TW436503B - Perhalogenated polyorganosiloxanes and the processes for their preparation - Google Patents

Perhalogenated polyorganosiloxanes and the processes for their preparation Download PDF

Info

Publication number: TW436503B
Authority: TW; Taiwan
Prior art keywords: patent application; item; scope; group; cns
Prior art date: 1995-07-25

Application number

TW085109105A

Other languages

English (en)

Chinese (zh)

Inventor

Philippe Jost

Philippe Karrer

Gerard Mignani

Philippe Olier

Original Assignee

Rhodia Chimie Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-07-25

Filing date

1996-07-25

Publication date

2001-05-28

1996-07-25 Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa

2001-05-28 Application granted granted Critical

2001-05-28 Publication of TW436503B publication Critical patent/TW436503B/zh

Links

238000000034 method Methods 0.000 title claims abstract description 52
230000008569 process Effects 0.000 title claims abstract description 11
238000002360 preparation method Methods 0.000 title claims abstract description 7
-1 antiadhesives Substances 0.000 claims abstract description 30
239000003795 chemical substances by application Substances 0.000 claims abstract description 13
230000002209 hydrophobic effect Effects 0.000 claims abstract description 10
239000000314 lubricant Substances 0.000 claims abstract description 9
230000000181 anti-adherent effect Effects 0.000 claims abstract description 8
238000000576 coating method Methods 0.000 claims abstract description 5
238000006243 chemical reaction Methods 0.000 claims description 50
238000011049 filling Methods 0.000 claims description 46
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 45
239000002243 precursor Substances 0.000 claims description 42
239000003921 oil Substances 0.000 claims description 38
239000003054 catalyst Substances 0.000 claims description 29
150000001336 alkenes Chemical class 0.000 claims description 24
230000002079 cooperative effect Effects 0.000 claims description 24
229910052697 platinum Inorganic materials 0.000 claims description 22
238000006459 hydrosilylation reaction Methods 0.000 claims description 21
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 20
239000000203 mixture Substances 0.000 claims description 19
229910052739 hydrogen Inorganic materials 0.000 claims description 17
239000001257 hydrogen Substances 0.000 claims description 17
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
125000000217 alkyl group Chemical group 0.000 claims description 15
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
239000000376 reactant Substances 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 11
239000000126 substance Substances 0.000 claims description 11
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
239000000839 emulsion Substances 0.000 claims description 10
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
229910052710 silicon Inorganic materials 0.000 claims description 10
239000010703 silicon Substances 0.000 claims description 10
125000003118 aryl group Chemical group 0.000 claims description 9
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
235000015170 shellfish Nutrition 0.000 claims description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
125000003545 alkoxy group Chemical group 0.000 claims description 7
230000000875 corresponding effect Effects 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
229910052760 oxygen Inorganic materials 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
229920000642 polymer Polymers 0.000 claims description 7
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 6
150000008064 anhydrides Chemical class 0.000 claims description 5
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 5
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
239000000853 adhesive Substances 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
239000007795 chemical reaction product Substances 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 4
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
229920001843 polymethylhydrosiloxane Polymers 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 4
239000007858 starting material Substances 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 3
239000007806 chemical reaction intermediate Substances 0.000 claims description 3
238000012937 correction Methods 0.000 claims description 3
NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 3
229910052717 sulfur Inorganic materials 0.000 claims description 3
238000005809 transesterification reaction Methods 0.000 claims description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
