ECSP13013030A - Proceso de hidropirolisis catalítica de lecho burbujeante que utiliza partículas catalizadoras más grandes y particulas de biomasa más pequeñas representando un reactor anti - ensuciamiento - Google Patents

Proceso de hidropirolisis catalítica de lecho burbujeante que utiliza partículas catalizadoras más grandes y particulas de biomasa más pequeñas representando un reactor anti - ensuciamiento

Info

Publication number
ECSP13013030A
ECSP13013030A ECSP13013030A ECSP13013030A EC SP13013030 A ECSP13013030 A EC SP13013030A EC SP13013030 A ECSP13013030 A EC SP13013030A EC SP13013030 A ECSP13013030 A EC SP13013030A
Authority
EC
Ecuador
Prior art keywords
reactor
particles
biomass
bed
vapor stream
Prior art date
Application number
Other languages
English (en)
Inventor
Michael Roberts
Terry L Marker
Larry G Felix
Martin B Linck
Original Assignee
Gas Technology Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gas Technology Inst filed Critical Gas Technology Inst
Publication of ECSP13013030A publication Critical patent/ECSP13013030A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809—Controlling processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/34—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/57—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds according to the fluidised bed technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B01J2208/00061—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/0084—Stationary elements inside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00252—Formation of deposits other than coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1018—Biomass of animal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.
ECSP13013030 2011-04-18 2013-11-18 Proceso de hidropirolisis catalítica de lecho burbujeante que utiliza partículas catalizadoras más grandes y particulas de biomasa más pequeñas representando un reactor anti - ensuciamiento ECSP13013030A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US13/089,010 US8841495B2 (en) 2011-04-18 2011-04-18 Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

Publications (1)

Publication Number Publication Date
ECSP13013030A true ECSP13013030A (es) 2015-03-31

Family

ID=45922854

Family Applications (1)

Application Number Title Priority Date Filing Date
ECSP13013030 ECSP13013030A (es) 2011-04-18 2013-11-18 Proceso de hidropirolisis catalítica de lecho burbujeante que utiliza partículas catalizadoras más grandes y particulas de biomasa más pequeñas representando un reactor anti - ensuciamiento

Country Status (17)

