Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, e.g. by ultrasonic waves, corona discharge, irradiation, electric currents or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
  • D06M10/02—Sonic or ultrasonic waves; Corona discharge
  • D06M10/025—Corona discharge or low temperature plasma
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
  • D06M2101/02—Natural fibres, other than mineral fibres
  • D06M2101/10—Animal fibres
  • D06M2101/12—Keratin fibres or silk
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
  • D06M2200/45—Shrinking resistance, anti-felting properties

Definitions

• the present invention relates to a process for antifelt finishing of animal fibres that are prone to felting, especially wool, by subjecting the fibres to a low temperature plasma treatment.
• German Offenlegungsschrift DE-41-17-332-A1 describes a process for the plasma treatment of moving textile webs wherein, inter alia, dried wool fabrics are subjected to a direct current discharge in air at about 80 to 90 Pa.
• German Offenlegungsschrift DE-43-39-427-A1 likewise describes a plasma treatment process for fabric webs, but it is additionally supplemented by a downstream ozone treatment. This process is used for cleaning and desizing a cloth so as to replace traditional liquid pretreatments of textile webs. Both processes concern the treatment of already woven or knitted fabrics or of other webs of material. The references do not concern the pretreatment of unspun fibres or raw wool.
• EP-0 548 013 A1 describes a process for dyeing wool level in the fibre and the piece by subjecting the dried wool to a low temperature plasma or corona discharge with a non-polymerizable gas and then dyeing it from an aqueous liquor free of levelling agent.
• the felting of wool is customarily reduced by finishing the wool with applied auxiliaries.
• plasma treatment processes are handicapped by the presence of water, present in most wools up to a maximum proportion of 33% by weight or even up to 40% by weight in the case of alkali treatment.
• the varying moisture content of the fibre is considered a disadvantage for these processes because the production throughput fluctuates as a result. For this reason, in the processes, the wool material is dried prior to the plasma treatment at the cost of additional complication and expense.
• This object is achieved according to the invention by a process for antifelt finishing of wool material composed of especially animal hairs by means of a low temperature plasma treatment, characterized in that moist wool material having a water content of 4 to 40% by weight is exposed, prior to further processing into textile fabrics or webs, to a high frequency discharge having a frequency of 1 kHz to 3 GHz and a discharge power density of 0.001 to 3 W/cm 3 at a pressure of 10 -2 to 10 mbar for a period of 1 to 600 sec in the presence or absence of non-polymerizing gases.
• the wool material used is raw wool following the raw wool scour, combed sliver or wool yam, preferably raw wool or combed sliver.
• the wool material used in the preferred process has a water content of 5 to 30% by weight, preferably 8 to 25% by weight.
• the plasma treatment is carried out in a preferred variant at a pressure of 10 -1 to 1 mbar and especially for a period of 2 to 5 minutes.
• the plasma treatment in a microwave discharge of 1 to 3 GHz is preferred.
• the plasma treatment is carried out in a particular embodiment in a pulsed high frequency discharge, the pulsing frequency being up to 10 kHz.
• non-polymerizing gases are additionally used as plasma process gases, they are introduced into the plasma treatment room at a flow rate of up to 200 l/h.
• Particulary suitable gases are oxygen, nitrogen, noble gases, especially argon, or air or mixtures thereof.
• the design and construction of a low temperature plasma reactor are known per se. Preference is given to using an electrodeless reactor having an outcoupling for microwaves.
• the wool material to be treated is preferably placed underneath the outcoupling unit.
• the distance of the wool material from the outcoupling unit preferably is 1-30 cm, especially 2-10 cm.
• the reactor is suitably evacuated with vacuum pumps in such a way that the pressure during the plasma treatment is between 10 -2 to 10 mbar, preferably at 10 -1 to 1 mbar.
• a continuous flow-through operation is enabled by applying in particular specific vacuum locks which make it possible for the material to enter and exit without leakage.
• the actual low temperature plasma is generated by feeding in electromagnetic radiation within the frequency range from 1 kHz to 3 GHz, preferably microwaves of the frequency 1-3 GHz. (The power density at the outcoupling is especially 0.1 to 15 W/cm 2 .)
• the electromagnetic radiation can be supplied to the recipient continuously or pulsed, in which case a pulsing frequency of up to 10 kHz is used.
