WO2000077286A1 - Procede pour la realisation d'un materiau non tisse, installation pour sa mise en oeuvre et non tisse ainsi obtenu - Google Patents

Procede pour la realisation d'un materiau non tisse, installation pour sa mise en oeuvre et non tisse ainsi obtenu Download PDF

Info

Publication number
WO2000077286A1
WO2000077286A1 PCT/FR2000/001428 FR0001428W WO0077286A1 WO 2000077286 A1 WO2000077286 A1 WO 2000077286A1 FR 0001428 W FR0001428 W FR 0001428W WO 0077286 A1 WO0077286 A1 WO 0077286A1
Authority
WO
WIPO (PCT)
Prior art keywords
spunbond
fibers
sheet
complex
veil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2000/001428
Other languages
English (en)
French (fr)
Inventor
André Vuillaume
Frédéric NOELLE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rieter Perfojet SAS
Original Assignee
Rieter Perfojet SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rieter Perfojet SAS filed Critical Rieter Perfojet SAS
Priority to JP2001503723A priority Critical patent/JP4546010B2/ja
Priority to DE60030120T priority patent/DE60030120T2/de
Priority to PL00352192A priority patent/PL352192A1/xx
Priority to AU49320/00A priority patent/AU4932000A/en
Priority to IL14686700A priority patent/IL146867A0/xx
Priority to EP00931356A priority patent/EP1192306B1/de
Publication of WO2000077286A1 publication Critical patent/WO2000077286A1/fr
Priority to US09/997,069 priority patent/US20020157766A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/74Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H18/00Needling machines
    • D04H18/04Needling machines with water jets
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/11Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • D04H5/03Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling by fluid jet
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/08Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of fibres or yarns