Country Link
US (2) US8841495B2 (es)
EP (2) EP3190165B1 (es)
JP (2) JP6133272B2 (es)
KR (2) KR101926353B1 (es)
CN (2) CN105001897B (es)
AU (1) AU2012246685B2 (es)
BR (1) BR112013026816B1 (es)
CA (1) CA2833347C (es)
CL (1) CL2013003009A1 (es)
DK (2) DK2699642T3 (es)
EC (1) ECSP13013030A (es)
MX (2) MX350821B (es)
MY (2) MY182309A (es)
RU (2) RU2611631C2 (es)
UA (1) UA116332C2 (es)
WO (1) WO2012145123A1 (es)
ZA (2) ZA201307636B (es)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11084311B2 (en) 2008-02-29 2021-08-10 Illinois Tool Works Inc. Receiver material having a polymer with nano-composite filler material
US8841495B2 (en) 2011-04-18 2014-09-23 Gas Technology Institute Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
WO2013049368A1 (en) 2011-09-27 2013-04-04 Thermochem Recovery International, Inc. System and method for syngas clean-up
CN104169396B (zh) * 2011-11-04 2016-08-24 国际热化学恢复股份有限公司 用于原料向油和气的弹性转化的系统和方法
IN2014CN02732A (es) * 2011-11-14 2015-07-03 Shell Int Research
AU2013262762B2 (en) 2012-05-17 2015-08-20 Shell Internationale Research Maatschappij B.V. Methods and systems for processing biomass material
HUE033598T2 (hu) * 2012-10-08 2017-12-28 Shell Int Research Eljárás cellulózanyag cseppfolyósítására
US10173207B2 (en) * 2013-03-12 2019-01-08 Anellotech, Inc. Regeneration of catalytic fast pyrolysis catalyst
BR112016017226B1 (pt) 2014-01-28 2022-01-25 Shell Internationale Research Maatschappij B.V. Processo para produzir produtos de hidrocarboneto líquido
SG11201609646XA (en) 2014-07-01 2017-01-27 Shell Int Research Conversion of solid biomass into a liquid hydrocarbon material
US10167429B2 (en) 2014-07-01 2019-01-01 Shell Oil Company Conversion of solid biomass into a liquid hydrocarbon materials
CA2953855C (en) 2014-07-01 2022-07-12 Shell Internationale Research Maatschappij B.V. Conversion of solid biomass into a liquid hydrocarbon material
US10563130B2 (en) 2014-07-17 2020-02-18 Sabic Global Technologies B.V. Upgrading hydrogen deficient streams using hydrogen donor streams in a hydropyrolysis process
US9644150B2 (en) * 2014-12-18 2017-05-09 Inaeris Technologies, Llc Method of thermolyzing biomass in presence of hydrogen sulfide
EP3240868B1 (en) * 2014-12-29 2019-06-19 Shell International Research Maatschappij B.V. Process for production of aromatics via pyrolysis of lignin-comprising material
DE102015108552A1 (de) 2015-02-27 2016-09-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Pyrolyseöl und Verfahren zu dessen Herstellung
US10392566B2 (en) 2015-04-27 2019-08-27 Gas Technology Institute Co-processing for control of hydropyrolysis processes and products thereof
BR112018005995A2 (pt) * 2015-09-25 2018-10-23 Shell Int Research conversão de biomassa em metano
ES2923073T3 (es) 2016-03-25 2022-09-22 Thermochem Recovery Int Inc Sistema de generación de producto gaseoso integrada en energía de tres fases
US10364398B2 (en) 2016-08-30 2019-07-30 Thermochem Recovery International, Inc. Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas
CN106247323B (zh) * 2016-09-14 2019-01-18 东南大学 一种基于塔式鼓泡流化床燃料反应器的化学链燃烧装置及其方法
US10906808B2 (en) 2017-11-15 2021-02-02 Gas Technology Institute Noble metal catalysts and processes for reforming of methane and other hydrocarbons
US10738247B2 (en) 2017-11-15 2020-08-11 Gas Technology Institute Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels
