WO1999067332A2 - Composes de polychlorure de vinyle chlores avec d'excellentes caracteristiques de combustion - Google Patents

Composes de polychlorure de vinyle chlores avec d'excellentes caracteristiques de combustion Download PDF

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WO1999067332A2
WO1999067332A2 PCT/US1999/022881 US9922881W WO9967332A2 WO 1999067332 A2 WO1999067332 A2 WO 1999067332A2 US 9922881 W US9922881 W US 9922881W WO 9967332 A2 WO9967332 A2 WO 9967332A2
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parts
weight
compound according
compound
polyvinyl chloride
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WO1999067332A3 (fr
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Girish T. Dalal
Andrew M. Olah
Theodore J. Schmitz
Donald R. Townley
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Goodrich Corp
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BF Goodrich Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/16—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C08L23/286—Chlorinated polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

Definitions

  • This invention relates to unique thermoplastic compounds having less than 40 weight percent inorganic content and exceptional combustion characteristics.
  • the invention relates to chlorinated polyvinyl chloride compounds having a low inorganic content which at a minimum meet Factory Mutual Test Standard Class Number 4910 requirements.
  • the invention relates to an article made from this unique compound.
  • thermoplastic materials Due to the use of thermoplastic materials in various environments, the combustion characteristics of these materials are very important. In one particular environment, clean rooms used in the semiconductor industry, these characteristics are of utmost importance so that if combustion of the thermoplastic material did occur, it would not severely damage the equipment or the contents of the clean room. These characteristics are important in other environments also since the thermoplastic material may possibly spread and propagate the fire, and generate smoke as the combustion occurs. Additionally, the thermoplastic material may emit corrosive materials subject to decomposition by combustion.
  • Factory Mutual Test Standard Class Number 4910 sets forth the flammability test protocol. The test according to the standard is performed in a 50 kW Peak Heat Release Rate Apparatus according to the conditions set forth in the standard. These standard specifications are especially useful for semiconductor clean room materials. It is believed that these standard specifications could be applicable to building codes or any other codes regulating combustible materials. This test standard is incorporated herein in its entirety. This test standard sets forth criteria used in the evaluation of the fire propagation behavior of a material, the possibility for smoke contamination caused by the material as well as the possibility of contamination due to corrosive by products of the combustion of the material.
  • the Factory Mutual Test Standard Class Number 4910 uses three indices to characterize the materials evaluated. The indices are Fire Propagation Ratio ("FPI”), the Smoke Damage Index (“SDI”) as well as the Corrosion Damage Index (“CDI”).
  • FPI Fire Propagation Ratio
  • SDI Smoke Damage Index
  • CDI Corrosion Damage Index
  • FPI indicates the propensity of the material to support fire propagation. It is defined as the ratio of the heat flux from the flame of the burning material to the material's response to the heat flux. The flame heat flux is estimated based upon the heat release rate.
  • the limit for the FPI in the Factory Mutual Test Standard Class Number 4910 is ⁇ 6 (m/s 1 2 )/ (kW/m) 2/ .
  • the SDI is used to determines the smoke contamination of the environment during the propagation of a fire.
  • the SDI is determined by multiplying the smoke yield by the FPI.
  • the smoke yield is defined in the standard as the ratio of the total mass of smoke released to the total mass of the material vaporized.
  • the limit for the SDI in the Factory Mutual Test Standard is ⁇ 0.40 (m/s 1 2 )/ (kW/m) 2 3 .
  • the CDI is an indicator of the amount of corrosive products released by the combustion of the thermoplastic material.
  • the value for the CDI is obtained by multiplying the average corrosion index by the fire propagation index.
  • the average corrosion index is based upon a specific corrosion constant determined using a Rohrback-Cosasco (RC) 2500 A modified corrosion probe as described in the Factory
  • the Mutual Test Standard Class Number 4910 multiplied by the yield of corrosive products of combustion.
  • the average corrosion index is the average corrosion rate per unit of concentration of the material vapors.
  • the limit for the CDI in the Factory Mutual Test Standard 4910 is ⁇ 1.1 [ (m/s I/2 )/ (kW/m) 2/3 ][(A/min)/(g/m 3 )].