Definitions

  • non-woven fabrics known as “wet” produced using a technology close to the manufacture of paper
  • dry made of staple fibers, natural or chemical, obtained by carding, coating or any other material for textile preparation
  • _ nonwovens known as “melted” made up of continuous chemical filaments and commonly designated under the generic name of “spunbond”.
  • the present invention relates to an improvement made to the technology allowing such spunbond type nonwoven plies to be produced and more specifically relates to a process, an installation and a new type of product obtained by the use of these means, product having the appearance and the properties such as touch, mechanical characteristics, flexibility, close to a conventional textile, fabric in particular.
  • the sheet After production, and in general continuously, the sheet is consolidated, for example by performing a calibration or calendering, preferably hot, so that the elementary filaments are linked to each other.
  • the process according to the invention making it possible to obtain a nonwoven of the “spunbond” type having the appearance and the properties of a conventional textile, consists, continuously:
  • _ producing a “spunbond” type sheet, the bundle of extruded and drawn continuous filaments being received on a movable conveyor belt in the form of an unbound sheet; _ to deliver, against at least one face of the “spunbond” sheet thus formed, a veil of staple fibers - natural and / or artificial and / or synthetic - obtained by carding or other conventional technique; _ compacting the complex thus formed by pressing; _ to transfer, always continuously, said complex onto a binding treatment line by means of water jets, acting against the surface or surfaces of the complex consisting of staple fibers, entraining said fibers in the thickness direction, fibers which bind like a splice between and around the continuous filaments while remaining visible on the surface; _ to carry out a drying treatment;
  • compaction is carried out by pressing of the assembly constituted by the supe ⁇ osition of the layer or layers of staple fibers which cover or trap between them the "spunbond" tablecloth produced.
  • Such compaction which can be carried out by any suitable means, such as in particular by means of a pressing roller, can in no case be assimilated to a calendering operation since it is carried out cold.
  • a single veil of staple fibers can be associated with the veil with the “spunbond” type web, said veil of staple fibers being able to be delivered either upstream of the zone of formation of the “spunbond” veil and being brought on the conveyor belt on which are deposited the filaments coming from the “spunbond” installation, filaments which are therefore distributed on the surface of this veil, that is to say, delivered downstream of the zone of formation of the veil of continuous filaments.
  • the “spunbond” type sheet is covered on its two faces by a veil of discontinuous fibers, produced one upstream of the zone of formation of the “spunbond” veil, the other downstream , the web of continuous filaments thus being trapped sandwiched between the two layers of staple fibers.
  • the complex thus made up of three layers is, after compacting by pressing, transferred, always continuously, onto a binding treatment line by means of water jets, jets which act successively against the surfaces of said complexes entraining the staple fibers in the thickness direction, fibers which bond in the manner of a splice between and around the continuous filaments while remaining visible on the two outer faces.
  • an additional “texturing” treatment (carried out for example in accordance with the teachings of patent EP-059 608), consisting in transferring the complex linked on a conveyor constituted by a coarse cloth and to subject the tablecloth to the action of water jets obtained by the intermediary of an assembly essentially comprising a rotary perforated drum, inside which is disposed a fuel injector in pressurized water, this assembly producing jets reorienting the fibers, a suction assembly for removing water being provided below the conveyor.
  • the invention also relates to an installation allowing the continuous implementation of the above method.
  • such an installation comprises, arranged in line:
  • _ a formation assembly, on a conveyor belt, of a web of continuous spunbond type filaments; _ at least one card or other equivalent system making it possible to deliver against at least one face of the “spunbond” sheet produced a web of staple fibers;
  • such an installation comprises, between the means of binding by water jets and the drying means, a set of texturing producing jets redirecting the fibers.
  • the article obtained is characterized in that the continuous filaments which compose it are associated with discontinuous fibers, fibers which cover the sheet based on continuous filaments and penetrate inside this. the latter by binding around said filaments.
  • Such a product retains all the mechanical characteristics of resistance of conventional spunbond plies, the cohesion of which is given by a calendering treatment, the product obtained also having the appearance and the properties such as feel and flexibility comparable to a conventional textile.
  • the staple fibers which are associated with the spunbond layer can be of any type, natural or chemical, hydrophobic or hydrophilic, depending on the applications for which the product is intended, the length of said fibers being between 5 mm and 60 mm and their titer between 0.8 dtex and 6.6 dtex.
  • the grammage of the veil (s) of staple fibers which are associated with the spunbond batt may vary depending on the applications, but will advantageously be between 10 g / m2 and 50 g / m2, a batt having a lower grammage at 10 g / m2 which does not allow correct binding of the spunbond ply, while a ply greater than 50 g / m2 reduces the economic advantage of the process.
