US3443946A - Photographic material having a roughened protective layer - Google Patents

Photographic material having a roughened protective layer Download PDF

Info

Publication number: US3443946A
Authority: US; United States
Prior art keywords: protective layer; photographic material; photographic; layers; layer
Prior art date: 1964-06-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US455605A

Other languages

English (en)

Inventor

Herbert Grabhofer

Gunter Meinhardt

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Agfa Gevaert NV

Original Assignee

Agfa AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1964-06-04

Filing date

1965-05-13

Publication date

1969-05-13

1965-05-13 Application filed by Agfa AG filed Critical Agfa AG

1969-05-13 Application granted granted Critical

1969-05-13 Publication of US3443946A publication Critical patent/US3443946A/en

1986-05-13 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000011241 protective layer Substances 0.000 title description 14
239000000463 material Substances 0.000 title description 12
239000010410 layer Substances 0.000 description 20
239000004014 plasticizer Substances 0.000 description 11
125000004432 carbon atom Chemical group C* 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 7
238000005266 casting Methods 0.000 description 7
239000000839 emulsion Substances 0.000 description 7
239000010408 film Substances 0.000 description 7
239000000243 solution Substances 0.000 description 7
-1 alkali metal salts Chemical class 0.000 description 6
229920000159 gelatin Polymers 0.000 description 5
235000019322 gelatine Nutrition 0.000 description 5
239000000203 mixture Substances 0.000 description 5
239000002245 particle Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
239000001828 Gelatine Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
229910052709 silver Inorganic materials 0.000 description 4
239000004332 silver Substances 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
229920002239 polyacrylonitrile Polymers 0.000 description 3
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 2
BCGCCTGNWPKXJL-UHFFFAOYSA-N 3-(2-cyanoethoxy)propanenitrile Chemical compound N#CCCOCCC#N BCGCCTGNWPKXJL-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
239000004372 Polyvinyl alcohol Substances 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000005018 casein Substances 0.000 description 2
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
235000021240 caseins Nutrition 0.000 description 2
125000004966 cyanoalkyl group Chemical group 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
238000000034 method Methods 0.000 description 2
150000003014 phosphoric acid esters Chemical class 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920002689 polyvinyl acetate Polymers 0.000 description 2
239000011118 polyvinyl acetate Substances 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000011253 protective coating Substances 0.000 description 2
VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 description 1
HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
241001479434 Agfa Species 0.000 description 1
102000009027 Albumins Human genes 0.000 description 1
108010088751 Albumins Proteins 0.000 description 1
101000623895 Bos taurus Mucin-15 Proteins 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
229920000623 Cellulose acetate phthalate Polymers 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
241000124008 Mammalia Species 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical group CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
238000006359 acetalization reaction Methods 0.000 description 1
125000005396 acrylic acid ester group Chemical group 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
239000000783 alginic acid Substances 0.000 description 1
235000010443 alginic acid Nutrition 0.000 description 1
229920000615 alginic acid Polymers 0.000 description 1
229960001126 alginic acid Drugs 0.000 description 1
150000004781 alginic acids Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
229940081734 cellulose acetate phthalate Drugs 0.000 description 1
238000007600 charging Methods 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000007786 electrostatic charging Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
239000011521 glass Substances 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
125000001475 halogen functional group Chemical group 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
238000002156 mixing Methods 0.000 description 1
125000002560 nitrile group Chemical group 0.000 description 1
230000010494 opalescence Effects 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
229920003214 poly(methacrylonitrile) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
235000018102 proteins Nutrition 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
238000007788 roughening Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000010409 thin film Substances 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
229940117958 vinyl acetate Drugs 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/85—Photosensitive materials characterised by the base or auxiliary layers characterised by antistatic additives or coatings
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/95—Photosensitive materials characterised by the base or auxiliary layers rendered opaque or writable, e.g. with inert particulate additives
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/162—Protective or antiabrasion layer

