TW418263B - Process and apparatus for electrolytic deposition of metal layers - Google Patents
Process and apparatus for electrolytic deposition of metal layers Download PDFInfo
- Publication number
- TW418263B TW418263B TW084106215A TW84106215A TW418263B TW 418263 B TW418263 B TW 418263B TW 084106215 A TW084106215 A TW 084106215A TW 84106215 A TW84106215 A TW 84106215A TW 418263 B TW418263 B TW 418263B
- Authority
- TW
- Taiwan
- Prior art keywords
- anode
- metal
- plating
- plating solution
- cathode
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 104
- 239000002184 metal Substances 0.000 title claims abstract description 104
- 238000000034 method Methods 0.000 title claims abstract description 62
- 230000008569 process Effects 0.000 title abstract description 12
- 230000008021 deposition Effects 0.000 title abstract 5
- 238000007747 plating Methods 0.000 claims abstract description 201
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 118
- 150000001875 compounds Chemical class 0.000 claims abstract description 96
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 75
- 229910052802 copper Inorganic materials 0.000 claims abstract description 74
- 239000010949 copper Substances 0.000 claims abstract description 74
- 238000009713 electroplating Methods 0.000 claims description 54
- 239000007788 liquid Substances 0.000 claims description 38
- 238000011049 filling Methods 0.000 claims description 32
- 230000001590 oxidative effect Effects 0.000 claims description 28
- 229910000831 Steel Inorganic materials 0.000 claims description 18
- 239000010959 steel Substances 0.000 claims description 18
- 150000002500 ions Chemical class 0.000 claims description 16
- 230000002829 reductive effect Effects 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 10
- 238000004090 dissolution Methods 0.000 claims description 9
- 238000005192 partition Methods 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 230000002441 reversible effect Effects 0.000 claims description 7
- 230000002079 cooperative effect Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 159000000014 iron salts Chemical class 0.000 claims description 3
- 238000009499 grossing Methods 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims 8
- 229910052762 osmium Inorganic materials 0.000 claims 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
- 239000008186 active pharmaceutical agent Substances 0.000 claims 1
- 230000001804 emulsifying effect Effects 0.000 claims 1
- 238000011010 flushing procedure Methods 0.000 claims 1
- 238000005242 forging Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 239000013589 supplement Substances 0.000 abstract description 6
- 238000009826 distribution Methods 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 140
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 35
- -1 iron ions Chemical class 0.000 description 34
- 229910052742 iron Inorganic materials 0.000 description 30
- 238000000576 coating method Methods 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 238000010521 absorption reaction Methods 0.000 description 12
- 230000008929 regeneration Effects 0.000 description 11
- 238000011069 regeneration method Methods 0.000 description 11
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 229910001431 copper ion Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
- 238000003306 harvesting Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000007639 printing Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 238000005476 soldering Methods 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 238000007664 blowing Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910000365 copper sulfate Inorganic materials 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 229910001447 ferric ion Inorganic materials 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000010405 anode material Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 229910001448 ferrous ion Inorganic materials 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241001424392 Lucia limbaria Species 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910000912 Bell metal Inorganic materials 0.000 description 1