230000001588 bifunctional effect Effects 0.000 claims description 2
238000005202 decontamination Methods 0.000 claims description 2
230000003588 decontaminative effect Effects 0.000 claims description 2
239000003599 detergent Substances 0.000 claims description 2
239000000806 elastomer Substances 0.000 claims description 2
229920001971 elastomer Polymers 0.000 claims description 2
238000003682 fluorination reaction Methods 0.000 claims description 2
150000002431 hydrogen Chemical class 0.000 claims description 2
238000007639 printing Methods 0.000 claims description 2
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 2
239000002994 raw material Substances 0.000 claims description 2
239000013589 supplement Substances 0.000 claims description 2
239000004094 surface-active agent Substances 0.000 claims description 2
150000003573 thiols Chemical class 0.000 claims description 2
150000001335 aliphatic alkanes Chemical class 0.000 claims 3
239000003638 chemical reducing agent Substances 0.000 claims 2
PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims 1
239000002518 antifoaming agent Substances 0.000 claims 1
239000011248 coating agent Substances 0.000 claims 1
238000005886 esterification reaction Methods 0.000 claims 1
150000002148 esters Chemical class 0.000 claims 1
239000010408 film Substances 0.000 claims 1
RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims 1
238000010413 gardening Methods 0.000 claims 1
239000000543 intermediate Substances 0.000 claims 1
238000004898 kneading Methods 0.000 claims 1
239000007787 solid Substances 0.000 claims 1
239000002023 wood Substances 0.000 claims 1
239000005871 repellent Substances 0.000 abstract description 4
230000002940 repellent Effects 0.000 abstract description 3
239000007788 liquid Substances 0.000 description 23
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
229920001296 polysiloxane Polymers 0.000 description 12
125000004122 cyclic group Chemical group 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
229910052731 fluorine Inorganic materials 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 8
239000011737 fluorine Substances 0.000 description 8
DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 8
239000011347 resin Substances 0.000 description 8
229920005989 resin Polymers 0.000 description 8
238000003786 synthesis reaction Methods 0.000 description 8
238000012360 testing method Methods 0.000 description 8
239000003039 volatile agent Substances 0.000 description 8
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
239000000178 monomer Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
241000894007 species Species 0.000 description 6
125000002947 alkylene group Chemical group 0.000 description 5
239000000047 product Substances 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
125000002015 acyclic group Chemical group 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
238000007654 immersion Methods 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
229920000962 poly(amidoamine) Polymers 0.000 description 4
230000009467 reduction Effects 0.000 description 4
239000000243 solution Substances 0.000 description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000008859 change Effects 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
239000000463 material Substances 0.000 description 3
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
229920002545 silicone oil Polymers 0.000 description 3
238000001308 synthesis method Methods 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
229920002292 Nylon 6 Polymers 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
150000008065 acid anhydrides Chemical class 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
239000013530 defoamer Substances 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
239000004205 dimethyl polysiloxane Substances 0.000 description 2
235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
150000007857 hydrazones Chemical class 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
238000009434 installation Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
238000004987 plasma desorption mass spectroscopy Methods 0.000 description 2
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
229910052704 radon Inorganic materials 0.000 description 2
SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 2
239000012429 reaction media Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
238000011160 research Methods 0.000 description 2
238000012552 review Methods 0.000 description 2
239000013049 sediment Substances 0.000 description 2
