US3435534A - Process for continuously heating,drying and heat-setting tows of filaments of synthetic polymers - Google Patents

Process for continuously heating,drying and heat-setting tows of filaments of synthetic polymers Download PDF

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Publication number
US3435534A
US3435534A US649135A US3435534DA US3435534A US 3435534 A US3435534 A US 3435534A US 649135 A US649135 A US 649135A US 3435534D A US3435534D A US 3435534DA US 3435534 A US3435534 A US 3435534A
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US
United States
Prior art keywords
filaments
tows
heat
drying
tow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US649135A
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English (en)
Inventor
Peter Knobloch
Adalbert Kuhn
Otto Pfannenschmidt
Werner Schneider
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Hoechst AG
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Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of US3435534A publication Critical patent/US3435534A/en
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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J13/00Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/20Combinations of two or more of the above-mentioned operations or devices; After-treatments for fixing crimp or curl
    • D02G1/205After-treatments for fixing crimp or curl
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, e.g. by ultrasonic waves, corona discharge, irradiation, electric currents or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/006Ultra-high-frequency heating

Definitions

  • the present invention relates to a process for continuously heating, drying and heat-setting tows of filaments or fibers of synthetic polymers of high molecular weight.
  • fibrous materials consisting of or containing synthetic polymers of high molecular weight, such as polyesters, polyamides, polyolefins or polyacrylonitrile must be heated during that part of the manufacturing process which follows the spinning process, for example before, during or after the drawing process.
  • the fibers can be heated with the aid of contact heating, for example on hot rotating rolls or drums, with hot gases or vapors, with air or with hot liquids or melts. All these processes enable, however, only relatively thin layers of fibers to be heated rapidly enough and, above all, uniformly so that the fibers must be used in a stretched or slightly expanded form.
  • the present invention provides a process for continuously heating, drying and heat-setting wet tows of filaments or fibers consisting of or containing synthetic polymers of high polymers of high molecular weight, such as polyesters, polyamides, polyolefins, or polyacrylonitrile, by passing said tows of filaments or fibers through an electric high frequency field. It is advantageous to use an electric high frequency field having an intensity in the range of from 0.2 to kilovolts/centimeter and a frequency of 2 to 60 megacycles. It has proved particularly advantageous, however, to use an electric high frequency field having an intensity of 1 to 1.5 kilovolts/centimeter and a frequency of 5 to 25 megacycles.
  • the process according to the invention is especially suitable for heating, drying and heat-setting tows of crimped filaments or fibers, respectively, which are wet as they have left the crimping chamber and are not expanded or laid down.
  • the tows of filaments are continuously passed between the plates of a plate condenser at the speed of the processing line of the sliver.
  • a strong electric alternating field is generated, pref- 3,435,534 Patented Apr. 1, 1969 erably having a field strength of 0.2 to 5 kilovolts/centimeter, and more preferably of 1 to 1.5 kilovolts/centimeter.
  • the frequency of the electric alternating field ranges of from 2 to -60 megacycles and advantageously 5 to 25 megacycles.
  • the dielectric losses of wet tows of filaments involve a generation of heat within the tow of filaments. Thus the heat is not applied to the tow from the outside with formation of disturbing temperature gradients, but generated inside the tow itself.
  • the drying and heat-setting of wet tows of filaments according to the invention is especially advantageous when the tows contain 4 to 20% of water, calculated on the weight of the wet tows, prior to the high frequency treatment.
  • the amounts of humidity and treating agents always present in tows of filaments commonly considered to be dry provoke a dielectric absorption in the electric alternating tfield, so that also dry tows of filaments can be heated and, if desired, further dried and set. In this case, however, a longer time of treatment in the electric alternating field is required than for drying and heatsetting wet tows of filaments with a higher water content in the same electric alternating field.
  • the process of the present invention offers the following advantages:
  • the processing line of the sliver can be essentially shortened because drying and heat-setting take place simultaneously and the tow of filaments is densely pushed together.
  • the simultaneity of drying and heat-setting involves a higher dyestuff absorption with otherwise identical textile properties. Owing to the wet crimping the closeness of the tow is improved.
  • As the tow of filaments is not expanded after crimping a higher packing density in the container is obtained and simultaneously the discharge of the container, which is important for the further treatment, is improved.
  • the process according to the invention permits a considerable economy in space and in the case of wet and crimped tows of filaments a higher packing density in the container, because relaying and expanding are no longer necessary, and a better cohesion of the tow.
  • the process of the invention is not limited to tows of filaments of a definite size as the drying period at a given frequency substantially depends on the energy density of the electric field characterized by the electric field strength. Hence, it follows that with a sufficient power intensity of the generator the drying period does not increase with a higher amount of fibrous material to be dried per unit of time.
  • the high frequency power of the generator required is hardly higher than that calculated from the specific heat of the fibrous material and of water and the vaporization heat of the water.
  • EXAMPLE 1 (a) A tow of polyethylene terephthalate fibers having an individual titer of 3 deniers which, after spinning, had been shrunk by 41-42% at 97 C. was drawn in a ratio of 124.5 in superheated steam of about 190 C. The tow was then dried on drums of C., the circumferential speed of which was equal to that of the tow, and crimped in the dry state. The bundle of fibers was then slightly expanded to form a wavy band and heat-setting was performed for 60 seconds in superheated steam having a temperature of -185 C. at the outlet of the steam (sample 1a).
  • the amount of dyestuff remaining in the bath was determined colorimetrically. The following dyestuff absorptions were found:
  • a tow of polyethylene terephthalate fibers of the type specified above was likewise drawn in a ratio of 1:4.5, crimped in the wet state and then passed through the high frequency condenser in the state in which it left the crimping chamber as a bundle having a cross section of about 40 x 120 mm. After crimping the tow had a degree of humidity of 7%, calculated on the weight of the 4 moist tow.
  • the applied field strength was 1.2 kilovolt/ centimeter with afrequency of 16 megacyclesrThe tow remained in the condenser for seconds.
  • the shrinking values indicated under 2b reveal that besides drying a heat-setting analogous to Zn had taken place.
  • a process for continuously heating, drying, and heatsetting Wet tows of filaments consisting of or containing synthetic polymers of high molecular weight which comprises passing the tows of filaments continuously through an electric high frequency field said tows being in the wet and crimped state in which they leave a crimping chamber without being expanded or laid down.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Nonwoven Fabrics (AREA)
  • Drying Of Solid Materials (AREA)
US649135A 1966-08-10 1967-06-27 Process for continuously heating,drying and heat-setting tows of filaments of synthetic polymers Expired - Lifetime US3435534A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0049918 1966-08-10

