US3623850A - Composite chill cast iron rolling mill rolls having increased resistance to the spalling - Google Patents

Composite chill cast iron rolling mill rolls having increased resistance to the spalling Download PDF

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Publication number
US3623850A
US3623850A US810025A US3623850DA US3623850A US 3623850 A US3623850 A US 3623850A US 810025 A US810025 A US 810025A US 3623850D A US3623850D A US 3623850DA US 3623850 A US3623850 A US 3623850A
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US
United States
Prior art keywords
rolls
cast iron
chill
spalling
composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US810025A
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English (en)
Inventor
Paul J Horvath Jr
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Bethlehem Steel Corp
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Bethlehem Steel Corp
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Filing date
Publication date
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Publication of US3623850A publication Critical patent/US3623850A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2267/00Roll parameters
    • B21B2267/10Roughness of roll surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12951Fe-base component
    • Y10T428/12958Next to Fe-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12993Surface feature [e.g., rough, mirror]

Definitions

  • Composite chill cast iron rolls have found limited use as work rolls in severe applications, for example in the latter strands of cold rolling mills. While the rolls have good resistance to Wear and high hardness on the surface they are brittle and therefore susceptible to spalling and have insufiicient toughness to resist bruising when contacted by the stock being worked. The stock is marked causing it to be rejected and decreasing the product yield. The bruise is many times a focal point for the beginning of a spall. The rolls must be removed from the mill and the surface reground to below the bruised area, thereby decreasing the life expectancy of the rolls.
  • Cold rolling blackplate requires rolls which will take a highly polished surface finish and which have high surface hardness, good resistance to spelling, good resistance to bruising, suflicient strength to resist deflection stresses and which will not mark the sheet being processed.
  • Cold rolling sheet for exterior automotive body parts requires rolls which, in addition to the above mentioned qualities, have a surface which will take and retain a blast pattern having a finish of about 55 microinches to about 70 microinches. This finish is necessary to impart a finish of about 40 microinches to about 60 microinches on the surfaces of the sheet being rolled.
  • the above mentioned operations required the use of expensive forged steel rolls which required elaborate heat treatments to obtain the desired properties.
  • the rolls are susceptible to marking and spalling and have relatively short service life.
  • the rolls of this invention resist marking and bruising and, when required, clean up with less metal removal than the other old prior art rolls.
  • the composite chill cast iron working rolls of the invention contain about 3.20% to 3.40% carbon, about 0.55% to 0.65% manganese, about 1.45% to about 1.65% silicon, about 4.00% to about 4.40% nickel, about 0.90% to about 1.10% chromium, about 0.50% to about 0.70% molybdenum, about 0.03% to about 0.08% magnesium, not more than .07% phosphorus and not more than 0.02% sulfur and the remainder iron and incidental impurities.
  • Rolls having a composition within the above specified ranges have good resistance to wear, high surface hardness, improved resistance to bruising, increased resistance to spalling and suflicient strength to resist deflection stresses and will not mark the material being rolled.
  • a composite chill cast iron roll I mean a roll having a chill portion and a core, said chill portion having a composition as heretofore described and said core being a low alloy cast iron composition as is well known in the art.
  • Such a composition may contain about 3.40% to about 3.50% carbon, about 0.50% to about 0.60% manganese, about 1.25% to about 1.35% silicon, about 0.30% to about 0.50% chromium, about 0.75% to about 1.25% nickel, about 0.15% phosphorus, not more than 0.10% sulfur, the remainder iron and incidental impurities.
  • the composition of the rolls must be balanced to obtain the optimum mechanical properties.
  • the carbon content in the surface of the rolls must be suflicient to impart the hardness necessary for the surface to resist deformation when rolling cold sheet products.
  • the carbon content must be low enough to provide sufficient depth of the chill in the roll. Therefore, I use a carbon content of between about 3.20% to about 3.40%, but I prefer a carbon content of between about 3.25% and 3.35%.
  • the manganese must be sufficient to prevent mottling of the iron in heavy sections, that is, about 0.55% to about 0.65%. Nickel in the iron suppresses pearlite formation and favors formation of martensite and also aids in refining carbides.
  • the nickel should be from about 4.00% to about 4.40%, but I prefer to limit the the upper range of the nickel to 4.20%. Chromium within a range of about 0.90% to about 1.10% will be suflicie-nt to stabilize the carbides and to suppress graphite formation. However I prefer to use a range of 0.95% to about 1.05%. Molybdenum in the range of about 0.50% to about 0.70% will increase the resistance of the chill surface to spalling, however, I prefer to use a range of 0.55% to about 0.65%. While silicon aids in graphite formation, and increases the strength, the ductility and the bend test energy to fracture, too high a silicon will increase the amount of graphite formed and decrease the depth of chill.
