TW474914B - Catalyst, process for producing the catalyst and process for preparing vinyl acetate using the catalyst - Google Patents

Catalyst, process for producing the catalyst and process for preparing vinyl acetate using the catalyst Download PDF

Info

Publication number: TW474914B
Authority: TW; Taiwan
Prior art keywords: catalyst; scope; item; patent application; palladium
Prior art date: 1997-12-11

Application number

TW087120392A

Other languages

English (en)

Chinese (zh)

Inventor

Bernhard Herzog

Original Assignee

Celanese Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-12-11

Filing date

1998-12-09

Publication date

2002-02-01

1998-12-09 Application filed by Celanese Gmbh filed Critical Celanese Gmbh

2002-02-01 Application granted granted Critical

2002-02-01 Publication of TW474914B publication Critical patent/TW474914B/zh

Links

239000003054 catalyst Substances 0.000 title claims abstract description 74
238000004519 manufacturing process Methods 0.000 title claims abstract description 41
238000000034 method Methods 0.000 title claims abstract description 29
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title claims abstract description 25
230000008569 process Effects 0.000 title abstract description 3
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 74
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 53
229910052763 palladium Inorganic materials 0.000 claims abstract description 37
239000007789 gas Substances 0.000 claims abstract description 30
150000001875 compounds Chemical class 0.000 claims abstract description 28
150000002344 gold compounds Chemical class 0.000 claims abstract description 28
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 21
239000001301 oxygen Substances 0.000 claims abstract description 21
229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
239000012071 phase Substances 0.000 claims abstract description 19
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 16
239000005977 Ethylene Substances 0.000 claims abstract description 16
238000001035 drying Methods 0.000 claims abstract description 16
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052737 gold Inorganic materials 0.000 claims abstract description 15
239000010931 gold Substances 0.000 claims abstract description 15
150000001339 alkali metal compounds Chemical class 0.000 claims abstract description 13
239000003638 chemical reducing agent Substances 0.000 claims abstract description 11
239000012670 alkaline solution Substances 0.000 claims abstract description 9
239000007791 liquid phase Substances 0.000 claims abstract description 6
238000005470 impregnation Methods 0.000 claims description 21
229910052783 alkali metal Inorganic materials 0.000 claims description 16
150000001340 alkali metals Chemical class 0.000 claims description 14
229910052751 metal Inorganic materials 0.000 claims description 12
239000002184 metal Substances 0.000 claims description 12
238000011049 filling Methods 0.000 claims description 11
230000009467 reduction Effects 0.000 claims description 11
-1 ethylene, propylene, isobutylene Chemical group 0.000 claims description 9
150000003839 salts Chemical class 0.000 claims description 9
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
239000007864 aqueous solution Substances 0.000 claims description 8
239000011591 potassium Substances 0.000 claims description 8
229910052700 potassium Inorganic materials 0.000 claims description 8
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical group [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 6
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
235000011056 potassium acetate Nutrition 0.000 claims description 3
230000005855 radiation Effects 0.000 claims description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 2
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
235000019253 formic acid Nutrition 0.000 claims description 2
150000007857 hydrazones Chemical class 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
239000012279 sodium borohydride Substances 0.000 claims description 2
229910000033 sodium borohydride Inorganic materials 0.000 claims description 2
230000002079 cooperative effect Effects 0.000 claims 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
229910001882 dioxygen Inorganic materials 0.000 claims 1
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
239000007792 gaseous phase Substances 0.000 abstract 1
239000000243 solution Substances 0.000 description 30
239000002245 particle Substances 0.000 description 22
239000012876 carrier material Substances 0.000 description 21
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 20
238000006243 chemical reaction Methods 0.000 description 18
229960000583 acetic acid Drugs 0.000 description 15
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
229910002092 carbon dioxide Inorganic materials 0.000 description 11
239000000463 material Substances 0.000 description 11
239000001569 carbon dioxide Substances 0.000 description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
239000000203 mixture Substances 0.000 description 8
239000002904 solvent Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
239000003513 alkali Substances 0.000 description 7
239000010970 precious metal Substances 0.000 description 7
150000001450 anions Chemical class 0.000 description 6
239000011261 inert gas Substances 0.000 description 6
238000010521 absorption reaction Methods 0.000 description 5
150000007514 bases Chemical class 0.000 description 5
150000002736 metal compounds Chemical class 0.000 description 5
229910000510 noble metal Inorganic materials 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 4
