US2901383A - Process for cleaning objects - Google Patents
Process for cleaning objects Download PDFInfo
- Publication number
- US2901383A US2901383A US612971A US61297156A US2901383A US 2901383 A US2901383 A US 2901383A US 612971 A US612971 A US 612971A US 61297156 A US61297156 A US 61297156A US 2901383 A US2901383 A US 2901383A
- Authority
- US
- United States
- Prior art keywords
- objects
- polyvinyl chloride
- cleaning
- particles
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004140 cleaning Methods 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 17
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 29
- 239000004800 polyvinyl chloride Substances 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 27
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 12
- 239000007788 liquid Substances 0.000 description 17
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 15
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 12
- 229950011008 tetrachloroethylene Drugs 0.000 description 12
- 239000002904 solvent Substances 0.000 description 8
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 7
- 238000009835 boiling Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 101100406879 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) par-2 gene Proteins 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Definitions
- the polyvinyl chloride particles may be kept in motion by mechanically stirring the liquid cleaning solvent, particularly when the solvent is not boiling; but if the solvent is boiling a mechanical motion is not necessary since the polyvinyl chloride par- 2 ticles are kept in constant distribution in the liquid by the bubbles of vapor.
- the cleaning fluid consists of liquid trichlorethylene contained in a vat or tank of .any suitable dimensions which may be heated in any convenient manner since in some cases, depending upon the objects to be cleaned, it may be desirable to maintain the bath at an elevated or boiling temperature.
- liquid trichlorethylene there are dumped about 5% by weight of ball-shaped particles of polyvinyl chloride (mean molecular weight 47,000) of 0.5-1 mm. diameter. If the temperature of the trichloroethylene is 35 C. or less, the particles of polyvinyl chloride will float on the liquid, hence at such temperatures the bath is preferably kept in motion by any suitable mechanical means to elfect a distribution of the particles in the bath. When the temperature is raised above 35 C. the heating and boiling of the liquid agitates the liquid and effects a distribution of the polyvinyl chloride particles.
- the objects to be cleaned are lowered into, and submerged in, the cleaning bath. Not only the motion of the liquid referred to above, but also the descending motion of the submerging objects or plates themselves, and their subsequent ascending motion, causes the particles of polyvinyl chloride to positively wipe and rub against thesurfaces of said objects.
- the combined action of the trichlorethylene and the particles of polyvinyl chloride quickly removes all soluble impurities as well as insoluble impurities from the submerged objects.
- Any particles of polyvinyl chloride adhering to the cleaned objects after withdrawing the latter from the trichlorethylene are quickly removed by simply dipping such objects in a rinsing bath consisting of a liquid chlorinated hydrocarbon, for example liquid trichlorethylene.
- Example II The process described in Example 1 is repeated with only one difference, namely, the cleaning fluid consists of liquid perchlorethylene.
- the ball-shaped particles of polyvinyl chloride ordinarily float on perchlorethylene at any temperature. However, the particles are uniformly distributed in the liquid perchlorethylene either by any suitable mechanical motion or stirring, or by heating the liquid to a temperature of C. or higher, particularly during boiling.
- an effective distribution of the polyvinyl chloride balls in the solvent takes place positively by simply dipping (submerging) the objects to be cleaned into, and removing same from, the solvent. As a result the polyvinyl chloride balls are always distributed in the solvent, whether the solvent boils or not.
- Process for cleaning objects which comprises irnmersing them in and removing them from a substance selected from the group consisting of trichlorethylene and perchlorethylene and containing about 5% by weight of ball shapedarticles of polyvinyl chloride of 05-15mm. diameter.
