US2901383A - Process for cleaning objects - Google Patents

Process for cleaning objects Download PDF

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Publication number
US2901383A
US2901383A US612971A US61297156A US2901383A US 2901383 A US2901383 A US 2901383A US 612971 A US612971 A US 612971A US 61297156 A US61297156 A US 61297156A US 2901383 A US2901383 A US 2901383A
Authority
US
United States
Prior art keywords
objects
polyvinyl chloride
cleaning
particles
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US612971A
Other languages
English (en)
Inventor
Lebsanft Kurt
Schmidt Ernst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Chemie AG
Original Assignee
Wacker Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG
Application granted granted Critical
Publication of US2901383A publication Critical patent/US2901383A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/16Metals

Definitions

  • the polyvinyl chloride particles may be kept in motion by mechanically stirring the liquid cleaning solvent, particularly when the solvent is not boiling; but if the solvent is boiling a mechanical motion is not necessary since the polyvinyl chloride par- 2 ticles are kept in constant distribution in the liquid by the bubbles of vapor.
  • the cleaning fluid consists of liquid trichlorethylene contained in a vat or tank of .any suitable dimensions which may be heated in any convenient manner since in some cases, depending upon the objects to be cleaned, it may be desirable to maintain the bath at an elevated or boiling temperature.
  • liquid trichlorethylene there are dumped about 5% by weight of ball-shaped particles of polyvinyl chloride (mean molecular weight 47,000) of 0.5-1 mm. diameter. If the temperature of the trichloroethylene is 35 C. or less, the particles of polyvinyl chloride will float on the liquid, hence at such temperatures the bath is preferably kept in motion by any suitable mechanical means to elfect a distribution of the particles in the bath. When the temperature is raised above 35 C. the heating and boiling of the liquid agitates the liquid and effects a distribution of the polyvinyl chloride particles.
  • the objects to be cleaned are lowered into, and submerged in, the cleaning bath. Not only the motion of the liquid referred to above, but also the descending motion of the submerging objects or plates themselves, and their subsequent ascending motion, causes the particles of polyvinyl chloride to positively wipe and rub against thesurfaces of said objects.
  • the combined action of the trichlorethylene and the particles of polyvinyl chloride quickly removes all soluble impurities as well as insoluble impurities from the submerged objects.
  • Any particles of polyvinyl chloride adhering to the cleaned objects after withdrawing the latter from the trichlorethylene are quickly removed by simply dipping such objects in a rinsing bath consisting of a liquid chlorinated hydrocarbon, for example liquid trichlorethylene.
  • Example II The process described in Example 1 is repeated with only one difference, namely, the cleaning fluid consists of liquid perchlorethylene.
  • the ball-shaped particles of polyvinyl chloride ordinarily float on perchlorethylene at any temperature. However, the particles are uniformly distributed in the liquid perchlorethylene either by any suitable mechanical motion or stirring, or by heating the liquid to a temperature of C. or higher, particularly during boiling.
  • an effective distribution of the polyvinyl chloride balls in the solvent takes place positively by simply dipping (submerging) the objects to be cleaned into, and removing same from, the solvent. As a result the polyvinyl chloride balls are always distributed in the solvent, whether the solvent boils or not.
  • Process for cleaning objects which comprises irnmersing them in and removing them from a substance selected from the group consisting of trichlorethylene and perchlorethylene and containing about 5% by weight of ball shapedarticles of polyvinyl chloride of 05-15mm. diameter.
  • Process for cleaningobjects which comprises immer sing them. 'in and removing them from a chlorinated aliphatic hydrocarbon selected from the group; consisting of trichlorethylene a-nd perchlorethylene and containing about 5% by weightof finely distributed ball-shaped particles of polyvinyl chloride of 0.5-1 mm. diameter and means molecular weight 47,000, and'then rinsing the cleaned objects in a chlorinated hydrocarbon selected from the aforesaid group to remove the polyvinyl chloride particles.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
US612971A 1950-10-26 1956-10-01 Process for cleaning objects Expired - Lifetime US2901383A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEW4384A DE829645C (de) 1950-10-26 1950-10-26 Verfahren zur Reinigung von Gegenstaenden

Publications (1)

Publication Number Publication Date
US2901383A true US2901383A (en) 1959-08-25

Family

ID=7592269

Family Applications (1)

Application Number Title Priority Date Filing Date
US612971A Expired - Lifetime US2901383A (en) 1950-10-26 1956-10-01 Process for cleaning objects

Country Status (5)