- 101100493713 Caenorhabditis elegans bath-45 gene Proteins 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- 206010011906 Death Diseases 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241001124569 Lycaenidae Species 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 239000001888 Peptone Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 241000710779 Trina Species 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- NSIMQTOXNOFWBP-UHFFFAOYSA-N acetamidothiourea Chemical compound CC(=O)NNC(N)=S NSIMQTOXNOFWBP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- LCPUDZUWZDSKMX-UHFFFAOYSA-K azane;hydrogen sulfate;iron(3+);sulfate;dodecahydrate Chemical compound [NH4+].O.O.O.O.O.O.O.O.O.O.O.O.[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LCPUDZUWZDSKMX-UHFFFAOYSA-K 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000014987 copper Nutrition 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- QCHWBGRKGNYJSM-UHFFFAOYSA-N ethene Chemical group C=C.C=C.C=C QCHWBGRKGNYJSM-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 210000001061 forehead Anatomy 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000004688 heptahydrates Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- FCKJABJGVFTWPW-UHFFFAOYSA-H iron(3+);trisulfate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FCKJABJGVFTWPW-UHFFFAOYSA-H 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001521 polyalkylene glycol ether Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000004313 potentiometry Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000009192 sprinting Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
- C25D21/14—Controlled addition of electrolyte components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S205/00—Electrolysis: processes, compositions used therein, and methods of preparing the compositions
- Y10S205/92—Electrolytic coating of circuit board or printed circuit, other than selected area coating
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Automation & Control Theory (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrolytic Production Of Metals (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Physical Vapour Deposition (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4344387A DE4344387C2 (de) | 1993-12-24 | 1993-12-24 | Verfahren zur elektrolytischen Abscheidung von Kupfer und Anordnung zur Durchführung des Verfahrens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW418263B true TW418263B (en) | 2001-01-11 |
Family
ID=6506149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW084106215A TW418263B (en) | 1993-12-24 | 1995-06-16 | Process and apparatus for electrolytic deposition of metal layers |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5976341A (de) |
| EP (1) | EP0690934B1 (de) |
| JP (1) | JP3436936B2 (de) |
| AT (1) | ATE167532T1 (de) |
| CA (1) | CA2156407C (de) |
| DE (2) | DE4344387C2 (de) |
| ES (1) | ES2118549T3 (de) |
| SG (1) | SG52609A1 (de) |
| TW (1) | TW418263B (de) |
| WO (1) | WO1995018251A1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106591932A (zh) * | 2016-12-30 | 2017-04-26 | 宁波工程学院 | 用于深孔电镀的电镀制具及电镀方法 |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19545231A1 (de) * | 1995-11-21 | 1997-05-22 | Atotech Deutschland Gmbh | Verfahren zur elektrolytischen Abscheidung von Metallschichten |