238000002444 silanisation Methods 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
UYSWTFXPYLWMJS-UHFFFAOYSA-N 2,3-bis(ethenyl)-2,3,5,6-tetramethyl-1,4-dioxane Chemical compound C(=C)C1(C(OC(C(O1)C)C)(C)C=C)C UYSWTFXPYLWMJS-UHFFFAOYSA-N 0.000 description 1
OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
JKXYOQDLERSFPT-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-octadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO JKXYOQDLERSFPT-UHFFFAOYSA-N 0.000 description 1
ZQDPJFUHLCOCRG-UHFFFAOYSA-N 3-hexene Chemical group CCC=CCC ZQDPJFUHLCOCRG-UHFFFAOYSA-N 0.000 description 1
WUMMIJWEUDHZCL-UHFFFAOYSA-N 3-prop-2-enyloxolane-2,5-dione Chemical compound C=CCC1CC(=O)OC1=O WUMMIJWEUDHZCL-UHFFFAOYSA-N 0.000 description 1
101100439665 Arabidopsis thaliana SWI2 gene Proteins 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000004594 Masterbatch (MB) Substances 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
241000208125 Nicotiana Species 0.000 description 1
235000002637 Nicotiana tabacum Nutrition 0.000 description 1
241001365789 Oenanthe crocata Species 0.000 description 1
229920002675 Polyoxyl Polymers 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
YKVXXEAJYNVLML-UHFFFAOYSA-N [IH]1[IH]OCCC1 Chemical compound [IH]1[IH]OCCC1 YKVXXEAJYNVLML-UHFFFAOYSA-N 0.000 description 1
MSQXEKLRMKCFIU-UHFFFAOYSA-N [O-2].C(C)[Ti+3].[O-2].[O-2].C(C)[Ti+3] Chemical compound [O-2].C(C)[Ti+3].[O-2].[O-2].C(C)[Ti+3] MSQXEKLRMKCFIU-UHFFFAOYSA-N 0.000 description 1
OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical group [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
OXRMMGBHYZHRMG-UHFFFAOYSA-N [Si].[Ar] Chemical class [Si].[Ar] OXRMMGBHYZHRMG-UHFFFAOYSA-N 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000002048 anodisation reaction Methods 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 description 1
210000000481 breast Anatomy 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
125000003636 chemical group Chemical group 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
238000007872 degassing Methods 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
238000000151 deposition Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
NZZFYRREKKOMAT-UHFFFAOYSA-N diiodomethane Chemical compound ICI NZZFYRREKKOMAT-UHFFFAOYSA-N 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002118 epoxides Chemical class 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
150000002220 fluorenes Chemical class 0.000 description 1
125000001153 fluoro group Chemical group F* 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
230000026030 halogenation Effects 0.000 description 1
238000005658 halogenation reaction Methods 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000033444 hydroxylation Effects 0.000 description 1
238000005805 hydroxylation reaction Methods 0.000 description 1
210000003127 knee Anatomy 0.000 description 1
238000002386 leaching Methods 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
238000011068 loading method Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
BQJCRHHNABKAKU-KBQPJGBKSA-N morphine Chemical group O([C@H]1[C@H](C=C[C@H]23)O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4O BQJCRHHNABKAKU-KBQPJGBKSA-N 0.000 description 1
238000000465 moulding Methods 0.000 description 1
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
125000005375 organosiloxane group Chemical group 0.000 description 1
230000035515 penetration Effects 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
238000005325 percolation Methods 0.000 description 1
125000005010 perfluoroalkyl group Chemical group 0.000 description 1
125000005005 perfluorohexyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 description 1
239000011941 photocatalyst Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000015067 sauces Nutrition 0.000 description 1
238000007789 sealing Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
229910021332 silicide Inorganic materials 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000006884 silylation reaction Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000004575 stone Substances 0.000 description 1
238000012916 structural analysis Methods 0.000 description 1
229940014800 succinic anhydride Drugs 0.000 description 1
239000004753 textile Substances 0.000 description 1
230000001225 therapeutic effect Effects 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/385—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing halogens
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Silicon Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Ceramic Products (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

