TWI316975B - - Google Patents

Download PDF

Info

Publication number: TWI316975B
Authority: TW; Taiwan
Prior art keywords: plating solution; plating; weight; hypophosphite; solution according
Prior art date: 2006-05-04

Application number

TW95115897A

Other languages

English (en)

Chinese (zh)

Other versions

TW200742773A (en

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-05-04

Filing date

2006-05-04

Publication date

2009-11-11

2006-05-04 Application filed filed Critical

2006-05-04 Priority to TW095115897A priority Critical patent/TW200742773A/zh

2007-11-16 Publication of TW200742773A publication Critical patent/TW200742773A/zh

2009-11-11 Application granted granted Critical

2009-11-11 Publication of TWI316975B publication Critical patent/TWI316975B/zh

Links

238000007747 plating Methods 0.000 claims description 36
238000009713 electroplating Methods 0.000 claims description 13
150000003839 salts Chemical class 0.000 claims description 13
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 9
239000003795 chemical substances by application Substances 0.000 claims description 7
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical group [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
239000011574 phosphorus Substances 0.000 claims description 6
229910052698 phosphorus Inorganic materials 0.000 claims description 6
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
229910052759 nickel Inorganic materials 0.000 claims description 5
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 5
229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 4
BWHOZHOGCMHOBV-UHFFFAOYSA-N Benzalacetone Natural products CC(=O)C=CC1=CC=CC=C1 BWHOZHOGCMHOBV-UHFFFAOYSA-N 0.000 claims description 3
235000019270 ammonium chloride Nutrition 0.000 claims description 3
239000001509 sodium citrate Substances 0.000 claims description 3
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical group CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 claims description 3
KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 2
GJYJYFHBOBUTBY-UHFFFAOYSA-N alpha-camphorene Chemical compound CC(C)=CCCC(=C)C1CCC(CCC=C(C)C)=CC1 GJYJYFHBOBUTBY-UHFFFAOYSA-N 0.000 claims description 2
238000005660 chlorination reaction Methods 0.000 claims description 2
ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 2
229910001380 potassium hypophosphite Inorganic materials 0.000 claims description 2
CRGPNLUFHHUKCM-UHFFFAOYSA-M potassium phosphinate Chemical compound [K+].[O-]P=O CRGPNLUFHHUKCM-UHFFFAOYSA-M 0.000 claims description 2
229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 2
239000004902 Softening Agent Substances 0.000 claims 1
239000002253 acid Substances 0.000 claims 1
239000000243 solution Substances 0.000 description 18
229910000831 Steel Inorganic materials 0.000 description 11
239000010959 steel Substances 0.000 description 11
230000000052 comparative effect Effects 0.000 description 10
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
229910052725 zinc Inorganic materials 0.000 description 8
239000011701 zinc Substances 0.000 description 8
239000007921 spray Substances 0.000 description 7
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
239000007788 liquid Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
230000007797 corrosion Effects 0.000 description 4
238000005260 corrosion Methods 0.000 description 4
239000011521 glass Substances 0.000 description 4
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
229910052718 tin Inorganic materials 0.000 description 4
229910001297 Zn alloy Inorganic materials 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000011592 zinc chloride Substances 0.000 description 3
235000005074 zinc chloride Nutrition 0.000 description 3
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229910001209 Low-carbon steel Inorganic materials 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
239000000956 alloy Substances 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000002309 gasification Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000000034 method Methods 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
239000001119 stannous chloride Substances 0.000 description 2
235000011150 stannous chloride Nutrition 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000758 substrate Substances 0.000 description 2
NCOYDQIWSSMOEW-UHFFFAOYSA-K 2-hydroxypropane-1,2,3-tricarboxylate;lanthanum(3+) Chemical compound [La+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NCOYDQIWSSMOEW-UHFFFAOYSA-K 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
240000000233 Melia azedarach Species 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
239000005708 Sodium hypochlorite Substances 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
239000005083 Zinc sulfide Substances 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000005611 electricity Effects 0.000 description 1
230000003203 everyday effect Effects 0.000 description 1
238000005242 forging Methods 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
239000004575 stone Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000011135 tin Substances 0.000 description 1
229910001432 tin ion Inorganic materials 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
ZULTYUIALNTCSA-UHFFFAOYSA-N zinc hydride Chemical compound [ZnH2] ZULTYUIALNTCSA-UHFFFAOYSA-N 0.000 description 1
229910000051 zinc hydride Inorganic materials 0.000 description 1
229910052984 zinc sulfide Inorganic materials 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1

