Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
  • C09B47/00—Porphines; Azaporphines
  • C09B47/04—Phthalocyanines abbreviation: Pc
  • C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex

Definitions

• the present invention relates to particular processes for making tetra-aminophthalocyanines.
• This invention relates to the manufacture of metal-free and metallic tetra- (4) and tetra-(3) aminophthalocyanines. It is an object of the present invention to provide tetra-amino phthalocyanines, as defined below, by reduction of the corresponding tetranitro phthalocyanines.
• the said tetra-aminophthalocyanines by reducing the corresponding tetra-nitrophthalocyanines by the reducing agents specified below.
• reducing agents for instance, copper tetra-4-nitroor -tetra-3-nitro-phthalocyanine.
• M i x t u r e s of phthalocyanines may also beutilised, for example, a mixture of copper tetra- (4) -nltro and -tetra-(3) -nitrophthalocyanines.
• Other metallic tetra-nitrophthalocyanines for instance, those of cobalt, nickel, aluminium, lead or magnesium, may also be used.
• Metallic tetra-nitrophthalocyanines are conveniently made, for example, from a compound of the desired metal or the metal itself, together with the appropriate nitrophthalo-dinitrile or riitro-phthalic anhydride,
• Metal-free tetra-nitrophthalocyanines which may be made by heating the requisite nitro-phthalodinitrile'with calcium oxide, are likewise useful as starting materials.
• the reducing agents which are used in this invention are those of the alkali sulphide class, in which expression are included sodium sulphide, sodium hydrogen sulphide and sodium, disulphide.
• Stannous chloride and sodium hydrosulphite sodium hyposulphitel are also used as reducing agents according to the invention. By this means there are obtained in good yield tetra-aminophthalocyanines. These compounds are green in colour and insoluble in water. They are turned blue by the action of acids, for example, hydrochloric acid, seemingly owing to salt-formation.
• Tetra-aminophthalocyanines are readily diazotised and are useful as intermediates, namely, diazocomponents, in the preparation of colouring matters.
• the diazotisation of tetra-aminophthalocyanines which have been made from tetra-nitrophthalocyanines by the above reduction process, constitutes part of the present invention.
• the invention includes also the precipitation of the tetra-diazo compounds in a form suitable for technical handling, and so in solid state, by adding to the solutions thereof, zinc chloride, cadmium chloride or other salt suitable for the production of double salts, or of naphthalene or other sulphonic acids which will give sulphonic acid salts of the tetra-diazo compounds sparingly enough soluble in water to be precipitated.
• Tetra-aminophthalocyanines obtained by de-acylating tetra-acylaminophthalocyanines may be diazotiscd, as already mentioned, but owing to gross decomposition of the phthalocyanine molecule having occurred during deacylation the By working according to the present invention, tetra-aminophthalocyanines may be obtained and diazotised in excellent yield.
• Example 1 I parts of copper tetra-(4)-nitrophthalocyanine (made from i-nitrophthalimide) in the form of an aqueous paste is mixed with 1400 parts of water, 200 parts of 33% aqueous sodium hydroxide and 150 parts of sodium hydrosul phite. The mixture is stirred and heated at 50-55 C. for 1 hour. The blue suspension becomes bright green. The mixture is filtered. The filter cake is stirred with 1000 parts of boiling 20% sodium chloride solution, filtered, washed with cold 10% sodium chloride solution and dried. There is thus obtained a dark green pulverulent solid which dissolves in concentrated sulphuric acid to give a bright yellowish green solution. It is almost insoluble in high boiling organic solvents. When stirred into dilute aqueous mineral acids the colour changes to blue seemingly by salt formation although the substance does not dissolve. When this blue substance is treated with aqueous sodium by hydroxide, the colour changes back to green.
• copper tetra-3-nitro-phthalocyanlne made from 3-nitro-phthalic anhydride
• copper tetra-4- aminophthalocyanine copper tetra-3-aminophthalocyanine is obtained. It is similar in appearance and chemical properties to the product obtained in the first part of this example.
• Example 2 aqueous sodium hydrogen sulphide solution are added at such a rate that the temperature of the mixture does not exceed 25 C. After 20 hours, the dark green suspension is diluted with.
• the purity of the copper tetra-4-aminophthalocyanine so-obtained is about 96% when assessed in the following manner. 3.25 parts of copper tetra-4-aminophthalocyanine as a aqueous paste are mixed with 3 parts by volume of 10% aqueous sodium nitrite solution and introduced into the closed limb of a Lunge nitrometer. 30 parts by volume, of concentrated hydrochloric acid are added and the mixture shaken. A solution of cuprou chloride in hydrochloric acid is introduced. Ferrous sulphate solution i added to absorb the excess of nitrous gases. The tetraaminophthalocyanine that was present is calculated from the residual volume of nitrogen.