TW085109105A 1995-07-25 1996-07-25 Perhalogenated polyorganosiloxanes and the processes for their preparation TW436503B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9509269A FR2737215B1 (fr)	1995-07-25	1995-07-25	Polyorganosiloxanes perhalogenes et leurs procedes d'obtention

Publications (1)

Publication Number	Publication Date
TW436503B true TW436503B (en)	2001-05-28

Family

ID=9481537

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW085109105A TW436503B (en)	1995-07-25	1996-07-25	Perhalogenated polyorganosiloxanes and the processes for their preparation

Country Status (18)

Country	Link
US (1)	US5834613A (cs)
EP (1)	EP0755961B1 (cs)
JP (1)	JP3046244B2 (cs)
AT (1)	ATE260312T1 (cs)
AU (1)	AU707666B2 (cs)
BR (1)	BR9604019A (cs)
CA (1)	CA2182110C (cs)
CZ (1)	CZ220096A3 (cs)
DE (1)	DE69631622T2 (cs)
FR (1)	FR2737215B1 (cs)
HU (1)	HUP9602031A3 (cs)
IL (1)	IL118952A0 (cs)
MX (1)	MX9602966A (cs)
PL (1)	PL315409A1 (cs)
SG (1)	SG64941A1 (cs)
SK (1)	SK98396A3 (cs)
TR (1)	TR199600614A2 (cs)
TW (1)	TW436503B (cs)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2780407B1 (fr) *	1998-06-30	2000-09-15	Rhodia Chimie Sa	Composition silicone reticulable utilisable, notamment pour la realisation de revetement et/ou d'impregnation hydrophobe et/ou oleophobe, a faible energie de surface
DE10012913A1 (de)	2000-03-16	2001-09-20	Ciba Sc Pfersee Gmbh	Polyorganosiloxane mit alkoxilierten Seitenketten
FR2809111B1 (fr) *	2000-05-16	2004-04-16	Rhodia Chimie Sa	Huile polyoganosiloxane lubrifiante, emulsion aqueuse en contenant, leur preparation et leur utilisation pour le demoulage de metaux
ES2206431T3 (es) *	2002-04-17	2004-05-16	Goldschmidt Ag	Uso de formulaciones de organopolisiloxanos exentes de disolvente, agua y emulsionante como lubricante para empaquetaduras perfiladas.
US7514092B2 (en) *	2004-12-22	2009-04-07	Avon Products, Inc.	Compositions and methods of their use for improving the condition and appearance of skin
JP5299147B2 (ja) *	2009-07-28	2013-09-25	信越化学工業株式会社	エステル基含有オルガノポリシロキサン及びそれを含む化粧料
CN104479131B (zh) *	2014-11-14	2018-07-13	衢州氟硅技术研究院	一种含氟硅油消泡剂及其制备方法
JP7493704B2 (ja) *	2017-04-28	2024-06-03	国立大学法人山形大学	印刷装置及び印刷方法
JP2022535815A (ja) *	2019-06-04	2022-08-10	スリーエムイノベイティブプロパティズカンパニー	多官能性フッ素化化合物、その化合物から製造されるフッ素化ポリマー、及び関連方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6017416B2 (ja) *	1980-05-28	1985-05-02	信越化学工業株式会社	オルガノポリシロキサン化合物
JPS62277470A (ja) *	1986-05-23	1987-12-02	Shin Etsu Chem Co Ltd	合成樹脂用改質剤
US5288891A (en) *	1990-11-22	1994-02-22	Nippon Oil And Fats Co. Ltd.	Fluoralykyl group-containing organosilicon oligomer, method for preparing same and surface treating agent
US5233071A (en) *	1992-03-17	1993-08-03	E. I. Du Pont De Nemours And Company	Hydrosilation of fluorinated olefins with cobalt catalysts
DE4240274B4 (de) *	1992-12-01	2004-02-12	Minnesota Mining And Manufacturing Co., Saint Paul	Polysiloxane mit fluoraliphaten- und carboxylhaltigen terminalen Gruppen, ihre Herstellung und ihre Verwendung bei der Behandlung von Fasersubstraten

1995
- 1995-07-25 FR FR9509269A patent/FR2737215B1/fr not_active Expired - Fee Related
1996
- 1996-07-24 MX MX9602966A patent/MX9602966A/es unknown
- 1996-07-25 TR TR96/00614A patent/TR199600614A2/xx unknown
- 1996-07-25 AU AU60710/96A patent/AU707666B2/en not_active Ceased
- 1996-07-25 JP JP8213303A patent/JP3046244B2/ja not_active Expired - Fee Related
- 1996-07-25 TW TW085109105A patent/TW436503B/zh not_active IP Right Cessation
- 1996-07-25 HU HU9602031A patent/HUP9602031A3/hu unknown
- 1996-07-25 IL IL11895296A patent/IL118952A0/xx unknown
- 1996-07-25 US US08/686,400 patent/US5834613A/en not_active Expired - Fee Related
- 1996-07-25 EP EP96420252A patent/EP0755961B1/fr not_active Expired - Lifetime
- 1996-07-25 AT AT96420252T patent/ATE260312T1/de not_active IP Right Cessation
- 1996-07-25 CZ CZ962200A patent/CZ220096A3/cs unknown
- 1996-07-25 BR BR9604019A patent/BR9604019A/pt not_active IP Right Cessation
- 1996-07-25 PL PL96315409A patent/PL315409A1/xx unknown
- 1996-07-25 CA CA002182110A patent/CA2182110C/fr not_active Expired - Fee Related
- 1996-07-25 SK SK983-96A patent/SK98396A3/sk unknown
- 1996-07-25 SG SG1996010336A patent/SG64941A1/en unknown
- 1996-07-25 DE DE69631622T patent/DE69631622T2/de not_active Expired - Fee Related