  • _ Figure 1 illustrates, seen from the side, an entire production line for implementing the method according to the invention
  • _ Figure 2 is also a side view, showing in more detail how the binding operation is carried out by means of water jets and any additional texturing treatment.
  • the invention therefore relates to a method and an installation which makes it possible to produce, continuously, a new type of “spunbond” plies made of continuous synthetic filaments, plies which not only retain the properties of mechanical resistance ( elongation, tensile strength, tear resistance ...), equivalent to conventional "spunbond” plies consolidated by hot calendering and which, moreover, have the appearance, feel and flexibility of a conventional textile such than a fabric.
  • a “spunbond” type nonwoven sheet is produced according to the conventional technique which consists in extruding a molten organic polymer, through a die (2) pierced with holes so as to form a bundle or curtain of filaments (3).
  • the “spunbond” sheet (S) in order to consolidate the “spunbond” sheet (S) thus formed and to give cohesion to this sheet and high mechanical characteristics of tensile and tear resistance while giving it an appearance, a feel and the flexibility of a conventional textile, the “spunbond” sheet (S) is received not directly on the surface of a conveyor belt (5) subjected to a suction source, but, on a veil (NI) of fibers discontinuous - natural and / or artificial and / or synthetic - produced immediately upstream of the “spunbond” installation (1).
  • NI veil
  • This veil (NI) is for example produced by means of a conventional assembly (6) consisting of a card possibly associated with a lapper spreader assembly, the veil (NI) produced being delivered to the conveyor belt (5) of the “spunbond” installation (1) by a supply assembly also consisting of a conveyor belt (7).
  • the two textile layers (NI) and (S) supe ⁇ osées then pass, still being held on the conveyor belt (5), on a first assembly (8), constituted for example by two cylinders to ensure compaction.
  • the three textile layers are delivered to the surface of the spunbond ply (S), a second web (N2) of staple fibers.
  • elementary supe ⁇ oses (NI, S and N2) being compacted again by pressing between two cylinders (8).
  • the compacted assembly is then brought to a treatment line, illustrated in more detail in FIG. 2, designated by the general reference (10) enabling said complex to be subjected to a binding treatment by means of jets of water, acting successively against the two surfaces of said complex.
  • a treatment line illustrated in more detail in FIG. 2, designated by the general reference (10) enabling said complex to be subjected to a binding treatment by means of jets of water, acting successively against the two surfaces of said complex.
  • such a treatment assembly (10) is constituted by a hydraulic binding unit of the “Jetlace 2000” type marketed by the Applicant and implementing the teachings of FR-A-
  • Such a binding unit essentially consists of a conveyor (11) onto which the fibrous structure constituted by the three supe ⁇ osed layers (NI, S and N2) is transferred.
  • the structure is compacted between the conveyor (11) and a first suction cylinder (12), preferably coated with a microperforated envelope, the holes of which are arranged randomly as described in French patent 2,734,285.
  • this cylinder can be covered with a wire mesh.
  • the complex sheet (N1 / S / N2) designated in the following description by the reference ( ⁇ )
  • can receiving a first wetting treatment by means of a ramp (13), illustrated in dotted lines in FIG. 2, and which delivers a curtain of water which passes through the conveyor belt (11) as well as the supe ⁇ osed layers.
  • the compacted complex supported by the suction drum (12), is then subjected to the action of water jets coming from an injector (14), the jets therefore acting against the surface formed by the fibrous web (NI) and entraining the fibers which constitute this veil inside the complex.
  • the ramp or injector (14) arranged parallel to a generator of the cylinder (12), is a conventional ramp which makes it possible to create jets or needles of water having a diameter of 100 to 170 microns, the jets being spaced from each other with a value between 0.5 and 2.2 mm, the supply pressure itself between 50 and 150 bars depending on the grammage of the complex.
  • the treated complex is brought to the surface of a second cylinder (15), identical to the previous suction cylinder, associated with one or two series of injectors (16,17) delivering jets of water which therefore act on the face of the sheet ( ⁇ ) formed by the web (N2).
  • the ramps (16,17) create jets or needles of water having a diameter of 100 to 170 microns, said jets being spaced as before from each other between 0.5 and 2.4 mm, and the supply pressure being between 50 bars and 400 bars.
  • the action of the injectors (16,17) therefore makes it possible to entrain the fibers of the NI veil in the thickness of the sheet ( ⁇ ), said fibers surrounding the continuous filaments and binding to the latter.
  • the linked spun web designated by the reference (18) can be brought directly to the drying assembly (19) by passing over a conventional heating drum (26) before being received.
  • a third hydraulic binding treatment can be carried out by means of a third suction drum (20) associated with a ramp of injectors (21), the jets of which act against the face which was constituted by the veil (NI).
