US3623850A - Composite chill cast iron rolling mill rolls having increased resistance to the spalling - Google Patents
Composite chill cast iron rolling mill rolls having increased resistance to the spalling Download PDFInfo
- Publication number
- US3623850A US3623850A US810025A US3623850DA US3623850A US 3623850 A US3623850 A US 3623850A US 810025 A US810025 A US 810025A US 3623850D A US3623850D A US 3623850DA US 3623850 A US3623850 A US 3623850A
- Authority
- US
- United States
- Prior art keywords
- rolls
- cast iron
- chill
- spalling
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001018 Cast iron Inorganic materials 0.000 title abstract description 16
- 239000002131 composite material Substances 0.000 title abstract description 15
- 238000004901 spalling Methods 0.000 title description 8
- 238000005096 rolling process Methods 0.000 title description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 23
- 229910052799 carbon Inorganic materials 0.000 abstract description 13
- 229910052742 iron Inorganic materials 0.000 abstract description 13
- 229910052759 nickel Inorganic materials 0.000 abstract description 13
- 229910052710 silicon Inorganic materials 0.000 abstract description 13
- 239000010703 silicon Substances 0.000 abstract description 13
- 239000011651 chromium Substances 0.000 abstract description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052804 chromium Inorganic materials 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 10
- 239000012535 impurity Substances 0.000 abstract description 10
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 10
- 239000011574 phosphorus Substances 0.000 abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 abstract description 10
- 239000011593 sulfur Substances 0.000 abstract description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 8
- 239000011777 magnesium Substances 0.000 abstract description 8
- 229910052749 magnesium Inorganic materials 0.000 abstract description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 6
- 239000011733 molybdenum Substances 0.000 abstract description 6
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- 239000000956 alloy Substances 0.000 abstract description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 229910002804 graphite Inorganic materials 0.000 description 10
- 239000010439 graphite Substances 0.000 description 10
- 229910001566 austenite Inorganic materials 0.000 description 9
- 208000034656 Contusions Diseases 0.000 description 6
- 229910000734 martensite Inorganic materials 0.000 description 6
- 230000000717 retained effect Effects 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005097 cold rolling Methods 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 150000001247 metal acetylides Chemical class 0.000 description 5
- 230000005496 eutectics Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 229910001037 White iron Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000005028 tinplate Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 241001164593 Merica Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000034526 bruise Diseases 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2267/00—Roll parameters
- B21B2267/10—Roughness of roll surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12951—Fe-base component
- Y10T428/12958—Next to Fe-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12993—Surface feature [e.g., rough, mirror]
Definitions
- Composite chill cast iron rolls have found limited use as work rolls in severe applications, for example in the latter strands of cold rolling mills. While the rolls have good resistance to Wear and high hardness on the surface they are brittle and therefore susceptible to spalling and have insufiicient toughness to resist bruising when contacted by the stock being worked. The stock is marked causing it to be rejected and decreasing the product yield. The bruise is many times a focal point for the beginning of a spall. The rolls must be removed from the mill and the surface reground to below the bruised area, thereby decreasing the life expectancy of the rolls.
- Cold rolling blackplate requires rolls which will take a highly polished surface finish and which have high surface hardness, good resistance to spelling, good resistance to bruising, suflicient strength to resist deflection stresses and which will not mark the sheet being processed.
- Cold rolling sheet for exterior automotive body parts requires rolls which, in addition to the above mentioned qualities, have a surface which will take and retain a blast pattern having a finish of about 55 microinches to about 70 microinches. This finish is necessary to impart a finish of about 40 microinches to about 60 microinches on the surfaces of the sheet being rolled.
- the above mentioned operations required the use of expensive forged steel rolls which required elaborate heat treatments to obtain the desired properties.
- the rolls are susceptible to marking and spalling and have relatively short service life.
- the rolls of this invention resist marking and bruising and, when required, clean up with less metal removal than the other old prior art rolls.
- the composite chill cast iron working rolls of the invention contain about 3.20% to 3.40% carbon, about 0.55% to 0.65% manganese, about 1.45% to about 1.65% silicon, about 4.00% to about 4.40% nickel, about 0.90% to about 1.10% chromium, about 0.50% to about 0.70% molybdenum, about 0.03% to about 0.08% magnesium, not more than .07% phosphorus and not more than 0.02% sulfur and the remainder iron and incidental impurities.