| EP0848012A1 (de) | 1996-12-13 | 1998-06-17 | Roche Diagnostics GmbH | Verwendung von Polypeptiden zur Behandlung von Thrombozytopenien |
| DE19653681C2 (de) * | 1996-12-13 | 2000-04-06 | Atotech Deutschland Gmbh | Verfahren zur elektrolytischen Abscheidung von Kupferschichten mit gleichmäßiger Schichtdicke und guten optischen und metallphysikalischen Eigenschaften und Anwendung des Verfahrens |
| DE19708208C2 (de) * | 1997-02-28 | 1999-11-25 | Hans Juergen Pauling | Verfahren und Vorrichtung zum Herstellen einer Elektrodenschicht |
| DE19717512C3 (de) | 1997-04-25 | 2003-06-18 | Atotech Deutschland Gmbh | Vorrichtung zum Galvanisieren von Leiterplatten unter konstanten Bedingungen in Durchlaufanlagen |
| DE19736350C1 (de) * | 1997-08-21 | 1999-08-05 | Atotech Deutschland Gmbh | Verfahren zur Konzentrationsregulierung von Stoffen in Elektrolyten und Vorrichtung zur Durchführung des Verfahrens |
| US7147827B1 (en) * | 1998-05-01 | 2006-12-12 | Applied Materials, Inc. | Chemical mixing, replenishment, and waste management system |
| EP1029954A4 (de) * | 1998-09-08 | 2006-07-12 | Ebara Corp | Substratbeschichtungsvorrichtung |
| ATE282248T1 (de) * | 1999-01-21 | 2004-11-15 | Atotech Deutschland Gmbh | Verfahren zum galvanischen bilden von leiterstrukturen aus hochreinem kupfer bei der herstellung von integrierten schaltungen |
| JP2000256898A (ja) * | 1999-03-03 | 2000-09-19 | Permelec Electrode Ltd | ウェーハの銅めっき方法 |
| JP2001053188A (ja) * | 1999-08-12 | 2001-02-23 | Shinko Electric Ind Co Ltd | 多層配線基板の製造方法 |
| US6503375B1 (en) * | 2000-02-11 | 2003-01-07 | Applied Materials, Inc | Electroplating apparatus using a perforated phosphorus doped consumable anode |
| DE10013339C1 (de) | 2000-03-17 | 2001-06-13 | Atotech Deutschland Gmbh | Verfahren und Vorrichtung zum Regulieren der Konzentration von Metallionen in einer Elektrolytflüssigkeit sowie Anwendung des Verfahrens und Verwendung der Vorrichtung |
| JP2001267726A (ja) * | 2000-03-22 | 2001-09-28 | Toyota Autom Loom Works Ltd | 配線基板の電解メッキ方法及び配線基板の電解メッキ装置 |
| RU2198967C2 (ru) * | 2000-06-28 | 2003-02-20 | Общество с ограниченной ответственностью "АФИНОР" | Способ переработки отработанных сернокислых, азотнокислых, хлоридных электролитов электродиализом |
| US6348142B1 (en) * | 2000-08-07 | 2002-02-19 | Advanced Micro Devices, Inc. | Electroplating multi-trace circuit board substrates using single tie bar |
| US6432291B1 (en) * | 2000-08-18 | 2002-08-13 | Advanced Micro Devices, Inc. | Simultaneous electroplating of both sides of a dual-sided substrate |
| WO2002048430A2 (en) * | 2000-09-27 | 2002-06-20 | Innovative Technology Licensing, Llc. | Oxide-reducing agent composition, system and process |
| US6527934B1 (en) * | 2000-10-31 | 2003-03-04 | Galvan Industries, Inc. | Method for electrolytic deposition of copper |
| WO2002086196A1 (en) * | 2001-04-19 | 2002-10-31 | Rd Chemical Company | Copper acid baths, system and method for electroplating high aspect ratio substrates |
| SE523309E (sv) * | 2001-06-15 | 2010-03-02 | Replisaurus Technologies Ab | Metod, elektrod och apparat för att skapa mikro- och nanostrukturer i ledande material genom mönstring med masterelektrod och elektrolyt |
| WO2003038158A2 (de) * | 2001-10-25 | 2003-05-08 | Infineon Technologies Ag | Galvanisiereinrichtung und galvanisiersystem zum beschichten von bereits leitfähig ausgebildeten strukturen |
| JP3725083B2 (ja) * | 2002-02-21 | 2005-12-07 | アトーテヒ ドイッチュラント ゲゼルシャフト ミット ベシュレンクテル ハフツング | メッキ設備における金属イオン供給源の有効保存を可能とする方法 |
| US6676823B1 (en) | 2002-03-18 | 2004-01-13 | Taskem, Inc. | High speed acid copper plating |
| JP3819840B2 (ja) * | 2002-07-17 | 2006-09-13 | 大日本スクリーン製造株式会社 | メッキ装置およびメッキ方法 |
| US20040159551A1 (en) * | 2003-02-14 | 2004-08-19 | Robert Barcell | Plating using an insoluble anode and separately supplied plating material |