  • Such treatment consists, as more particularly of FIG. 2, of transferring the linked “spun” ply (18) onto an assembly produced for example in accordance with the teachings of patent EP 059
  • such an assembly is constituted by a conveyor belt (22), of the "Fourdrinier” type, used in the paper industry.
  • the linked spun (18) maintained on this canvas is subjected to the action of a series of water jets obtained by means of a ramp (23) projecting a curtain of water against the internal surface of a perforated rotary cylinder (24), these jets redirect the fibers.
  • a suction assembly (25) for removing water is of course provided below the conveyor (22).
  • This example uses the realization of a complex in which the veil the "spunbond" sheet is trapped between two veils of staple fibers.
  • a veil of fibers (NI) weighing 30 g / m 2 and composed of 100% viscose fibers of 1.7 dtex and 38 mm in length is produced.
  • This veil is produced at a speed of 100 m / minute.
  • the web (NI) is transferred to the receiving mat (5) of the installation (1) for producing a ply (S) of the "spunbond" type.
  • the “spunbond” sheet produced is obtained from polypropylene and is distributed over the web (NI) so as to form a sheet made up of filaments having a titer of 1.7 dtex, weighing 40 g / m 2 .
  • the two superposed layers (NI) and (S) are compressed by means of a pressing cylinder (8) and a second veil of fibers (N2) reproduced in a similar manner to the veil (NI), weighing 30 g / m 2 , is delivered to the surface of the tablecloth
  • the complex formed is brought to a treatment line comprising a hydraulic binding unit (10) of the “Jetlace 2000” type, sold by the Applicant.
  • Such an installation essentially comprises a conveyor belt (11), and three sets of treatment by jets comprising suction cylinders
  • the ramps (14,16,17,21) all produce 1666 jets per meter and are adjusted as follows.
  • a texturing assembly constituted by a conveyor belt (22) made of a polyester fabric, associated with a texturing assembly proper comprising a rotary perforated drum (24) with inside which is arranged an injector (23) supplied with water at 150 bars.
  • This injector (23) produces water jets of 130 ⁇ m in diameter which redirect the fibers.
  • the water coming from the injector (23) is recovered by means of the suction assembly (25) arranged below the conveyor (22).
  • a sheet according to the invention is obtained at the outlet of the installation which, after drying on a heating drum, weighs 95 g / m 2 .
  • This example illustrates the implementation of the method according to the invention for the production of a structure composed of a “spunbond” type sheet associated with a single fibrous sheet which, in this embodiment, is formed upstream of the spunbond formation area.
  • a veil of fibers (NI) weighing 20 g / m2 is produced, composed of 100% viscose fibers of 1.7 dtex and 38 mm in length.
  • This veil is produced at a speed of 150 m / min.
  • the web (NI) is transferred to the receiving mat (5) of the spunbond unit.
  • a spunbond sheet (S) made of polypropylene filaments is deposited on the web (NI).
  • This 25 g / m2 spunbond tablecloth is made of 2 dtex filaments.
  • the two superposed layers (NI) and (S) are compressed by means of a pressure roller (8) thus forming a complex of 45 g / m2 which is transferred continuously onto a hydraulic binding unit (10) of the “Jetlace” type. 2000 ”marketed by the Applicant.
  • This installation comprises a conveyor belt (11) and two sets of treatment by water jets consisting of suction cylinders (12) and (15) followed by a final conveyor (22) on which is placed a patterning / texturing device.
  • the two cylinders (12) and (15) are covered with a microperforated envelope, the holes of which are arranged randomly as described in French patent 2,634,285. These cylinders are associated with injector ramps (14) (16) (17).
  • the injectors produce all 1,666 water jets of 120 microns per meter and the water pressure in these injectors is 60, 80 and 110 bars respectively.
  • the bonded complex is textured on the preceding cylinders by a perforated drum (23) as described in the previous example, the injector of which is supplied at a water pressure of 80 bars.
  • the final product of 45 g / m2 has excellent mechanical characteristics, superior to those of a spunlace veil made of fibers of the same kind.
  • the aspect and the flexibility of the veil are also remarkable, very superior to those of a spunbond in polypropylene or polyester of equivalent grammage bound by calendering.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
PCT/FR2000/001428 1999-06-10 2000-05-26 Procede pour la realisation d'un materiau non tisse, installation pour sa mise en oeuvre et non tisse ainsi obtenu Ceased WO2000077286A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2001503723A JP4546010B2 (ja) 1999-06-10 2000-05-26 不織布を製造するための方法およびそれを実施するためのプラントならびにそのようにして得られた不織布
DE60030120T DE60030120T2 (de) 1999-06-10 2000-05-26 Verfahren zur herstellung eines vliesstoffes, anlage zur durchführung dieses verfahren, hergestellter vliesstoff
PL00352192A PL352192A1 (en) 1999-06-10 2000-05-26 Method of and apparatus for production of unwoven fabric and the unwoven fabric obtained by this method
AU49320/00A AU4932000A (en) 1999-06-10 2000-05-26 Method for producing a nonwoven material, installation therefor and resulting nonwoven
IL14686700A IL146867A0 (en) 1999-06-10 2000-05-26 Method for producing a nonwoven material, installation therefor and material produced thereby
EP00931356A EP1192306B1 (de) 1999-06-10 2000-05-26 Verfahren zur herstellung eines vliesstoffes, anlage zur durchführung dieses verfahren, hergestellter vliesstoff
US09/997,069 US20020157766A1 (en) 1999-06-10 2001-11-29 Process for producing a nonwoven material, plant for implementing it and nonwoven thus obtained