- Process for cleaningobjects which comprises immer sing them. 'in and removing them from a chlorinated aliphatic hydrocarbon selected from the group; consisting of trichlorethylene a-nd perchlorethylene and containing about 5% by weightof finely distributed ball-shaped particles of polyvinyl chloride of 0.5-1 mm. diameter and means molecular weight 47,000, and'then rinsing the cleaned objects in a chlorinated hydrocarbon selected from the aforesaid group to remove the polyvinyl chloride particles.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEW4384A DE829645C (de) | 1950-10-26 | 1950-10-26 | Verfahren zur Reinigung von Gegenstaenden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2901383A true US2901383A (en) | 1959-08-25 |
Family
ID=7592269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US612971A Expired - Lifetime US2901383A (en) | 1950-10-26 | 1956-10-01 | Process for cleaning objects |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2901383A (fr) |
| CH (1) | CH293129A (fr) |
| DE (1) | DE829645C (fr) |
| FR (1) | FR1044059A (fr) |
| GB (1) | GB696622A (fr) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3028267A (en) * | 1958-06-13 | 1962-04-03 | Wacker Chemie Gmbh | Process and apparatus for cleaning rigid objects |
| US3167797A (en) * | 1962-05-23 | 1965-02-02 | Om Edwards Co Inc | Apparatus for vehicle washing |
| US3956162A (en) * | 1973-06-15 | 1976-05-11 | E. I. Du Pont De Nemours And Company | Thixotropic cleaning composition containing particulate resins and fumed silica |
| US3969195A (en) * | 1971-05-07 | 1976-07-13 | Siemens Aktiengesellschaft | Methods of coating and surface finishing articles made of metals and their alloys |
| US4101386A (en) * | 1971-05-07 | 1978-07-18 | Siemens Aktiengesellschaft | Methods of coating and surface finishing articles made of metals and their alloys |
| US4148204A (en) * | 1971-05-07 | 1979-04-10 | Siemens Aktiengesellschaft | Process of mechanically shaping metal articles |
| USH442H (en) | 1984-04-16 | 1988-03-01 | The United States Of America As Represented By The Secretary Of The Navy | Composition and method for cleaning embedded soil from surfaces having low gloss coatings |
| US4832865A (en) * | 1988-01-05 | 1989-05-23 | Ppg Industries, Inc. | Composition containing non-ionic surfactant |
| US5593339A (en) * | 1993-08-12 | 1997-01-14 | Church & Dwight Co., Inc. | Slurry cleaning process |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1098321B (de) * | 1950-10-26 | 1961-01-26 | Wacker Chemie Gmbh | Verfahren zum Reinigen von Gegenstaenden |
| DE1109293B (de) * | 1959-04-27 | 1961-06-22 | Ekkehard Friedl | Verfahren zum Reinigen fester Gegenstaende durch Abspritzen |
| DE1175961B (de) * | 1960-11-17 | 1964-08-13 | Wacker Chemie Gmbh | Zusatz zu organischen Fluessigkeiten fuer die Reinigung von starrem Material |
| DE1276261C2 (de) * | 1965-05-17 | 1974-09-19 | Hoechst Ag | Pasten zum beizen von edelstahloberflaechen |
| US4481126A (en) * | 1982-07-26 | 1984-11-06 | The Procter & Gamble Company | No rinse liquid car cleaner with solid polymers |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2517356A (en) * | 1948-12-23 | 1950-08-01 | Rhodiaceta | Solutions of polyvinyl chloride in a mixture of acetone and perchloroethylene |
| FR965236A (fr) * | 1950-09-06 | |||
| US2525303A (en) * | 1946-03-25 | 1950-10-10 | Lenoble Jacques Paul | Hand cleaning composition |
| US2627148A (en) * | 1953-02-03 | Process for cleaneng spark plugs |
-
1950
- 1950-10-26 DE DEW4384A patent/DE829645C/de not_active Expired
-
1951
- 1951-02-15 CH CH293129D patent/CH293129A/de unknown
- 1951-10-17 GB GB24280/51A patent/GB696622A/en not_active Expired
- 1951-10-22 FR FR1044059D patent/FR1044059A/fr not_active Expired
-
1956
- 1956-10-01 US US612971A patent/US2901383A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR965236A (fr) * | 1950-09-06 | |||
| US2627148A (en) * | 1953-02-03 | Process for cleaneng spark plugs | ||
| US2525303A (en) * | 1946-03-25 | 1950-10-10 | Lenoble Jacques Paul | Hand cleaning composition |
| US2517356A (en) * | 1948-12-23 | 1950-08-01 | Rhodiaceta | Solutions of polyvinyl chloride in a mixture of acetone and perchloroethylene |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3028267A (en) * | 1958-06-13 | 1962-04-03 | Wacker Chemie Gmbh | Process and apparatus for cleaning rigid objects |
| US3167797A (en) * | 1962-05-23 | 1965-02-02 | Om Edwards Co Inc | Apparatus for vehicle washing |
| US3969195A (en) * | 1971-05-07 | 1976-07-13 | Siemens Aktiengesellschaft | Methods of coating and surface finishing articles made of metals and their alloys |
| US4101386A (en) * | 1971-05-07 | 1978-07-18 | Siemens Aktiengesellschaft | Methods of coating and surface finishing articles made of metals and their alloys |
| US4148204A (en) * | 1971-05-07 | 1979-04-10 | Siemens Aktiengesellschaft | Process of mechanically shaping metal articles |
| US3956162A (en) * | 1973-06-15 | 1976-05-11 | E. I. Du Pont De Nemours And Company | Thixotropic cleaning composition containing particulate resins and fumed silica |
| USH442H (en) | 1984-04-16 | 1988-03-01 | The United States Of America As Represented By The Secretary Of The Navy | Composition and method for cleaning embedded soil from surfaces having low gloss coatings |
| US4832865A (en) * | 1988-01-05 | 1989-05-23 | Ppg Industries, Inc. | Composition containing non-ionic surfactant |
| US5593339A (en) * | 1993-08-12 | 1997-01-14 | Church & Dwight Co., Inc. | Slurry cleaning process |
| US5863883A (en) * | 1993-08-12 | 1999-01-26 | Church & Dwight Co., Inc | Slurry cleaning process |
Also Published As
| Publication number | Publication date |
|---|---|
| CH293129A (de) | 1953-09-15 |
| GB696622A (en) | 1953-09-02 |
| DE829645C (de) | 1952-01-28 |
| FR1044059A (fr) | 1953-11-13 |
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