UA79962C2 - Process for the production of an alkenyl carboxylate or an alkyl carboxylate and process for the production of vinyl acetate - Google Patents

Process for the production of an alkenyl carboxylate or an alkyl carboxylate and process for the production of vinyl acetate Download PDF

Info

Publication number: UA79962C2
Authority: UA; Ukraine
Prior art keywords: alkene; reaction zone; stream; differs; alkane
Prior art date: 2002-03-04

Application number

UA20041007969A

Other languages

English (en)

Ukrainian (uk)

Inventor

Robert William Clarke

Robert Croll

Andrew Richard Lucy

Bruce Leo Williams

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-03-04

Filing date

2003-12-02

Publication date

2007-08-10

2003-12-02 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

2007-08-10 Publication of UA79962C2 publication Critical patent/UA79962C2/uk

Links

238000000034 method Methods 0.000 title claims abstract description 121
-1 alkenyl carboxylate Chemical class 0.000 title claims abstract description 56
238000004519 manufacturing process Methods 0.000 title claims abstract description 25
125000005599 alkyl carboxylate group Chemical group 0.000 title claims abstract description 15
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title claims description 31
150000001336 alkenes Chemical class 0.000 claims abstract description 166
238000007254 oxidation reaction Methods 0.000 claims abstract description 98
150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 71
230000003647 oxidation Effects 0.000 claims abstract description 36
238000000926 separation method Methods 0.000 claims abstract description 31
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 198
238000006243 chemical reaction Methods 0.000 claims description 112
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 93
239000005977 Ethylene Substances 0.000 claims description 92
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 71
239000003054 catalyst Substances 0.000 claims description 66
239000007789 gas Substances 0.000 claims description 59
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical group CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 56
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 54
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
229910001882 dioxygen Inorganic materials 0.000 claims description 43
229910052751 metal Inorganic materials 0.000 claims description 43
239000002184 metal Substances 0.000 claims description 43
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 36
229910052760 oxygen Inorganic materials 0.000 claims description 35
239000001301 oxygen Substances 0.000 claims description 34
239000007788 liquid Substances 0.000 claims description 25
239000012266 salt solution Substances 0.000 claims description 22
238000004821 distillation Methods 0.000 claims description 21
239000000463 material Substances 0.000 claims description 21
230000001590 oxidative effect Effects 0.000 claims description 21
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 18
229910002092 carbon dioxide Inorganic materials 0.000 claims description 18
239000001569 carbon dioxide Substances 0.000 claims description 18
150000003839 salts Chemical class 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 14
238000010521 absorption reaction Methods 0.000 claims description 13
VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 claims description 9
229910052763 palladium Inorganic materials 0.000 claims description 9
239000002994 raw material Substances 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 8
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical group [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
238000009833 condensation Methods 0.000 claims description 7
230000005494 condensation Effects 0.000 claims description 7
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 7
229910052737 gold Inorganic materials 0.000 claims description 7
239000010931 gold Substances 0.000 claims description 7
229910052709 silver Inorganic materials 0.000 claims description 7
239000004332 silver Substances 0.000 claims description 7
239000007858 starting material Substances 0.000 claims description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
229910052750 molybdenum Inorganic materials 0.000 claims description 6
239000011733 molybdenum Substances 0.000 claims description 6
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
229910052702 rhenium Inorganic materials 0.000 claims description 6
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical group [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 6
239000000243 solution Substances 0.000 claims description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 4
XVOMHXSMRIJNDW-UHFFFAOYSA-N copper(1+);nitrate Chemical compound [Cu+].[O-][N+]([O-])=O XVOMHXSMRIJNDW-UHFFFAOYSA-N 0.000 claims description 4