Landscapes

Electroplating And Plating Baths Therefor (AREA)

TW095115897A 2006-05-04 2006-05-04 Electroplated layer and electroplating solution for forming the same TW200742773A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
TW095115897A TW200742773A (en)	2006-05-04	2006-05-04	Electroplated layer and electroplating solution for forming the same

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
TW095115897A TW200742773A (en)	2006-05-04	2006-05-04	Electroplated layer and electroplating solution for forming the same

Publications (2)

Publication Number	Publication Date
TW200742773A TW200742773A (en)	2007-11-16
TWI316975B true TWI316975B (fr)	2009-11-11

Family

ID=45073301

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW095115897A TW200742773A (en)	2006-05-04	2006-05-04	Electroplated layer and electroplating solution for forming the same

Country Status (1)

Country	Link
TW (1)	TW200742773A (fr)

2006
- 2006-05-04 TW TW095115897A patent/TW200742773A/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
TW200742773A (en)	2007-11-16

Legal Events

Date	Code	Title	Description
2019-08-11	MM4A	Annulment or lapse of patent due to non-payment of fees

Publication	Publication Date	Title
CA2822476C (fr)	2016-12-13	Substrat dote d'un revetement resistant a la corrosion et son procede de production
CA3006141C (fr)	2025-02-11	Revetements multicouches zinc-fer modules par la composition
CN107841771A (zh)	2018-03-27	一种基于复合配位体系的无氰镀银液组合物及其应用
US20090211914A1 (en)	2009-08-27	Trivalent Chromium Electroplating Solution and an Operational Method Thereof
KR900000794B1 (ko)	1990-02-16	고내식성 표면 처리강판 및 그 제조방법
JP2012126951A (ja)	2012-07-05	ニッケルめっき液及びニッケルめっき方法
CN109137016A (zh)	2019-01-04	一种碱性石墨烯锌铁合金电镀液、制备方法及电镀工艺
KR20090123928A (ko)	2009-12-02	블랙 루테늄의 장식층 및 기술층을 전착시키기 위한 전해액 및 방법
CN103429794B (zh)	2016-11-09	锌‑铁合金层材料
TWI316975B (fr)	2009-11-11
US9435047B2 (en)	2016-09-06	Process for corrosion protection of iron containing materials
US20190136383A1 (en)	2019-05-09	Trivalent chromium chemical conversion liquid for zinc or zinc alloy bases and chemical conversion coating film
CN106521574B (zh)	2018-10-26	一种适用于宽pH和宽电流密度范围的无氰镀铜电镀液及其制备方法
CN101392395B (zh)	2011-10-26	环保型化学镀镍光亮剂及其应用
JP2009079263A (ja)	2009-04-16	表面処理亜鉛系めっき金属材及びその製造方法
CN102644097A (zh)	2012-08-22	在水溶液中电共沉积锌镁合金镀层的制备方法
CN101760769A (zh)	2010-06-30	非晶态铁磷合金电镀液及其配制方法
CN106544707A (zh)	2017-03-29	钢芯酸性亚铜亚锡电镀阶梯仿金青铜
CN120945449B (zh)	2026-02-06	一种电镀金镀液与电镀金的方法和金镀层
CN114808050B (zh)	2024-05-10	一种纳米镀镍药液及镀镍方法
JPS61130498A (ja)	1986-06-18	無塗装および塗装後の耐食性に優れた複合めつき鋼板
Galeotti	2022	Electrodeposition of Zn-Cr alloy coatings for corrosion protection
TWI316974B (en)	2009-11-11	Phosphate treated zinc-coated steel sheet having excellent corrosion resistance and blackening resistance
TWI322200B (fr)	2010-03-21
Popescu et al.	2013	Morphology and corrosion behavior of Zn-Ni-P thin films electrolessly deposited from chloride baths