| DE10311575B4 (de) * | 2003-03-10 | 2007-03-22 | Atotech Deutschland Gmbh | Verfahren zum elektrolytischen Metallisieren von Werkstücken mit Bohrungen mit einem hohen Aspektverhältnis |
| DE10325101A1 (de) * | 2003-06-03 | 2004-12-30 | Atotech Deutschland Gmbh | Verfahren zum Auffüllen von µ-Blind-Vias (µ-BVs) |
| US20050016857A1 (en) * | 2003-07-24 | 2005-01-27 | Applied Materials, Inc. | Stabilization of additives concentration in electroplating baths for interconnect formation |
| US7181837B2 (en) * | 2004-06-04 | 2007-02-27 | Micron Technology, Inc. | Plating buss and a method of use thereof |
| EA011312B1 (ru) | 2004-06-29 | 2009-02-27 | Текстура Корпорейшн | Система и способ управления платежом в строительстве |
| JP2006283072A (ja) * | 2005-03-31 | 2006-10-19 | Atotech Deutsche Gmbh | マイクロビアやスルーホールをめっきする方法 |
| US7851222B2 (en) | 2005-07-26 | 2010-12-14 | Applied Materials, Inc. | System and methods for measuring chemical concentrations of a plating solution |
| DE502007005345D1 (de) * | 2006-03-30 | 2010-11-25 | Atotech Deutschland Gmbh | Elektrolytisches verfahren zum füllen von löchern und vertiefungen mit metallen |
| EP1961842A1 (de) * | 2007-02-22 | 2008-08-27 | Atotech Deutschland Gmbh | Vorrichtung und Verfahren zum elektrolytischen Galvanisieren eines Metalls |
| JP5293276B2 (ja) | 2008-03-11 | 2013-09-18 | 上村工業株式会社 | 連続電気銅めっき方法 |
| DE102008031003B4 (de) | 2008-06-30 | 2010-04-15 | Siemens Aktiengesellschaft | Verfahren zum Erzeugen einer CNT enthaltenen Schicht aus einer ionischen Flüssigkeit |
| US20100206737A1 (en) * | 2009-02-17 | 2010-08-19 | Preisser Robert F | Process for electrodeposition of copper chip to chip, chip to wafer and wafer to wafer interconnects in through-silicon vias (tsv) |
| DE102009043594B4 (de) | 2009-09-25 | 2013-05-16 | Siemens Aktiengesellschaft | Verfahren zum elektrochemischen Beschichten und Einbau von Partikeln in die Schicht |
| DE102009060937A1 (de) | 2009-12-22 | 2011-06-30 | Siemens Aktiengesellschaft, 80333 | Verfahren zum elektrochemischen Beschichten |
| US20120024713A1 (en) | 2010-07-29 | 2012-02-02 | Preisser Robert F | Process for electrodeposition of copper chip to chip, chip to wafer and wafer to wafer interconnects in through-silicon vias (tsv) with heated substrate and cooled electrolyte |
| US9017528B2 (en) | 2011-04-14 | 2015-04-28 | Tel Nexx, Inc. | Electro chemical deposition and replenishment apparatus |
| US9005409B2 (en) | 2011-04-14 | 2015-04-14 | Tel Nexx, Inc. | Electro chemical deposition and replenishment apparatus |
| DE102012206800B3 (de) * | 2012-04-25 | 2013-09-05 | Atotech Deutschland Gmbh | Verfahren und Vorrichtung zum elektrolytischen Abscheiden eines Abscheidemetalls auf einem Werkstück |
| JP5876767B2 (ja) * | 2012-05-15 | 2016-03-02 | 株式会社荏原製作所 | めっき装置及びめっき液管理方法 |
| KR20140034529A (ko) * | 2012-09-12 | 2014-03-20 | 삼성전기주식회사 | 전기 동도금 장치 |
| EP2735627A1 (de) | 2012-11-26 | 2014-05-28 | ATOTECH Deutschland GmbH | Kupferplattierbadzusammensetzung |
| JP2015021154A (ja) * | 2013-07-18 | 2015-02-02 | ペルメレック電極株式会社 | 電解金属箔の連続製造方法及び電解金属箔連続製造装置 |
| US9303329B2 (en) | 2013-11-11 | 2016-04-05 | Tel Nexx, Inc. | Electrochemical deposition apparatus with remote catholyte fluid management |
| EP3286358B1 (de) | 2015-04-20 | 2019-03-20 | ATOTECH Deutschland GmbH | Elektrolytische kupferplattierungsbadzusammensetzungen und verfahren zu deren verwendung |
| EP3135709B1 (de) | 2015-08-31 | 2018-01-10 | ATOTECH Deutschland GmbH | Imidazoylharnstoffpolymere und deren verwendung in metall- oder metalllegierung-galvanisierungsbadzusammensetzungen |
| KR102457077B1 (ko) | 2015-08-31 | 2022-10-19 | 아토테크 도이칠란트 게엠베하 운트 콤파니 카게 | 수성 구리 도금 조 및 구리 또는 구리 합금을 기판 상에 침착시키는 방법 |
| ES2681836T3 (es) | 2015-09-10 | 2018-09-17 | Atotech Deutschland Gmbh | Composición de baño para chapado de cobre |