UA126089C2 (uk) * 2017-11-15 2022-08-10 Ґез Текнолоджи Інститьют Процеси і системи для риформінгу метану та світлих вуглеводнів у рідкі вуглеводневі палива
EP3575384A1 (en) 2018-05-28 2019-12-04 Total Research & Technology Feluy Biphasic solvent catalytic process for the production of mono-oxygenated molecules from a bio-feedstock comprising carbohydrates and use of said mono-oxygenated molecules in a fluid catalytic cracking process
EP3575383A1 (en) 2018-05-28 2019-12-04 Total Research & Technology Feluy Biphasic solvent catalytic process for the production of mono-oxygenated molecules from a bio-feedstock comprising carbohydrates
US12122962B2 (en) 2018-09-18 2024-10-22 Gti Energy Processes and catalysts for reforming of impure methane-containing feeds
CN109453824B (zh) * 2018-11-15 2021-09-10 新奥科技发展有限公司 催化剂负载方法及催化加氢气化方法
FR3089827B1 (fr) 2018-12-17 2021-01-01 Ifp Energies Now Réacteur de combustion en boucle chimique à toit plat
CN111377450B (zh) * 2018-12-29 2025-03-14 江苏中能硅业科技发展有限公司 一种用于处理多晶硅副产高沸物的装置和方法
US20200354636A1 (en) * 2019-05-08 2020-11-12 Exxonmobil Research And Engineering Company Removal of catalyst fines from fluidized bed effluent in the conversion of oxygenate feedstock
FR3097556B1 (fr) * 2019-06-24 2021-11-26 Europeenne De Biomasse Procédé de vapocraquage comprenant une étape de séparation et traitement différentiel des particules obtenues en fonction d’une valeur seuil.
US11555157B2 (en) 2020-03-10 2023-01-17 Thermochem Recovery International, Inc. System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas
CN111514826B (zh) * 2020-03-13 2022-04-08 宁波巨化化工科技有限公司 一种分段独立控制式固定床反应器
US12065618B2 (en) 2020-05-06 2024-08-20 Gti Energy Hydrodeoxygenation of oxygenated polymers to liquid hydrocarbons
FR3112148B1 (fr) * 2020-07-01 2022-07-15 Safran Ceram Dispositif pour le dépôt chimique en phase vapeur en lit fluidisé
CN113908779A (zh) * 2020-07-10 2022-01-11 国家能源投资集团有限责任公司 固定流化床、流化系统以及流化方法
EP3945066B1 (en) * 2020-07-28 2024-10-30 TotalEnergies OneTech Process to conduct a steam cracking reaction in a fluidized bed reactor
KR102803647B1 (ko) * 2020-10-16 2025-05-07 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 코크 조절 반응기, 장치 및 산소 함유 화합물로부터 저탄소 올레핀을 제조하는 방법
FR3118134B1 (fr) 2020-12-18 2022-12-16 Ifp Energies Now Procédé et réacteur de combustion en boucle chimique comportant une fluidisation étagée
EP4263758A1 (en) 2020-12-18 2023-10-25 Shell Internationale Research Maatschappij B.V. Fluidized bed reactor and associated hydropyrolysis processes
US12241027B2 (en) 2021-07-15 2025-03-04 Shell Usa, Inc. Method of subjecting a biomass feedstock to hydropyrolysis
KR102915600B1 (ko) * 2022-12-05 2026-01-23 엔오월드 주식회사 바이오메스를 이용한 액체 연료 및 그 제조방법과 제조장치
EP4648898A2 (en) 2023-01-13 2025-11-19 Shell Internationale Research Maatschappij B.V. Preparation method for hydropyrolysis catalyst with higher density; biomass hydropyrolysis process using obtained catalyst
CN116850903A (zh) * 2023-07-05 2023-10-10 同济大学 一种在线提升固体反应活性的气固反应器
CN117431082B (zh) * 2023-12-11 2024-03-08 成都万潜科延科技有限公司 生物质热解产生的焦油的催化碳化方法、碳材料及应用
CN118239594B (zh) * 2024-05-07 2026-01-09 浙江省生态环境科学设计研究院 一种基于磁性炭生物膜载体的污水生物强化脱氮除磷工艺
WO2026003233A1 (en) * 2024-06-28 2026-01-02 Plastogaz Sa Device and process for depolymerisation of plastics
CN118963282B (zh) * 2024-08-01 2025-03-14 邹城市经开区中压热力有限公司 一种水煤浆产线运行安全监管系统

