WO1990014909A1 - Procede pour realiser un revetement sur un recipient metallurgique, composition et machine pour sa mise en ×uvre - Google Patents
Procede pour realiser un revetement sur un recipient metallurgique, composition et machine pour sa mise en ×uvre Download PDFInfo
- Publication number
- WO1990014909A1 WO1990014909A1 PCT/FR1990/000375 FR9000375W WO9014909A1 WO 1990014909 A1 WO1990014909 A1 WO 1990014909A1 FR 9000375 W FR9000375 W FR 9000375W WO 9014909 A1 WO9014909 A1 WO 9014909A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- container
- movable wall
- coating
- face
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/6303—Inorganic additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/02—Linings
- B22D41/023—Apparatus used for making or repairing linings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0087—Uses not provided for elsewhere in C04B2111/00 for metallurgical applications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00939—Uses not provided for elsewhere in C04B2111/00 for the fabrication of moulds or cores
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
- C04B2235/9676—Resistance against chemicals, e.g. against molten glass or molten salts against molten metals such as steel or aluminium
Definitions
- the present invention relates to a method for producing a coating on the interior faces of a metallurgical vessel, such as a tundish or ladle to protect their wall or their permanent refractory lining.
- the invention also relates to the composition used to produce the above-mentioned coating.
- the invention further relates to the machine for implementing the above method.
- the above protective coating is currently most often applied to the interior faces of a metallurgical vessel by spraying an aqueous slurry of a mixture of refractory materials, fibers and a binder. This process is entirely satisfactory. However, it has the drawback of providing a coating containing a lot of water on the interior faces of the container, which must then be removed by long and costly drying.
- a method which consists in pouring the composition of the coating into the space between the interior faces of a metallurgical container and a large mold placed in the latter.
- This mold includes preheating means and valves allowing the escape of air during the blowing of the composition into the aforementioned space.
- the object of the present invention is to remedy the drawbacks of the known methods.
- the method for producing a coating on the inner faces of a metallurgical container, intended to receive liquid metal comprises the following steps: a) positioning at a certain distance from the face inside said container at least one movable wall; b) a composition containing at least one refractory pulverulent material is introduced between the face of the container and the movable wall, and c) this pulverulent material is heated to agglomerate at least the surface which is to come into contact with the liquid steel; d) moving said movable wall and repeating the above steps so as to obtain a continuous coating on said faces of the container.
- this movable wall can be moved using means of low power therefore economical in energy.
- this movable wall makes it possible to precisely control the thickness of the coating, thus avoiding any excess thickness and any wastage of the initial composition.
- the pulverulent composition is introduced either manually between said face and movable wall, or using a device ensuring a constant supply between said face and wall as the advancement of the movable wall.
- the pulverulent material is heated by preheating at least one of said faces or movable wall around 190 ° C. to 500 ° C. for the practically dry compositions then up to 900 ° C if the composition contains water of crystallization or rehydration or if the decarbonation of certain refractories is necessary.
- said refractory pulverulent material is chosen from the following materials: silica, alumina, magnesia, chromium-magnesia, raw dolomite, cooked dolomite, calcite, lime, chromium oxide, silicate of zirconiu, silico-aluminous and their mixture.
- the composition may also contain a binder chosen from mineral, organic, hydraulic binders and their mixture.
- the machine for implementing the method according to the invention comprises at least one movable wall along an inner face of the container and forming with this face a space of substantially constant thickness, corresponding to that of the coating to be produced and means for introducing into said space, the pulverulent composition of the coating to be formed.
- said movable wall extends over substantially the entire height of the face of the container and its lateral edges are shaped so as to match the shape of the end faces of the container.
- Said movable wall preferably comprises sufficient heating means to form a hard crust on the surface of the pulverulent composition adjacent to this movable wall, even if the container is not itself heating.
- the heating means associated with the movable wall thus make it possible to heat the composition situated opposite this wall, until the formation of a surface crust sufficiently hardened or polymerized in order to ensure the cohesion of the coating, so that it is then possible to move the wall, to form just next to the coating portion already formed another coating portion which continuously extends the previous one.