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR99/07602 1999-06-10
FR9907602A FR2794776B1 (fr) 1999-06-10 1999-06-10 Procede pour la realisation d'un materiau non tisse, installation pour sa mise en oeuvre et non tisse ainsi obtenu

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US09/997,069 Continuation US20020157766A1 (en) 1999-06-10 2001-11-29 Process for producing a nonwoven material, plant for implementing it and nonwoven thus obtained

Publications (1)

Publication Number Publication Date
WO2000077286A1 true WO2000077286A1 (fr) 2000-12-21

Family

ID=9546854

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2000/001428 Ceased WO2000077286A1 (fr) 1999-06-10 2000-05-26 Procede pour la realisation d'un materiau non tisse, installation pour sa mise en oeuvre et non tisse ainsi obtenu

Country Status (14)

Country Link
US (1) US20020157766A1 (de)
EP (1) EP1192306B1 (de)
JP (1) JP4546010B2 (de)
CN (1) CN1355864A (de)
AT (1) ATE336611T1 (de)
AU (1) AU4932000A (de)
DE (1) DE60030120T2 (de)
DK (1) DK1192306T3 (de)
ES (1) ES2270833T3 (de)
FR (1) FR2794776B1 (de)
IL (1) IL146867A0 (de)
PL (1) PL352192A1 (de)
TR (1) TR200103471T2 (de)
WO (1) WO2000077286A1 (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1275764A1 (de) * 2001-07-10 2003-01-15 Rieter Perfojet (S.A.) Vliesstoff mit einer Schicht aus endlosen Filamenten, Verfahren zur dessen Herstellung und Verwendung als Reinigungstuch
WO2002068744A3 (de) * 2001-02-07 2003-11-13 Fleissner Maschf Gmbh Co Wasservernadeltes kompositvlies aus stapel- und endlosfasern und verfahren zur herstellung
US6737141B2 (en) 2002-03-20 2004-05-18 Kimberly-Clark Worldwide, Inc. Usable splice for a stabilized absorbent and method for making the splice
WO2004059062A1 (en) * 2002-12-27 2004-07-15 Unilever Plc Hydroentangled textile and use in a personal cleansing implement
US6863945B2 (en) 2001-12-31 2005-03-08 Kimberly-Clark Worldwide, Inc. Usable splice for a stabilized absorbent
US11136699B2 (en) 2018-05-14 2021-10-05 Fitesa Simpsonville, Inc. Composite sheet material, system, and method of preparing same