Publications (1)

Publication Number Publication Date
US3435534A true US3435534A (en) 1969-04-01

Family

ID=7103375

Family Applications (1)

Application Number Title Priority Date Filing Date
US649135A Expired - Lifetime US3435534A (en) 1966-08-10 1967-06-27 Process for continuously heating,drying and heat-setting tows of filaments of synthetic polymers

Country Status (9)

Country Link
US (1) US3435534A (de)
AT (1) AT293595B (de)
BE (1) BE702528A (de)
CH (2) CH508753A (de)
DE (1) DE1604532A1 (de)
ES (1) ES343819A1 (de)
GB (1) GB1192397A (de)
LU (1) LU54255A1 (de)
NL (1) NL6710719A (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003774A (en) * 1973-09-24 1977-01-18 Baumgartner Papiers S.A. Stabilization of tows of filamentary material
CN120867085A (zh) * 2025-07-30 2025-10-31 温州威龙被服有限公司 一种防静电服装布料及其加工工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2421334A (en) * 1944-04-26 1947-05-27 Ind Rayon Corp Method of treating twisted filamentary materials
US3096161A (en) * 1957-09-16 1963-07-02 Owens Corning Fiberglass Corp Heat setting of binder of fibrous masses
US3205334A (en) * 1963-07-30 1965-09-07 Radio Frequency Company Inc Textile thread heating apparatus

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2421334A (en) * 1944-04-26 1947-05-27 Ind Rayon Corp Method of treating twisted filamentary materials
US3096161A (en) * 1957-09-16 1963-07-02 Owens Corning Fiberglass Corp Heat setting of binder of fibrous masses
US3205334A (en) * 1963-07-30 1965-09-07 Radio Frequency Company Inc Textile thread heating apparatus

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003774A (en) * 1973-09-24 1977-01-18 Baumgartner Papiers S.A. Stabilization of tows of filamentary material
CN120867085A (zh) * 2025-07-30 2025-10-31 温州威龙被服有限公司 一种防静电服装布料及其加工工艺

Also Published As

Publication number Publication date
BE702528A (de) 1968-02-12
LU54255A1 (de) 1969-06-16
CH1110067A4 (de) 1971-02-15
DE1604532A1 (de) 1972-03-23
GB1192397A (en) 1970-05-20
CH508753A (de) 1971-02-15
ES343819A1 (es) 1968-12-01
AT293595B (de) 1971-10-11
NL6710719A (de) 1968-02-12

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