TWI494617B - 帶有圖像之稜柱狀逆反射物件及其製造方法 - Google Patents

帶有圖像之稜柱狀逆反射物件及其製造方法 Download PDF

Info

Publication number: TWI494617B
Authority: TW; Taiwan
Prior art keywords: image; retroreflective article; optical layer; prismatic retroreflective; donor sheet
Prior art date: 2008-12-08

Application number

TW098141393A

Other languages

English (en)

Chinese (zh)

Other versions

TW201030386A (en

Inventor

Warren Paul Caswell

Stewart Henry Corn

Chester Arthur Bacon

Original Assignee

3M Innovative Properties Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2008-12-08

Filing date

2009-12-03

Publication date

2015-08-01

2009-12-03 Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co

2010-08-16 Publication of TW201030386A publication Critical patent/TW201030386A/zh

2015-08-01 Application granted granted Critical

2015-08-01 Publication of TWI494617B publication Critical patent/TWI494617B/zh

Links

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Classifications

- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B21/00—Microscopes
- G02B21/36—Microscopes arranged for photographic purposes or projection purposes or digital imaging or video purposes including associated control and data processing arrangements
- G02B21/365—Control or image processing arrangements for digital or video microscopes
- G02B21/367—Control or image processing arrangements for digital or video microscopes providing an output produced by processing a plurality of individual source images, e.g. image tiling, montage, composite images, depth sectioning, image comparison

Landscapes

Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Optics & Photonics (AREA)
Engineering & Computer Science (AREA)
Multimedia (AREA)
Computer Vision & Pattern Recognition (AREA)
Chemical & Material Sciences (AREA)
Analytical Chemistry (AREA)
Optical Elements Other Than Lenses (AREA)
Laminated Bodies (AREA)

TW098141393A 2008-12-08 2009-12-03 帶有圖像之稜柱狀逆反射物件及其製造方法 TWI494617B (zh)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US12068908P	2008-12-08	2008-12-08

Publications (2)

Publication Number	Publication Date
TW201030386A TW201030386A (en)	2010-08-16
TWI494617B true TWI494617B (zh)	2015-08-01

Family

ID=42310468

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW098141393A TWI494617B (zh)	2008-12-08	2009-12-03	帶有圖像之稜柱狀逆反射物件及其製造方法

Country Status (8)

Country	Link
US (1)	US8668341B2 (de)
EP (1)	EP2361396A4 (de)
JP (1)	JP2012511177A (de)
KR (1)	KR101610427B1 (de)
CN (1)	CN102272637B (de)
CA (1)	CA2745761A1 (de)
TW (1)	TWI494617B (de)
WO (1)	WO2010077474A2 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2012511178A (ja)	2008-12-08	2012-05-17	スリーエムイノベイティブプロパティズカンパニー	図形を有する保護オーバーレイ及びオーバーレイを含む再帰反射性物品
US10925268B1 (en) *	2015-03-13	2021-02-23	Ray D. Flasco	Inside corner cubic surface reflector fishing lure
JP6452815B2 (ja) *	2015-06-12	2019-01-16	日本カーバイド工業株式会社	画像表示装置
US20170030553A1 (en) *	2015-07-31	2017-02-02	LED Living Technology, Inc.	Lighting System that Reduces Environmental Light Pollution
EP3583450A1 (de)	2017-02-20	2019-12-25	3M Innovative Properties Company	Optische artikel und damit interagierende systeme
TWI756466B (zh)	2017-08-29	2022-03-01	美商艾維利丹尼森公司	用於基於投影機的顯示系統的回射片
CN108120834B (zh) *	2017-12-08	2020-04-24	上海君联医疗设备有限公司	一种凝集变异细胞的试剂组合物
WO2020167853A1 (en) *	2019-02-11	2020-08-20	Fiberlok Technologies	Light retroreflective graphic textile
US12032059B2 (en) *	2019-05-24	2024-07-09	3M Innovative Properties Company	Radar-optical fusion article and system
CN111751557A (zh) *	2020-07-16	2020-10-09	上海君联医疗设备有限公司	糖链蛋白及钙-组蛋白检测试剂组合物及其用途
JP2025510699A (ja) *	2022-03-25	2025-04-15	アプライドマテリアルズインコーポレイテッド	個別の回折モジュールアセンブリを使用する光学装置の低コスト製造