| KR102381803B1 (ko) | 2016-08-15 | 2022-04-01 | 아토테크 도이칠란트 게엠베하 운트 콤파니 카게 | 전해 구리 도금용 산성 수성 조성물 |
| EP3360988B1 (de) | 2017-02-09 | 2019-06-26 | ATOTECH Deutschland GmbH | Pyridiniumverbindungen, ein syntheseverfahren dafür, metall- oder metalllegierungsplattierungsbäder mit besagten pyridiniumverbindungen und verfahren zur verwendung besagter metall- oder metalllegierungsplattierungsbäder |
| EP3470552B1 (de) | 2017-10-13 | 2020-12-30 | ATOTECH Deutschland GmbH | Saure wässrige zusammensetzung zur elektrolytischen abscheidung einer kupferabscheidung |
| ES2800292T3 (es) | 2017-11-09 | 2020-12-29 | Atotech Deutschland Gmbh | Composiciones de electrodeposición para deposición electrolítica de cobre, su uso y un método para depositar electrolíticamente una capa de cobre o aleación de cobre sobre al menos una superficie de un sustrato |
| ES2881029T3 (es) | 2018-01-09 | 2021-11-26 | Atotech Deutschland Gmbh | Aditivo de ureileno, su uso y un método para su preparación |
| EP3511444B1 (de) | 2018-01-16 | 2020-07-22 | ATOTECH Deutschland GmbH | Metall- oder metalllegierungsabscheidungszusammensetzung und plattierungsverbindung |
| KR102875198B1 (ko) | 2019-08-19 | 2025-10-22 | 아토테크 도이칠란트 게엠베하 운트 콤파니 카게 | 구리로 충전된 마이크로비아들을 포함하는 고밀도 상호연결 인쇄 회로 기판을 제조하는 방법 |
| CN114342569A (zh) | 2019-08-19 | 2022-04-12 | 德国艾托特克有限两合公司 | 高密度互连印刷电路板的制造顺序及高密度互连印刷电路板 |
| EP3901331A1 (de) | 2020-04-23 | 2021-10-27 | ATOTECH Deutschland GmbH | Saure wässrige zusammensetzung zur elektrolytischen abscheidung einer kupferabscheidung |
| EP3933073B1 (de) | 2020-06-29 | 2023-11-29 | Atotech Deutschland GmbH & Co. KG | Kupfergalvanisierbad |
| CN112888169B (zh) * | 2020-12-30 | 2022-11-08 | 深圳市迅捷兴科技股份有限公司 | 图形电镀电流分流方法 |
| TWI806328B (zh) * | 2020-12-31 | 2023-06-21 | 葉濤 | 不溶性陽極酸性硫酸鹽電鍍銅的優化製程及裝置 |
| EP4032930B1 (de) | 2021-01-22 | 2023-08-30 | Atotech Deutschland GmbH & Co. KG | Biuretbasierte quaternisierte polymere und deren verwendung in metall- oder metalllegierungsbädern |
| CN114808057B (zh) * | 2021-01-29 | 2024-06-21 | 泰科电子(上海)有限公司 | 电镀装置和电镀系统 |
| EP4400634A1 (de) | 2023-01-13 | 2024-07-17 | Atotech Deutschland GmbH & Co. KG | Verfahren zur herstellung einer kupferfolie durch elektrolytische abscheidung von kupfer |
| CN117144365A (zh) * | 2023-09-01 | 2023-12-01 | 东莞市百良电子科技有限公司 | 一种微蚀液合成工艺以及循环再生方法 |
| WO2025168540A1 (en) | 2024-02-09 | 2025-08-14 | Atotech Deutschland GmbH & Co. KG | Process for producing a flexible plastic-copper layer composite by electrolytic deposition of copper |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE215589C (de) * | ||||
| US4270984A (en) * | 1978-11-29 | 1981-06-02 | Nasa | Catalyst surfaces for the chromous/chromic REDOX couple |
| JPS6021240B2 (ja) * | 1980-01-12 | 1985-05-25 | 株式会社小糸製作所 | 堆積される銅をメッキ液に補給する方法及び装置 |
| ZM2281A1 (en) * | 1980-03-17 | 1981-12-21 | Nat Res Dev | Anode-assisted action reduction |
| JPS59170299A (ja) * | 1983-03-14 | 1984-09-26 | Nippon Steel Corp | 鉄系電気めつき浴中のFe↑3↑+イオン還元方法 |
| DD215589B5 (de) * | 1983-05-11 | 1994-06-01 | Heinz Dr Rer Nat Liebscher | Verfahren zur elektrolytischen Metallabscheidung bei erzwungener Konvektion |
| JPS6148599A (ja) * | 1984-08-13 | 1986-03-10 | Nippon Steel Corp | 鉄系又は鉄系合金電気めつきのイオン補給方法 |
| NL8602730A (nl) * | 1986-10-30 | 1988-05-16 | Hoogovens Groep Bv | Werkwijze voor het electrolytisch vertinnen van blik met behulp van een onoplosbare anode. |
| DD261613A1 (de) * | 1987-06-05 | 1988-11-02 | Leipzig Galvanotechnik | Verfahren zur elektrolytischen kupferabscheidung aus sauren elektrolyten mit dimensionsstabiler anode |
| US5262020A (en) * | 1991-03-13 | 1993-11-16 | M.A. Industries, Inc. | Hydrometallurgical method of producing metallic lead from materials containing oxides, particularly from the active material of accumulators |