Definitions

the invention relates to a photographic material having a transparent roughened protective layer.
photographic materials provided with such protective coatings can only be retouched and written on with difficulty.
Newtons rings are formed on printing or on projection.
Smooth surfaces also have a tendency to become elec trostatically charged, causing local blackening on the light-sensitive layer.
starch in finely divided form into light-sensitive photographic layers.
water-insoluble plastic particles of polystyrene, polyesters and similar synthetic materials of high molecular weight have been used for roughening the surface.
a transparent protective layer with a roughened surface of the composition as indicated below, applied as an outer layer to the front and/or back of a light-sensitive photographic material, has properties which satisfy all requirements.
the protective layer according to the invention contains the following components:
Film-forming binding agent Suitable for this'purpose are numerous polymers which must be pervious to water and are capable of forming thin films. It is preferred to use gelatin, but this can be wholly or partially replaced by other products, such as casein, albumin, polyvinyl alcohol, partially hydrolyzed polyvinyl acetate, preferably having at the last 10 mol percent vinylacetate units, polyamides, polyvinyl pyrrolidone, carboxymethyl cellulose, alginic acid and derivatives thereof, such as salts, particularly alkali metal salts, esters preferably with lower aliphatic alcohols having up to 5 carbon atoms, or amides, carraghenates and similar substances.
other products such as casein, albumin, polyvinyl alcohol, partially hydrolyzed polyvinyl acetate, preferably having at the last 10 mol percent vinylacetate units, polyamides, polyvinyl pyrrolidone, carboxymethyl cellulose, alginic acid and derivatives thereof, such as salts,
(II) Polymer containing nitrile groups This component is heterogeneously distributed in the protective layer, but cannot be detected optically in the final layer by simply looking therethrough, or can only be detected by a very weak opalescence.
the polymers contain acrylonitrile or methacrylonitrile units in polymerized form, advantageously in quantities of at least 50 mol percent.
Polyacrylonitrile or polymethacrylonitrile, more especially the former, are preferred.
Suitable as components forcopolymers are for example acrylic acid esters or methacrylic acid esters with an aliphatic alcohol having up to about 6 carbon atoms, vinyl acetate, alkylvinyl ethers, of which the alkyl group contains up to 4 carbon atoms, and also N-vinylpyrrolidone, N-vinylimidazole, vinyl pyridine, acrylamide or methacrylamide.
the grain size of the polymers to be used should be 1 to 25H, advantageously 1 to 5,u.
plasticizer prevents the optical detection of the particles of Component II. This effect is based on the fact that the smaller polymer particles, which would cause a clouding and matting, are completely solvated, but the larger particles are only softened on the surface.
plasticizers which are characterized by a content of fi-cyanethoxy-and/or ethylene oxide groups.
the following types of plasticizers exhibit particular utility:
Suitable products are described in US. Patent 2,401,607. The following are mentioned as example:
the protective layers can be applied onto silver halide 043%: CHz-0-CHr-C r-CN emulsion layer, filter layers, anti-halo layers, non-curling wherein R and R represent hydrogen, alkyl advanlayers and the liketageously containing up to 6 carbon atoms, aryl, advan There is no dependence on the composition and the tageously phenyl, or heterocyclic radicals, such as number of the layers 0f the material Coatedpyrimidine or morpholine.
the aqueous dispersions of the polymers are incorporated 35 of a 10% aqueous Solution of Plastieiler 7 and by stirring, together with the plasticizers, into the binder a 10% aqueous Solution 9 Plasticizfir f solution which can be provided with the usual casting mlxed 2 of aqPeous 10% polyacrYlomtnle additives.
the photographic P P Q addefi to 1 mm of a gelatme P film material is coated on the light-sensitive silver halide tlon- Thls mlxtura 15 cast on both sldes to the 811V emulsion layer and/or on the rear side by known casting 6D ha1 ide emulsion layers of P P P eY ThlS film can be satisfactorily wrltten on and is charmethods.
the mixing ratio between polymer Proportion and acterized by an excellent antistatic action, by complasticizer proportion depends on the required degree of Panson with a film mammal havmg a P gelatme P tective layer.
the protective layers should have a thickness of about measuring instrument according sehwen'khagen and 0.5 to 15 the electric surface resistivity in ohms is measured with The protective layers of the invention have no deleteria knife-edge instrument.
R and R are alkyl, cyanoalkyl or phenyl and each n is a number from 1 to 20.
plasticizer is a beta-cyanoethyl ether of a polyhydric alcohol having up to ten carbon atoms and two to four alcohol groups.
plasticizer is R2 OCH2 CH2OCH2CN in which R and R are hydrogen, alkyl containing up to six carbon atoms, or aryl.