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 4
239000000047 product Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000002253 acid Substances 0.000 description 3
150000008044 alkali metal hydroxides Chemical class 0.000 description 3
238000004939 coking Methods 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
238000007598 dipping method Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 3
150000004679 hydroxides Chemical class 0.000 description 3
239000011148 porous material Substances 0.000 description 3
229910052702 rhenium Inorganic materials 0.000 description 3
239000012266 salt solution Substances 0.000 description 3
229910052814 silicon oxide Inorganic materials 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
OTCKNHQTLOBDDD-UHFFFAOYSA-K gold(3+);triacetate Chemical compound [Au+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OTCKNHQTLOBDDD-UHFFFAOYSA-K 0.000 description 2
125000001475 halogen functional group Chemical group 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 2
GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 2
238000012545 processing Methods 0.000 description 2
238000000197 pyrolysis Methods 0.000 description 2
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000005049 silicon tetrachloride Substances 0.000 description 2
229910052722 tritium Inorganic materials 0.000 description 2
238000005406 washing Methods 0.000 description 2
UYSIEGCCYVPJLE-UHFFFAOYSA-N 1,2-dihydroacenaphthylen-1-yl acetate Chemical compound C1=CC(C(OC(=O)C)C2)=C3C2=CC=CC3=C1 UYSIEGCCYVPJLE-UHFFFAOYSA-N 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
ZOZNCAMOIPYYIK-UHFFFAOYSA-N 1-aminoethylideneazanium;acetate Chemical compound CC(N)=N.CC(O)=O ZOZNCAMOIPYYIK-UHFFFAOYSA-N 0.000 description 1
XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 description 1
GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 description 1
GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 1
238000004438 BET method Methods 0.000 description 1
235000017166 Bambusa arundinacea Nutrition 0.000 description 1
235000017491 Bambusa tulda Nutrition 0.000 description 1
241001330002 Bambuseae Species 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
229910052692 Dysprosium Inorganic materials 0.000 description 1
229910016287 MxOy Inorganic materials 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
235000015334 Phyllostachys viridis Nutrition 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
CAYCVXCVDAARCI-UHFFFAOYSA-N [Re].C(C)(=O)OC=C Chemical compound [Re].C(C)(=O)OC=C CAYCVXCVDAARCI-UHFFFAOYSA-N 0.000 description 1
GZRDJPGWGMWUQZ-UHFFFAOYSA-N [Re].[Au] Chemical compound [Re].[Au] GZRDJPGWGMWUQZ-UHFFFAOYSA-N 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
238000010420 art technique Methods 0.000 description 1
239000011425 bamboo Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000011449 brick Substances 0.000 description 1
230000003139 buffering effect Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000007857 degradation product Substances 0.000 description 1
238000011161 development Methods 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
206010015037 epilepsy Diseases 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
150000002343 gold Chemical class 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
229910000449 hafnium oxide Inorganic materials 0.000 description 1
WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
230000036541 health Effects 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000001788 irregular Effects 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
238000002386 leaching Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 1
229910052756 noble gas Inorganic materials 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 description 1
238000010422 painting Methods 0.000 description 1
150000002940 palladium Chemical class 0.000 description 1
150000002941 palladium compounds Chemical class 0.000 description 1
229910003445 palladium oxide Inorganic materials 0.000 description 1
LXNAVEXFUKBNMK-UHFFFAOYSA-N palladium(II) acetate Substances [Pd].CC(O)=O.CC(O)=O LXNAVEXFUKBNMK-UHFFFAOYSA-N 0.000 description 1
YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000006187 pill Substances 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
150000003112 potassium compounds Chemical class 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
ABKQFSYGIHQQLS-UHFFFAOYSA-J sodium tetrachloropalladate Chemical compound [Na+].[Na+].Cl[Pd+2](Cl)(Cl)Cl ABKQFSYGIHQQLS-UHFFFAOYSA-J 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000010025 steaming Methods 0.000 description 1
239000012085 test solution Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229940098465 tincture Drugs 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
- B01J37/344—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
- C07C69/01—Vinyl esters

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Toxicology (AREA)
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TW087120392A 1997-12-11 1998-12-09 Catalyst, process for producing the catalyst and process for preparing vinyl acetate using the catalyst TW474914B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19754992A DE19754992C2 (de)	1997-12-11	1997-12-11	Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators

Publications (1)

Publication Number	Publication Date
TW474914B true TW474914B (en)	2002-02-01

Family

ID=7851508

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW087120392A TW474914B (en)	1997-12-11	1998-12-09	Catalyst, process for producing the catalyst and process for preparing vinyl acetate using the catalyst

Country Status (24)