- FIG. 1 is a view in longitudinal section of a flow distributor in which is placed a machine for applying a protective coating according to the invention
- FIG. 2 is a sectional view on an enlarged scale along the plane II-II of FIG. 1,
- the method for producing a coating on the internal lateral faces 2 of a metallurgical container 1, intended to receive liquid metal comprises the following steps: a) positioning at a certain distance from the internal face 2 of said container a movable wall 3, b) between composition 2 of the container 1 and the movable wall 3, a composition 4 containing at least one refractory pulverulent material is introduced, and c) this pulverulent material is heated to agglomerate at least the surface to come into contact with
- the pulverulent composition 4 is introduced either manually between said face and movable wall 3, or using a device ensuring a constant supply between said face and wall as the moving wall 3 advances.
- the pulverulent material 4 is heated by preheating at least one of said face 2 or movable wall 3 at around 190 ° C to 500 ° C for practically dry compositions then up to 900 ° C if the composition contains water of crystallization or rehydration or if the decarbonation of certain refractories is necessary or still around 1300 ° C if you want to flow into a hot container.
- the refractory pulverulent material 4 is chosen from the following materials: silica, alumina, magnesia, chromium-magnesia, raw dolomite, cooked dolomite, calcite, lime, chromium oxide, zirconium silicate, silico-aluminous and their mixture.
- composition 4 additionally contains a binder chosen from mineral, organic and hydraulic binders and their mixture, the refractory pulverulent material being able to be calibrated in a very large particle size class and to be pre-coated using at least one binder.
- the pulverulent material may have the following weight composition:
- - refractory pulverulent material 60 to 100% - binder (cement and / or silicate and / or resin: 0 to 20%
- the composition may contain: 20 to 0.5%, preferably 4% of binder (phenolic resin and / or silicate and / or cement)
- lightening products for example wood flour and / or paper particles
- refractory grains for example silica.
- the composition has a density of approximately 1.10 to 1.40.
- composition can also be as follows: 0 to 20% of binder, preferably 4% 0 to 20% of lightening products, for example wood flour and / or paper particles preferably 1%
- lubricant for example stereate
- boric acid preferably 1% 100 to 50% of magnesia and / or silica and / or alumina and / or dolomite and / or lime and / or lime and / or calcite and / or sulfate and / or phosphate and / or zircon preferably 93.5%, the composition in this case having a density between 1.6 and 2.2 approximately.
- the machine according to the invention comprises at least one wall 3 movable along an inner face 2 of the container 1 and forming with this face a space 5 (see FIG. 2) of substantially constant thickness, corresponding to that of the coating producing and means for introducing into said space 5 the pulverulent composition 4 of the coating to be formed.
- the wall 3 carries at its lower end a roller 6 which bears on the bottom 7 of the container 1 so that this end of the wall 3 practically touches this bottom 7.
- the upper end of the movable wall 3 carries two yokes 8 inside which are mounted in rotation of the rollers 9 bearing on the upper edge .10 of the container.
- a hopper 11 containing the pulverulent material 4.
- This hopper 11 carries at its lower part a conduit 12 which opens above the space 5 comprised between the face 2 of the container and the movable wall 3.
- This hopper 11 can move at the same time as the movable plate 3 between the two end faces 13 of the container 1.
- the movable wall 3 extends over substantially the entire height of the side face 2 of the container 1 and its lateral edges 3a, 3b (see Figure 1) are shaped to match the shape of the end faces 13 of the container. Thus when the edge 3a, 3b comes into contact with an end face 13, this edge produces a substantially tight seal with this face 13.
- the edge 3b of the wall 3 carries a rim 3c (see FIG. 3) which substantially closes the space 5 comprised between the wall 3 and the face 2, which prevents any leakage of pulverulent material from this edge 3b.
- the movable wall 3 includes heating means (not shown) sufficient to form by chemical bond (for example silicate) and / or by hydraulic bond (for example cement) and / or by ceramic bond (for example sintering) and / or by polymerization (for example resin) of the pulverulent material a hard crust 14 (see FIG. 2) on the surface of the pulverulent composition 4 adjacent to this movable wall 3, even if the container is not itself heating, or preheated.
- chemical bond for example silicate
- hydraulic bond for example cement
- ceramic bond for example sintering
- polymerization for example resin
- These heating means can be constituted by electrical resistances or by a gas-heated device carried by the movable wall 3.
- a preheater capable of uniformly preheating the said container to a temperature of at least 110 ° C. at the core so as to solidify the composition 4 intended to form the coating, even if the movable wall 3 is not heating.
- the movable wall 3 is preferably paired with a wall which can be moved on the opposite side of the container in the same direction or in the opposite direction, so as to be able to produce a protective coating at the same time on the two longitudinal faces 2.