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Laminated Bodies (AREA)

US455605A 1964-06-04 1965-05-13 Photographic material having a roughened protective layer Expired - Lifetime US3443946A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DEA46219A DE1202136B (de)	1964-06-04	1964-06-04	Photographisches Material mit einer aussen angeordneten, eine rauhe Oberflaeche besitzenden Schutzschicht

Publications (1)

Publication Number	Publication Date
US3443946A true US3443946A (en)	1969-05-13

Family

ID=6935153

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
US455605A Expired - Lifetime US3443946A (en)	1964-06-04	1965-05-13	Photographic material having a roughened protective layer

Country Status (6)

Country	Link
US (1)	US3443946A (de)
BE (1)	BE664869A (de)
CH (1)	CH454617A (de)
DE (1)	DE1202136B (de)
FR (1)	FR1435636A (de)
GB (1)	GB1106544A (de)

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3861911A (en) *	1972-09-28	1975-01-21	Xerox Corp	Image fixing method
DE2606793A1 (de) *	1975-02-19	1976-09-02	Fuji Photo Film Co Ltd	Lichtempfindliche druckplatten und verfahren zu deren herstellung
US4072528A (en) *	1972-09-27	1978-02-07	E. I. Du Pont De Nemours And Company	Oxygen barrier layers for photopolymerizable elements
US4072527A (en) *	1972-09-27	1978-02-07	E. I. Du Pont De Nemours And Company	Oxygen barrier layers for photopolymerizable elements
US4211560A (en) *	1977-07-12	1980-07-08	Asahi Kasei Kogyo Kabushiki Kaisha	Process for producing image using laminated oriented cover film
US4232111A (en) *	1973-09-17	1980-11-04	Fuji Photo Film Co., Ltd.	Photographic photosensitive element with protective layer and image forming method using same
US4319252A (en) *	1980-07-21	1982-03-09	Drexler Technology Corporation	Optical data storage and recording medium having a replaceable protective coverplate
US4340659A (en) *	1977-08-24	1982-07-20	Allied Paper Incorporated	Electrostatic masters
EP0790526A1 (de)	1996-02-19	1997-08-20	Agfa-Gevaert N.V.	System von Film und Schirm zur Herstellung radiographischen Bildes
US5853926A (en) *	1997-07-23	1998-12-29	Eastman Kodak Company	Pre-coated, fused plastic particles as a protective overcoat for color photographic prints
US5856051A (en) *	1997-07-23	1999-01-05	Eastman Kodak Company	Water-resistant protective overcoat for AgX photographic system
US5952130A (en) *	1998-08-19	1999-09-14	Eastman Kodak Company	Protective layer for gelatin based AGX photographic products
US5965304A (en) *	1997-11-06	1999-10-12	Eastman Kodak Company	Protecting layer for gelatin based AGX photographic products
US6077648A (en) *	1999-01-22	2000-06-20	Eastman Kodak Company	Protective overcoat for photographic elements
US6083676A (en) *	1999-04-26	2000-07-04	Eastman Kodak Company	Method for applying a protective overcoat to a photographic element using a fuser belt
US6171770B1 (en)	1999-11-24	2001-01-09	Jiann Chen	Method for applying a protective overcoat to a photographic element
US6197482B1 (en)	1999-05-14	2001-03-06	Eastman Kodak Company	Polymer overcoat for imaging elements
US6232049B1 (en)	1999-01-22	2001-05-15	Eastman Kodak Company	Protective overcoat for photographic elements
US6258517B1 (en)	2000-06-06	2001-07-10	Eastman Kodak Company	Imaged element with improved wet abrasion resistance
US6274298B1 (en)	2000-06-07	2001-08-14	Eastman Kodak Company	Protective overcoat comprising polyester ionomers for photographic elements
US6303184B1 (en)	1999-05-14	2001-10-16	Eastman Kodak Company	Method of forming a discontinuous polymer overcoat for imaging elements
US6465165B2 (en)	1999-05-14	2002-10-15	Eastman Kodak Company	Scratch resistant-water resistant overcoat for photographic systems
US6573011B1 (en)	2001-12-21	2003-06-03	Eastman Kodak Company	Label with curl and moisture resistant protective layer
US6723402B2 (en)	2001-12-21	2004-04-20	Eastman Kodak Company	Protective layer for hydrophilic packaging material
US20050031983A1 (en) *	2003-08-04	2005-02-10	Eastman Kodak Company	Imaging material with improved mechanical properties
US20050031982A1 (en) *	2003-08-04	2005-02-10	Eastman Kodak Company	Imaging material with improved scratch resistance
US20060147658A1 (en) *	2003-06-18	2006-07-06	Fuji Photo Film B.V.	Ink-jet recording medium
US20060222788A1 (en) *	2003-10-03	2006-10-05	Fuji Photo Film B.V.	Recording medium

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1534154A (en) *	1975-04-15	1978-11-29	Agfa Gevaert	Radiographic intensifying screens
DE2823914A1 (de) *	1978-05-04	1979-11-15	Eastman Kodak Co	Verwendung einer beschichtungsmasse zur beseitigung von kratzspuren auf photographischen materialien