239000012528 membrane Substances 0.000 claims description 4
229910001961 silver nitrate Inorganic materials 0.000 claims description 4
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
229910052721 tungsten Inorganic materials 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 3
239000011651 chromium Substances 0.000 claims description 3
RFKZUAOAYVHBOY-UHFFFAOYSA-M copper(1+);acetate Chemical group [Cu+].CC([O-])=O RFKZUAOAYVHBOY-UHFFFAOYSA-M 0.000 claims description 3
238000010438 heat treatment Methods 0.000 claims description 3
229910052742 iron Inorganic materials 0.000 claims description 3
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 3
229910052753 mercury Inorganic materials 0.000 claims description 3
229910052759 nickel Inorganic materials 0.000 claims description 3
229910052762 osmium Inorganic materials 0.000 claims description 3
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
229910052697 platinum Inorganic materials 0.000 claims description 3
229910052703 rhodium Inorganic materials 0.000 claims description 3
239000010948 rhodium Substances 0.000 claims description 3
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
229910052707 ruthenium Inorganic materials 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 2
229910000336 copper(I) sulfate Inorganic materials 0.000 claims description 2
WIVXEZIMDUGYRW-UHFFFAOYSA-L copper(i) sulfate Chemical compound [Cu+].[Cu+].[O-]S([O-])(=O)=O WIVXEZIMDUGYRW-UHFFFAOYSA-L 0.000 claims description 2
125000001477 organic nitrogen group Chemical group 0.000 claims description 2
239000007800 oxidant agent Substances 0.000 claims description 2
239000000376 reactant Substances 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
229910017464 nitrogen compound Inorganic materials 0.000 claims 1
150000002830 nitrogen compounds Chemical class 0.000 claims 1
150000001735 carboxylic acids Chemical class 0.000 abstract description 2
239000000047 product Substances 0.000 description 45
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 27
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 16
229910002091 carbon monoxide Inorganic materials 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
239000000203 mixture Substances 0.000 description 11
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
239000006227 byproduct Substances 0.000 description 7
239000003153 chemical reaction reagent Substances 0.000 description 7
239000011949 solid catalyst Substances 0.000 description 7
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
229910052786 argon Inorganic materials 0.000 description 5
238000009434 installation Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000002585 base Substances 0.000 description 4
229910052796 boron Inorganic materials 0.000 description 4
229910002090 carbon oxide Inorganic materials 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
238000000746 purification Methods 0.000 description 4
229910052715 tantalum Inorganic materials 0.000 description 4
229910052719 titanium Inorganic materials 0.000 description 4
239000010936 titanium Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 3
239000012535 impurity Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
229910052714 tellurium Inorganic materials 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
238000006137 acetoxylation reaction Methods 0.000 description 2
239000000969 carrier Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000003795 desorption Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000010410 layer Substances 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
238000012856 packing Methods 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011148 porous material Substances 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
229910052711 selenium Inorganic materials 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
229910001020 Au alloy Inorganic materials 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000012223 aqueous fraction Substances 0.000 description 1
238000010533 azeotropic distillation Methods 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
238000012993 chemical processing Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000010908 decantation Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000003353 gold alloy Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000010955 niobium Substances 0.000 description 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 1
238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
235000011056 potassium acetate Nutrition 0.000 description 1
238000010926 purge Methods 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
230000009466 transformation Effects 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/152—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Analytical Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Water Supply & Treatment (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