- the movement of the movable wall 3 (or of the two walls) can be controlled by means of a robot.
- the machine further comprises and preferably a device for spreading and / or packing the composition 4 which should give rise to the coating located on the bottom 7 of the container.
- the device for spreading and / or packing (for example a tire) the composition 4 on the bottom 7 of the container 1 comprises heating means making it possible to solidify said composition, in particular when the container 1 is cold.
- This composition can also be spread manually on the bottom of the container.
- a complementary mineral binder in the analysis of said coating (silicate for example). If one wishes, in particular for certain qualities of steel, to flow into a hot container, the risk mentioned above arises for the entire coating, in this case it must be preheated to around:
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP90908955A EP0426834B1 (fr) | 1989-05-31 | 1990-05-30 | Procede pour realiser un revetement sur un recipient metallurgique, composition et machine pour sa mise en oeuvre |
| DE69011041T DE69011041T2 (de) | 1989-05-31 | 1990-05-30 | Verfahren zur herstellung einer beschichtung auf einem metallurgischen gefäss sowie zusammensetzung und maschine zu deren herstellung. |
| RO146849A RO110794B1 (ro) | 1989-05-31 | 1990-05-30 | Procedeu de realizare a unei captusiri la un vas metalurgic, compozitie si masina pentru utilizarea sa |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR89/07150 | 1989-05-31 | ||
| FR8907150A FR2647779B1 (fr) | 1989-05-31 | 1989-05-31 | Procede pour realiser un revetement sur un recipient metallurgique, composition et machine pour sa mise en oeuvre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1990014909A1 true WO1990014909A1 (fr) | 1990-12-13 |
Family
ID=9382202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FR1990/000375 Ceased WO1990014909A1 (fr) | 1989-05-31 | 1990-05-30 | Procede pour realiser un revetement sur un recipient metallurgique, composition et machine pour sa mise en ×uvre |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5176873A (fr) |
| EP (1) | EP0426834B1 (fr) |
| AT (1) | ATE109048T1 (fr) |
| AU (1) | AU5747390A (fr) |
| CA (1) | CA2033201A1 (fr) |
| CS (1) | CS263190A3 (fr) |
| DE (1) | DE69011041T2 (fr) |
| FR (1) | FR2647779B1 (fr) |
| RO (1) | RO110794B1 (fr) |
| WO (1) | WO1990014909A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2695582A1 (fr) * | 1992-09-11 | 1994-03-18 | Lorraine Laminage | Dispositif de coulée du béton dans un réacteur métallurgique. |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2732915B1 (fr) * | 1995-04-14 | 1997-06-13 | Daussan & Co | Procede pour appliquer a l'interieur d'un recipient metallurgique un revetement de protection comportant au moins deux couches |
| US7092520B2 (en) * | 1996-02-28 | 2006-08-15 | Nokia Corporation | Radiotelephone |
| FR2749200B1 (fr) * | 1996-05-29 | 1998-07-31 | Daussan & Co | Procede pour realiser un revetement comportant au moins deux couches sur les faces interieures d'un recipient tel qu'un recipient metallurgique et revetement ainsi obtenu |
| CH699405B1 (de) * | 2008-08-26 | 2021-06-15 | Mokesys Ag | Feuerfeste Wand, insbesondere für einen Verbrennungsofen. |
| JP5754295B2 (ja) * | 2011-08-17 | 2015-07-29 | 品川リフラクトリーズ株式会社 | ドライコーティング材 |
| CN107999732B (zh) * | 2017-11-07 | 2019-10-18 | 河钢股份有限公司承德分公司 | 超低碳涂抹料中间包的修砌方法 |
| CN110280750A (zh) * | 2019-08-02 | 2019-09-27 | 武汉精鼎科技股份有限公司 | 钢水罐罐壁工作层局部的修补方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1483584A1 (de) * | 1965-08-27 | 1969-10-30 | Juenkerather Maschb Gmbh | Verfahren und Vorrichtung zum Einbringen (Slingern) der feuerfesten Auskleidung von metallurgischen Gefaessen,insbesondere von Giess- und Transportpfannen |