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2823511B1 (fr) * 2001-04-13 2003-12-26 Rieter Perfojet Installation de production d'une nappe non tissee spunbond consolidee par projection d'un fluide
US20030003832A1 (en) * 2001-06-29 2003-01-02 The Procter & Gamble Company Cleaning sheets comprising a fibrous web of carded staple fibers hydroentangled with a reinforcing fibrous web
CA2503495A1 (en) * 2002-10-22 2004-05-06 Polymer Group, Inc. Nonwoven secondary carpet backing
EP1424422A1 (de) * 2002-11-27 2004-06-02 Polyfelt Gesellschaft m.b.H. Strukturierte Gerotextilien und Verfahren zu deren Herstellung
EP1424418A1 (de) * 2002-11-27 2004-06-02 Polyfelt Gesellschaft m.b.H. Strukturierte Geotextilien und Verfahren zu deren Herstellung
EP1524350B2 (de) * 2003-10-17 2013-04-17 Reifenhäuser GmbH & Co. KG Maschinenfabrik Faserlaminat und Verfahren zur Herstellung eines Faserlaminates
FR2861750B1 (fr) * 2003-10-31 2006-02-24 Rieter Perfojet Machine de production d'un nontisse fini.
SE0303413D0 (sv) * 2003-12-18 2003-12-18 Sca Hygiene Prod Ab a composite nonwoven material containing continuous filaments and short fibres
CA2554819A1 (en) * 2004-03-18 2005-09-22 Sca Hygiene Products Ab Method of producing a nonwoven material
WO2006118492A1 (en) 2005-04-29 2006-11-09 Sca Hygiene Products Ab Hydroentangled integrated composite nonwoven material
ATE529556T1 (de) 2008-04-25 2011-11-15 Bc Nonwovens S L Verfahren zur herstellung von vliesstoffen
ES2338619B1 (es) * 2008-04-25 2011-03-22 Bc Nonwovens, S.L. Metodo de fabricacion de telas de tejido no tejido.
US20100159775A1 (en) * 2008-12-19 2010-06-24 Chambers Jr Leon Eugene Nonwoven Composite And Method For Making The Same
US20100159774A1 (en) * 2008-12-19 2010-06-24 Chambers Jr Leon Eugene Nonwoven composite and method for making the same
CA2704301A1 (en) * 2009-06-22 2010-12-22 Paul Dagesse Method for land stabilization
CN103597135B (zh) * 2011-05-04 2016-01-06 Sca卫生用品公司 制备水力缠结的非织造材料的方法
CN102493125A (zh) * 2011-11-21 2012-06-13 成都彩虹环保科技有限公司 复合材料加工设备
CN102501392A (zh) * 2011-11-21 2012-06-20 成都彩虹环保科技有限公司 复合材料加工设备
AU2012379139B2 (en) * 2012-05-03 2015-09-24 Essity Hygiene And Health Aktiebolag Method of producing a hydroentangled nonwoven material
TW201508118A (zh) * 2013-08-30 2015-03-01 Kang Na Hsiung Entpr Co Ltd 非織造紙巾及其製備方法
DE102013111499A1 (de) 2013-10-18 2015-04-23 Ascania Nonwoven Germany Gmbh Voluminöses Vlieskomposit und Verfahren zur Herstellung desselben
JP6270487B2 (ja) * 2014-01-06 2018-01-31 ユニ・チャーム株式会社 不織布の製造装置
DE112015005693A5 (de) * 2014-12-18 2017-08-31 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum Aufladen einer Faserbahn
DE102015112955A1 (de) * 2015-04-13 2016-10-13 TRüTZSCHLER GMBH & CO. KG Anlage und Verfahren zur Verbindung bzw. Verfestigung einer Bahn von Faserstoff mit einem Vlies
CN110485058B (zh) * 2019-08-27 2022-04-29 山东省永信非织造材料有限公司 蒲公英面膜水刺无纺布的制备方法
CN110468501B (zh) * 2019-08-27 2022-04-29 山东省永信非织造材料有限公司 金银花卫生护理水刺无纺布的制造方法
DE102020113137A1 (de) * 2020-05-14 2021-11-18 Trützschler GmbH & Co Kommanditgesellschaft Anlage und Verfahren zur Herstellung eines mehrlagigen Vlieses
DE102021107900B4 (de) 2021-03-29 2023-02-02 Andritz Küsters Gmbh Anlage zum Verfestigen von Fasern umfassenden Lagen zu einer Vliesbahn
DE102021107902A1 (de) 2021-03-29 2022-09-29 Andritz Küsters Gmbh Anlage zur Verfestigung mindestens einer nass- oder trockengelegten Faserlage zu einer Vliesbahn, mit einem Förderer, der ein umlaufendes Band mit einem oberen Trum umfasst, auf welches die mindestens eine Faserlage ablegbar und in einer Produktionsrichtung verlagerbar ist
DE102021107901A1 (de) 2021-03-29 2022-09-29 Andritz Küsters Gmbh Anlage und Verfahren zum Verfestigen von Fasern umfassenden Lagen zu einer Vliesbahn
CN115434074B (zh) * 2022-09-15 2023-09-19 东纶科技实业有限公司 一种水刺用铜网3d提花网套及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0308320A2 (de) * 1987-09-15 1989-03-22 Fiberweb North America, Inc. Fester Vliesstoff
EP0333228A2 (de) * 1988-03-18 1989-09-20 Kimberly-Clark Corporation Nichtgewebtes, faseriges, nichtelastisches Material und Verfahren zu dessen Herstellung
EP0534863A1 (de) * 1991-09-30 1993-03-31 Fiberweb North America, Inc. Vliesstof-Laminat und Verfahren zu seiner Herstellung
US5431991A (en) * 1992-01-24 1995-07-11 Fiberweb North America, Inc. Process stable nonwoven fabric
EP0796940A1 (de) * 1995-10-06 1997-09-24 Nippon Petrochemicals Co., Ltd. Verfahren und herstellung zur hydroverwirrung von vliesstoffen

