UA85579C2 - Интегрированный способ производства метанола и уксусной кислоты - Google Patents
Интегрированный способ производства метанола и уксусной кислотыInfo
- Publication number
- UA85579C2 UA85579C2 UAA200609271A UAA200609271A UA85579C2 UA 85579 C2 UA85579 C2 UA 85579C2 UA A200609271 A UAA200609271 A UA A200609271A UA A200609271 A UAA200609271 A UA A200609271A UA 85579 C2 UA85579 C2 UA 85579C2
- Authority
- UA
- Ukraine
- Prior art keywords
- acetic acid
- supplied
- methanol
- syngas
- unit
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 5
- 230000015572 biosynthetic process Effects 0.000 abstract 3
- 238000003786 synthesis reaction Methods 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000003345 natural gas Substances 0.000 abstract 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000002453 autothermal reforming Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 238000010926 purge Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000000629 steam reforming Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Способ получения метанола, уксусной кислоты и продукта из объединенного процесса. Синтез-газ получают путем объединения парового и автотермического риформинга природного газа (102), причем часть природного газа обходит паровой риформер и смешивается с исходным потоком из парового риформера для дальнейшей подачи в автотермический риформер (АТР) с рецикловым СО2. Часть синтеза-газа подают на устройство удаления СО2 для получения рециклового СО2 и к холодильнику для получения потоков водорода и СО. Синтез-газ, который остался, поток водорода и СО2 из связанного процесса подают в средство синтеза метанола, в котором изготовляется метанол и продувочный поток, который подают на устройство удаления СО2. Метанол вместе с СО подают в установку по изготовлению уксусной кислоты, а последнюю, в свою очередь, подают в установку для синтеза винилацетата. Кислород, как для АТР, так и для синтеза винилацетата, может поставляться из общей установки воздушной сепарации, а вспомогательные системы, такие как паровой генератор, могут способствовать объединению процесса.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CY2004/000002 WO2005070855A1 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA85579C2 true UA85579C2 (ru) | 2009-02-10 |
Family
ID=34800359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA200609271A UA85579C2 (ru) | 2004-01-22 | 2004-01-22 | Интегрированный способ производства метанола и уксусной кислоты |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7470811B2 (ru) |
| EP (1) | EP1708982A1 (ru) |
| JP (1) | JP4633741B2 (ru) |
| KR (2) | KR20100131528A (ru) |
| CN (1) | CN1906145B (ru) |
| AU (1) | AU2004314237B2 (ru) |
| BR (1) | BRPI0418477B1 (ru) |
| CA (1) | CA2551223C (ru) |
| MX (1) | MXPA06007682A (ru) |
| NO (1) | NO20063692L (ru) |
| NZ (1) | NZ548230A (ru) |
| PL (1) | PL209862B1 (ru) |
| RS (1) | RS20060418A (ru) |
| UA (1) | UA85579C2 (ru) |
| WO (1) | WO2005070855A1 (ru) |
| ZA (1) | ZA200605928B (ru) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY146697A (en) * | 2004-07-09 | 2012-09-14 | Acetex Cyprus Ltd | Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock |
| US7569085B2 (en) * | 2004-12-27 | 2009-08-04 | General Electric Company | System and method for hydrogen production |
| GB0510823D0 (en) * | 2005-05-27 | 2005-07-06 | Johnson Matthey Plc | Methanol synthesis |
| US7901662B2 (en) * | 2005-11-01 | 2011-03-08 | Celanese International Corporation | Steam generation apparatus and method |
| EP2228358A1 (en) * | 2009-03-13 | 2010-09-15 | Methanol Casale S.A. | Recovery of CO2 in a process for synthesis of methanol |
| ES2433231T3 (es) | 2009-08-14 | 2013-12-10 | Saudi Basic Industries Corporation | Proceso de reformado combinado para la producción de metanol |
| US20120067079A1 (en) * | 2010-03-25 | 2012-03-22 | Sethna Rustam H | Nitrogen rejection and liquifier system for liquified natural gas production |
| CN201768471U (zh) * | 2010-07-23 | 2011-03-23 | 镇海石化建安工程有限公司 | 低温甲醇洗原料气冷却器 |