| US5304297A (en) * | 1993-02-26 | 1994-04-19 | Rockwell International Corporation | Reducing agent regeneration system |
| US5312539A (en) * | 1993-06-15 | 1994-05-17 | Learonal Inc. | Electrolytic tin plating method |
| JP6211893B2 (ja) | 2012-10-30 | 2017-10-11 | 東京エレクトロン株式会社 | エッチング処理方法及び基板処理装置 |
-
1993
- 1993-12-24 DE DE4344387A patent/DE4344387C2/de not_active Expired - Fee Related
-
1994
- 1994-12-23 AT AT95904386T patent/ATE167532T1/de active
- 1994-12-23 ES ES95904386T patent/ES2118549T3/es not_active Expired - Lifetime
- 1994-12-23 SG SG1996006707A patent/SG52609A1/en unknown
- 1994-12-23 WO PCT/DE1994/001542 patent/WO1995018251A1/de not_active Ceased
- 1994-12-23 DE DE59406281T patent/DE59406281D1/de not_active Expired - Lifetime
- 1994-12-23 JP JP51772495A patent/JP3436936B2/ja not_active Expired - Lifetime
- 1994-12-23 EP EP95904386A patent/EP0690934B1/de not_active Expired - Lifetime
- 1994-12-23 CA CA002156407A patent/CA2156407C/en not_active Expired - Fee Related
- 1994-12-23 US US08/507,499 patent/US5976341A/en not_active Expired - Lifetime
-
1995
- 1995-06-16 TW TW084106215A patent/TW418263B/zh not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106591932A (zh) * | 2016-12-30 | 2017-04-26 | 宁波工程学院 | 用于深孔电镀的电镀制具及电镀方法 |
| CN106591932B (zh) * | 2016-12-30 | 2023-09-29 | 宁波工程学院 | 用于深孔电镀的电镀制具及电镀方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3436936B2 (ja) | 2003-08-18 |
| EP0690934B1 (de) | 1998-06-17 |
| ES2118549T3 (es) | 1998-09-16 |
| DE59406281D1 (de) | 1998-07-23 |
| DE4344387A1 (de) | 1995-06-29 |
| CA2156407C (en) | 2003-09-02 |
| ATE167532T1 (de) | 1998-07-15 |
| DE4344387C2 (de) | 1996-09-05 |
| US5976341A (en) | 1999-11-02 |
| SG52609A1 (en) | 1998-09-28 |
| WO1995018251A1 (de) | 1995-07-06 |
| JPH08507106A (ja) | 1996-07-30 |
| CA2156407A1 (en) | 1995-07-06 |
| EP0690934A1 (de) | 1996-01-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW418263B (en) | Process and apparatus for electrolytic deposition of metal layers | |
| TWI503455B (zh) | Electroplating device and electroplating method | |
| TW557332B (en) | Method and device for regulating the metal ion concentration in an electrolyte fluid | |
| CN102102218B (zh) | 在电解液中补充锡和制造合金的金属的方法 | |
| EP1300488B1 (de) | Plattierungsbad und Verfahren zur Abscheidung einer Metallschicht auf einem Substrat | |
| US8540857B1 (en) | Plating method and apparatus with multiple internally irrigated chambers | |
| EP1300486B1 (de) | Plattierungsbad und Verfahren zur Abscheidung einer Metallschicht auf einem Substrat | |
| CN101532160B (zh) | 连续电镀铜的方法 | |
| CN112714803B (zh) | 不溶性阳极酸性电镀铜的镀液生产和再生工艺及装置 | |
| TWI648435B (zh) | Acidic copper plating process using insoluble anode and its equipment | |
| US20060151328A1 (en) | Method of electroplating a workpiece having high-aspect ratio holes | |
| CN115522235A (zh) | 一种药液循环系统及纯铜阳极电镀线 | |
| CN106835211A (zh) | 一种新型阳极电镀液及使用该电镀液的酸性电镀铜工艺 | |
| CN1153855C (zh) | 用于调节电解液中的金属离子浓度的方法与装置 | |
| CN109056002B (zh) | 一种通孔隔离法酸性电镀铜工艺及其装置 | |
| CN101781770A (zh) | 一种溶液平行双向旋转流动的电解或电积方法及装置 | |
| KR100426159B1 (ko) | 금속막의전착방법및이를위한장치 | |
| JP3903120B2 (ja) | 硫酸銅めっき方法 | |
| Bai et al. | High current density on electroplating smooth alkaline zinc coating | |
| JPH09509222A (ja) | プロセス有機物で電解液から金属を電解的に析出する方法 | |
| CN117396638A (zh) | 用铬层涂覆部件或半成品的装置和方法 | |
| CN219136979U (zh) | 一种不溶性阳极的脉冲电镀装置 | |
| CN207391573U (zh) | 一种电镀废水中多种重金属同时分离回收的装置 | |
| AU2021105178A4 (en) | Conductive membrane filtration electrocoagulation coupling wastewater treatment device | |
| KR102005521B1 (ko) | 전해 인산염 피막처리 멀티 트랙 시스템 및 이를 이용한 전해 인산염 피막처리 방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GD4A | Issue of patent certificate for granted invention patent | ||
| MK4A | Expiration of patent term of an invention patent |