  • the present invention comprises novel CPVC compounds meeting at a minimum the requirements of the Factory Mutual Test Standard Class No. 4910, while maintaining suitable processability, physical properties such as tensile strength, impact resistance and heat distortion, and low inorganic content.
  • a unique CPVC compound comprises CPVC resin, impact modifiers, tin stabilizer, as well as an acid scavenger.
  • the impact modifiers are chlorinated polyethylene, and an acrylic impact modifier and a methacrylate-butadiene-styrene ("MBS”) impact modifier.
  • the unique CPVC compound comprises CPVC resin, PVC resin, impact modifiers and a tin stabilizer.
  • Another aspect of the invention is an article made from the novel CPVC compounds which has a excellent combustion characteristics.
  • Chlorinated polyvinyl chloride is known to have excellent high temperature performance characteristics, among other desirable physical properties. Typically, CPVC has an excess of 57% bound chlorine. CPVC is conveniently made by the chlorination of a polymer of vinyl chloride (PVC). Vinyl chloride polymers include both homopolymers and copolymers of vinyl chloride, having a chlorine content of up to 56.7%. The vinyl chloride polymers used in the post chlorination process are obtained by either mass, suspension or emulsion polymerization techniques.
  • CPVC is obtained by chlorinating homopolymers or copolymers containing less than fifty percent (50%) by weight of one or more copolymerizable comonomers.
  • suitable comonomers include acrylic and methacrylic acids; esters of acrylic and methacrylic acid wherein the ester portion has from 1 to 12 carbons; hydroxyalkyl esters of acrylic and methacrylic acid (for example hydroxymethyl methacrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate and the like); glycidyl ester of acrylic and methacrylic acid (for example glycidyl acrylate, glycidyl methacrylate and the like); alpha,beta-unsaturated dicarboxylic acids and their anhydrides (for example maleic acid, fumaric acid, itaconic acid and the like); acrylamide and methacrylamide; acrylonitrile and mefhacrylon
  • any post chlorination processes can be used to form CPVC polymer having more than fifty-seven percent (57%) by weight chlorine based upon the total weight of the polymer.
  • the CPVC polymer has a chlorine content in the range of about sixty percent (60%) to about seventy four percent (74%) by weight based upon the total weight of the polymer.
  • the post chlorination processes which can be used include any commercial process or the like such as solution process, fluidized bed process, water slurry process, thermal process or liquid chlorine process or two step process which comprises post chlorinating the vinyl chloride polymer in the presence of a peroxy catalyst during both steps. In as much as the post chlorination processes are known to the art as well as the literature, they will not be discussed in detail here.
  • PVC is the aqueous suspension process disclosed in U.S. Patent No. 4,412,898.
  • blends of various CPVC resins can also be used.
  • the CPVC resin can be blended with another CPVC resin in an amount of other resin of about 1% to about 50%.
  • These blends of CPVC can be used so long as the requirements of the Factory Mutual Test Standard Number 4910 are still met and the compound containing the blend has an inorganic content of less than 40 weight percent.
  • the CPVC used in the invention desirably will have a fused density in the range of approximately 138 to 156 grams /cubic centimeter at 25° Centigrade, an inherent viscosity (IN.) in the range of about 0.52 to about 1.0 and a chlorine content of at least sixty percent (60%).
  • the preferred fused density of the CPVC is in the range of about 146 to about 156 grams/cubic centimeter.
  • the preferred inherent viscosity is in the range of about 0.68 to about 0.92.
  • the preferred chlorine content of the CPVC is about 63 % to about 68 %.
  • the most preferred chlorine content is 67%, with a 0.68 IN. and a fused density of 1.53 grams/cubic centimeter.
  • suitable CPVC to use in forming the compound of the instant invention include TempRite 677x 670 CPVC, and
  • TempRite 674x571 CPVC all available from The B.F. Goodrich Company.
  • TempRite is a registered trademark of The B.F. Goodrich Company.
  • the most preferred CPVC resin is TempRite 677x670 CPVC.
  • the CPVC is formed into a compound with chlorinated polyethylene, acrylic impact modifier, a MBS impact modifier, a tin stabilizer and an acid scavenger.
  • the chlorinated polyethylene (CPE) used in the compound of the first embodiment is a rubbery material resulting from the chlorination of polyethylene having a substantially linear structure.
