UA116332C2 - Спосіб каталітичного гідропіролізу з шаром, який барботується, що використовує крупні частинки каталізатора і дрібні частинки біомаси, які характеризують реактор з "антипробкоутворенням" - Google Patents

Спосіб каталітичного гідропіролізу з шаром, який барботується, що використовує крупні частинки каталізатора і дрібні частинки біомаси, які характеризують реактор з "антипробкоутворенням"

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Publication number
UA116332C2
UA116332C2 UAA201313337A UAA201313337A UA116332C2 UA 116332 C2 UA116332 C2 UA 116332C2 UA A201313337 A UAA201313337 A UA A201313337A UA A201313337 A UAA201313337 A UA A201313337A UA 116332 C2 UA116332 C2 UA 116332C2
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UA
Ukraine
Prior art keywords
reactor
particles
bed
vapor stream
slugging
Prior art date
Application number
UAA201313337A
Other languages
English (en)
Inventor
Террі Л. Маркер
Ларрі Дж. Фелікс
Мартін Б. Лінк
Майкл Дж. РОБЕРТС
Original Assignee
Гез Текнолоджи Інстітьют
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Publication date
Application filed by Гез Текнолоджи Інстітьют filed Critical Гез Текнолоджи Інстітьют
Publication of UA116332C2 publication Critical patent/UA116332C2/uk

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    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Даний винахід стосується способу термохімічного перетворення біомаси або іншої насиченої киснем вихідної сировини у високоякісне рідке вуглеводневе паливо. Зокрема, реактор каталітичного гідропіролізу, що містить глибокий шар псевдозріджених частинок каталізатора, використовується для введення частинок біомаси або іншої насиченої киснем вихідної сировини, які є значно дрібнішими, ніж частинки каталізатора в псевдозрідженому шарі. Реактор характеризується вставкою або іншою конструкцією, розташованою в реакторній посудині, яка перешкоджає "пробкоутворенню" шару і тому мінімізує стирання каталізатора. У шарі вихідна сировина біомаси перетворюється в парофазний продукт, що містить вуглеводневі молекули й інші пари способу, і продукт віднесеного твердого вугілля, який відділяється від потоку парів після того, як потік парів виходить з верхньої частини реактора. Коли потік парів продукту охолоджується до навколишньої температури, значна пропорція вуглеводнів в потоці парів продукту може бути витягнута як рідкий потік гідрофобних вуглеводнів з властивостями, співпадаючими з властивостями бензину, гасу і дизельного палива. Також можуть бути одержані окремі потоки бензину, гасу і дизельного палива або шляхом селективної конденсації кожного виду палива, або шляхом подальшої дистиляції об'єднаної вуглеводневої рідини.
UAA201313337A 2011-04-18 2012-03-23 Спосіб каталітичного гідропіролізу з шаром, який барботується, що використовує крупні частинки каталізатора і дрібні частинки біомаси, які характеризують реактор з "антипробкоутворенням" UA116332C2 (uk)

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US13/089,010 US8841495B2 (en) 2011-04-18 2011-04-18 Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
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