Country Link
US (1) US2901383A (fr)
CH (1) CH293129A (fr)
DE (1) DE829645C (fr)
FR (1) FR1044059A (fr)
GB (1) GB696622A (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3028267A (en) * 1958-06-13 1962-04-03 Wacker Chemie Gmbh Process and apparatus for cleaning rigid objects
US3167797A (en) * 1962-05-23 1965-02-02 Om Edwards Co Inc Apparatus for vehicle washing
US3956162A (en) * 1973-06-15 1976-05-11 E. I. Du Pont De Nemours And Company Thixotropic cleaning composition containing particulate resins and fumed silica
US3969195A (en) * 1971-05-07 1976-07-13 Siemens Aktiengesellschaft Methods of coating and surface finishing articles made of metals and their alloys
US4101386A (en) * 1971-05-07 1978-07-18 Siemens Aktiengesellschaft Methods of coating and surface finishing articles made of metals and their alloys
US4148204A (en) * 1971-05-07 1979-04-10 Siemens Aktiengesellschaft Process of mechanically shaping metal articles
USH442H (en) 1984-04-16 1988-03-01 The United States Of America As Represented By The Secretary Of The Navy Composition and method for cleaning embedded soil from surfaces having low gloss coatings
US4832865A (en) * 1988-01-05 1989-05-23 Ppg Industries, Inc. Composition containing non-ionic surfactant
US5593339A (en) * 1993-08-12 1997-01-14 Church & Dwight Co., Inc. Slurry cleaning process

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1098321B (de) * 1950-10-26 1961-01-26 Wacker Chemie Gmbh Verfahren zum Reinigen von Gegenstaenden
DE1109293B (de) * 1959-04-27 1961-06-22 Ekkehard Friedl Verfahren zum Reinigen fester Gegenstaende durch Abspritzen
DE1175961B (de) * 1960-11-17 1964-08-13 Wacker Chemie Gmbh Zusatz zu organischen Fluessigkeiten fuer die Reinigung von starrem Material
DE1276261C2 (de) * 1965-05-17 1974-09-19 Hoechst Ag Pasten zum beizen von edelstahloberflaechen
US4481126A (en) * 1982-07-26 1984-11-06 The Procter & Gamble Company No rinse liquid car cleaner with solid polymers

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2517356A (en) * 1948-12-23 1950-08-01 Rhodiaceta Solutions of polyvinyl chloride in a mixture of acetone and perchloroethylene
FR965236A (fr) * 1950-09-06
US2525303A (en) * 1946-03-25 1950-10-10 Lenoble Jacques Paul Hand cleaning composition
US2627148A (en) * 1953-02-03 Process for cleaneng spark plugs

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR965236A (fr) * 1950-09-06
US2627148A (en) * 1953-02-03 Process for cleaneng spark plugs
US2525303A (en) * 1946-03-25 1950-10-10 Lenoble Jacques Paul Hand cleaning composition
US2517356A (en) * 1948-12-23 1950-08-01 Rhodiaceta Solutions of polyvinyl chloride in a mixture of acetone and perchloroethylene

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3028267A (en) * 1958-06-13 1962-04-03 Wacker Chemie Gmbh Process and apparatus for cleaning rigid objects
US3167797A (en) * 1962-05-23 1965-02-02 Om Edwards Co Inc Apparatus for vehicle washing
US3969195A (en) * 1971-05-07 1976-07-13 Siemens Aktiengesellschaft Methods of coating and surface finishing articles made of metals and their alloys
US4101386A (en) * 1971-05-07 1978-07-18 Siemens Aktiengesellschaft Methods of coating and surface finishing articles made of metals and their alloys
US4148204A (en) * 1971-05-07 1979-04-10 Siemens Aktiengesellschaft Process of mechanically shaping metal articles
US3956162A (en) * 1973-06-15 1976-05-11 E. I. Du Pont De Nemours And Company Thixotropic cleaning composition containing particulate resins and fumed silica
USH442H (en) 1984-04-16 1988-03-01 The United States Of America As Represented By The Secretary Of The Navy Composition and method for cleaning embedded soil from surfaces having low gloss coatings
US4832865A (en) * 1988-01-05 1989-05-23 Ppg Industries, Inc. Composition containing non-ionic surfactant
US5593339A (en) * 1993-08-12 1997-01-14 Church & Dwight Co., Inc. Slurry cleaning process
US5863883A (en) * 1993-08-12 1999-01-26 Church & Dwight Co., Inc Slurry cleaning process

Also Published As

Publication number Publication date
CH293129A (de) 1953-09-15
GB696622A (en) 1953-09-02
DE829645C (de) 1952-01-28
FR1044059A (fr) 1953-11-13

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