| DE1927816A1 (de) * | 1969-05-31 | 1970-12-03 | Plibrico Co Gmbh | Verfahren und Vorrichtung zum Ausbessern profilierter Wand- oder Deckenteile von Industrieoefen |
| FR2220163A5 (fr) * | 1973-03-02 | 1974-09-27 | Garreau Jean | |
| US3876354A (en) * | 1973-09-12 | 1975-04-08 | Shin Nippon Koki Co Ltd | Apparatus for automatically lining containers |
| GB1426135A (en) * | 1974-03-19 | 1976-02-25 | Novolipetsky Metall Z | Lining metallurgical vessels |
| US4589633A (en) * | 1984-01-26 | 1986-05-20 | Jacques Gilson | Process and installation for moulding a refractory lining of a container for liquid metal |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4218050A (en) * | 1974-11-22 | 1980-08-19 | Spribag Aktiengesellschaft | Apparatus and methods for automatically lining containers, especially casting ladles |
| US4117052A (en) * | 1975-03-19 | 1978-09-26 | Dorentruper Sand- Und Thonwerker G.M.B.H. | Method and arrangement for use in lining articles, particularly melting oven |
| SU1258608A2 (ru) * | 1985-05-22 | 1986-09-23 | Всесоюзный Проектно-Технологический Институт Литейного Производства | Машина дл футеровки металлургических ковшей |
-
1989
- 1989-05-31 FR FR8907150A patent/FR2647779B1/fr not_active Expired - Lifetime
-
1990
- 1990-05-29 CS CS902631A patent/CS263190A3/cs unknown
- 1990-05-30 DE DE69011041T patent/DE69011041T2/de not_active Expired - Fee Related
- 1990-05-30 US US07/635,546 patent/US5176873A/en not_active Expired - Fee Related
- 1990-05-30 RO RO146849A patent/RO110794B1/ro unknown
- 1990-05-30 AT AT90908955T patent/ATE109048T1/de not_active IP Right Cessation
- 1990-05-30 EP EP90908955A patent/EP0426834B1/fr not_active Expired - Lifetime
- 1990-05-30 WO PCT/FR1990/000375 patent/WO1990014909A1/fr not_active Ceased
- 1990-05-30 AU AU57473/90A patent/AU5747390A/en not_active Abandoned
- 1990-05-30 CA CA002033201A patent/CA2033201A1/fr not_active Abandoned
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1483584A1 (de) * | 1965-08-27 | 1969-10-30 | Juenkerather Maschb Gmbh | Verfahren und Vorrichtung zum Einbringen (Slingern) der feuerfesten Auskleidung von metallurgischen Gefaessen,insbesondere von Giess- und Transportpfannen |
| DE1927816A1 (de) * | 1969-05-31 | 1970-12-03 | Plibrico Co Gmbh | Verfahren und Vorrichtung zum Ausbessern profilierter Wand- oder Deckenteile von Industrieoefen |
| FR2220163A5 (fr) * | 1973-03-02 | 1974-09-27 | Garreau Jean | |
| US3876354A (en) * | 1973-09-12 | 1975-04-08 | Shin Nippon Koki Co Ltd | Apparatus for automatically lining containers |
| GB1426135A (en) * | 1974-03-19 | 1976-02-25 | Novolipetsky Metall Z | Lining metallurgical vessels |
| US4589633A (en) * | 1984-01-26 | 1986-05-20 | Jacques Gilson | Process and installation for moulding a refractory lining of a container for liquid metal |
Non-Patent Citations (1)
| Title |
|---|
| Soviet Inventions Illustrated, Semaine 8720, 27 Mai 1987, Section C, Classe M, Resume No. 8-141375/20, Derwent Publications Ltd, (Londres, GB), & SU, A, 1258608 (Casting MFR. ENG. DES) 23 Septembre 1986 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2695582A1 (fr) * | 1992-09-11 | 1994-03-18 | Lorraine Laminage | Dispositif de coulée du béton dans un réacteur métallurgique. |
Also Published As
| Publication number | Publication date |
|---|---|
| AU5747390A (en) | 1991-01-07 |
| EP0426834A1 (fr) | 1991-05-15 |
| CS263190A3 (en) | 1992-03-18 |
| DE69011041D1 (de) | 1994-09-01 |
| FR2647779B1 (fr) | 1993-06-25 |
| RO110794B1 (ro) | 1996-04-30 |
| DE69011041T2 (de) | 1995-03-30 |
| US5176873A (en) | 1993-01-05 |
| EP0426834B1 (fr) | 1994-07-27 |
| FR2647779A1 (fr) | 1990-12-07 |
| CA2033201A1 (fr) | 1990-12-01 |
| ATE109048T1 (de) | 1994-08-15 |
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