UST965005I4 - Nucleating agents, radiation-sensitive compositions and photographic elements - Google Patents
Nucleating agents, radiation-sensitive compositions and photographic elements Download PDFInfo
- Publication number
- UST965005I4 UST965005I4 US05/768,519 US76851977A UST965005I4 US T965005 I4 UST965005 I4 US T965005I4 US 76851977 A US76851977 A US 76851977A US T965005 I4 UST965005 I4 US T965005I4
- Authority
- US
- United States
- Prior art keywords
- alkyl
- nucleating agents
- hydrogen
- elements
- radiation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002667 nucleating agent Substances 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 2
- 230000005855 radiation Effects 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 abstract 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 abstract 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 abstract 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 101100386054 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) CYS3 gene Proteins 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- AEOCXXJPGCBFJA-UHFFFAOYSA-N ethionamide Chemical compound CCC1=CC(C(N)=S)=CC=N1 AEOCXXJPGCBFJA-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000003884 phenylalkyl group Chemical group 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 239000011669 selenium Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- -1 silver halide Chemical class 0.000 abstract 1
- 101150035983 str1 gene Proteins 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/08—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/485—Direct positive emulsions
- G03C1/48538—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure
- G03C1/48546—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure characterised by the nucleating/fogging agent
- G03C1/48561—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure characterised by the nucleating/fogging agent hydrazine compounds
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Plural Heterocyclic Compounds (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
heterocyclic N-(acylhydrazinophenyl)thioamide nucleating agents are disclosed as well as radiation-sensitive compositions and elements containing such nucleating agents in combination with silver halide grains capable of forming an internal latent image. The elements can be used to form direct-positive photographic images. Dye image transfer photographic elements are specifically contemplated.
A specifically preferred compound class comprised of a combination of preferred moieties can be indicated by the formula: ##STR1## wherein: A is ═N--R2, --S-- or --O--;
Q3 is represented by the formula ##STR2## X is ═S or ═O; T1 is ##STR3## or --H2 ; R3 is an alkyl substituent:
R4 is hydrogen, an alkyl, ##STR4## or an alkoxy substituent; Z represents the non-metallic atoms necessary to complete a basic 5- or 6-membered heterocyclic nucleus of the type found in cyanine dyes having ring-forming atoms chosen from the class consisting of carbon, nitrogen, oxygen, sulfur and selenium;
n and d are independently chosen from the integers 1 and 2;
R8 is hydrogen, phenyl, methyl, ethyl, propyl or butyl;
R9 is a meta- or para-phenylene group;
R2, r5 and R6 are independently chosen from hydrogen, phenyl, alkyl, alkylphenyl and phenylalkyl; and
The alkyl moieties in each instance include from 1 to 6 carbon atoms.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/700,981 US4080207A (en) | 1976-06-29 | 1976-06-29 | Radiation-sensitive compositions and photographic elements containing N-(acylhydrazinophenyl) thioamide nucleating agents |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/700,981 Division US4080207A (en) | 1976-06-29 | 1976-06-29 | Radiation-sensitive compositions and photographic elements containing N-(acylhydrazinophenyl) thioamide nucleating agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UST965005I4 true UST965005I4 (en) | 1977-12-06 |
Family
ID=24815603
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/700,981 Expired - Lifetime US4080207A (en) | 1976-06-29 | 1976-06-29 | Radiation-sensitive compositions and photographic elements containing N-(acylhydrazinophenyl) thioamide nucleating agents |