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6024455A (en) *	1998-01-13	2000-02-15	3M Innovative Properties Company	Reflective article with concealed retroreflective pattern
TW467829B (en) *	1999-05-07	2001-12-11	Chang-San Lin	The manufacturing method of light-reversing reflection material for color images

Family Cites Families (72)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP4063472B2 (ja)	2000-04-10	2008-03-19	日本カーバイド工業株式会社	印刷された再帰反射シート
US3684348A (en)	1970-09-29	1972-08-15	Rowland Dev Corp	Retroreflective material
US4025159A (en)	1976-02-17	1977-05-24	Minnesota Mining And Manufacturing Company	Cellular retroreflective sheeting
US4153412A (en) *	1977-04-25	1979-05-08	Minnesota Mining And Manufacturing Company	Process for printing reflective sheet material
US4588258A (en)	1983-09-12	1986-05-13	Minnesota Mining And Manufacturing Company	Cube-corner retroreflective articles having wide angularity in multiple viewing planes
EP0201323B1 (de) *	1985-05-07	1994-08-17	Dai Nippon Insatsu Kabushiki Kaisha	Artikel mit transparentem Hologramm
US5064272A (en)	1985-11-18	1991-11-12	Minnesota Mining And Manufacturing Company	Encapsulated-lens retroreflective sheeting and method of making
US4664966A (en)	1985-11-18	1987-05-12	Minnesota Mining And Manufacturing Company	Enclosed-lens retroreflective sheeting having tough, weather-resistant, transparent cover film
US4775219A (en)	1986-11-21	1988-10-04	Minnesota Mining & Manufacturing Company	Cube-corner retroreflective articles having tailored divergence profiles
US4983436A (en)	1987-04-15	1991-01-08	Minnesota Mining And Manufacturing Company	Retroreflective sheeting with backing film
US5066098A (en)	1987-05-15	1991-11-19	Minnesota Mining And Manufacturing Company	Cellular encapsulated-lens high whiteness retroreflective sheeting with flexible cover sheet
US5262225A (en)	1988-09-02	1993-11-16	Minnesota Mining And Manufacturing Company	Embossable sign construction
US5069964A (en)	1989-05-23	1991-12-03	Minnesota Mining And Manufacturing Company	Flexible, substrate-insular retroreflective sheeting
US5080463A (en)	1989-06-21	1992-01-14	Minnesota Mining And Manufacturing Company	Retroreflective security laminates with protective cover sheets
US6790578B1 (en)	1990-05-15	2004-09-14	3M Innovative Properties Company	Printing of reflective sheeting
US5085918A (en)	1990-05-15	1992-02-04	Minnesota Mining And Manufacturing Company	Printed retroreflective sheet
US5229882A (en)	1990-05-16	1993-07-20	Reflexite Corporation	Colored retroreflective sheeting and method of making same
US5138488A (en)	1990-09-10	1992-08-11	Minnesota Mining And Manufacturing Company	Retroreflective material with improved angularity
ZA918849B (en)	1990-12-06	1992-08-26	Minnesota Mining & Mfg	Articles exhibiting durable fluorescence
US5213872A (en)	1991-04-19	1993-05-25	Stimsonite Corporation	Preprinted retroreflective highway sign and method for making the sign
US5169707A (en)	1991-05-08	1992-12-08	Minnesota Mining And Manufacturing Company	Retroreflective security laminates with dual level verification
US5977263A (en)	1992-12-10	1999-11-02	3M Innovative Properties Company	Thermal transfer compositions, articles and graphic articles made with same
US5272562A (en) *	1993-02-05	1993-12-21	Minnesota Mining And Manufacturing Company	Cube-corner retroreflective articles
CA2115325A1 (en)	1993-03-12	1994-09-13	Robert F. Watkins	Retroreflective article clear coats
US5324621A (en)	1993-04-08	1994-06-28	Agfa-Gavaert, N.V.	Dyes and dye-donor elements for thermal dye transfer recording
US5344705A (en)	1993-05-05	1994-09-06	Minnesota Mining And Manufacturing Company	Retroreflective transfer sheet material
US5393590A (en)	1993-07-07	1995-02-28	Minnesota Mining And Manufacturing Company	Hot stamping foil
US5450235A (en)	1993-10-20	1995-09-12	Minnesota Mining And Manufacturing Company	Flexible cube-corner retroreflective sheeting
US5691846A (en)	1993-10-20	1997-11-25	Minnesota Mining And Manufacturing Company	Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture
US5614286A (en)	1993-10-20	1997-03-25	Minnesota Mining And Manufacturing Company	Conformable cube corner retroreflective sheeting
JPH0885251A (ja)	1994-07-21	1996-04-02	Canon Inc	捺染方法及びそれによって得られる捺染物
EP0794975B1 (de)	1994-11-28	2000-02-09	Minnesota Mining And Manufacturing Company	Gegenstände mit dauerhaften farb- und/oder fluoreszenzeigenschaften
US5706133A (en)	1995-02-09	1998-01-06	Minnesota Mining And Manufacturing Company	Retroreflective signage articles, kits for producing same, and methods of making signage articles