Also Published As

Publication number	Publication date
SK98396A3 (en)	1997-04-09
SG64941A1 (en)	1999-05-25
CZ220096A3 (en)	1997-02-12
FR2737215A1 (fr)	1997-01-31
AU6071096A (en)	1997-01-30
DE69631622D1 (de)	2004-04-01
EP0755961B1 (fr)	2004-02-25
TR199600614A2 (tr)	1997-02-21
DE69631622T2 (de)	2004-09-23
CA2182110A1 (fr)	1997-01-26
EP0755961A1 (fr)	1997-01-29
HUP9602031A3 (en)	1997-08-28
CA2182110C (fr)	2001-01-16
HU9602031D0 (en)	1996-09-30
US5834613A (en)	1998-11-10
ATE260312T1 (de)	2004-03-15
JPH0940781A (ja)	1997-02-10
MX9602966A (es)	1998-04-30
AU707666B2 (en)	1999-07-15
IL118952A0 (en)	1996-10-31
HUP9602031A2 (en)	1997-03-28
BR9604019A (pt)	1998-06-09
JP3046244B2 (ja)	2000-05-29
PL315409A1 (en)	1997-02-03
FR2737215B1 (fr)	1997-10-17

Legal Events

Date	Code	Title	Description
2001-09-13	GD4A	Issue of patent certificate for granted invention patent
2004-07-11	MM4A	Annulment or lapse of patent due to non-payment of fees

Publication	Publication Date	Title
JP2583412B2 (ja)	1997-02-19	ヒドロキシル基含有シロキサン化合物
US5593787A (en)	1997-01-14	Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use
EP1904557B2 (en)	2016-02-17	Aldehyde functional siloxanes
JPH05320346A (ja)	1993-12-03	アルケニルオキシ基を有するシロキサンコポリマー、その製法、これを含有する光架橋可能なオルガノポリシロキサンの組成物及び光架橋可能な被覆物の製法
JP3150288B2 (ja)	2001-03-26	多官能性ペルハロゲン化ポリオルガノシロキサン及びその製造方法
TW436503B (en)	2001-05-28	Perhalogenated polyorganosiloxanes and the processes for their preparation
US5447997A (en)	1995-09-05	Silicone polyether carboxylic acids
EP0576246B1 (en)	1999-05-12	Silicone polyether copolymers
JP2624060B2 (ja)	1997-06-25	片末端ジオールシロキサン化合物及びその製造方法
JP2014500376A (ja)	2014-01-09	シリコーンアスパラギン酸共重合体
JP2020090580A (ja)	2020-06-11	ω末端にポリアルキレンオキシド基を有する片末端メタクリル変性オルガノ（ポリ）シロキサン及びその製造方法。
JP2000234025A (ja)	2000-08-29	シロキサン―オキシアルキレンコポリマ―類の製造方法
JPH0781008B2 (ja)	1995-08-30	アルケニル基を有するシロキサンコポリマー、その製造方法、その組成物及び粘着性物質を固着防止する被覆の製造方法
JPH06299079A (ja)	1994-10-25	エポキシ末端分岐状シリコーン及びそれらの共重合体
JPH09227688A (ja)	1997-09-02	ヒドロキシル基含有シロキサン化合物の製造方法
JPH0822922B2 (ja)	1996-03-06	ビニルオキシ基を有するシロキサン共重合体，その製造および使用
EP4410869A1 (en)	2024-08-07	New functionalized organopolysiloxane compounds, manufacturing method, and uses thereof
JPH03190930A (ja)	1991-08-20	スルホサクシネート基を有するオルガノポリシロキサン及びその製法
JP2806216B2 (ja)	1998-09-30	ケイ素化合物
WO2001032750A1 (en)	2001-05-10	Fluoroelastomers for a wide temperature range of applications
JP7750285B2 (ja)	2025-10-07	架橋剤
JP2002020491A (ja)	2002-01-23	ジアセチレン系ポリオルガノシロキサン、その中間体およびその硬化組成物
JP2000273178A (ja)	2000-10-03	クロロメチルフェニル基含有ジオルガノポリシロキサンおよびその製造方法
US20260035515A1 (en)	2026-02-05	Surface additive based on polysiloxane modified unsaturated polyester
JP2587226B2 (ja)	1997-03-05	ヒドロキシル基含有ポリシロキサン化合物