• Example 3 10 parts of copper tetra-(4)-nitrophthalocyanine in the form of a finely milled aqueous paste are stirred with 200 parts of 33% aqueous hydrochloric acid .till a smooth paste is formed. The suspension is cooled to 5 C. and 50 parts of crystalline stannous chloride added gradually so that the temperature of the mixture does not exceed 10 C. The reduction is complete when a test portion added to water gives a violet coloured precipitate which rapidly change to bright blue when exposed toair.
• Example 2 washed with water until free from inorganic matter and dried.
• the purity of this material is found to be 98% by the method of Example 2. It is green in colour and becomes blue on treatment with sulphuric acid.
• Copper tetra-(4)-aminophthalocyanine is diazotized as follows. 30 parts thereof as a finely milled aqueous paste are stirred with parts of sodium nitrite and in all 500 parts of cold water. To this mixture (at below 10 C.) is quickly added with stirring 500 parts of 33% aqueous hydrochloric acid. After afew minutes stirring a clear deep green solution of the tetradiazo com pound is obtained.
• Example 4 10 parts of copper tetra-(4) -nitrophthalocyanine in the form of a finely milled 10% aqueous paste are stirred in a vessel immersed in a bath of cold water, and 24 parts of crystalline sodium sulphide, dissolved in the minimum quantity of water, added slowly so that the temperature does not exceed 20 C. After stirring for 20 hours parts of 10% sodium sulphite solution are added. The dark green product is filtered off, washed well with water and dried.
• the zinc chloride double salt of copper tetra-(4) diazonium-phthalocyanine chloride is made as follows. 12.3 parts of finely divided copper tetra- (4)-aminophthalocyanine in the form of an aqueous paste are mixed with parts of water and 6 parts of sodium nitrite. This mixture, cooled to 5 C., is then added to 90 parts of concentrated aqueous hydrochloric acid (sp. gr. 1.16) previously cooled to 0 C. To the clear dark green solution of diazo compound thus obtained there is added a solution of 25 parts of zinc chloride in 50 parts of 0.5% aqueous hydrochloric J acid.
• nickel tetra-4-nitrophthalocyanine is reduced as described above, nickel tetra-4-aminophthalocyanine is obtained. It is a dark green substance which becomes blue when treated with 2N-hydrochloric acid.
• Example 6 30 parts of metal-free tetra-(4)-nitrophtha1ocyanine (made by heating 4-nitrophthalonitrile with quick lime) in the form of a finely milled 10% aqueous paste are stirred in an ice-bath and 145 parts 01 30% sodium hydrogen sulphide solution added at such a rate that the temperature of the mixtures does not exceed 20 C. After stirring for 20 hours 220 parts of 10% sodium sulphite solution are added. The suspension is filtered, the filter cake washed with 5% sodium sulphite solution and then with water and dried. The soobtained product is a dark green powder which gives a blue suspension when stirred with 2N- hydrochloric acid.
• a process for the manufacture of tetraamino derivatives or phthalocyanine compounds selected from the group consisting of metal-free and metallic phthalocyanines which comprises subjecting the corresponding tetranitro phthalocyanine compounds to reduction by means of a reducing agent selected from the group consisting of stannous chloride, sodium hydrosulfite, and the alkali sulfide class.
• a process for the manufacture of tetraminocopper-phthalocyanine which comprises reducing tetranitro-copper-phthalocyanine in aqueous medium by the aid of a reducing agent of the alkali sulfide class.
• a process for the manufacture of tetraminocopper-phthalocyanine which comprises reducing tetra-nitro-copper-phthalocyanine in alkaline aqueous medium by the aid of an alkaline hydrosulfite.
• a process for the manufacture of tetraminocopper-phthalocyanine which comprises reducing tetranitro-copper-phthalocyanine in acid aqueous medium by the aid of stannous chloride.
• a process for the manufacture of tetraamino derivatives of phthalocyanine compounds selected from the group consisting of metal-free and metallic phthalocyanines which comprises subjecting the corresponding tetranitro phthalocyanine compounds to, reduction in aqueous medium by the aid of sodium hydrogen sulfide.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Photoreceptors In Electrophotography (AREA)
• Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
• Nitrogen Condensed Heterocyclic Rings (AREA)

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Cited By (2)

• 1939
  • 1939-05-25 GB GB15564/39A patent/GB529847A/en not_active Expired
• 1940
  • 1940-05-01 CH CH219146D patent/CH219146A/de unknown
  • 1940-05-17 US US335871A patent/US2280072A/en not_active Expired - Lifetime
  • 1940-05-24 FR FR865797D patent/FR865797A/fr not_active Expired

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