Family Cites Families (139)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2581134A (en) 1947-03-15 1952-01-01 Standard Oil Dev Co Apparatus for contacting solids and gases
US2635949A (en) * 1949-03-24 1953-04-21 Standard Oil Dev Co Apparatus for contacting solids with fluids
US2893851A (en) * 1955-12-29 1959-07-07 American Oil Co Powdered catalyst contacting unit
US2893849A (en) 1956-05-01 1959-07-07 Standard Oil Co Fluidized solids contacting apparatus
US3267586A (en) * 1964-09-17 1966-08-23 Exxon Research Engineering Co Apparatus for treating fluidized solids systems
US3997423A (en) 1975-10-20 1976-12-14 Cities Service Company Short residence time low pressure hydropyrolysis of carbonaceous materials
US4013543A (en) 1975-10-20 1977-03-22 Cities Service Company Upgrading solid fuel-derived tars produced by low pressure hydropyrolysis
US4166786A (en) 1976-06-25 1979-09-04 Occidental Petroleum Corporation Pyrolysis and hydrogenation process
FR2371227A1 (fr) * 1976-11-17 1978-06-16 Anvar Procede de mise en contact de phases avec mise en suspension et en circulation naturelle d'au moins un produit solide a l'etat divise dans un fluide, et appareillage de mise en oeuvre
JPS5450005A (en) * 1977-09-28 1979-04-19 Nippon Mining Co Ltd Fluidized thermal cracker for heavy oil
US4199432A (en) 1978-03-22 1980-04-22 Chevron Research Company Staged turbulent bed retorting process
JPS54152148U (es) * 1978-04-12 1979-10-23
SU808089A1 (ru) * 1978-11-01 1981-02-28 Poltavtsev Vladimir Устройство дл ввода газа в аппа-PAT
JPS55100214A (en) 1979-01-18 1980-07-31 Ibiden Co Ltd Method and apparatus for refining free carbon-containing metal carbide
US4260473A (en) 1979-05-03 1981-04-07 Occidental Research Corporation Removal of particulates from pyrolytic oil
GB2071132A (en) 1979-10-19 1981-09-16 Coal Industry Patents Ltd Fuel oils from coal
US4326944A (en) 1980-04-14 1982-04-27 Standard Oil Company (Indiana) Rapid hydropyrolysis of carbonaceous solids
US4456504A (en) 1980-04-30 1984-06-26 Chevron Research Company Reactor vessel and process for thermally treating a granular solid
US4337120A (en) * 1980-04-30 1982-06-29 Chevron Research Company Baffle system for staged turbulent bed
JPS57209635A (en) * 1981-06-22 1982-12-23 Res Assoc Residual Oil Process<Rarop> Method and apparatus for preventing slagging of particulate material
US4828581A (en) 1985-09-20 1989-05-09 Battelle Development Corporation Low inlet gas velocity high throughput biomass gasifier
US4808289A (en) 1987-07-09 1989-02-28 Amoco Corporation Resid hydrotreating with high temperature flash drum recycle oil
US5055181A (en) 1987-09-30 1991-10-08 Exxon Research And Engineering Company Hydropyrolysis-gasification of carbonaceous material
JPH01217106A (ja) * 1988-02-23 1989-08-30 Babcock Hitachi Kk 流動層高制御装置を備えた流動層燃焼装置
US4990371A (en) 1989-08-01 1991-02-05 Gte Products Corporation Process for coating small solids
US5096569A (en) 1990-02-27 1992-03-17 Exxon Research And Engineering Company Catalytic hydropyrolysis of carbonaceous material with char recycle
GB9224783D0 (en) 1992-11-26 1993-01-13 Univ Waterloo An improved process for the thermal conversion of biomass to liquids
FI931785A7 (fi) 1993-04-20 1994-10-21 Valtion Teknillinen Menetelmä ja laitteisto nestemäisen polttoaineen valmistamiseksi pyrolysoimalla raakapolttoainetta
CA2095480C (en) 1993-05-04 1995-02-14 Paulo Goes Koeberle Multistage turbulent circulating fluidized bed reactor
GB9313442D0 (en) * 1993-06-30 1993-08-11 Bp Chem Int Ltd Method of mixing heterogegeous systems
JPH07256228A (ja) * 1994-03-22 1995-10-09 Kunio Kato 木材、炭水化物、廃プラスチック類の接触熱分解法
US5522160A (en) 1995-01-05 1996-06-04 Foster Wheeler Energia Oy Fluidized bed assembly with flow equalization
US6060631A (en) 1997-06-23 2000-05-09 Uop Llc Process for the conversion of plastic to produce a synthetic crude oil
US5969201A (en) 1997-06-23 1999-10-19 Uop Llc Process for the conversion of plastic to produce a synthetic crude oil
WO2002051966A1 (en) 2000-12-26 2002-07-04 Ebara Corporation Fluidized-bed gasification method and apparatus
US6793698B1 (en) 2001-03-09 2004-09-21 Uop Llc Fuel processor reactor with integrated pre-reforming zone