  • microstructure may be obtained by subjecting the rolls to a stress-relief treatment. Two such treatments are listed below:
  • Rolls treated by the above methods were found to have a surface hardness of Rockwell C 57.0 to 59.0, an ultimate bend strength of about 86,000 to 90,000 p.s.i., a total deflection on bend test of about 0.040 to 0.045 inch and a bend to fracture strength of about 1.10 ft. lbs. to about 1.15 ft. lbs. and about 11.3% retained austenite in the microstructure.
  • the bend test used to determine the ultimate bend strength, total deflection and toughness (bend to fracture strength) is described in International Nickel Company, Inc., Technical Paper 541-CP dated Nov. 3, 1967, by F. K. Kies and R. D. Schelleng.
  • Rolls having a standard white cast iron composition and treated as above had a surface hardness of Rockwell C 54.0 to 56.5, an ultimate bend strength of 77,000 to 78,000 p.s.i., a total deflection on bend test of 0.037 to 0.040 inch and a bend to fracture strength of .92 to 1.03 ft. lbs., and 18% retained austenite in the microstructure of massive continuous carbide network, martensite, nodule graphite and eutectic austenite. It must be understood that where percent retained austenite is noted such percent is by volume.
  • the casting was cooled in the mold to about 300 F., shaken from the mold and cooled to ambient temperature.
  • the roll was placed in a furnace and heated to 850 F. held for 4 hours, cooled at 50 F./hour to 100 F., reheated to 500 F., held for 4 hours and cooled to ambient temperature.
  • Test specimens from the casting had a surface hardness of Rockwell C 58, an ultimate bend strength of 88,410 p.s.i., a total deflection on bend test of 0.042 inch and a bend to fracture strength of 1.15 ft. lbs.
  • the roll was mated with a standard white cast iron roll in the No. 5 stand of a 5 stand, 4 high, 48" cold mill rolling tinplate.
  • the pair of rolls rolled 5,252 tons of tinplate.
  • the standard roll was bruised four times and had to be redressed to prevent marking the sheet.
  • the roll of the invention was also redressed so as to mate with the standard roll although it had not shown evidence of bruising nor did it mark the sheet.
  • EXAMPLE 2 In another specific example of the invention, 2 composite tats-Q05? Chill cast iron work rolls 21 x 78" were 75 4 processed in a conventional manner. The chill and core were found to have the following chemical compositions:
  • the rolls were processed in the manner described in Example 1 above and were found to have a similar microstructure as the roll in Example 1.
  • the rolls were ground to a finish of 20 microinches and shot-blasted to a finish of 75 microinches.
  • the rolls were placed in a 78 inch 4 high temper mill and were used to process sheet for use in forming exterior automotive body parts.
  • the rolls processed 8 coils of sheet before redressing was required.
  • Rolls of the invention may be used as work rolls in the final stands of a tandem mill to cold roll blackplate and in a temper mill to cold roll sheet from which exterior automotive body parts are formed. Rolls of the invention when used in this application have processed as many as 9 coils of sheet before requiring redressing due to wear of the blast pattern, while standard forged rolls process about 3 to 4 coils before requiring dressing. The rolls of the invention may be redressed by removing less metal than rolls heretofore used in these applications and therefore have a longer life expectancy than prior art rolls.
  • a composite work roll for cold rolling sheet stock said roll having a low alloy cast iron core consisting of:
  • Carbon about 3.40% to about 3.50%
  • Manganese about 0.50% to about 0.60%
  • Phosphorus not more than about 0.15%
  • ulfur not more than about 0.10%
  • Silicon about 1.25% to about 1.35%
  • Nickel about 0.75 to about 1.25%
  • Chromium about 0.30% to about 0.50%
  • Carbon about 3.20% to about 3.40%
  • Manganese about 0.55% to about 0.65%
  • Phosphorus not more than 0.07%
  • Silicon about 1.45% to about 1.65% Nickel: about 4.00% to about 4.40% Chromium: about 0.90% to about 1.10% Molybdenum: about 0.50% to about 0.70% Magnesium: about 0.03 to about 0.08%
  • the microstructure in said chill area comprising finely divided, welldispersed nodules of graphite, finer than normal primary and eutectic martensite and martensite-austenite grains not more than 15% retained austenite, a secondary precipitation of carbides in areas of former austenitic grains, and a discontinuous carbide network and characterized by having an ultimate bend strength of about 86,000 psi. to about 90,000 p.s.i.
  • the composite work roll of claim 1 having a gritblasted surface of a roughness of between 55 microinches to about microinches.
  • a composite work roll for cold rolling sheet stock said roll having a low alloy cast iron core consisting of:
  • Carbon about 3.40% to about 3.50%
  • Manganese about 0.50% to about 0.60%
  • Phosphorus not more than about 0.15%
  • Sulfur not more than about 0.10%
  • Silicon about 1.25% to about 1.35%
  • Nickel about 0.75% to about 1.25%
  • Chromium about 0.30% to about 0.50%
  • the composite work roll of claim 3 having a gritface area consisting essentially of: blasted surface of a roughness of between 55 microinches Carbon: about 3.25% to about 3.35% to about 70 microinches' Manganese: about 0.55% to about 0.65%
  • Phosphorus not more than 0.07% 5 References Cited Sulfur: not more than 0.02% UNITED STATES PATENTS Silicon: about 1.50% about 1.60% 1,910,034 /1933 Mitchell et al 75128 X Nickel: about 4.00% to a o t 1,988,910 1/1935 Merica et a1.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Heat Treatment Of Articles (AREA)
US810025A 1969-03-24 1969-03-24 Composite chill cast iron rolling mill rolls having increased resistance to the spalling Expired - Lifetime US3623850A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81002569A 1969-03-24 1969-03-24