DE69620779T2 (de)	1995-11-02	2002-11-07	Minnesota Mining And Mfg. Co., Saint Paul	Mikrostrukturierter gegenstand mit einem träger und verfahren zur herstellung
US5656360A (en)	1996-02-16	1997-08-12	Minnesota Mining And Manufacturing Company	Article with holographic and retroreflective features
US5770124A (en)	1996-04-30	1998-06-23	Minnesota Mining And Manufacturing Company	Method of making glittering cube-corner retroreflective sheeting
US5814355A (en) *	1996-04-30	1998-09-29	Minnesota Mining And Manufacturing Company	Mold for producing glittering cube-corner retroreflective sheeting
US6200666B1 (en)	1996-07-25	2001-03-13	3M Innovative Properties Company	Thermal transfer compositions, articles, and graphic articles made with same
JP3974959B2 (ja)	1996-09-30	2007-09-12	スリーエムカンパニー	再帰反射性情報表示シートの製造方法
DE19736083A1 (de)	1997-08-20	1999-02-25	Basf Coatings Ag	Mehrschichtlackierungen und Verfahren zu deren Herstellung
KR100259503B1 (ko)	1997-12-31	2001-09-22	이종수	컴퓨터를이용한인쇄강판제작방법
US6157486A (en)	1998-01-13	2000-12-05	3M Innovative Properties Company	Retroreflective dichroic reflector
US6054208A (en)	1998-01-16	2000-04-25	Avery Dennison Corporation	Film forming mixtures, image bearing films and image bearing retroreflective sheeting
US6120636A (en)	1998-01-26	2000-09-19	Reflexite Corporation	Apparatus and method for producing retroreflective material having printed patterns thereon
US6119751A (en)	1998-01-26	2000-09-19	Reflexite Corporation	Apparatus and method for producing retroreflective material having printed patterns thereon
JP3477361B2 (ja)	1998-03-06	2003-12-10	ソニーケミカル株式会社	熱転写記録媒体
KR20010041727A (ko) *	1998-03-09	2001-05-25	스프레이그 로버트 월터	광각 이미지 디스플레이 시트 및 시스템
JP4225599B2 (ja)	1998-03-09	2009-02-18	スリーエムカンパニー	イメージ表示シートおよびイメージ表示システム
US6172810B1 (en)	1999-02-26	2001-01-09	3M Innovative Properties Company	Retroreflective articles having polymer multilayer reflective coatings
US6677028B1 (en)	1999-09-10	2004-01-13	3M Innovative Properties Company	Retroreflective articles having multilayer films and methods of manufacturing same
WO2002019038A2 (en)	2000-08-30	2002-03-07	3M Innovative Properties Company	Graphic base construction, retroreflective graphic article made therefrom and method of making
CN1245643C (zh)	2000-10-27	2006-03-15	林昌三	彩色图案的光线回逆反射材料制造方法
US6534128B1 (en)	2000-11-09	2003-03-18	3M Innovative Properties Company	Inks and other compositions incorporating low viscosity, radiation curable, polyester urethane oligomer
US6534158B2 (en)	2001-02-16	2003-03-18	3M Innovative Properties Company	Color shifting film with patterned fluorescent and non-fluorescent colorants
US6506480B2 (en)	2001-02-16	2003-01-14	3M Innovative Properties Company	Color shifting film with a plurality of fluorescent colorants
US6953624B2 (en)	2001-03-02	2005-10-11	3M Innovative Properties Company	Printable film and coating composition exhibiting stain resistance
US6723433B2 (en)	2001-03-02	2004-04-20	3M Innovative Properties Company	Printable film and coating composition exhibiting stain resistance
US6720042B2 (en)	2001-04-18	2004-04-13	3M Innovative Properties Company	Primed substrates comprising radiation cured ink jetted images
US20030211299A1 (en)	2001-09-27	2003-11-13	3M Innovative Properties Company	Adhesion-enhancing surfaces for marking materials
DE10226932A1 (de)	2002-06-17	2003-12-24	Bayer Ag	Strahlenhärtende Beschichtungsmittel
JP2004036161A (ja) *	2002-07-02	2004-02-05	Sekisui Jushi Co Ltd	再帰反射体
JP2004037831A (ja) *	2002-07-03	2004-02-05	Nitto Denko Corp	再帰性反射板、再帰性反射板付き偏光板及びこれを用いた液晶表示装置
JP4024094B2 (ja) *	2002-07-09	2007-12-19	日東電工株式会社	再帰性反射板、再帰性反射板付き偏光板及びこれを用いた液晶表示装置
US20040029044A1 (en)	2002-08-08	2004-02-12	3M Innovative Properties Company	Photocurable composition
JP2004136541A (ja) *	2002-10-17	2004-05-13	Toshiba Corp	熱転写記録媒体及び印刷物
DE20316349U1 (de) *	2003-10-24	2003-12-24	Fer Fahrzeugelektrik Gmbh	Schild
US7648744B2 (en) *	2004-08-06	2010-01-19	3M Innovative Properties Company	Tamper-indicating printable sheet for securing documents of value and methods of making the same
US7195360B2 (en) *	2004-12-28	2007-03-27	3M Innovative Properties Company	Prismatic retroreflective article and method
US7611251B2 (en) *	2006-04-18	2009-11-03	3M Innovative Properties Company	Retroreflective articles comprising olefinic seal films
EP2131218A4 (de) *	2007-03-30	2012-02-29	Nippon Carbide Kogyo Kk	Rückstrahlendes objekt
US7547105B2 (en)	2007-07-16	2009-06-16	3M Innovative Properties Company	Prismatic retroreflective article with cross-linked image layer and method of making same
JP2012511178A (ja)	2008-12-08	2012-05-17	スリーエムイノベイティブプロパティズカンパニー	図形を有する保護オーバーレイ及びオーバーレイを含む再帰反射性物品

