US3392062A - Process of producing heat-treatable strips and sheets from heat-treatable aluminum alloys with a copper content of less than 1% - Google Patents

Process of producing heat-treatable strips and sheets from heat-treatable aluminum alloys with a copper content of less than 1% Download PDF

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Publication number
US3392062A
US3392062A US483345A US48334565A US3392062A US 3392062 A US3392062 A US 3392062A US 483345 A US483345 A US 483345A US 48334565 A US48334565 A US 48334565A US 3392062 A US3392062 A US 3392062A
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United States
Prior art keywords
less
heat
treatable
hot
temperature
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Expired - Lifetime
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US483345A
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English (en)
Inventor
Altenpohl Dietrich
Zoller Heinrich
Cohen Hans Michael
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Rio Tinto Switzerland AG
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Alusuisse Holdings AG
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/05Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions

Definitions

  • the present invention refers to the production of strips and sheets from heat-treatable aluminum alloys, containing less than 1% copper which strips and sheets can reach their maximum strength by subsequent simple aging treatment.
  • the process of the present invention is especially suitable for aluminum-magnesium-silicon alloys, but is also suitable for aluminum-zinc-magnesium alloys with low magnesium content.
  • aluminummagnesium-silicon alloy herein refers to all aluminum alloys with a chemical composition lying between the following limits:
  • the basic metal can be aluminum of commercial purity (i.e. according to ASTN B209) as well as aluminum of high or highest purity (refined aluminum).
  • AA6011, AA6061 or AA6063 according to the Registration Record of Aluminum Association Alloy Designations and Chemical Composition Limites for Wrought Aluminum Alloys, published by The American Association, 420 Lexington Ave., N.Y., N.Y., 10017.
  • the aluminum-zinc-magnesium alloys referred to in this invention may contain Percent Zinc 3.5-5 Magnesium 0.5-1.5 Copper 1 Aluminum Balance Furthermore, these alloys may contain additions like manganese, chromium or other elements. Because of their 3,392,062 Patented July 9, 1968 ice relatively low magnesium content compared to materials like e.g. AA7075, AA7079, AA7178 etc. these alloys are designated as low alloyed.
  • the present invention allows a noticeable increase in the transit speed, thus permitting an economic production of sheets and strips in essentially copper-free, heat-treatable aluminnum alloys suitable for artificially aging.
  • the initial slab or plate has to be homogenized and hot-rolled while still in the warm condition.
  • the hot-rolled strip which should have a temperature of more than 350 C., preferably more than 400 C., then immediately has to be cooled down to a temperature of 200 C., or less preferably quenched to room temperature in less than 2 minutes, preferably less than 1 minute.
  • the material is coldrolled with a thickness reduction of at least 20%, then solution-treated in a continuous furnace for less than 1 minute, preferably less than 30 seconds and immediately quenched after leaving the furnace.
  • Such sheets and strips can, at least, be naturally aged or preferably artificially aged.
  • Hot-rolling speeds for the subsequent passes have to be chosen individually in order to take advantage of the heat produced by rolling down the material, to maintain the metal temperature above 350 C., preferably above 400 C.
  • the process of the invention has the advantage of maintaining the homogenized condition of the initial slab or plate during hot rolling and subsequently in the strip leaving the hot mill by a quench.