Publications (1)

Publication Number Publication Date
US3623850A true US3623850A (en) 1971-11-30

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Country Status (9)

Country Link
US (1) US3623850A (fr)
JP (1) JPS4837495B1 (fr)
AT (1) AT320568B (fr)
BE (1) BE747828A (fr)
CA (1) CA922938A (fr)
DE (1) DE2013728C3 (fr)
FR (1) FR2039871A5 (fr)
GB (1) GB1271185A (fr)
SE (1) SE349061B (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3894325A (en) * 1973-05-11 1975-07-15 Hitachi Metals Ltd Large-sized and thick compound sleeves of high hardness
US3997370A (en) * 1975-11-17 1976-12-14 Bethlehem Steel Corporation Method of hot reducing ferrous and ferrous alloy products with composite martensitic nodular cast chill iron rolls
US4484959A (en) * 1981-07-17 1984-11-27 Creusot-Loire Process for the production of a composite metal part and products thus obtained
US4783378A (en) * 1986-06-30 1988-11-08 Kawasaki Steel Corporation Steel sheets for drawing and ironing worked cans
US4795681A (en) * 1986-03-31 1989-01-03 Kawasaki Steel Corporation Steel sheets for painting and a method of producing the same
US4798772A (en) * 1986-01-17 1989-01-17 Kawasaki Steel Corporation Steel sheets for painting and a method of producing the same
US5334125A (en) * 1991-03-20 1994-08-02 Valmet Paper Machinery Inc. Martensite roll
US5611143A (en) * 1994-10-21 1997-03-18 Voith Sulzer Paper Technology North America, Inc. Process for making chilled iron rolls
CN108588546A (zh) * 2018-05-11 2018-09-28 铜陵市大明玛钢有限责任公司 一种铸铁轧辊制造工艺

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH574280A5 (fr) * 1973-10-17 1976-04-15 Alusuisse
FR2493191A1 (fr) * 1980-10-31 1982-05-07 Usinor Cydindre de laminage a froid fabrique par coulee et son procede de fabrication

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3894325A (en) * 1973-05-11 1975-07-15 Hitachi Metals Ltd Large-sized and thick compound sleeves of high hardness
US3997370A (en) * 1975-11-17 1976-12-14 Bethlehem Steel Corporation Method of hot reducing ferrous and ferrous alloy products with composite martensitic nodular cast chill iron rolls
FR2347116A1 (fr) * 1975-11-17 1977-11-04 Bethlehem Steel Corp Cylindre de faconnage composite en fer coule trempe
US4484959A (en) * 1981-07-17 1984-11-27 Creusot-Loire Process for the production of a composite metal part and products thus obtained
US4798772A (en) * 1986-01-17 1989-01-17 Kawasaki Steel Corporation Steel sheets for painting and a method of producing the same
US4795681A (en) * 1986-03-31 1989-01-03 Kawasaki Steel Corporation Steel sheets for painting and a method of producing the same
US4783378A (en) * 1986-06-30 1988-11-08 Kawasaki Steel Corporation Steel sheets for drawing and ironing worked cans
US5334125A (en) * 1991-03-20 1994-08-02 Valmet Paper Machinery Inc. Martensite roll
US5611143A (en) * 1994-10-21 1997-03-18 Voith Sulzer Paper Technology North America, Inc. Process for making chilled iron rolls
CN108588546A (zh) * 2018-05-11 2018-09-28 铜陵市大明玛钢有限责任公司 一种铸铁轧辊制造工艺

Also Published As

Publication number Publication date
SE349061B (fr) 1972-09-18
JPS4837495B1 (fr) 1973-11-12
GB1271185A (en) 1972-04-19
BE747828A (fr) 1970-09-23
AT320568B (de) 1975-02-25
CA922938A (en) 1973-03-20
DE2013728B2 (de) 1979-01-04
FR2039871A5 (fr) 1971-01-15
DE2013728C3 (de) 1979-08-30
DE2013728A1 (de) 1970-10-15

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