2009
- 2009-11-20 CA CA2745761A patent/CA2745761A1/en not_active Abandoned
- 2009-11-20 KR KR1020117015499A patent/KR101610427B1/ko not_active Expired - Fee Related
- 2009-11-20 WO PCT/US2009/065228 patent/WO2010077474A2/en not_active Ceased
- 2009-11-20 EP EP09836610.7A patent/EP2361396A4/de not_active Withdrawn
- 2009-11-20 JP JP2011539584A patent/JP2012511177A/ja active Pending
- 2009-11-20 CN CN200980153674.2A patent/CN102272637B/zh not_active Expired - Fee Related
- 2009-11-20 US US13/130,833 patent/US8668341B2/en active Active
- 2009-12-03 TW TW098141393A patent/TWI494617B/zh not_active IP Right Cessation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6024455A (en) *	1998-01-13	2000-02-15	3M Innovative Properties Company	Reflective article with concealed retroreflective pattern
TW467829B (en) *	1999-05-07	2001-12-11	Chang-San Lin	The manufacturing method of light-reversing reflection material for color images

Also Published As

Publication number	Publication date
EP2361396A2 (de)	2011-08-31
CN102272637A (zh)	2011-12-07
EP2361396A4 (de)	2018-01-24
US20110228393A1 (en)	2011-09-22
WO2010077474A2 (en)	2010-07-08
WO2010077474A3 (en)	2010-08-26
JP2012511177A (ja)	2012-05-17
KR101610427B1 (ko)	2016-04-07
CN102272637B (zh)	2016-01-20
US8668341B2 (en)	2014-03-11
KR20110098782A (ko)	2011-09-01
TW201030386A (en)	2010-08-16
CA2745761A1 (en)	2010-07-08

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Date	Code	Title	Description
2020-05-01	MM4A	Annulment or lapse of patent due to non-payment of fees

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