| US9561476B2 (en) | 2010-12-15 | 2017-02-07 | Praxair Technology, Inc. | Catalyst containing oxygen transport membrane |
| CN103987681B (zh) | 2011-12-15 | 2016-08-24 | 普莱克斯技术有限公司 | 复合氧气传送膜 |
| US9486735B2 (en) | 2011-12-15 | 2016-11-08 | Praxair Technology, Inc. | Composite oxygen transport membrane |
| WO2014100376A1 (en) | 2012-12-19 | 2014-06-26 | Praxair Technology, Inc. | Method for sealing an oxygen transport membrane assembly |
| US9453644B2 (en) | 2012-12-28 | 2016-09-27 | Praxair Technology, Inc. | Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream |
| US9174903B2 (en) | 2013-03-15 | 2015-11-03 | Gas Technologies Llc | Reactive scrubbing for upgrading product value, simplifying process operation and product handling |
| US9255051B2 (en) | 2013-03-15 | 2016-02-09 | Gas Technologies Llc | Efficiency, flexibility, and product value of a direct alkanes to oxygenates process |
| US20140275634A1 (en) | 2013-03-15 | 2014-09-18 | Gas Technologies Llc | Ether Blends Via Reactive Distillation |
| US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
| US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| US9023245B2 (en) | 2013-04-26 | 2015-05-05 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming |
| US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
| US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
| US9115045B2 (en) | 2013-04-26 | 2015-08-25 | Praxair Technology, Inc. | Method and system for producing methanol using an oxygen transport membrane based reforming system |
| US9365422B2 (en) | 2013-04-26 | 2016-06-14 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system with recycling of the produced synthesis gas |
| CN105492379B (zh) | 2013-09-05 | 2018-08-03 | 普莱克斯技术有限公司 | 使用集成的基于氧传输膜的重整系统生产甲醇的方法和系统 |
| US9587189B2 (en) | 2013-10-01 | 2017-03-07 | Gas Technologies L.L.C. | Diesel fuel composition |
| MX391612B (es) | 2013-10-07 | 2025-03-12 | Praxair Technology Inc | Reactor cerámico de conversión de conjunto de membranas de transporte de oxígeno. |
| CA2924201A1 (en) | 2013-10-08 | 2015-04-16 | Praxair Technology, Inc. | System and method for temperature control in an oxygen transport membrane based reactor |
| US9556027B2 (en) | 2013-12-02 | 2017-01-31 | Praxair Technology, Inc. | Method and system for producing hydrogen using an oxygen transport membrane based reforming system with secondary reforming |
| US9562472B2 (en) | 2014-02-12 | 2017-02-07 | Praxair Technology, Inc. | Oxygen transport membrane reactor based method and system for generating electric power |
| WO2015160609A1 (en) | 2014-04-16 | 2015-10-22 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (igcc) |
| EA201692175A1 (ru) * | 2014-04-29 | 2017-06-30 | Хальдор Топсёэ А/С | Способ получения метанола |
| WO2016057164A1 (en) | 2014-10-07 | 2016-04-14 | Praxair Technology, Inc | Composite oxygen ion transport membrane |
| ES3039641T3 (en) * | 2014-11-25 | 2025-10-23 | Topsoe As | A process for generation of synthesis gas by flue gas recycle |
| US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
| US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
| JP2019513081A (ja) | 2016-04-01 | 2019-05-23 | プラクスエア・テクノロジー・インコーポレイテッド | 触媒含有酸素輸送膜 |
| CN113577812B (zh) | 2017-12-04 | 2023-03-17 | 碳回收国际公司 | 用于通过蒸馏和气提来分离溶解的气体的系统和方法 |
| WO2019212072A1 (ko) * | 2018-05-02 | 2019-11-07 | 한국과학기술원 | 이산화탄소를 이용하는 건식 개질 반응을 이용한 아세트산의 생성 방법 및 그 시스템 |
| EP3797085A1 (en) | 2018-05-21 | 2021-03-31 | Praxair Technology, Inc. | Otm syngas panel with gas heated reformer |
| GB201908450D0 (en) * | 2019-06-12 | 2019-07-24 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
| GB201908449D0 (en) * | 2019-06-12 | 2019-07-24 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
| US12491484B2 (en) | 2021-01-15 | 2025-12-09 | CRI, hf | Reactor for synthesis of methanol or other products |
| WO2022153214A1 (en) | 2021-01-15 | 2022-07-21 | Cri, Ehf | Methanol synthesis reactor |
| EP4039639A1 (en) * | 2021-02-04 | 2022-08-10 | Casale Sa | Process for methanol production |