US7619012B2 (en) 2006-07-18 2009-11-17 The Regents Of The University Of California Method and apparatus for steam hydro-gasification in a fluidized bed reactor
US7500997B2 (en) 2002-02-05 2009-03-10 The Regents Of The University Of California Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials
WO2011038046A2 (en) 2009-09-22 2011-03-31 The Regetns Of The University Of California A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor
WO2004041426A1 (en) * 2002-11-08 2004-05-21 Morten Müller Ltd., Aps Mixing device for two-phase concurrent vessels
WO2005021686A1 (en) 2003-08-29 2005-03-10 Ebara Corporation Recycling method and system
EP1711432A1 (en) 2004-02-03 2006-10-18 Ebara Corporation Hydrocarbon material processing system and method
US7829030B2 (en) * 2004-12-30 2010-11-09 Exxonmobil Chemical Patents Inc. Fluidizing a population of catalyst particles having a low catalyst fines content
CN101155631B (zh) * 2005-03-17 2012-08-15 沙索技术有限公司 平板型流化床反应器
US7575052B2 (en) 2005-04-22 2009-08-18 Shell Oil Company In situ conversion process utilizing a closed loop heating system
CN101273114A (zh) 2005-04-29 2008-09-24 海塞特有限责任公司 用于转化烃物质的体系和方法
US7288685B2 (en) 2005-05-19 2007-10-30 Uop Llc Production of olefins from biorenewable feedstocks
US7585104B2 (en) 2005-09-12 2009-09-08 Uop Llc Rotary processor
EP1772202A1 (de) 2005-10-04 2007-04-11 Paul Scherrer Institut Verfahren zur Erzeugung von Methan und/oder Methanhydrat aus Biomasse
US7396966B2 (en) 2005-12-20 2008-07-08 Uop Llc Olefinic feedstock treatment processes
WO2007094766A1 (en) 2006-02-13 2007-08-23 Uop Llc Process for the production of hydrogen
KR100651418B1 (ko) 2006-03-17 2006-11-30 에스케이 주식회사 고속유동층을 이용하여 탄화수소 원료로부터 경질 올레핀을제조하는 접촉분해 공정
US8529646B2 (en) 2006-05-01 2013-09-10 Lpp Combustion Llc Integrated system and method for production and vaporization of liquid hydrocarbon fuels for combustion
US7511181B2 (en) 2006-05-02 2009-03-31 Uop Llc Production of diesel fuel from biorenewable feedstocks
US20080006519A1 (en) 2006-07-06 2008-01-10 Badger Phillip C Method and system for accomplishing flash or fast pyrolysis with carbonaceous materials
CN101511971A (zh) * 2006-07-17 2009-08-19 BIOeCON国际控股有限公司 细颗粒状生物质的催化热解以及降低固体生物质颗粒粒度的方法
US7578927B2 (en) 2006-08-31 2009-08-25 Uop Llc Gasoline and diesel production from pyrolytic lignin produced from pyrolysis of cellulosic waste
US7615142B2 (en) 2006-08-31 2009-11-10 Headwaters Technology Innovation, Llc Expanded bed reactor system and method for hydroprocessing wax produced by Fischer-Tropsch reaction and contaminated with solids
US8444725B2 (en) 2006-09-11 2013-05-21 Purdue Research Foundation System and process for producing synthetic liquid hydrocarbon
US7994375B2 (en) 2006-09-26 2011-08-09 Uop Llc Production of gasoline, diesel, naphthenes and aromatics from lignin and cellulosic waste by one step hydrocracking
JP5081246B2 (ja) 2006-10-05 2012-11-28 ユーオーピー エルエルシー バイオリニューアブル供給原料からのオレフィンの製造
US20100317907A1 (en) 2006-12-29 2010-12-16 Bauman Richard F High throughput clean feed hydroprocessing development method
US20100174129A1 (en) 2006-12-29 2010-07-08 Bauman Richard F High throughput propylene from methanol catalytic process development method
US20100320121A1 (en) 2006-12-29 2010-12-23 Bauman Richard F High throughput development method for catalytic hydroprocessing of dirty feedstocks
WO2008080360A1 (en) 2006-12-29 2008-07-10 Accelergy Shanghai R & D Center Co., Ltd. High throughput fischer-tropsch catalytic process development method
US7425657B1 (en) 2007-06-06 2008-09-16 Battelle Memorial Institute Palladium catalyzed hydrogenation of bio-oils and organic compounds
FR2917424B1 (fr) 2007-06-12 2012-10-19 Inst Francais Du Petrole Production de charges de vapocraquage a haut rendement en ethylene, propylene et polymeres resultants par hydrotraitement d'huile vegetales
ITMI20071198A1 (it) 2007-06-14 2008-12-15 Eni Spa Procedimento migliorato per l'idroconversione di oli pesanti con sistemi a letto ebullato
US8119847B2 (en) 2007-06-15 2012-02-21 E. I. Du Pont De Nemours And Company Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks
US7960520B2 (en) 2007-06-15 2011-06-14 Uop Llc Conversion of lignocellulosic biomass to chemicals and fuels
