
HUP0004280A3 (en)	2001-06-28
HUP0004280A2 (hu)	2001-04-28
AU724363B2 (en)	2000-09-21
PL331037A1 (en)	1999-06-21
AU3664997A (en)	1998-02-09
CA2259539A1 (en)	1998-01-22
TR199900097T2 (xx)	1999-03-22
EA199900108A1 (ru)	1999-06-24
CZ9699A3 (cs)	1999-04-14
JP2000515185A (ja)	2000-11-14
EA001619B1 (ru)	2001-06-25

Publication	Publication Date	Title
TW399092B (en)	2000-07-21	Layered catalyst system for lube oil hydroconversion
JP3581365B2 (ja)	2004-10-27	潤滑基油の製造方法
TWI466995B (zh)	2015-01-01	烴類之經整合加氫裂解與脫蠟法
TWI491725B (zh)	2015-07-11	烴類之整合加氫裂解及脫蠟法
US6884339B2 (en)	2005-04-26	Flexible method for producing oil bases with a ZSM-48 zeolite
JP6042328B2 (ja)	2016-12-14	炭化水素の統合水素化分解および脱ロウ処理
KR100241173B1 (ko)	2000-02-01	탄화수소의 이성화시 변형된 5 내지 7å 세공분자체의 용도
CN1046309C (zh)	1999-11-10	制备高粘度指数的润滑油基油和高十六烷值的柴油工艺
KR100695181B1 (ko)	2007-03-16	분산도가 낮은 촉매를 사용하는 전환-수소화 이성화 반응후 접촉 탈왁스화 처리에 의한 베이스 오일 및 증류물의 플렉시블 제조 방법
AU2009333803B2 (en)	2016-09-29	Integrated hydrocracking and dewaxing of hydrocarbons
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