- Rolls having a composition within the above specified ranges have good resistance to wear, high surface hardness, improved resistance to bruising, increased resistance to spalling and suflicient strength to resist deflection stresses and will not mark the material being rolled.
- a composite chill cast iron roll I mean a roll having a chill portion and a core, said chill portion having a composition as heretofore described and said core being a low alloy cast iron composition as is well known in the art.
- Such a composition may contain about 3.40% to about 3.50% carbon, about 0.50% to about 0.60% manganese, about 1.25% to about 1.35% silicon, about 0.30% to about 0.50% chromium, about 0.75% to about 1.25% nickel, about 0.15% phosphorus, not more than 0.10% sulfur, the remainder iron and incidental impurities.
- the composition of the rolls must be balanced to obtain the optimum mechanical properties.
- the carbon content in the surface of the rolls must be suflicient to impart the hardness necessary for the surface to resist deformation when rolling cold sheet products.
- the carbon content must be low enough to provide sufficient depth of the chill in the roll. Therefore, I use a carbon content of between about 3.20% to about 3.40%, but I prefer a carbon content of between about 3.25% and 3.35%.
- the manganese must be sufficient to prevent mottling of the iron in heavy sections, that is, about 0.55% to about 0.65%. Nickel in the iron suppresses pearlite formation and favors formation of martensite and also aids in refining carbides.
- the nickel should be from about 4.00% to about 4.40%, but I prefer to limit the the upper range of the nickel to 4.20%. Chromium within a range of about 0.90% to about 1.10% will be suflicie-nt to stabilize the carbides and to suppress graphite formation. However I prefer to use a range of 0.95% to about 1.05%. Molybdenum in the range of about 0.50% to about 0.70% will increase the resistance of the chill surface to spalling, however, I prefer to use a range of 0.55% to about 0.65%. While silicon aids in graphite formation, and increases the strength, the ductility and the bend test energy to fracture, too high a silicon will increase the amount of graphite formed and decrease the depth of chill.
- microstructure may be obtained by subjecting the rolls to a stress-relief treatment. Two such treatments are listed below:
- Rolls treated by the above methods were found to have a surface hardness of Rockwell C 57.0 to 59.0, an ultimate bend strength of about 86,000 to 90,000 p.s.i., a total deflection on bend test of about 0.040 to 0.045 inch and a bend to fracture strength of about 1.10 ft. lbs. to about 1.15 ft. lbs. and about 11.3% retained austenite in the microstructure.
- the bend test used to determine the ultimate bend strength, total deflection and toughness (bend to fracture strength) is described in International Nickel Company, Inc., Technical Paper 541-CP dated Nov. 3, 1967, by F. K. Kies and R. D. Schelleng.
- Rolls having a standard white cast iron composition and treated as above had a surface hardness of Rockwell C 54.0 to 56.5, an ultimate bend strength of 77,000 to 78,000 p.s.i., a total deflection on bend test of 0.037 to 0.040 inch and a bend to fracture strength of .92 to 1.03 ft. lbs., and 18% retained austenite in the microstructure of massive continuous carbide network, martensite, nodule graphite and eutectic austenite. It must be understood that where percent retained austenite is noted such percent is by volume.
- the casting was cooled in the mold to about 300 F., shaken from the mold and cooled to ambient temperature.
- the roll was placed in a furnace and heated to 850 F. held for 4 hours, cooled at 50 F./hour to 100 F., reheated to 500 F., held for 4 hours and cooled to ambient temperature.
- Test specimens from the casting had a surface hardness of Rockwell C 58, an ultimate bend strength of 88,410 p.s.i., a total deflection on bend test of 0.042 inch and a bend to fracture strength of 1.15 ft. lbs.
- the roll was mated with a standard white cast iron roll in the No. 5 stand of a 5 stand, 4 high, 48" cold mill rolling tinplate.
- the pair of rolls rolled 5,252 tons of tinplate.
- the standard roll was bruised four times and had to be redressed to prevent marking the sheet.
- the roll of the invention was also redressed so as to mate with the standard roll although it had not shown evidence of bruising nor did it mark the sheet.
- EXAMPLE 2 In another specific example of the invention, 2 composite tats-Q05? Chill cast iron work rolls 21 x 78" were 75 4 processed in a conventional manner. The chill and core were found to have the following chemical compositions:
- the rolls were processed in the manner described in Example 1 above and were found to have a similar microstructure as the roll in Example 1.