  • the polyethylene can be chlorinated by various methods including aqueous suspension, solution or gas phase methods.
  • An example of a method for preparing CPE can be found in U.S. Patent No. 3,563,974.
  • the aqueous suspension method is used to form the CPE.
  • the CPE material contains from 5 to 50% by weight of chlorine.
  • the CPE contains from 25 to 45 % by weight of chlorine.
  • CPE is commercially available from The Dow Chemical Company.
  • the preferred CPE materials to be used in the compound include Tyrin 361 IP, Tyrin 2000 and Tyrin 3615P; all available from the Dow Chemical Company. Tyrin is a trademark of the Dow Chemical Company. The most preferred CPE material is Tyrin 361 IP, from the Dow Chemical Company. Additionally, the CPE can comprise a mixture of chlorinated polyethylenes, provided that the overall mixture has a chlorine content in the range of about 25 to 45% by weight chlorine.
  • the CPE is added to CPVC of the compound of the instant invention in the range of from about 1 to 10 parts per hundred parts of CPVC resin. Preferably, the amount of CPE added to the compound is 2.5 to 7.0 parts per 100 parts of the CPVC resin.
  • the amount of CPE added to the compound is 2.0 parts per 100 parts of the CPVC resin.
  • the first embodiment of the instant invention also includes a acrylic impact modifiers.
  • U.S. Patent No. 3,678,133 describes the compositions conventionally referred to as acrylic impact modifiers.
  • the acrylic impact modifier is a composite interpolymer comprising a multi-phase acrylic base material comprising a first elastomeric phase polymerized from a monomer mix comprising at least 50 wt.% alkyl methacrylate having 1-4 carbon atoms in the alkyl group and having a molecular weight of from 50,000 to 600,000.
  • Acrylic impact modifiers are polyacrylates including (C 4 - C I2 ) acrylate homo or copolymers, second stage graft copolymerized with methyl methacrylate and styrene, poly(ethylhexyl acrylate-co-butyl-acrylate) graft copolymerized with styrene, and/or acrylonitrile and/or methyl methacrylate; polybutyl acrylate graft polymerized with acrylonitrile and styrene.
  • acrylic impact modifiers examples include Paraloid EXL-2330, KM 330, KM 334, and KM 365; all of which are available from Rohm and Haas. Paraloid is a trademark of the Rohm & Haas Company. Other commercially available acrylic impact modifiers include Blendex 975,
  • the acrylic impact modifiers are added to CPVC of the compound of the instant invention in the range of from about 1 to 10 parts per hundred parts of CPVC resin.
  • the amount of acrylic impact modifier added to the compound is 1.0 to 5.0 parts per 100 parts of the CPVC resin.
  • the acrylic impact modifier is added in 2.0 parts per 100 parts of CPVC resin.
  • MBS impact modifiers are graft polymers.
  • MBS impact modifiers are prepared by polymerizing methyl methacrylate or mixtures of methyl methacrylate with other monomers in the presence of polybutadiene or polybutadiene- styrene rubbers. Further information on MBS impact modifiers can be found in the Second Edition of the Encyclopedia of PVC, edited by Leonard I. Nass, Marcel Dekker, Inc. (N.Y. 1988, pp.448-452).
  • the amount of MBS impact modifier added to the CPVC of the compound of the instant invention is in the range of 1.0 to 10.0 parts per
  • MBS impact modifiers include Paraloid KM 680, available from Rohm & Haas, Kane Ace B-22 impact modifier and Kane Ace B-56 impact modifier available from Kaneka.
  • the most preferred MBS impact modifier is Paraloid KM 680. If used in the composition of the first embodiment. 5 parts of the MBS impact modifier are added.
  • the tin stabilizer used in the present invention can be any stabilizer containing tin. Suitable stabilizers include tin salts of monocarboxylic acids such as stannous maleate. Additionally, organo-tin stabilizers such as dialkyl tin mercaptides, carboxylates, and thiazoles can be used.
  • organo-tin stabilizers include without limitation: dibutyltin dilaurate, dibutyltin maleate, di(n-octyl) tin maleate, dibutyl tin bis(2-ethylhexyl mercaptoacetate), dibutyltin bis(lauryl mercaptide), dibutyltin, S,S-bis(isooctyl thioglycoate), dibutyltin ⁇ -mercaptoproprionate, di-n-octyltin S,S-bis(isooctyl thioglycolate), and di-n-octyltin ⁇ -mercaptoproprionate.