Country	Link
US (2)	US5968860A (2)
EP (1)	EP0922491B1 (2)
JP (1)	JP4116170B2 (2)
KR (1)	KR100617886B1 (2)
CN (1)	CN1101731C (2)
AR (1)	AR013796A1 (2)
AT (1)	ATE314142T1 (2)
AU (1)	AU9705298A (2)
BR (1)	BR9805322A (2)
CA (1)	CA2255326C (2)
CZ (1)	CZ294655B6 (2)
DE (2)	DE19754992C2 (2)
DK (1)	DK0922491T3 (2)
ES (1)	ES2255125T3 (2)
HU (1)	HUP9802833A3 (2)
ID (1)	ID21457A (2)
MY (1)	MY117157A (2)
NO (1)	NO985784L (2)
NZ (1)	NZ333248A (2)
PL (1)	PL330213A1 (2)
SG (1)	SG75903A1 (2)
TR (1)	TR199802558A2 (2)
TW (1)	TW474914B (2)
ZA (1)	ZA9811282B (2)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19828491A1 (de) *	1998-06-26	1999-12-30	Degussa	Formkörper auf Basis von Siliciumdioxid
DE19843693A1 (de) *	1998-09-24	2000-03-30	Degussa	Trägerkatalysator für die Produktion von Vinylacetatmonomer
CN1101729C (zh) *	1999-11-10	2003-02-19	大连化学工业股份有限公司	氧酰化反应用催化剂和其制备方法及其应用
CA2389448A1 (en) *	1999-11-17	2001-05-25	Celanese International Corporation	Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6303537B1 (en)	1999-11-17	2001-10-16	Celanese International Corporation	Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6794332B2 (en) *	2000-07-07	2004-09-21	Saudi Basic Industries Corporation	Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
US6420308B1 (en) *	2000-07-07	2002-07-16	Saudi Basic Industries Corp	Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
EP1792652A1 (en) *	2000-11-09	2007-06-06	Dairen Chemical Corporation	Process for preparation of catalyst
CN1281322C (zh) *	2001-03-30	2006-10-25	国际壳牌研究有限公司	制备含viii族金属的催化剂的方法和该催化剂用于制备烯基羧酸酯的用途
JP4421201B2 (ja) *	2002-03-27	2010-02-24	シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー	触媒を調製する方法、触媒、および触媒の使用
US6936568B2 (en)	2002-06-12	2005-08-30	Sud-Chemie Inc.	Selective hydrogenation catalyst
TW201236755A (en) *	2003-12-19	2012-09-16	Celanese Int Corp	Halide free precursors for catalysts
JP2008524217A (ja)	2004-12-20	2008-07-10	セラニーズ・インターナショナル・コーポレーション	触媒用の改質担持材
US8227369B2 (en) *	2005-05-25	2012-07-24	Celanese International Corp.	Layered composition and processes for preparing and using the composition
CN100551523C (zh) *	2005-10-28	2009-10-21	厦门大学	一种金属氧化物负载的贵金属催化剂制备方法
EP2368629B1 (en)	2008-11-26	2019-04-03	China Petroleum&Chemical Corporation	Metal loaded catalyst and preparation method thereof
CN102247838B (zh) *	2010-05-21	2013-03-27	中国石油化工股份有限公司	具有特定红外吸收特征的负载型钯催化剂
JP6392218B2 (ja) *	2012-07-02	2018-09-19	ビーエーエスエフコーポレーション	酢酸ビニルモノマーの製造のための方法及び複合触媒
KR20230024351A (ko)	2020-06-11	2023-02-20	셀라니즈 인터내셔날 코포레이션	비닐 아세테이트 생성을 위한 촉매의 제조 방법
CN116550383B (zh) *	2023-07-12	2023-10-31	中国天辰工程有限公司	一种不饱和醋酸酯及其催化剂的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3627821A (en) *	1967-12-23	1971-12-14	Knapsack Ag	Process for the manufacture of unsaturated esters of carboxylic acids
EP0519824A1 (fr) *	1991-06-19	1992-12-23	Georges Roussy	Procédé catalytique micro-onde de réformage des hydrocarbures
FR2677898B1 (fr) *	1991-06-19	1994-10-07	Georges Roussy	Procede de fabrication des catalyseurs metalliques deposes sur supports d'oxydes.
DE4120492A1 (de) *	1991-06-21	1992-12-24	Hoechst Ag	Verfahren zur herstellung von vinylacetat
US5332710A (en) *	1992-10-14	1994-07-26	Hoechst Celanese Corporation	Vinyl acetate catalyst preparation method
DE19613791C2 (de) *	1996-04-04	2002-01-31	Celanese Chem Europe Gmbh	Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat

1997
- 1997-12-11 DE DE19754992A patent/DE19754992C2/de not_active Expired - Fee Related
1998
- 1998-11-26 ID IDP981544A patent/ID21457A/id unknown
- 1998-12-02 ES ES98122922T patent/ES2255125T3/es not_active Expired - Lifetime
- 1998-12-02 DK DK98122922T patent/DK0922491T3/da active
- 1998-12-02 US US09/203,688 patent/US5968860A/en not_active Expired - Lifetime
- 1998-12-02 EP EP98122922A patent/EP0922491B1/de not_active Expired - Lifetime
- 1998-12-02 DE DE59813314T patent/DE59813314D1/de not_active Expired - Lifetime
- 1998-12-02 AT AT98122922T patent/ATE314142T1/de active
- 1998-12-07 HU HU9802833A patent/HUP9802833A3/hu unknown
- 1998-12-09 TW TW087120392A patent/TW474914B/zh not_active IP Right Cessation
- 1998-12-09 JP JP35032298A patent/JP4116170B2/ja not_active Expired - Fee Related
- 1998-12-09 AR ARP980106251A patent/AR013796A1/es unknown
- 1998-12-09 NZ NZ333248A patent/NZ333248A/xx unknown
- 1998-12-09 CA CA002255326A patent/CA2255326C/en not_active Expired - Fee Related
- 1998-12-09 SG SG1998005393A patent/SG75903A1/en unknown
- 1998-12-09 ZA ZA9811282A patent/ZA9811282B/xx unknown
- 1998-12-09 CZ CZ19984049A patent/CZ294655B6/cs not_active IP Right Cessation
- 1998-12-09 TR TR1998/02558A patent/TR199802558A2/xx unknown
- 1998-12-10 CN CN98123287A patent/CN1101731C/zh not_active Expired - Fee Related
- 1998-12-10 NO NO985784A patent/NO985784L/no not_active Application Discontinuation
- 1998-12-10 BR BR9805322-1A patent/BR9805322A/pt not_active Application Discontinuation
- 1998-12-10 KR KR1019980054067A patent/KR100617886B1/ko not_active Expired - Fee Related
- 1998-12-10 AU AU97052/98A patent/AU9705298A/en not_active Abandoned
- 1998-12-10 PL PL98330213A patent/PL330213A1/xx unknown
- 1998-12-10 MY MYPI98005583A patent/MY117157A/en unknown
1999
- 1999-06-02 US US09/324,819 patent/US6114573A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
ZA9811282B (en)	1999-06-10
HU9802833D0 (en)	1999-02-01
DE59813314D1 (de)	2006-02-02
EP0922491B1 (de)	2005-12-28
DE19754992C2 (de)	2000-03-23
NZ333248A (en)	2000-04-28
EP0922491A2 (de)	1999-06-16
JP4116170B2 (ja)	2008-07-09
AU9705298A (en)	1999-07-01
EP0922491A3 (de)	2000-03-29
US5968860A (en)	1999-10-19
TR199802558A3 (tr)	1999-07-21
TR199802558A2 (xx)	1999-07-21
MY117157A (en)	2004-05-31
ES2255125T3 (es)	2006-06-16
BR9805322A (pt)	1999-11-23
NO985784L (no)	1999-06-14
CZ294655B6 (cs)	2005-02-16
SG75903A1 (en)	2000-10-24
CA2255326C (en)	2007-05-29
CN1101731C (zh)	2003-02-19
PL330213A1 (en)	1999-06-21
JPH11244696A (ja)	1999-09-14
CN1221651A (zh)	1999-07-07
ID21457A (id)	1999-06-17
HUP9802833A2 (hu)	1999-10-28
KR19990062950A (ko)	1999-07-26
HUP9802833A3 (en)	2000-10-30
ATE314142T1 (de)	2006-01-15
DK0922491T3 (da)	2006-02-13
NO985784D0 (no)	1998-12-10
KR100617886B1 (ko)	2007-04-25
DE19754992A1 (de)	1999-06-24
CZ404998A3 (cs)	1999-06-16
AR013796A1 (es)	2001-01-10
CA2255326A1 (en)	1999-06-11
US6114573A (en)	2000-09-05

Legal Events

Date	Code	Title	Description
2002-05-24	GD4A	Issue of patent certificate for granted invention patent
2014-11-01	MM4A	Annulment or lapse of patent due to non-payment of fees

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