- the rolls were ground to a finish of 20 microinches and shot-blasted to a finish of 75 microinches.
- the rolls were placed in a 78 inch 4 high temper mill and were used to process sheet for use in forming exterior automotive body parts.
- the rolls processed 8 coils of sheet before redressing was required.
- Rolls of the invention may be used as work rolls in the final stands of a tandem mill to cold roll blackplate and in a temper mill to cold roll sheet from which exterior automotive body parts are formed. Rolls of the invention when used in this application have processed as many as 9 coils of sheet before requiring redressing due to wear of the blast pattern, while standard forged rolls process about 3 to 4 coils before requiring dressing. The rolls of the invention may be redressed by removing less metal than rolls heretofore used in these applications and therefore have a longer life expectancy than prior art rolls.
- a composite work roll for cold rolling sheet stock said roll having a low alloy cast iron core consisting of:
- Carbon about 3.40% to about 3.50%
- Manganese about 0.50% to about 0.60%
- Phosphorus not more than about 0.15%
- ulfur not more than about 0.10%
- Silicon about 1.25% to about 1.35%
- Nickel about 0.75 to about 1.25%
- Chromium about 0.30% to about 0.50%
- Carbon about 3.20% to about 3.40%
- Manganese about 0.55% to about 0.65%
- Phosphorus not more than 0.07%
- Silicon about 1.45% to about 1.65% Nickel: about 4.00% to about 4.40% Chromium: about 0.90% to about 1.10% Molybdenum: about 0.50% to about 0.70% Magnesium: about 0.03 to about 0.08%
- the microstructure in said chill area comprising finely divided, welldispersed nodules of graphite, finer than normal primary and eutectic martensite and martensite-austenite grains not more than 15% retained austenite, a secondary precipitation of carbides in areas of former austenitic grains, and a discontinuous carbide network and characterized by having an ultimate bend strength of about 86,000 psi. to about 90,000 p.s.i.
- the composite work roll of claim 1 having a gritblasted surface of a roughness of between 55 microinches to about microinches.
- a composite work roll for cold rolling sheet stock said roll having a low alloy cast iron core consisting of:
- Carbon about 3.40% to about 3.50%
- Manganese about 0.50% to about 0.60%
- Phosphorus not more than about 0.15%
- Sulfur not more than about 0.10%
- Silicon about 1.25% to about 1.35%
- Nickel about 0.75% to about 1.25%
- Chromium about 0.30% to about 0.50%
- the composite work roll of claim 3 having a gritface area consisting essentially of: blasted surface of a roughness of between 55 microinches Carbon: about 3.25% to about 3.35% to about 70 microinches' Manganese: about 0.55% to about 0.65%
- Phosphorus not more than 0.07% 5 References Cited Sulfur: not more than 0.02% UNITED STATES PATENTS Silicon: about 1.50% about 1.60% 1,910,034 /1933 Mitchell et al 75128 X Nickel: about 4.00% to a o t 1,988,910 1/1935 Merica et a1.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
- Heat Treatment Of Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81002569A | 1969-03-24 | 1969-03-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3623850A true US3623850A (en) | 1971-11-30 |
Family
ID=25202780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US810025A Expired - Lifetime US3623850A (en) | 1969-03-24 | 1969-03-24 | Composite chill cast iron rolling mill rolls having increased resistance to the spalling |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3623850A (fr) |
| JP (1) | JPS4837495B1 (fr) |
| AT (1) | AT320568B (fr) |
| BE (1) | BE747828A (fr) |
| CA (1) | CA922938A (fr) |
| DE (1) | DE2013728C3 (fr) |
| FR (1) | FR2039871A5 (fr) |
| GB (1) | GB1271185A (fr) |