  • tin stabilizer per 100 parts of CPVC resin
  • the composition uses between 2 and 4 parts by weight of dibutyl tin bis(2-ethylhexyl mercaptoacetate) per 100 parts of the CPVC resin.
  • Examples of a commercially available tin stabilizer are Mark 292-S stabilizer from
  • an acid scavenger is added to the composition.
  • the acid scavenger is any generated reactive ingredient which can react with any acid formed by the decomposition of the novel CPVC compound of the instant invention.
  • suitable acid scavengers include metal salts such as carbonates. More specifically, an example of a suitable metal salt includes calcium carbonate. An example of a commercially available calcium carbonate is Ultraflex H, available from Specialty Chemical.
  • the acid scavenger is used in the amount of 0.5 to 10 parts per 100 parts of CPVC resin. Most preferably, 0.5 parts of the acid scavenger are used in the compound of the instant invention.
  • the acid scavenger can be used to improve the combustion characteristics of any halohydrocarbon polymers.
  • polymers which could be compounded with the acid scavenger include polyvinyl chloride, chlorinated olefms such as chlorinated polyethylene, halogenated styrenics, and so forth. It is believed that the acid scavenger would react with the halogen released upon the decomposition of the halohydrocarbon polymer. It is believed that the addition of the acid scavenger to such a polymer would reduce the amount of smoke and corrosive materials generated during combustion and thus improve the combustion characteristics of the halogenated polymer.
  • a novel CPVC compound is obtained by the mixture of a CPVC, a PVC, tin stabilizer and a acrylic impact modifier and a MBS impact modifier.
  • the CPVC, tin stabilizer and the acrylic impact modifier and the MBS impact modifier were described above in conjunction with the first embodiment of the invention.
  • 50 parts of PVC per 50 parts of CPVC are added to the compound.
  • the PVC used in the blend has an inherent viscosity in the range of 0.52 to 1.0; a fused density of about 1.35 grams/cubic centimeter and a chlorine content of about 56.7%.
  • the PVC polymers can be homopolymers or copolymers of polyvinylchloride.
  • Copolymers of PVC are formed predominately with PVC and other copolymers such as for example vinyl acetate. Generally, the secondary monomer is present in the range of five percent.
  • PVC copolymers can be found in Volume 1 of Encyclopedia of PVC, edited by Leonard I. Nass, Marcel Dekker, Inc. (N.Y. 1976. Chap.4).
  • suitable PVC polymers include Geon 1 lOx 440 PVC from the Geon Company. In the most preferred embodiment, 20 parts of the PVC are added for every 80 parts of CPVC in the compound. Additionally, 10 parts of the MBS impact modifier are included in the composition. Additives can also be added to the unique CPVC compounds as needed.
  • additives known in the art as well any other additives may be used, provided that the additive does not alter the combustion characteristics and the processability associated with the novel compounds.
  • additives which can be used include antioxidants, lubricants, stabilizers, other impact modifiers, pigments, glass transition enhancing additives, processing aids, fusion aids, fillers, fibrous reinforcing agents and antistatic agents.
  • Exemplary lubricants are polyglycerols of di- and trioleates, polyolefins such as polyethylene, polypropylene and oxidized polyolefins such as oxidized polyethylene and high molecular weight paraffin waxes. Since several lubricants can be combined in countless variations, the total amount of lubricant can vary from application to application. Optimization of the particular lubricant composition is not within the scope of the present invention and can be determined easily by one of ordinary skill in the art.
  • an oxidized polyethylene is used.
  • An example of an oxidized polyethylene is AC 629A, sold by Allied Signal.
  • a paraffin wax is also included in the compounds of the instant invention.
  • paraffin wax is Paraffin 160F Prill from Witco.
  • Lubricants can be used in the amount of about 0.01 to about 5 parts by weight of lubricant per 100 parts of the CPVC resin. Preferably from about 0.4 to about 2.0 parts by weight of lubricant per 100 parts of CPVC resin are used. In the most preferred embodiment, 1.25 parts by weight of polyethylene and 1.25 parts of paraffin wax are used per 100 parts of CPVC resin.