US8013195B2 (en) 2007-06-15 2011-09-06 Uop Llc Enhancing conversion of lignocellulosic biomass
US8202332B2 (en) 2007-08-01 2012-06-19 Virginia Tech Intellectual Properties Fractional catalytic pyrolysis of biomass
US8217210B2 (en) 2007-08-27 2012-07-10 Purdue Research Foundation Integrated gasification—pyrolysis process
WO2009029660A2 (en) 2007-08-27 2009-03-05 Purdue Research Foundation Novel process for producing liquid hydrocarbon by pyrolysis of biomass in presence of hydrogen from a carbon-free energy source
US8088187B2 (en) 2007-09-10 2012-01-03 Rentech, Inc. Hydrogen and carbon utilization in synthetic fuels production plants
US20090077864A1 (en) 2007-09-20 2009-03-26 Marker Terry L Integrated Process of Algae Cultivation and Production of Diesel Fuel from Biorenewable Feedstocks
US7982076B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks
US8003834B2 (en) 2007-09-20 2011-08-23 Uop Llc Integrated process for oil extraction and production of diesel fuel from biorenewable feedstocks
US7982075B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with lower hydrogen consumption
US7982078B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen
US7999142B2 (en) 2007-09-20 2011-08-16 Uop Llc Production of diesel fuel from biorenewable feedstocks
US7982077B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen
US7915460B2 (en) 2007-09-20 2011-03-29 Uop Llc Production of diesel fuel from biorenewable feedstocks with heat integration
US7999143B2 (en) 2007-09-20 2011-08-16 Uop Llc Production of diesel fuel from renewable feedstocks with reduced hydrogen consumption
US8742183B2 (en) 2007-12-21 2014-06-03 Uop Llc Production of aviation fuel from biorenewable feedstocks
AU2009220133B2 (en) * 2008-03-04 2013-12-19 University Of Massachusetts Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds
US8039682B2 (en) 2008-03-17 2011-10-18 Uop Llc Production of aviation fuel from renewable feedstocks
US8058492B2 (en) 2008-03-17 2011-11-15 Uop Llc Controlling production of transportation fuels from renewable feedstocks
JP2011517470A (ja) 2008-04-06 2011-06-09 ユーオーピー エルエルシー バイオマス由来熱分解油からの燃料および燃料ブレンド成分
US7888540B2 (en) 2008-04-11 2011-02-15 General Electric Company Integrated system and method for producing fuel composition from biomass
US8212087B2 (en) 2008-04-30 2012-07-03 Xyleco, Inc. Processing biomass
US20090300971A1 (en) 2008-06-04 2009-12-10 Ramin Abhari Biorenewable naphtha
US8304592B2 (en) 2008-06-24 2012-11-06 Uop Llc Production of paraffinic fuel from renewable feedstocks
US20090326285A1 (en) 2008-06-30 2009-12-31 Bauer Lorenz J Use of Supported Mixed Metal Sulfides for Hydrotreating Biorenewable Feeds
US8038869B2 (en) 2008-06-30 2011-10-18 Uop Llc Integrated process for upgrading a vapor feed
US7968757B2 (en) 2008-08-21 2011-06-28 Syntroleum Corporation Hydrocracking process for biological feedstocks and hydrocarbons produced therefrom
WO2010033789A2 (en) 2008-09-18 2010-03-25 University Of Massachusetts Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils
EP2340295B1 (en) 2008-10-27 2017-04-19 KiOR, Inc. Biomass conversion process
US8921627B2 (en) 2008-12-12 2014-12-30 Uop Llc Production of diesel fuel from biorenewable feedstocks using non-flashing quench liquid
US8471079B2 (en) 2008-12-16 2013-06-25 Uop Llc Production of fuel from co-processing multiple renewable feedstocks
US8314274B2 (en) 2008-12-17 2012-11-20 Uop Llc Controlling cold flow properties of transportation fuels from renewable feedstocks
US8283506B2 (en) 2008-12-17 2012-10-09 Uop Llc Production of fuel from renewable feedstocks using a finishing reactor
EP2403926B1 (en) 2009-03-05 2019-10-02 G4 Insights Inc. Process for thermochemical conversion of biomass
US8492600B2 (en) * 2009-04-07 2013-07-23 Gas Technology Institute Hydropyrolysis of biomass for producing high quality fuels
US20100251600A1 (en) * 2009-04-07 2010-10-07 Gas Technology Institute Hydropyrolysis of biomass for producing high quality liquid fuels
US8915981B2 (en) 2009-04-07 2014-12-23 Gas Technology Institute Method for producing methane from biomass
US8052935B2 (en) 2009-04-30 2011-11-08 General Electric Company System and method for removing sulfur from gas stream