  • sheets or strips manufactured according to the present invention can pass a homogenization furnace of given length with a speed which is many times greater than that necessary with the common methods. This rise in efiiciency, therefore, correspondingly achieves an economical increase.
  • the procedure according to the invention is especially suitable for the continuous production of strips.
  • the finished products in this case are sheets instead of strips.
  • the rolling slab is soaked for 6 hours at 530 C. (metal temperature). This is followed by hotrolling it down to a thickness of 7 mm., for instance, starting with a metal temperature of 500 C.
  • the plate temperature after hot-rolling was not less than 380 C.
  • the last hot-rolling pass is followed by an immediate quench of the plate in water, the temperature of the plate falling down to 50-80 C.
  • the transit speed is 30 m./minute, i.e. the total heating cycle takes 20 seconds: 10 seconds are used for heating up the metal, Whilst the remaining 10 seconds count as soaking time. For the subsequent quenching, air blast or water .is used. Finally the strip or sheet is aged by reheating the material for 14 hours at a temperature of 160 C.
  • the strip produced in this way has the following mechanical strength properties:
  • Brinell No. (IO/2.5) 101 An aluminum plant is known where the hot-rolled strip is cooled with water spray before coiling. However, cooling the strip at the run-out of the rolling mill in this plant is not done to maintain the homogeneous structure, but to facilitate the handling of the strip only. They do not roll any heat-treatable aluminum alloys at all in this plant, but exclusively pure aluminum and the non-heattreatable aluminum-manganese alloys.
  • Banbury, Oxfordshire, a few years ago did not suggest the use of strip from heat-treatable aluminum alloys immediately quenched after hot-rolling as a basic material for the production of heat-treatable sheet and strip from aluminum alloys by cold-rolling followed by a heat-treatment in a continuous furnace.
  • the present invention therefore is based on a special treatment combination resulting in a distinct increased effect compared with that attainable by common procedures.
  • step (2) the hot-rolling temperature is maintained at not less than 400 C. and in step (3) the quenching is done from a temperature of at least 400 C. down to a temperature below 200 C. in less than 2 minutes.
  • step (3) the quenching is done in order that the temperature of the hot-rolled member falls below 200 C. in less than 1 minute.
  • step (4) The process as described in claim 1, wherein in step (4) the duration of solution-heat-treatment is less than 30 seconds.
  • step (2) the hot-rolling temperature is maintained at not less than 400 C.
  • the quenching of the rot rolled :member is done from the temperature of at least 400 C. down to below 200 C. in less than 1 minute, and in step (4) the duration of the solution-heat-treatment is of less than 30 seconds.
  • step (2) the hot-rolling temperature is maintained at not less than 400 C.
  • the quenching of the hot rolled member is done from a temperature of at least 400 C. down to 5080 C. in less than one minute, and in step (4) the duration of the solution-heat-treatment is of less than 30 seconds.
  • step (2) the hot-rolling temperature is maintained at not less than 400 C.
  • the quenching of the hot rolled member is done from the temperature of at least 400 C. down to room temperature in less than 1 minute, and in step (4) the duration of the solution-heat-treatment is of less than 30 seconds.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
US483345A 1964-08-27 1965-08-27 Process of producing heat-treatable strips and sheets from heat-treatable aluminum alloys with a copper content of less than 1% Expired - Lifetime US3392062A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1124364A CH480883A (de) 1964-08-27 1964-08-27 Verfahren zur Herstellung aushärtbarer Bänder und Bleche aus aushärtbaren Aluminiumlegierungen mit Kupfergehalten unter 1%