  • Co-stabilizers may be included, if desired, but are not necessary. However, if a solid co-stabilizer is added, the particle size of the co-stabilizer must be small enough so as not to affect the impact properties of the unique compound.
  • co- stabilizers include metal salts of phosphoric acid, polyols, epoxidized oils, and acid acceptors which are not detrimental to the base CPVC resin used. The stabilizers can be used by themselves or in any combination as desired.
  • metal salts of phosphoric acid include water-soluble, alkali metal phosphate salts, disodium hydrogen phosphate, orthophosphates such as mono-,di-, and tri- orthophosphates of said alkali metals, alkali metal polyphosphates, -tetrapolyphosphates and -metaphosphates and the like.
  • Polyols such as sugar alcohols, and epoxides such as epoxidized soya oil can be used.
  • acid acceptors include potassium citrate, aluminum magnesium hydroxy carbonate hydrate, magnesium aluminum silicates and alkali metal alumino silicates.
  • An example of commercially available aluminum magnesium hydroxy carbonate hydrate is Hysafe 510, available from the J.M.
  • magnesium aluminum silicates are molecular sieves, whereas examples of alkali metal alumino silicates are zeolites.
  • the most preferred co-stabilizer, if used at all, is disodium hydrogen phosphate (DSP) and is used by treating the CPVC resin itself, after the resin has been chlorinated. Typical levels of co-stabilizers can range from about 0.1 weight parts to about 7.0 weight parts per 100 weight parts of the CPVC resin, if used at all. DSP is commercially available from The Monsanto Company.
  • Suitable processing aids include acrylic polymers such as methyl acrylate copolymers.
  • process aids include Paraloid K 120ND. K-120N, K-175; all available from Rohm & Haas. A description of other types of processing aids which can be used in the compound can be found in The Plastics and Rubber Institute: International Conference on PVC Processing, April 26-28 (1983), Paper No. 17.
  • no processing aid is necessary, but if used, the processing aid should be used in the amount of 0.5 to about 2.0 by weight of processing aid per 100 parts of the CPVC Resin.
  • antioxidants to be used in the compound examples include Irganox 1010 (tetrakis[methylene(3,5-di-tert-butyl-4-hydoxy-hydrocinnamate)]methane) sold by Irganox 1010 (tetrakis[methylene(3,5-di-tert-butyl-4-hydoxy-hydrocinnamate)]methane) sold by Irganox 1010 (tetrakis[methylene(3,5-di-tert-butyl-4-hydoxy-hydrocinnamate)]methane) sold by Irganox 1010 (tetrakis[methylene(3,5-di-tert-butyl-4-hydoxy-hydrocinnamate)]methane) sold by Irganox 1010 (tetrakis[methylene(3,5-di-tert-butyl-4-hydoxy-hydrocinnamate)]
  • the antioxidant is used in the amount of about 0.1 to about 1.0 parts by weight per 100 parts of the CPVC resin, if used at all.
  • Suitable pigments include among others titanium dioxide, and carbon black. If included, the pigments are used generally in the amount of about 0.5 to about 12.0 parts by weight per 100 parts of the CPVC resin.
  • the preferred titanium dioxide is
  • the preferred carbon black is Raven 410 , available from Columbian Chemicals.
  • Suitable inorganic fillers include talc, clay, mica, wollastonite, silicas, and other filling agents. If used in the novel compound having exceptional combustion characteristics, the amount of filler used is less than 40 weight percent. More preferably, the amount of the filler is in the range of about 0.1 to about 12 parts by weight of filler per 100 parts of the CPVC resin.
  • the components of the unique CPVC compound can be made in any manner wherein the various components are added together and mixed under heat.
  • the appropriate amount of the CPVC resin can be added to a vessel such as Henschel mixer or a ribbon blender. The remaining ingredients of the compound can then be added thereto and mixed. If pellets are to be formed, the compound can be melt mixed. Melt mixing can generally occur in the temperature range of about 150 to about 250° C. Once the blend is formed, it can be processed further depending upon the desired application in any conventional manner, using extrusion or molding techniques. If extrusion techniques are used to process the composition of the present invention, generally conventional extrusion machinery such as a multi-screw extruder or a single screw extruder are used.