• the particular effect of the plasma treatment of the invention might be explained as follows:
• the liquid present in the fibre desorbs off the fibre surface as water vapour/gas during the process.
• a glow discharge develops in the reactor through incoupling of the electromagnetic radiation.
• High energy electrons, ions and also highly excited neutral molecules or radicals are formed and act on the surface of the fibre, the water vapour being desorbed off the fibre causing particularly reactive particles to be formed in the immediate vicinity of the respective fibre surface and to act on the surface.
• Preference is given to using a treatment time of 1 to 600 s.
• a further reaction gas can be passed through the reactor as described, so that in this case a gas mixture results of added and fibre-desorbed gas/vapour.
• the advantages of the invention are that the antifelting effect obtained on the wool material by this process is significantly better than in the case of material which has been dried prior to the plasma treatment.
• the process saves energy, since there is no need for any predrying of the material, as required in the prior art before the plasma treatment.
• the plasma treatment of the invention affords a further improvement in the dyeing with regard to levelness, bath exhaustion and amount of dye used, which is higher than in the case of predried material. The process thus offers economic as well as ecological advantages.
• the process described can be used to produce an antifelting finish on all natural protein fibres (wool fibres) which tend to felt because of their surface structure.
• the invention described herein is especially useful for the antifelt finishing of wool fibres of any fineness.
• the properties of the wool material with regard to felting tendency and/or dyeability can, if desired, be additionally augmented after the plasma treatment by treating the wool material with resins and other antifelting finishes or dyeing auxiliaries.
• Wool combed sliver having a fineness of 21 ⁇ m is subjected to a low temperature plasma treatment.
• the treatment has for its purpose to reduce the felting tendency of the wool combed sliver.
• the treatment is carried out according to two variants:
• the plasma treatment is carried out under the following conditions, which are the same for the two variants:
• the power density per unit area was 0.78 W/cm 2 at the outcoupling unit.
• the power density per unit volume was 0.022 W/cm 3 .
• the felting behaviour was determined using the IWTO standard IWTO-20-69.
• the process carried out according to the invention (on material having a moisture content of 15% by weight) reduces the felting tendency by 63% compared with the same material without plasma treatment.
• the felting tendency is only 49% reduced compared with a material without plasma treatment.
• Wool combed sliver having a fineness of 21 ⁇ m is subjected to a low temperature plasma treatment.
• the treatment has for its purpose to reduce the felting tendency of the wool combed sliver.
• the plasma treatment is carried out following different residence times of the wool in a vacuum prior to the actual plasma treatment. This reduces the moisture content of the wool prior to the actual plasma treatment.
• the conditions of the plasma treatment are as follows:
• Variant 1 Low temperature plasma treatment of combed sliver: ignition of
• the power density per unit area was 0.87 W/cm 2 at the outcoupling unit.
• the power density per unit volume was 0.022 W/cm 3 .
• Variant 2 Low temperature plasma treatment of combed sliver: ignition of
• the power density per unit volume was 0.022 W/cm 3 .
• Variant 3 Low temperature plasma treatment of combed sliver: ignition of
• the power density per unit volume was 0.022 W/cm 3 .
• the felting behaviour is determined as under Example 1.
• Variant 1 reduces the felting tendency by 69% compared with the untreated material.
• Variant2 reduces the felting tendency by 65% and variant 3 by merely 56%.

Landscapes

• Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Plasma & Fusion (AREA)
• Textile Engineering (AREA)
• Chemical Or Physical Treatment Of Fibers (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Applications Claiming Priority (3)

Publications (1)

Family

ID=7792571

Family Applications (1)

Country Status (6)

Cited By (17)

Families Citing this family (3)

Citations (10)

Family Cites Families (1)

• 1996
  • 1996-04-26 DE DE19616776A patent/DE19616776C1/de not_active Expired - Fee Related
• 1997
  • 1997-04-14 AU AU26970/97A patent/AU727965B2/en not_active Ceased
  • 1997-04-14 WO PCT/EP1997/001859 patent/WO1997041293A1/de not_active Ceased
  • 1997-04-14 EP EP97920676A patent/EP0904443A1/de not_active Withdrawn
  • 1997-04-14 US US09/171,345 patent/US6103068A/en not_active Expired - Fee Related
  • 1997-04-14 JP JP9538500A patent/JP2000509111A/ja active Pending

Patent Citations (11)

Non-Patent Citations (9)

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