| US05/768,519 Pending UST965005I4 (en) | 1976-06-29 | 1977-02-14 | Nucleating agents, radiation-sensitive compositions and photographic elements |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/700,981 Expired - Lifetime US4080207A (en) | 1976-06-29 | 1976-06-29 | Radiation-sensitive compositions and photographic elements containing N-(acylhydrazinophenyl) thioamide nucleating agents |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US4080207A (en) |
| JP (1) | JPS533326A (en) |
| BE (1) | BE856284A (en) |
| CA (1) | CA1078848A (en) |
| DE (1) | DE2729147A1 (en) |
| FR (1) | FR2356972A1 (en) |
| GB (1) | GB1583471A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5897692A (en) * | 1996-09-10 | 1999-04-27 | Denso Corporation | Electroless plating solution |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5937492B2 (en) * | 1977-11-28 | 1984-09-10 | 富士写真フイルム株式会社 | Direct positive silver halide photosensitive material |
| JPS5930257B2 (en) * | 1978-04-06 | 1984-07-26 | 富士写真フイルム株式会社 | Direct positive silver halide photosensitive material |
| DE2842228C2 (en) * | 1978-09-28 | 1980-07-24 | Kober Ag | Joint cover for expansion joints in traffic routes, especially bridges |
| JPS5931691B2 (en) * | 1978-11-30 | 1984-08-03 | 富士写真フイルム株式会社 | Direct positive silver halide photosensitive material |
| US4278748A (en) * | 1979-07-25 | 1981-07-14 | Eastman Kodak Company | Absorbed hydrazide nucleating agents and photographic elements containing such agents |
| EP0050558B1 (en) * | 1980-10-16 | 1985-07-17 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Photographic emulsions and elements capable of forming direct-positive images |
| FR2497367B1 (en) * | 1980-10-16 | 1987-08-14 | Kodak Pathe | POSITIVE-DIRECT SILVER HALIDE EMULSION WITH INCORPORATED NUCLEATION AGENT |
| US4315986A (en) * | 1980-11-10 | 1982-02-16 | Eastman Kodak Company | Photographic emulsions and elements capable of forming direct-positive images |
| US4306017A (en) * | 1980-11-17 | 1981-12-15 | Eastman Kodak Company | Photographic emulsions and elements capable of forming direct-positive images |
| CA1170886A (en) * | 1981-09-02 | 1984-07-17 | Paul M. Magee | Nucleating composition for silver halide including triazole substituted and thiourea substituted phenyl hydrazides |
| US4504570A (en) * | 1982-09-30 | 1985-03-12 | Eastman Kodak Company | Direct reversal emulsions and photographic elements useful in image transfer film units |
| JPS59200230A (en) * | 1983-04-28 | 1984-11-13 | Fuji Photo Film Co Ltd | Direct positive silver halide photosensitive material |
| US4459347A (en) * | 1983-05-11 | 1984-07-10 | Eastman Kodak Company | Adsorbable arylhydrazides and applications thereof to silver halide photography |
| US4478928A (en) * | 1983-05-11 | 1984-10-23 | Eastman Kodak Company | Application of activated arylhydrazides to silver halide photography |
| US4560638A (en) * | 1984-10-09 | 1985-12-24 | Eastman Kodak Company | Halftone imaging silver halide emulsions, photographic elements, and processes which employ novel arylhydrazides |
| US4594273A (en) * | 1984-11-19 | 1986-06-10 | International Business Machines Corporation | High-rate electroless deposition process |
| JP2824717B2 (en) | 1992-07-10 | 1998-11-18 | 富士写真フイルム株式会社 | Processing method of silver halide photographic material |
| EP0589460B1 (en) | 1992-09-24 | 2000-08-09 | Fuji Photo Film Co., Ltd. | Method for processing a black & white silver halide light-sensitive material |
| JP2001264946A (en) * | 2000-03-17 | 2001-09-28 | Fuji Photo Film Co Ltd | Color diffusion transfer photosensitive material |
| JP4536781B2 (en) | 2005-10-07 | 2010-09-01 | 日鉱金属株式会社 | Electroless nickel plating solution |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE502879A (en) * | 1950-04-29 | |||
| US2588982A (en) * | 1950-10-26 | 1952-03-11 | Eastman Kodak Co | Direct positive photographs using hydrazine in the emulsion |
| BE603747A (en) * | 1960-05-13 | |||
| US3367780A (en) * | 1963-08-19 | 1968-02-06 | Eastman Kodak Co | Direct-print photographic silver halide emulsions |
| US3759901A (en) * | 1969-04-28 | 1973-09-18 | Eastman Kodak Co | Certain arylhydrazonalkyl quaternary salts |
| US3615615A (en) * | 1970-04-13 | 1971-10-26 | Eastman Kodak Co | Photographic emulsions including reactive quaternary salts |