UA20041007969A 2002-03-04 2003-12-02 Process for the production of an alkenyl carboxylate or an alkyl carboxylate and process for the production of vinyl acetate UA79962C2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GBGB0205014.4A GB0205014D0 (en)	2002-03-04	2002-03-04	Process
PCT/GB2003/000619 WO2003074465A1 (fr)	2002-03-04	2003-02-12	Procede de production d'un carboxylate d'alcenyle ou d'un carboxylate d'alkyle

Publications (1)

Publication Number	Publication Date
UA79962C2 true UA79962C2 (en)	2007-08-10

Family

ID=9932216

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
UA20041007969A UA79962C2 (en)	2002-03-04	2003-12-02	Process for the production of an alkenyl carboxylate or an alkyl carboxylate and process for the production of vinyl acetate

Country Status (17)

Country	Link
US (1)	US7211688B2 (fr)
EP (1)	EP1480938A1 (fr)
JP (1)	JP2005519107A (fr)
KR (1)	KR101006038B1 (fr)
CN (1)	CN100430365C (fr)
AU (1)	AU2003205872A1 (fr)
BR (1)	BR0308042B8 (fr)
CA (1)	CA2476181C (fr)
GB (1)	GB0205014D0 (fr)
MX (1)	MXPA04008588A (fr)
MY (1)	MY142232A (fr)
NO (1)	NO20044119L (fr)
RS (1)	RS77004A (fr)
RU (1)	RU2315033C2 (fr)
TW (1)	TWI327562B (fr)
UA (1)	UA79962C2 (fr)
WO (1)	WO2003074465A1 (fr)

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GB0205016D0 (en) *	2002-03-04	2002-04-17	Bp Chem Int Ltd	Process
GB0312965D0 (en) *	2003-06-05	2003-07-09	Bp Chem Int Ltd	Process
CN102015100A (zh) *	2008-04-30	2011-04-13	陶氏技术投资有限公司	多孔体前体,成形多孔体,用于制备它们的方法和基于它们的最终用途产品
WO2009134839A1 (fr) *	2008-04-30	2009-11-05	Dow Technology Investments, Llc	Précurseurs de corps poreux, corps façonnés poreux, procédés de fabrication de ceux-ci et produits finis fondés sur ceux-ci
EP2274093A1 (fr)	2008-04-30	2011-01-19	Dow Technology Investments LLC	Précurseurs de corps poreux, corps poreux façonnés, leurs procédés de fabrication et produits finaux fondés sur ces corps poreux
WO2012118888A2 (fr)	2011-03-02	2012-09-07	Aither Chemicals, Llc	Procédés de purification intégrée de gaz naturel et produits associés
US9545610B2 (en)	2013-03-04	2017-01-17	Nova Chemicals (International) S.A.	Complex comprising oxidative dehydrogenation unit
CN107540540A (zh) *	2016-06-29	2018-01-05	中国石油化工股份有限公司	生产醋酸烯丙酯的方法
MX2019006874A (es) *	2016-12-19	2019-08-22	Shell Int Research	Deshidrogenacion oxidativa de etano con coproduccion de acetato de vinilo.
MX2022014701A (es)	2020-06-09	2022-12-16	Nova Chem Int Sa	Limitacion de produccion de acido acetico en el proceso de deshidrogenacion oxidativa de etano.

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DE2944151A1 (de) *	1979-11-02	1981-05-27	EC Erdölchemie GmbH, 5000 Köln	Verfahren zur abtrennung von olefinen aus olefine enthaltenden gasen
US5304678A (en) *	1990-12-10	1994-04-19	The Standard Oil Company	Acetic acid from ethylene
US5300682A (en) *	1991-06-10	1994-04-05	The Standard Oil Co.	Catalytic oxidation of ethane to acetic acid
EP0699468B1 (fr) *	1994-08-29	1998-03-11	BP Chemicals Limited	Procédé pour l'élimination d'oléfines de fluides
GB9419963D0 (en) *	1994-10-04	1994-11-16	Bp Chem Int Ltd	Process
GB9616573D0 (en) *	1996-08-07	1996-09-25	Bp Chem Int Ltd	Process
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GB9817362D0 (en) *	1998-08-11	1998-10-07	Bp Chem Int Ltd	Improved process for the production if vinyl acetate
GB9828337D0 (en) *	1998-12-22	1999-02-17	Bp Chem Int Ltd	Process for the production of olefins
US6143921A (en) *	1999-05-14	2000-11-07	Saudi Basic Industries Corporation	Method for producing vinyl acetate monomer from ethane or ethylene oxidation
PL200232B1 (pl) *	2000-05-19	2008-12-31	Celanese Int Corp	Zintegrowany sposób wytwarzania octanu winylu
ES2265943T3 (es) *	2000-05-19	2007-03-01	Celanese International Corporation	Proceso para la produccion de acetato de vinilo.
GB0026241D0 (en) *	2000-10-26	2000-12-13	Bp Chem Int Ltd	Process
GB0026243D0 (en) *	2000-10-26	2000-12-13	Bp Chem Int Ltd	Process
GB0200021D0 (en) *	2002-01-02	2002-02-13	Bp Chem Int Ltd	Process
GB0205016D0 (en) *	2002-03-04	2002-04-17	Bp Chem Int Ltd	Process
GB0312781D0 (en) *	2003-06-04	2003-07-09	Ythan Environmental Services L	Method

