US3457175A - Shampoos - Google Patents
Shampoos Download PDFInfo
- Publication number
- US3457175A US3457175A US515444A US3457175DA US3457175A US 3457175 A US3457175 A US 3457175A US 515444 A US515444 A US 515444A US 3457175D A US3457175D A US 3457175DA US 3457175 A US3457175 A US 3457175A
- Authority
- US
- United States
- Prior art keywords
- shampoo
- weight
- glycol
- solvent
- sebum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002453 shampoo Substances 0.000 title description 20
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- 239000003208 petroleum Substances 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
- 210000002374 sebum Anatomy 0.000 description 7
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- -1 alkyl sulphates Chemical class 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000012259 ether extract Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Definitions
- the specification discloses shampoo formulations containing a solvent combination having high solvency power for the grease of the hair.
- the solvent combinations disclosed are (1) mixtures of dipropylene glycol and the monomethyl ether of diethylene glycol and (2) mixtures of glycerine and polyethylene glycol.
- This invention relates to shampoos.
- a shampoo containing dipropylene glycol in combination with methyl digol (the monomethyl ether of diethylene glycol) or glycerine in combination with a polyethylene glycol containing dipropylene glycol in combination with methyl digol (the monomethyl ether of diethylene glycol) or glycerine in combination with a polyethylene glycol.
- the combined solvents may suitably constitute up to 5% by weight of the shampoo, preferably from 1 to 3%.
- the dipropylene glycol or the glycerine preferably constitutes from 20 to 80% by weight of the combined solvents.
- the molecular weight of the polyethylene glycol is not critical, similar results having been obtained with diand triethylene glycol as with the high molecular weight glycols.
- Conventional surface-active agents can be used in the shampoo, for example alkyl sulphates, alkyl benzene sulphonates, and alkyl ether sulphates.
- a synthetic sebum was first prepared; this had the fol lowing composition:
- the synthetic sebum was dissolved in petroleum ether 40-60 C.) to give a 5% solution. 10 mls. of this solutlon were pipetted into each of three ml. beakers and the solvent evaporated off on a steam bath to give 0.50 g. of sebum in each beaker. The beakers were then allowed to cool in a desiccator and then weighed to check that all the petroleum ether and moisture had been removed.
- the solidified sebum broke up under the treatment and become suspended in the form of small solid particles in the warm shampoo.
- the washed petroleum ether extract was then dried by filtering through a funnel containing anhydrous sodium sulphate into a tared flask and evaporating the petroleum ether on the steam bath.
- the residue in the flask was finally dried in an oven at 60 C. for one hour, cooled in a. desiccator, and then weighed. The sample was heated in the oven until a constant weight was obtained.
- the results are indicated in the following table.
- the shampoo base in each case was 16.5% monoethanolamine lauryl sulphate.
- a shampoo preparation for cleaning hair and dissolving hair grease cOnsisting essentially of an organic anionic surface active agent, water, and from about 1% to about 5% by weight of a solvent for the grease of the hair selected from the class consisting of (1) a mixture of from about 20% to about 80% by weight dipropylene glycol and the balance the monomethyl ether of diethyl ene glycol and (2) a mixture of from about 20% to about 80% by weight glycerine and the balance polyethylene glycol.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB312/65A GB1059741A (en) | 1965-01-04 | 1965-01-04 | Improvements relating to shampoos |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3457175A true US3457175A (en) | 1969-07-22 |
Family
ID=9702178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US515444A Expired - Lifetime US3457175A (en) | 1965-01-04 | 1965-12-21 | Shampoos |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3457175A (de) |
| AT (1) | AT275742B (de) |
| GB (1) | GB1059741A (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3819528A (en) * | 1968-12-23 | 1974-06-25 | Procter & Gamble | Stabilized aqueous enzyme compositions |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2978416A (en) * | 1955-07-14 | 1961-04-04 | Allied Chem | Concentrated aqueous detergent composition |
| GB911214A (en) * | 1960-10-28 | 1962-11-21 | Colgate Palmolive Co | Shampoos |
| US3085067A (en) * | 1960-02-10 | 1963-04-09 | Procter & Gamble | Sarcosinate shampoo |
| US3152046A (en) * | 1956-11-09 | 1964-10-06 | Kapral Ales Maria | Selenium disulfide dispersions |
-
1965
- 1965-01-04 GB GB312/65A patent/GB1059741A/en not_active Expired
- 1965-12-21 US US515444A patent/US3457175A/en not_active Expired - Lifetime
-
1966
- 1966-01-03 AT AT1066A patent/AT275742B/de active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2978416A (en) * | 1955-07-14 | 1961-04-04 | Allied Chem | Concentrated aqueous detergent composition |
| US3152046A (en) * | 1956-11-09 | 1964-10-06 | Kapral Ales Maria | Selenium disulfide dispersions |
| US3085067A (en) * | 1960-02-10 | 1963-04-09 | Procter & Gamble | Sarcosinate shampoo |
| GB911214A (en) * | 1960-10-28 | 1962-11-21 | Colgate Palmolive Co | Shampoos |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3819528A (en) * | 1968-12-23 | 1974-06-25 | Procter & Gamble | Stabilized aqueous enzyme compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| AT275742B (de) | 1969-11-10 |
| GB1059741A (en) | 1967-02-22 |
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