| GB1335851A (en) | 1970-08-14 | 1973-10-31 | Agfa Gevaert | Spectral sensitization of direct-positive silver halide emulsions |
| US3719494A (en) * | 1970-10-30 | 1973-03-06 | Eastman Kodak Co | Silver halide emulsion containing a dihydroaromatic quaternary salt nucleating agent and the use thereof |
| US3734738A (en) * | 1970-10-30 | 1973-05-22 | Eastman Kodak Co | Silver halide emulsions containing reactive quaternary salts nucleating agents |
| US3718470A (en) * | 1971-02-12 | 1973-02-27 | Eastman Kodak Co | Surface development process utilizing an internal image silver halide emulsion containing a composite nucleating agent-spectral sensitizing polymethine dye |
| US3761276A (en) * | 1971-03-10 | 1973-09-25 | Eastman Kodak Co | Photographic element containing monodispersed unfogged silver halide grains chemically sensitized internally and externally |
| US3923513A (en) * | 1973-01-18 | 1975-12-02 | Eastman Kodak Co | Direct positive processing of silver halide with metal dopants in diffusion transfer films |
| DE2348737C2 (en) | 1973-09-28 | 1982-04-15 | Agfa-Gevaert Ag, 5090 Leverkusen | Photographic light-sensitive material having a supersensitized silver halide emulsion layer |
| FR2320290A1 (en) * | 1975-08-06 | 1977-03-04 | Eastman Kodak Co | NEW ACYLHYDRAZINOPHENYLTHIOUREES AND THEIR APPLICATIONS AS NUCLEATION AGENTS IN PHOTOGRAPHY |
-
1976
- 1976-06-29 US US05/700,981 patent/US4080207A/en not_active Expired - Lifetime
- 1976-09-17 CA CA261,420A patent/CA1078848A/en not_active Expired
-
1977
- 1977-02-14 US US05/768,519 patent/UST965005I4/en active Pending
- 1977-06-28 DE DE19772729147 patent/DE2729147A1/en not_active Withdrawn
- 1977-06-28 FR FR7719727A patent/FR2356972A1/en active Granted
- 1977-06-29 BE BE178923A patent/BE856284A/en not_active IP Right Cessation
- 1977-06-29 JP JP7665777A patent/JPS533326A/en active Pending
- 1977-06-29 GB GB27237/77A patent/GB1583471A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5897692A (en) * | 1996-09-10 | 1999-04-27 | Denso Corporation | Electroless plating solution |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2729147A1 (en) | 1978-01-05 |
| GB1583471A (en) | 1981-01-28 |
| FR2356972A1 (en) | 1978-01-27 |
| BE856284A (en) | 1977-12-29 |
| JPS533326A (en) | 1978-01-13 |
| CA1078848A (en) | 1980-06-03 |
| FR2356972B1 (en) | 1979-07-20 |
| US4080207A (en) | 1978-03-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| UST965005I4 (en) | Nucleating agents, radiation-sensitive compositions and photographic elements | |
| EP0187343A3 (en) | Image forming method including heating step | |
| SE7613824L (en) | WAY TO PREPARE QUARTER AMMONIUM ASSOCIATIONS | |
| ATE167741T1 (en) | SENSITIZERS FOR PHOTOTHERMOGRAPHIC ELEMENTS | |
| SE7610050L (en) | AMIDOXIM DERIVATIVE | |
| SE8006365L (en) | CYKLOHEXANKARBOXYLSYRADERIVAT | |
| GB1428606A (en) | Heat-developable photogrpahic material | |
| GR78961B (en) | ||
| ES8502091A1 (en) | Benzylcarbamoylpyridine derivatives. | |
| EP1308480A4 (en) | Cyanine dyes | |
| GB989383A (en) | Photographic developing compositions | |
| KR890008121A (en) | Rhodanine Derivatives and Pharmaceutical Compositions | |
| UST969006I4 (en) | Spectrally sensitized silver halide photographic emulsions | |
| JPS54121126A (en) | Dye image formation process for silver halide photographic material | |
| JPS55144236A (en) | Sensitizing method for silver halide photographic emulsion | |
| JPS55144237A (en) | Sensitizing method for photographic emulsion | |
| KR860008180A (en) | Method for preparing bicyclic pyrazolidinone | |
| ES8106323A1 (en) | Styryl dyestuffs, their preparation and their use in dyeing paper in particular. | |
| JPS55142331A (en) | Heat developable photosensitive material | |
| GB1469871A (en) | Spectrally sensitized silver halide photographic emulsions | |
| JPS643641A (en) | Silver halide photographic sensitive material having high sensitivity | |
| JPS56121036A (en) | Silver complex salt image receiving material for diffusion transfer | |
| PT70956A (en) | NEW PENICILLINES, THEIR SALTS METHOD FOR THE PRODUCTION THEREOF, AND THE MEDICAMENTS CONTAINING THESE COMPOUNDS | |
| GB1371106A (en) | Diazo copying material and methods | |
| JPS5533120A (en) | Silver halide photographic material for forming direct positive image |