AU2010292845A1 (en) 2009-08-28 2012-03-22 Exxonmobil Research And Engineering Company Reducing hydrogen consumption in hydrotreating of biocomponent feeds
US9169442B2 (en) * 2009-09-09 2015-10-27 University Of Massachusetts Systems and processes for catalytic pyrolysis of biomass and hydrocarbonaceous materials for production of aromatics with optional olefin recycle, and catalysts having selected particle size for catalytic pyrolysis
US20110067306A1 (en) 2009-09-18 2011-03-24 Bp Corporation North America Inc. Processes and Apparatuses for Reducing Pollutants and Producing Syngas
FR2951734B1 (fr) 2009-10-27 2012-08-03 Inst Francais Du Petrole Procede d'hydrotraitement de charges issues de sources renouvelables avec chauffe indirecte
US8314275B2 (en) 2009-11-23 2012-11-20 Uop Llc Methods for producing biomass-derived pyrolysis oils having increased phase stability
WO2011064172A1 (en) 2009-11-24 2011-06-03 Shell Internationale Research Maatschappij B.V. Process for catalytic hydrotreatment of a pyrolysis oil
AU2010333904B2 (en) 2009-12-22 2015-05-07 Phillips 66 Company Conversion of carbohydrates to hydrocarbons
US8471081B2 (en) 2009-12-28 2013-06-25 Uop Llc Production of diesel fuel from crude tall oil
US9447347B2 (en) 2009-12-31 2016-09-20 Shell Oil Company Biofuels via hydrogenolysis-condensation
PL2348091T3 (pl) 2010-01-12 2013-04-30 Ifp Energies Now Sposób bezpośredniego hydroupłynniania biomasy obejmujący dwa etapy hydrokonwersji na złożu wrzącym
WO2011097584A1 (en) 2010-02-05 2011-08-11 The Texas A&M University System Devices and methods for a pyrolysis and gasification system for biomass feedstock
WO2011096912A1 (en) 2010-02-08 2011-08-11 Kior Inc. Two-step process for producing high yields of oil from biomass
US8519203B2 (en) 2010-02-17 2013-08-27 Uop Llc Low oxygen biomass-derived pyrolysis oils and methods for producing the same
WO2011103313A2 (en) 2010-02-17 2011-08-25 Virginia Tech Intellectual Properties, Inc. Production of pyrolysis oil
US8404910B2 (en) 2010-02-17 2013-03-26 Uop Llc Low oxygen biomass-derived pyrolysis oils and methods for producing the same
IT1399078B1 (it) 2010-03-24 2013-04-05 Eni Spa Procedimento per la conversione della lignina a idrocarburi liquidi
US20110232166A1 (en) 2010-03-25 2011-09-29 Uop Llc Low oxygen biomass-derived pyrolysis oils and methods for producing the same
US20110239530A1 (en) 2010-03-30 2011-10-06 Uop Llc Use of well mixed, backmixed reactors for processing of unstable bio feedstocks
US8575408B2 (en) 2010-03-30 2013-11-05 Uop Llc Use of a guard bed reactor to improve conversion of biofeedstocks to fuel
US9126174B2 (en) 2010-03-31 2015-09-08 Uop Llc Hydroprocessing method, or an apparatus relating thereto
FR2959503B1 (fr) 2010-05-03 2012-08-10 Arkema France Procede de traitement d'une eau usee issue de la synthese d'un polymere vinylique halogene
WO2011143391A1 (en) 2010-05-12 2011-11-17 Shell Oil Company Process including hydrogenolysis of biomass followed by dehydrogenation aldol condensation to produce alkanes
AT509586B8 (de) 2010-06-11 2011-12-15 Univ Wien Tech Verbessertes wirbelschichtreaktorsystem
US8519205B2 (en) 2010-07-23 2013-08-27 Ensyn Renewables, Inc. Low water biomass-derived pyrolysis oils and processes for producing the same
US20120017494A1 (en) 2010-07-26 2012-01-26 Uop Llc Processes for producing low acid biomass-derived pyrolysis oils
US20120017495A1 (en) 2010-07-26 2012-01-26 Uop Llc Methods for deoxygenating biomass-derived pyrolysis oils
US9222044B2 (en) 2010-07-26 2015-12-29 Uop Llc Methods for producing low oxygen biomass-derived pyrolysis oils
US20120023809A1 (en) 2010-07-28 2012-02-02 Uop Llc Methods for producing phase stable, reduced acid biomass-derived pyrolysis oils
CN103154213B (zh) 2010-08-18 2015-06-17 格雷特波因特能源公司 碳质原料的加氢甲烷化工艺
US8318996B2 (en) 2010-08-31 2012-11-27 Uop Llc Systems and methods for treating hydrogen recycle gas in a process for converting biorenewable feedstock into renewable fuels and chemicals
US8841495B2 (en) 2011-04-18 2014-09-23 Gas Technology Institute Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
US8100990B2 (en) 2011-05-15 2012-01-24 Avello Bioenery, Inc. Methods for integrated fast pyrolysis processing of biomass