| US11407667B1 (en) | 2021-06-06 | 2022-08-09 | Christopher R. Moylan | Systems and methods for removal of carbon dioxide from seawater |
| US11685673B2 (en) | 2021-06-06 | 2023-06-27 | Christopher R. Moylan | Systems and methods for removal of carbon dioxide from seawater |
| WO2023148605A1 (en) | 2022-02-01 | 2023-08-10 | CRI, hf | Heat integration |
| IT202200004013A1 (it) * | 2022-03-03 | 2023-09-03 | Milano Politecnico | Processo autosostenibile a zero emissioni per produzione di chemicals da fonti organiche |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2372116A1 (fr) * | 1977-03-22 | 1978-06-23 | Banquy David | Procede de production de gaz de synthese |
| US6781014B1 (en) * | 1999-11-01 | 2004-08-24 | Acetex (Cyprus) Limited | Methanol plant retrofit for manufacture of acetic acid |
| US6444712B1 (en) * | 2000-09-28 | 2002-09-03 | Exxonmobil Chemical Patents, Inc. | Methanol, olefin, and hydrocarbon synthesis process |
| US6495609B1 (en) * | 2000-11-03 | 2002-12-17 | Exxonmobil Chemical Patents Inc. | Carbon dioxide recovery in an ethylene to ethylene oxide production process |
| EA008283B1 (ru) * | 2002-05-20 | 2007-04-27 | Асетэкс (Кипр) Лимитед | Интегрированный способ производства уксусной кислоты и метанола |
| US7151198B2 (en) * | 2002-12-30 | 2006-12-19 | Exxonmobil Chemical Patents Inc. | Integration of a methanol synthesis system with a methanol to olefin reaction system |
| US6846951B1 (en) * | 2003-10-09 | 2005-01-25 | Acetex (Cyprus) Limited | Integrated process for acetic acid and methanol |
| US7199276B2 (en) * | 2003-11-19 | 2007-04-03 | Exxonmobil Chemical Patents Inc. | Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process |
| US7304197B2 (en) * | 2003-11-24 | 2007-12-04 | Exxonmobil Chemical Patents Inc. | Recycling oxygenate-rich streams in oxygenate-to-olefin processes |
-
2004
- 2004-01-22 NZ NZ548230A patent/NZ548230A/xx not_active IP Right Cessation
- 2004-01-22 CN CN2004800405271A patent/CN1906145B/zh not_active Expired - Fee Related
- 2004-01-22 UA UAA200609271A patent/UA85579C2/ru unknown
- 2004-01-22 US US10/596,955 patent/US7470811B2/en not_active Expired - Fee Related
- 2004-01-22 KR KR1020107026583A patent/KR20100131528A/ko not_active Ceased
- 2004-01-22 KR KR1020067016763A patent/KR101046116B1/ko not_active Expired - Fee Related
- 2004-01-22 EP EP04738452A patent/EP1708982A1/en not_active Withdrawn
- 2004-01-22 JP JP2006549841A patent/JP4633741B2/ja not_active Expired - Fee Related
- 2004-01-22 RS YUP-2006/0418A patent/RS20060418A/sr unknown
- 2004-01-22 BR BRPI0418477-7A patent/BRPI0418477B1/pt not_active IP Right Cessation
- 2004-01-22 WO PCT/CY2004/000002 patent/WO2005070855A1/en not_active Ceased
- 2004-01-22 PL PL380241A patent/PL209862B1/pl unknown
- 2004-01-22 CA CA2551223A patent/CA2551223C/en not_active Expired - Fee Related
- 2004-01-22 MX MXPA06007682A patent/MXPA06007682A/es active IP Right Grant
- 2004-01-22 AU AU2004314237A patent/AU2004314237B2/en not_active Ceased
-
2006
- 2006-07-18 ZA ZA2006/05928A patent/ZA200605928B/en unknown
- 2006-08-17 NO NO20063692A patent/NO20063692L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20070001962A (ko) | 2007-01-04 |
| KR20100131528A (ko) | 2010-12-15 |
| AU2004314237B2 (en) | 2011-03-10 |
| BRPI0418477A (pt) | 2007-06-19 |
| JP4633741B2 (ja) | 2011-02-16 |
| NO20063692L (no) | 2006-10-19 |
| CN1906145A (zh) | 2007-01-31 |
| AU2004314237A1 (en) | 2005-08-04 |
| RS20060418A (sr) | 2008-09-29 |
| BRPI0418477B1 (pt) | 2015-04-22 |
| PL209862B1 (pl) | 2011-10-31 |
| CA2551223A1 (en) | 2005-08-04 |
| ZA200605928B (en) | 2008-01-08 |
| MXPA06007682A (es) | 2007-01-26 |
| CN1906145B (zh) | 2010-09-29 |
| KR101046116B1 (ko) | 2011-07-01 |
| JP2007518745A (ja) | 2007-07-12 |
| US7470811B2 (en) | 2008-12-30 |
| EP1708982A1 (en) | 2006-10-11 |
| NZ548230A (en) | 2009-08-28 |
| CA2551223C (en) | 2011-05-03 |
| WO2005070855A1 (en) | 2005-08-04 |
| US20080039652A1 (en) | 2008-02-14 |
| PL380241A1 (pl) | 2007-01-08 |
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