2002
- 2002-03-04 GB GBGB0205014.4A patent/GB0205014D0/en not_active Ceased
2003
- 2003-02-12 KR KR1020047013644A patent/KR101006038B1/ko not_active Expired - Fee Related
- 2003-02-12 RU RU2004129597/04A patent/RU2315033C2/ru active
- 2003-02-12 JP JP2003572937A patent/JP2005519107A/ja active Pending
- 2003-02-12 US US10/505,660 patent/US7211688B2/en not_active Expired - Fee Related
- 2003-02-12 RS YUP-770/04A patent/RS77004A/sr unknown
- 2003-02-12 MX MXPA04008588A patent/MXPA04008588A/es active IP Right Grant
- 2003-02-12 CA CA2476181A patent/CA2476181C/fr not_active Expired - Fee Related
- 2003-02-12 BR BRPI0308042-0A patent/BR0308042B8/pt not_active IP Right Cessation
- 2003-02-12 AU AU2003205872A patent/AU2003205872A1/en not_active Abandoned
- 2003-02-12 EP EP03702750A patent/EP1480938A1/fr not_active Withdrawn
- 2003-02-12 CN CNB038052318A patent/CN100430365C/zh not_active Expired - Fee Related
- 2003-02-12 WO PCT/GB2003/000619 patent/WO2003074465A1/fr not_active Ceased
- 2003-02-20 TW TW092103547A patent/TWI327562B/zh not_active IP Right Cessation
- 2003-02-28 MY MYPI20030731A patent/MY142232A/en unknown
- 2003-12-02 UA UA20041007969A patent/UA79962C2/uk unknown
2004
- 2004-09-28 NO NO20044119A patent/NO20044119L/no not_active Application Discontinuation

Also Published As

Publication number	Publication date
CN1639103A (zh)	2005-07-13
KR20040098654A (ko)	2004-11-20
BR0308042B1 (pt)	2013-01-08
AU2003205872A1 (en)	2003-09-16
TW200306299A (en)	2003-11-16
RS77004A (sr)	2007-02-05
WO2003074465A1 (fr)	2003-09-12
BR0308042A (pt)	2004-12-07
MXPA04008588A (es)	2004-12-06
CN100430365C (zh)	2008-11-05
NO20044119L (no)	2004-12-03
US20050085659A1 (en)	2005-04-21
RU2315033C2 (ru)	2008-01-20
GB0205014D0 (en)	2002-04-17
TWI327562B (en)	2010-07-21
US7211688B2 (en)	2007-05-01
CA2476181A1 (fr)	2003-09-12
EP1480938A1 (fr)	2004-12-01
BR0308042B8 (pt)	2013-02-19
KR101006038B1 (ko)	2011-01-06
JP2005519107A (ja)	2005-06-30
CA2476181C (fr)	2011-07-26
RU2004129597A (ru)	2005-07-10
MY142232A (en)	2010-11-15

Publication	Publication Date	Title
CA2411000C (fr)	2006-11-14	Procede integre relatif a la production d'acetate de vinyle et/ou d'acide acetique
JP2011116789A (ja)	2011-06-16	アルケン分離方法
JP4084044B2 (ja)	2008-04-30	酢酸ビニルを製造するための統合された方法
RU2315033C2 (ru)	2008-01-20	Способ получения алкенилкарбоксилата (варианты) или алкилкарбоксилата
JP4317758B2 (ja)	2009-08-19	アルケニルカルボキシレート製造の統合的方法
RU2356884C2 (ru)	2009-05-27	Способ окисления для получения карбоновых кислот и алкенов и необязательно алкенилкарбоксилата или алкилкарбоксилата
RU2247709C2 (ru)	2005-03-10	Интегрированный способ получения винилацетата