UY32242A - Ácidos de 2-[(1-cianopropil)carbamoil]-5-metoximetil nicotínico y su uso para la fabricación de imidazolinonas herbicidas - Google Patents
Ácidos de 2-[(1-cianopropil)carbamoil]-5-metoximetil nicotínico y su uso para la fabricación de imidazolinonas herbicidasInfo
- Publication number
- UY32242A UY32242A UY32242A UY32242A UY32242A UY 32242 A UY32242 A UY 32242A UY 32242 A UY32242 A UY 32242A UY 32242 A UY32242 A UY 32242A UY 32242 A UY32242 A UY 32242A
- Authority
- UY
- Uruguay
- Prior art keywords
- hydrogen
- imidazolinones
- acids
- metoximethyl
- cianopropil
- Prior art date
Links
- 230000002363 herbicidal effect Effects 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- HLAHKMHLSYHRNO-UHFFFAOYSA-N 2-(1-cyanopropylcarbamoyl)-5-(methoxymethyl)pyridine-3-carboxylic acid Chemical class CCC(NC(=O)c1ncc(COC)cc1C(O)=O)C#N HLAHKMHLSYHRNO-UHFFFAOYSA-N 0.000 abstract 1
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical class O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001768 cations Chemical group 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Ácidos 2-[(1-cianopropil)carbamoil]-5-metoximetil nicotínicos de la fórmula (I) en donde Z es hidrógeno o halógeno; Z1 es hidrógeno, halógeno, ciano o nitro; R1 es C1-C4 alquilo; R2 es C1-C4 alquilo, C3-C6 cicloalquilo o R1 y R2, cuando se los toma junto con el átomo al cual están unidos, representan un grupo C3-C6 cicloalquilo opcionalmente sustituido con metilo y R3 es hidrogeno o un catión seleccionado preferentemente del grupo que consiste en metales alcalinos, metales alcalinotérreos, manganeso, cobre, hierro, zinc, cobalto, plomo, plata, níquel, amonio y amonio orgánico; son intermediarios útiles para la síntesis de imidazolinonas herbicidas.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11423008P | 2008-11-13 | 2008-11-13 | |
| US11422308P | 2008-11-13 | 2008-11-13 | |
| US12061308P | 2008-12-08 | 2008-12-08 | |
| US12095708P | 2008-12-09 | 2008-12-09 | |
| US14250609P | 2009-01-05 | 2009-01-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UY32242A true UY32242A (es) | 2010-05-31 |
Family
ID=41507836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UY32242A UY32242A (es) | 2008-11-13 | 2009-11-13 | Ácidos de 2-[(1-cianopropil)carbamoil]-5-metoximetil nicotínico y su uso para la fabricación de imidazolinonas herbicidas |
Country Status (4)
| Country | Link |
|---|---|
| AR (1) | AR074329A1 (es) |
| TW (1) | TW201021702A (es) |
| UY (1) | UY32242A (es) |
| WO (1) | WO2010055042A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2365965B1 (en) | 2008-11-13 | 2019-01-09 | Basf Se | Process for manufacturing substituted 3-pyridylmethyl ammonium bromides |
| CN102245577B (zh) | 2008-11-13 | 2014-03-26 | 巴斯夫欧洲公司 | 2-[(1-氰基丙基)氨基甲酰基]-5-氯甲基烟酸及其在制备除草咪唑啉酮中的用途 |
| CN102245578B (zh) | 2008-11-13 | 2015-01-07 | 巴斯夫欧洲公司 | 制备5-氯甲基-2,3-吡啶二甲酸酐的方法 |
| ES2670677T3 (es) | 2008-12-09 | 2018-05-31 | Basf Se | Procedimiento de fabricación de anhídrido 5-clorometil-2,3-dicarboxílico |
| CN105777623A (zh) * | 2016-02-29 | 2016-07-20 | 北京颖泰嘉和生物科技股份有限公司 | 一种吡啶侧链甲基季铵盐类化合物的制备方法 |
| CA3044164A1 (en) | 2016-11-21 | 2018-05-24 | Adama Agan Ltd. | Process for preparing methoxy methyl pyridine dicarboxylate |
| CN107216286B (zh) * | 2017-06-27 | 2020-03-31 | 江苏省农用激素工程技术研究中心有限公司 | 5-溴甲基-2,3-吡啶二甲酸二甲酯的制备方法 |
| RU2707043C1 (ru) * | 2019-03-25 | 2019-11-21 | Акционерное общество "Щелково Агрохим" | Способ получения гербицида имазамокса |
| CN113620928A (zh) * | 2021-08-16 | 2021-11-09 | 辽宁先达农业科学有限公司 | 一种甲氧咪草烟钠盐的合成方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4518780A (en) * | 1982-05-25 | 1985-05-21 | American Cyanamid Company | Process for the preparation of 2-(5,5-disubstituted-4-oxo-2-imidazolin-2-yl)nicotinic acids and quinoline-3-carboxylic acids |
| US4719303A (en) * | 1983-11-21 | 1988-01-12 | American Cyanamid Company | Preparation of substituted and unsubstituted 2-[(1-carbamoyl-1,2-dimethylpropyl)-carbamoyl]-3-quinolinecarboxylic, nicotinic and benzoic acids |
| US4709036A (en) * | 1985-06-13 | 1987-11-24 | American Cyanamid Company | Process for the preparation of herbicidal 2-(4,4-disubstituted-5-oxo-2-imidazolin-2-yl)benzoic, nicotinic and quinoline-3-carboxylic acids, esters and salts |
| US5334576A (en) * | 1986-07-28 | 1994-08-02 | American Cyanamid Company | 5 (and/or 6) substituted 2-(2-imidazolin-2-yl)nicotinic acids, esters and salts, useful as herbicidal agents and novel intermediates for the preparation of said nicotinic acids, esters and salts |
| EP0322616A3 (en) * | 1987-12-31 | 1989-10-18 | American Cyanamid Company | Novel 5(and/or 6)substituted 2-(2-imidazolin-2-yl)nicotinic acids, esters and salts, useful as herbicidal agents and nivel intermediates for the preparation of said nicotinic acids, esters and salts |
| US5973154A (en) * | 1999-05-03 | 1999-10-26 | American Cyanamid Company | Process for the preparation of chiral imidazolinone herbicides |
| US6339158B1 (en) * | 1999-05-03 | 2002-01-15 | American Cyanamid Co. | Process for the preparation of chiral nicotinic, quinolinic or benzoic acid imidazolinone herbicides |
-
2009
- 2009-11-11 WO PCT/EP2009/064950 patent/WO2010055042A1/en not_active Ceased
- 2009-11-13 TW TW98138670A patent/TW201021702A/zh unknown
- 2009-11-13 UY UY32242A patent/UY32242A/es unknown
- 2009-11-13 AR ARP090104387 patent/AR074329A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW201021702A (en) | 2010-06-16 |
| AR074329A1 (es) | 2011-01-05 |
| WO2010055042A1 (en) | 2010-05-20 |
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