| SE (1) | SE349061B (fr) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3894325A (en) * | 1973-05-11 | 1975-07-15 | Hitachi Metals Ltd | Large-sized and thick compound sleeves of high hardness |
| US3997370A (en) * | 1975-11-17 | 1976-12-14 | Bethlehem Steel Corporation | Method of hot reducing ferrous and ferrous alloy products with composite martensitic nodular cast chill iron rolls |
| US4484959A (en) * | 1981-07-17 | 1984-11-27 | Creusot-Loire | Process for the production of a composite metal part and products thus obtained |
| US4783378A (en) * | 1986-06-30 | 1988-11-08 | Kawasaki Steel Corporation | Steel sheets for drawing and ironing worked cans |
| US4795681A (en) * | 1986-03-31 | 1989-01-03 | Kawasaki Steel Corporation | Steel sheets for painting and a method of producing the same |
| US4798772A (en) * | 1986-01-17 | 1989-01-17 | Kawasaki Steel Corporation | Steel sheets for painting and a method of producing the same |
| US5334125A (en) * | 1991-03-20 | 1994-08-02 | Valmet Paper Machinery Inc. | Martensite roll |
| US5611143A (en) * | 1994-10-21 | 1997-03-18 | Voith Sulzer Paper Technology North America, Inc. | Process for making chilled iron rolls |
| CN108588546A (zh) * | 2018-05-11 | 2018-09-28 | 铜陵市大明玛钢有限责任公司 | 一种铸铁轧辊制造工艺 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH574280A5 (fr) * | 1973-10-17 | 1976-04-15 | Alusuisse | |
| FR2493191A1 (fr) * | 1980-10-31 | 1982-05-07 | Usinor | Cydindre de laminage a froid fabrique par coulee et son procede de fabrication |
-
1969
- 1969-03-24 US US810025A patent/US3623850A/en not_active Expired - Lifetime
-
1970
- 1970-03-21 DE DE2013728A patent/DE2013728C3/de not_active Expired
- 1970-03-23 GB GB03893/70A patent/GB1271185A/en not_active Expired
- 1970-03-23 AT AT268870A patent/AT320568B/de not_active IP Right Cessation
- 1970-03-23 BE BE747828D patent/BE747828A/fr not_active IP Right Cessation
- 1970-03-23 CA CA078113A patent/CA922938A/en not_active Expired
- 1970-03-23 SE SE03885/70A patent/SE349061B/xx unknown
- 1970-03-23 FR FR7010375A patent/FR2039871A5/fr not_active Expired
- 1970-03-24 JP JP45024771A patent/JPS4837495B1/ja active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3894325A (en) * | 1973-05-11 | 1975-07-15 | Hitachi Metals Ltd | Large-sized and thick compound sleeves of high hardness |
| US3997370A (en) * | 1975-11-17 | 1976-12-14 | Bethlehem Steel Corporation | Method of hot reducing ferrous and ferrous alloy products with composite martensitic nodular cast chill iron rolls |
| FR2347116A1 (fr) * | 1975-11-17 | 1977-11-04 | Bethlehem Steel Corp | Cylindre de faconnage composite en fer coule trempe |
| US4484959A (en) * | 1981-07-17 | 1984-11-27 | Creusot-Loire | Process for the production of a composite metal part and products thus obtained |
| US4798772A (en) * | 1986-01-17 | 1989-01-17 | Kawasaki Steel Corporation | Steel sheets for painting and a method of producing the same |
| US4795681A (en) * | 1986-03-31 | 1989-01-03 | Kawasaki Steel Corporation | Steel sheets for painting and a method of producing the same |
| US4783378A (en) * | 1986-06-30 | 1988-11-08 | Kawasaki Steel Corporation | Steel sheets for drawing and ironing worked cans |
| US5334125A (en) * | 1991-03-20 | 1994-08-02 | Valmet Paper Machinery Inc. | Martensite roll |
| US5611143A (en) * | 1994-10-21 | 1997-03-18 | Voith Sulzer Paper Technology North America, Inc. | Process for making chilled iron rolls |
| CN108588546A (zh) * | 2018-05-11 | 2018-09-28 | 铜陵市大明玛钢有限责任公司 | 一种铸铁轧辊制造工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| SE349061B (fr) | 1972-09-18 |
| JPS4837495B1 (fr) | 1973-11-12 |
| GB1271185A (en) | 1972-04-19 |
| BE747828A (fr) | 1970-09-23 |
| AT320568B (de) | 1975-02-25 |
| CA922938A (en) | 1973-03-20 |
| DE2013728B2 (de) | 1979-01-04 |
| FR2039871A5 (fr) | 1971-01-15 |
| DE2013728C3 (de) | 1979-08-30 |
| DE2013728A1 (de) | 1970-10-15 |
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