Citations (10)

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US2401607A (en) *	1941-01-15	1946-06-04	Resinous Prod & Chemical Co	Cyanoalkyl ethers of polyhydric alcohols
GB752791A (en) *	1953-01-02	1956-07-18	Kodak Ltd	Improvements in finishing photographic reproductions
US3079257A (en) *	1957-08-30	1963-02-26	Agfa Ag	Photographic materials containing acrylonitrile copolymers as matting agents
GB922251A (en) *	1959-11-17	1963-03-27	Agfa Ag	Pentaerythritol phosphate esters and their use as plasticising agents
GB926689A (en) *	1959-11-17	1963-05-22	Agfa Ag	Cyanethoxy derivatives and their use as plasticisers
GB933391A (en) *	1959-03-18	1963-08-08	Agfa Ag	Protective coatings, in particular for photographic films
US3158643A (en) *	1961-05-05	1964-11-24	Gen Mills Inc	Cyanoethylated aminohydroxy amines
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1965
- 1965-05-13 US US455605A patent/US3443946A/en not_active Expired - Lifetime
- 1965-05-19 GB GB21243/65A patent/GB1106544A/en not_active Expired
- 1965-05-28 CH CH746265A patent/CH454617A/de unknown
- 1965-06-03 BE BE664869D patent/BE664869A/xx unknown
- 1965-06-04 FR FR19546A patent/FR1435636A/fr not_active Expired

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US4072528A (en) *	1972-09-27	1978-02-07	E. I. Du Pont De Nemours And Company	Oxygen barrier layers for photopolymerizable elements
US4072527A (en) *	1972-09-27	1978-02-07	E. I. Du Pont De Nemours And Company	Oxygen barrier layers for photopolymerizable elements
US3861911A (en) *	1972-09-28	1975-01-21	Xerox Corp	Image fixing method
US4232111A (en) *	1973-09-17	1980-11-04	Fuji Photo Film Co., Ltd.	Photographic photosensitive element with protective layer and image forming method using same
DE2606793A1 (de) *	1975-02-19	1976-09-02	Fuji Photo Film Co Ltd	Lichtempfindliche druckplatten und verfahren zu deren herstellung
US4211560A (en) *	1977-07-12	1980-07-08	Asahi Kasei Kogyo Kabushiki Kaisha	Process for producing image using laminated oriented cover film
US4340659A (en) *	1977-08-24	1982-07-20	Allied Paper Incorporated	Electrostatic masters
US4319252A (en) *	1980-07-21	1982-03-09	Drexler Technology Corporation	Optical data storage and recording medium having a replaceable protective coverplate
EP0790526A1 (de)	1996-02-19	1997-08-20	Agfa-Gevaert N.V.	System von Film und Schirm zur Herstellung radiographischen Bildes
US5853926A (en) *	1997-07-23	1998-12-29	Eastman Kodak Company	Pre-coated, fused plastic particles as a protective overcoat for color photographic prints
US5856051A (en) *	1997-07-23	1999-01-05	Eastman Kodak Company	Water-resistant protective overcoat for AgX photographic system
US5965304A (en) *	1997-11-06	1999-10-12	Eastman Kodak Company	Protecting layer for gelatin based AGX photographic products
US5952130A (en) *	1998-08-19	1999-09-14	Eastman Kodak Company	Protective layer for gelatin based AGX photographic products
US6077648A (en) *	1999-01-22	2000-06-20	Eastman Kodak Company	Protective overcoat for photographic elements
US6153363A (en) *	1999-01-22	2000-11-28	Eastman Kodak Company	Protective overcoat comprising interpenetrating network for photographic elements
US6232049B1 (en)	1999-01-22	2001-05-15	Eastman Kodak Company	Protective overcoat for photographic elements
US6083676A (en) *	1999-04-26	2000-07-04	Eastman Kodak Company	Method for applying a protective overcoat to a photographic element using a fuser belt
US6465165B2 (en)	1999-05-14	2002-10-15	Eastman Kodak Company	Scratch resistant-water resistant overcoat for photographic systems
US6197482B1 (en)	1999-05-14	2001-03-06	Eastman Kodak Company	Polymer overcoat for imaging elements
US6300045B2 (en)	1999-05-14	2001-10-09	Eastman Kodak Company	Polymer overcoat for imaging elements
US6303184B1 (en)	1999-05-14	2001-10-16	Eastman Kodak Company	Method of forming a discontinuous polymer overcoat for imaging elements
US6171770B1 (en)	1999-11-24	2001-01-09	Jiann Chen	Method for applying a protective overcoat to a photographic element
US6258517B1 (en)	2000-06-06	2001-07-10	Eastman Kodak Company	Imaged element with improved wet abrasion resistance
US6428948B2 (en)	2000-06-06	2002-08-06	Eastman Kodak Company	Imaged element with improved wet abrasion resistance
US6274298B1 (en)	2000-06-07	2001-08-14	Eastman Kodak Company	Protective overcoat comprising polyester ionomers for photographic elements
US6723402B2 (en)	2001-12-21	2004-04-20	Eastman Kodak Company	Protective layer for hydrophilic packaging material
US6573011B1 (en)	2001-12-21	2003-06-03	Eastman Kodak Company	Label with curl and moisture resistant protective layer
US20060147658A1 (en) *	2003-06-18	2006-07-06	Fuji Photo Film B.V.	Ink-jet recording medium
US20060159872A1 (en) *	2003-06-18	2006-07-20	Fuji Photo Film B.V.	Ink-jet recording medium
US20050031983A1 (en) *	2003-08-04	2005-02-10	Eastman Kodak Company	Imaging material with improved mechanical properties
US20050031982A1 (en) *	2003-08-04	2005-02-10	Eastman Kodak Company	Imaging material with improved scratch resistance
US6946240B2 (en)	2003-08-04	2005-09-20	Eastman Kodak Company	Imaging material with improved scratch resistance
US7074551B2 (en)	2003-08-04	2006-07-11	Eastman Kodak Company	Imaging material with improved mechanical properties
US20060222788A1 (en) *	2003-10-03	2006-10-05	Fuji Photo Film B.V.	Recording medium