  • An extruder generally has conveying means, an intermediate screw processing means and a final die through which the material is discharged in the form of an extrudate.
  • a multi-screw extruder is used for the extrusion of pipe.
  • Examples of possible conventional extruders to be used to process the CPVC compound of the instant invention include the following twin screw counterrotating extruder models from Cincinnati Milacron: CM 35HP, CM 55HP, CM 65HP, CM 80HP, CM 92HP.
  • suitable conical twin screw extruders from Krauss Maffei include KMD-2/ 40KK and KMD-2/50KK.
  • the CPVC compound can be formed into any article desired. These articles will have excellent combustion characteristics and will meet Factory Mutual Test Standard Class Number 4910. Examples include but are not limited to sheet, pipe, ducts, fittings, valves, injection molded and thermoformed industrial parts, appliance housing, fabricated parts, and different containers.
  • the CPVC compound utilizing an acid scavenger is formed.
  • the second example shows the recipe for the second embodiment of the invention.
  • Comparative Example 1 is a recipe for a conventional compound.
  • This value is the value assigned by Factory Mutual and is not based upon actual test results.

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  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention concerne un composé de polychlorure de vinyle chloré, ainsi qu'un article fabriqué à partir de ce composé. Ce composé, qui renferme moins de 40 pour cent en poids de matière inorganique, est conforme à la norme 4910 de l'institut 'Factory Mutual'. Les composés de cette invention présentent des propriétés physiques satisfaisantes, d'excellentes caractéristiques de combustion, et une bonne aptitude au traitement.
PCT/US1999/022881 1998-05-01 1999-04-16 Composes de polychlorure de vinyle chlores avec d'excellentes caracteristiques de combustion Ceased WO1999067332A2 (fr)

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US09/071,206 1998-05-01

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2379221A (en) * 2001-08-29 2003-03-05 Anthony Richard Gaukroger Colouring masterbatch
CN103923420A (zh) * 2014-03-25 2014-07-16 潍坊高信化工科技有限公司 一种无毒、高维卡冷热水用cpvc及其制备方法
US20160017123A1 (en) * 2013-03-15 2016-01-21 Lubrizol Advanced Materials, Inc. Heavy Metal Free CPVC Compounds
CN113603988A (zh) * 2021-08-27 2021-11-05 山东高信化学股份有限公司 一种高阻燃cpvc车用板材组合物及制备方法
CN121022006A (zh) * 2025-09-17 2025-11-28 广东简典科技发展有限公司 Cpvc电力管及其制备方法

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JPH05222261A (ja) * 1991-12-11 1993-08-31 Sekisui Chem Co Ltd 塩素化塩化ビニル樹脂組成物
EP0568922A1 (fr) * 1992-05-04 1993-11-10 The B.F. Goodrich Company Composés de halopolymères thermoplastiques rigides et méthode de réduction d'émission de chaleur
EP0695782B1 (fr) * 1994-08-05 1998-11-18 The B.F. Goodrich Company Material de chlorure de polyvinyle chloré à stabilitée et ténacité améliorés et à basse émision de fumée et chaleur
CA2132599A1 (fr) * 1994-09-12 1996-03-13 Masaharu Kato Composition de resine a base de chlorure de vinyle et produits derives de celle-ci

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2379221A (en) * 2001-08-29 2003-03-05 Anthony Richard Gaukroger Colouring masterbatch
GB2379221B (en) * 2001-08-29 2005-08-17 Anthony Richard Gaukroger Masterbatch
US20160017123A1 (en) * 2013-03-15 2016-01-21 Lubrizol Advanced Materials, Inc. Heavy Metal Free CPVC Compounds
US10202500B2 (en) * 2013-03-15 2019-02-12 Lubrizol Advanced Materials, Inc. Heavy metal free CPVC compounds
CN103923420A (zh) * 2014-03-25 2014-07-16 潍坊高信化工科技有限公司 一种无毒、高维卡冷热水用cpvc及其制备方法
CN113603988A (zh) * 2021-08-27 2021-11-05 山东高信化学股份有限公司 一种高阻燃cpvc车用板材组合物及制备方法
CN121022006A (zh) * 2025-09-17 2025-11-28 广东简典科技发展有限公司 Cpvc电力管及其制备方法

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