Publications (1)

Publication Number Publication Date
US3392062A true US3392062A (en) 1968-07-09

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US483345A Expired - Lifetime US3392062A (en) 1964-08-27 1965-08-27 Process of producing heat-treatable strips and sheets from heat-treatable aluminum alloys with a copper content of less than 1%

Country Status (5)

Country Link
US (1) US3392062A (de)
CH (1) CH480883A (de)
DE (1) DE1279940B (de)
GB (1) GB1055687A (de)
NL (1) NL6511155A (de)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3542606A (en) * 1968-03-13 1970-11-24 Kaiser Aluminium Chem Corp Hot worked metal article of aluminum base alloy and method of producing same
US3935007A (en) * 1974-11-13 1976-01-27 Sumitomo Light Metal Industries, Ltd. Aluminum alloy of age hardening type
US3990922A (en) * 1975-10-20 1976-11-09 Swiss Aluminium Ltd. Processing aluminum alloys
US4066476A (en) * 1976-08-11 1978-01-03 Swiss Aluminium Ltd. Duplex process for improving the hot workability of aluminum-magnesium alloys
US4066480A (en) * 1976-08-11 1978-01-03 Swiss Aluminium Ltd. Process for improving the hot workability of aluminum-magnesium alloys
JPS5319117A (en) * 1976-08-05 1978-02-22 Aluminum Co Of America Modified aluminium structure
US4151013A (en) * 1975-10-22 1979-04-24 Reynolds Metals Company Aluminum-magnesium alloys sheet exhibiting improved properties for forming and method aspects of producing such sheet
US4163665A (en) * 1978-06-19 1979-08-07 Alumax Mill Products, Inc. Aluminum alloy containing manganese and copper and products made therefrom
US4174232A (en) * 1976-12-24 1979-11-13 Swiss Aluminium Ltd. Method of manufacturing sheets, strips and foils from age hardenable aluminum alloys of the Al-Si-Mg-type
JPS61201749A (ja) * 1985-03-05 1986-09-06 Sukai Alum Kk 成形加工用アルミニウム合金圧延板およびその製造方法
US4614552A (en) * 1983-10-06 1986-09-30 Alcan International Limited Aluminum alloy sheet product
US4808247A (en) * 1986-02-21 1989-02-28 Sky Aluminium Co., Ltd. Production process for aluminum-alloy rolled sheet
US6110297A (en) * 1997-01-10 2000-08-29 Honda Giken Kogyo Kabushiki Kaisha Aluminum alloy sheet with excellent formability and method for manufacture thereof
EP1375691A4 (de) * 2001-03-28 2004-07-21 Sumitomo Light Metal Ind Blech aus aluminiumlegierung mit hervorragender verfrombarkeit und härtbarkeit beim einbrennen einer beschichtung und herstellungsverfahren dafür
CN100415917C (zh) * 2001-03-28 2008-09-03 住友轻金属工业株式会社 成型性及涂敷烧结硬化性优良的铝合金板及其制造方法
WO2011000635A1 (de) 2009-06-30 2011-01-06 Hydro Aluminium Deutschland Gmbh Almgsi-band für anwendungen mit hohen umformungsanforderungen
CN101550509B (zh) * 2008-03-31 2012-07-11 株式会社神户制钢所 烤漆固化性优良、室温时效得到抑制的铝合金板及其制造方法
EP3060358B1 (de) 2013-10-25 2017-11-15 SMS group GmbH Aluminium-warmbandwalzstrasse und verfahren zum warmwalzen eines aluminium-warmbandes
CN117463818A (zh) * 2023-10-11 2024-01-30 湖南乾龙新材料有限公司 一种新能源汽车用非热处理铝合金导电扁带材及其生产方法

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164434A (en) * 1977-11-02 1979-08-14 Swiss Aluminium Ltd. Aluminum alloy capacitor foil and method of making
US4166755A (en) * 1977-11-02 1979-09-04 Swiss Aluminium Ltd. Aluminum alloy capacitor foil and method of making
WO1992003586A1 (en) * 1990-08-22 1992-03-05 Comalco Aluminium Limited Aluminium alloy suitable for can making
US9359660B2 (en) 2010-09-08 2016-06-07 Alcoa Inc. 6XXX aluminum alloys, and methods for producing the same
WO2013172910A2 (en) 2012-03-07 2013-11-21 Alcoa Inc. Improved 2xxx aluminum alloys, and methods for producing the same
US9587298B2 (en) 2013-02-19 2017-03-07 Arconic Inc. Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2887422A (en) * 1950-02-25 1959-05-19 United Eng Foundry Co Method of continuously heat treating aluminum strip
US3093459A (en) * 1958-08-02 1963-06-11 Aluminium Ind Ag Method for manufacturing highly polishable sheets of aluminum
US3194545A (en) * 1960-03-17 1965-07-13 Kaiser Aluminium Chem Corp Apparatus for continuously solution heat-treating aluminum and its alloys
US3264143A (en) * 1962-07-16 1966-08-02 Selas Corp Of America Heat treating strip material
US3312576A (en) * 1963-07-03 1967-04-04 Reynolds Metals Co Method of treating metal

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2887422A (en) * 1950-02-25 1959-05-19 United Eng Foundry Co Method of continuously heat treating aluminum strip
US3093459A (en) * 1958-08-02 1963-06-11 Aluminium Ind Ag Method for manufacturing highly polishable sheets of aluminum
US3194545A (en) * 1960-03-17 1965-07-13 Kaiser Aluminium Chem Corp Apparatus for continuously solution heat-treating aluminum and its alloys
US3264143A (en) * 1962-07-16 1966-08-02 Selas Corp Of America Heat treating strip material
US3312576A (en) * 1963-07-03 1967-04-04 Reynolds Metals Co Method of treating metal