Also Published As

Publication number	Publication date
GB1106544A (en)	1968-03-20
BE664869A (de)	1965-12-03
DE1202136B (de)	1965-09-30
FR1435636A (fr)	1966-04-15
CH454617A (de)	1968-04-15

Publication	Publication Date	Title
US3443946A (en)	1969-05-13	Photographic material having a roughened protective layer
EP0370404B1 (de)	1995-01-04	Photographische, lichtempfindliche Silberhalogenidmaterialien
EP0191302B1 (de)	1989-05-17	Verfahren zum Auftragen in zwei Schichten von Antistatikzusammensetzungen auf Polyestersubstraten
US4582781A (en)	1986-04-15	Antistatic compositions comprising polymerized oxyalkylene monomers and an inorganic tetrafluoroborate, perfluoroalkyl carboxylate, hexafluorophosphate or perfluoroalkylsulfonate salt
GB2043485A (en)	1980-10-08	Permanent antistatic layers
JPH04218537A (ja)	1992-08-10	帯電防止特性を有するシートまたはウエブ材料
GB1593332A (en)	1981-07-15	Antistatic articles
US4287299A (en)	1981-09-01	Process for the production of matting layers
US3552972A (en)	1971-01-05	Antistatic layer for photographic materials
US3791831A (en)	1974-02-12	Photographic materials with antistatic layers
US2976148A (en)	1961-03-21	Antistatic backing layers for photographic film
JPH0455492A (ja)	1992-02-24	帯電防止されたプラスチックフィルム
US3359102A (en)	1967-12-19	Optical brightening of photographic materials
EP0247648B1 (de)	1989-08-23	Eine antistatische Schicht tragendes Blatt oder Vlies
US3658573A (en)	1972-04-25	Support provided with antistatic layer
EP0127820B1 (de)	1989-08-02	Antistatischer photographischer Träger, Verfahren zur Herstellung und diesen enthaltendes photographisches Material
EP0300259B1 (de)	1992-01-29	Silberhalogenid enthaltende lichtempfindliche photographische Materialien
US4266015A (en)	1981-05-05	Light sensitive materials with fluorinated polymer antistats
EP0320692A2 (de)	1989-06-21	Antistatischer photographischer Träger und lichtempfindliches Element
US3255013A (en)	1966-06-07	Increasing the sensitivity of photographic emulsions
US2940854A (en)	1960-06-14	Gelatin silver halide emulsion plasticized with dicarboxylic acid esters
US3547642A (en)	1970-12-15	Photographic layers containing gelatin and methylol polyvinyl urethane
US3033680A (en)	1962-05-08	Plasticized gelating compositions
US3756828A (en)	1973-09-04	Es photographic light sensitive material having good antistatic properti
US3895950A (en)	1975-07-22	Photographic material with improved antistatic properties