Also Published As

Publication number Publication date
ZA201307636B (en) 2015-04-29
MX2013012024A (es) 2014-02-03
JP6133272B2 (ja) 2017-05-24
MX350821B (es) 2017-09-21
WO2012145123A1 (en) 2012-10-26
CA2833347A1 (en) 2012-10-26
ZA201500377B (en) 2016-10-26
KR102039965B1 (ko) 2019-11-06
NZ713659A (en) 2017-06-30
CL2013003009A1 (es) 2014-06-27
MX336692B (es) 2016-01-28
US9512364B2 (en) 2016-12-06
MY164844A (en) 2018-01-30
MY182309A (en) 2021-01-18
CN103649275A (zh) 2014-03-19
EP2699642A1 (en) 2014-02-26
AU2012246685B2 (en) 2017-04-20
CN105001897B (zh) 2019-02-12
US20120260563A1 (en) 2012-10-18
CN103649275B (zh) 2015-09-09
CN105001897A (zh) 2015-10-28
RU2611631C2 (ru) 2017-02-28
US8841495B2 (en) 2014-09-23
CA2833347C (en) 2019-07-16
BR112013026816A2 (pt) 2017-01-10
EP3190165A1 (en) 2017-07-12
US20150141716A1 (en) 2015-05-21
KR20180133929A (ko) 2018-12-17
DK3190165T3 (da) 2020-10-19
JP2014511940A (ja) 2014-05-19
DK2699642T3 (en) 2017-08-28
JP2017095726A (ja) 2017-06-01
EP3190165B1 (en) 2020-07-15
RU2013151054A (ru) 2015-05-27
EP2699642B1 (en) 2017-05-03
AU2012246685A1 (en) 2013-10-31
RU2643810C1 (ru) 2018-02-06
KR20140035904A (ko) 2014-03-24
UA116332C2 (uk) 2018-03-12
BR112013026816B1 (pt) 2020-11-24
NZ616634A (en) 2015-12-24
JP6352454B2 (ja) 2018-07-04
KR101926353B1 (ko) 2018-12-07

Similar Documents

Publication Publication Date Title
ECSP13013030A (es) Proceso de hidropirolisis catalítica de lecho burbujeante que utiliza partículas catalizadoras más grandes y particulas de biomasa más pequeñas representando un reactor anti - ensuciamiento
US8829258B2 (en) Integrated FCC biomass pyrolysis/upgrading
RU2539598C2 (ru) Гидропиролиз биомассы для получения высококачественных жидких топлив
JP2014511940A5 (es)
Gollakota et al. A review on the upgradation techniques of pyrolysis oil
Hu et al. Application of Fischer–Tropsch synthesis in biomass to liquid conversion
RU2015116460A (ru) Производство фракционированных топлив повышенного качества из биомассы
JP2012523474A5 (es)
Valle et al. Upgrading of bio-oil in a continuous process with dolomite catalyst
BR112013005821A2 (pt) métodos de transformação de bio-óleo em combustíveis de hidrocarboneto do tipo de transporte
EA200800578A1 (ru) Способы и системы для производства освобожденных от легких фракций кубовых остатков и продуктов без кубовых остатков из исходного сырья, содержащего тяжелые углеводороды
WO2011001445A3 (en) An improved process for recovery of propylene and lpg from fcc fuel gas using stripped main column overhead distillate as absorber oil
RU2011144858A (ru) Гидропиролиз биомассы для получения высококачественного жидкого горючего
BRPI0715873A2 (pt) processo para o craqueamento catalÍtico de fluido de compostos de hidrocarbonetos oxigenados
EP2268775A4 (en) MANUFACTURE OF LIQUID HYDROCARBONS
US20110239530A1 (en) Use of well mixed, backmixed reactors for processing of unstable bio feedstocks
BR112016029955B1 (pt) Processo para produzir produtos de hidrocarboneto líquido a partir de uma matériaprima de biomassa sólida
Kakku et al. Co-processing of organic fraction from groundnut shell biocrude with VGO in FCC unit to produce petrochemical products
US9303213B2 (en) Process for producing renewable biofuel from a pyrolyzed biomass containing bio-oil stream
RU2011117948A (ru) Способ каталитического крекинга с рециклом олефиновой фракции, отобранной до секции разделения газа, в целях максимального увеличения производства пропилена
Muradov et al. Production of Fischer–Tropsch hydrocarbons via oxygen-blown gasification of charred pinewood pellets
Pala et al. Recycling of product gas does not affect fast pyrolysis oil yield and composition
TH154768A (th) กระบวนการไฮโดรไพโรไลซิสแบบเร่งปฏิกิริยาชนิดบับบลิ่งเบด โดยใช้ปฏิกรณ์ที่จัดให้มีลักษณะของอนุภาคตัวเร่งปฏิกิริยา ขนาดใหญ่กว่าและอนุภาคสารชีวมวลขนาดเล็กกว่าและป้องกันการรวมตัวเป็นก้อน
Canter Production of bio-oil
Forsberg Nuclear hydrogen for production of liquid hydrocarbon transport fuels