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3542606A (en) * 1968-03-13 1970-11-24 Kaiser Aluminium Chem Corp Hot worked metal article of aluminum base alloy and method of producing same
US3935007A (en) * 1974-11-13 1976-01-27 Sumitomo Light Metal Industries, Ltd. Aluminum alloy of age hardening type
US3990922A (en) * 1975-10-20 1976-11-09 Swiss Aluminium Ltd. Processing aluminum alloys
US4151013A (en) * 1975-10-22 1979-04-24 Reynolds Metals Company Aluminum-magnesium alloys sheet exhibiting improved properties for forming and method aspects of producing such sheet
JPS5319117A (en) * 1976-08-05 1978-02-22 Aluminum Co Of America Modified aluminium structure
US4066476A (en) * 1976-08-11 1978-01-03 Swiss Aluminium Ltd. Duplex process for improving the hot workability of aluminum-magnesium alloys
US4066480A (en) * 1976-08-11 1978-01-03 Swiss Aluminium Ltd. Process for improving the hot workability of aluminum-magnesium alloys
US4174232A (en) * 1976-12-24 1979-11-13 Swiss Aluminium Ltd. Method of manufacturing sheets, strips and foils from age hardenable aluminum alloys of the Al-Si-Mg-type
US4163665A (en) * 1978-06-19 1979-08-07 Alumax Mill Products, Inc. Aluminum alloy containing manganese and copper and products made therefrom
US4614552A (en) * 1983-10-06 1986-09-30 Alcan International Limited Aluminum alloy sheet product
JPS61201749A (ja) * 1985-03-05 1986-09-06 Sukai Alum Kk 成形加工用アルミニウム合金圧延板およびその製造方法
US4808247A (en) * 1986-02-21 1989-02-28 Sky Aluminium Co., Ltd. Production process for aluminum-alloy rolled sheet
US6110297A (en) * 1997-01-10 2000-08-29 Honda Giken Kogyo Kabushiki Kaisha Aluminum alloy sheet with excellent formability and method for manufacture thereof
EP1375691A4 (de) * 2001-03-28 2004-07-21 Sumitomo Light Metal Ind Blech aus aluminiumlegierung mit hervorragender verfrombarkeit und härtbarkeit beim einbrennen einer beschichtung und herstellungsverfahren dafür
KR100833145B1 (ko) * 2001-03-28 2008-05-29 스미토모 게이 긴조쿠 고교 가부시키가이샤 굽힘성과 도장 베이킹 경화성이 우수한 알루미늄 합금판의제조 방법
CN100415917C (zh) * 2001-03-28 2008-09-03 住友轻金属工业株式会社 成型性及涂敷烧结硬化性优良的铝合金板及其制造方法
KR100861036B1 (ko) * 2001-03-28 2008-10-01 스미토모 게이 긴조쿠 고교 가부시키가이샤 성형성과 도장 베이킹 경화성이 우수한 알루미늄 합금판
KR100870164B1 (ko) * 2001-03-28 2008-11-25 스미토모 게이 긴조쿠 고교 가부시키가이샤 성형성과 도장 베이킹 경화성이 우수한 알루미늄 합금판
CN101550509B (zh) * 2008-03-31 2012-07-11 株式会社神户制钢所 烤漆固化性优良、室温时效得到抑制的铝合金板及其制造方法
WO2011000635A1 (de) 2009-06-30 2011-01-06 Hydro Aluminium Deutschland Gmbh Almgsi-band für anwendungen mit hohen umformungsanforderungen
US10047422B2 (en) 2009-06-30 2018-08-14 Hydro Aluminium Deutschland Gmbh AlMgSi strip for applications having high formability requirements
EP2449145B1 (de) * 2009-06-30 2019-08-07 Hydro Aluminium Rolled Products GmbH AlMgSi-Band für Anwendungen mit hohen Umformungsanforderungen
US10612115B2 (en) 2009-06-30 2020-04-07 Hydro Aluminium Deutschland Gmbh AlMgSi strip for applications having high formability requirements
EP2270249B2 (de) 2009-06-30 2020-05-27 Hydro Aluminium Deutschland GmbH AlMgSi-Band für Anwendungen mit hohen Umformungsanforderungen
EP3060358B1 (de) 2013-10-25 2017-11-15 SMS group GmbH Aluminium-warmbandwalzstrasse und verfahren zum warmwalzen eines aluminium-warmbandes
CN117463818A (zh) * 2023-10-11 2024-01-30 湖南乾龙新材料有限公司 一种新能源汽车用非热处理铝合金导电扁带材及其生产方法

Also Published As

Publication number Publication date
NL6511155A (de) 1966-02-28
DE1279940B (de) 1968-10-10
GB1055687A (en) 1967-01-18
CH480883A (de) 1969-11-15

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