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA82846B (en) * 1981-02-27 1983-01-26 Dexter Ltd C H Method and apparatus for making a patterned non-woven fabric
JPH0339509Y2 (de) * 1986-11-17 1991-08-20
JPH05209353A (ja) * 1991-08-05 1993-08-20 Oji Paper Co Ltd 不織布の製造方法
JP3201671B2 (ja) * 1993-02-17 2001-08-27 ユニチカ株式会社 複合不織布の製造方法
FR2731236B1 (fr) * 1995-03-02 1997-04-11 Icbt Perfojet Sa Installation pour la realisation de nappes non tissees dont la cohesion est obtenue par l'action de jets de fluide
EP0859076B1 (de) * 1997-02-12 2002-08-28 Fleissner GmbH & Co. Maschinenfabrik Vorrichtung zum hydrodynamischen Verschlingen der Fasern einer Faserbahn

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0308320A2 (de) * 1987-09-15 1989-03-22 Fiberweb North America, Inc. Fester Vliesstoff
EP0333228A2 (de) * 1988-03-18 1989-09-20 Kimberly-Clark Corporation Nichtgewebtes, faseriges, nichtelastisches Material und Verfahren zu dessen Herstellung
EP0534863A1 (de) * 1991-09-30 1993-03-31 Fiberweb North America, Inc. Vliesstof-Laminat und Verfahren zu seiner Herstellung
US5431991A (en) * 1992-01-24 1995-07-11 Fiberweb North America, Inc. Process stable nonwoven fabric
EP0796940A1 (de) * 1995-10-06 1997-09-24 Nippon Petrochemicals Co., Ltd. Verfahren und herstellung zur hydroverwirrung von vliesstoffen

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002068744A3 (de) * 2001-02-07 2003-11-13 Fleissner Maschf Gmbh Co Wasservernadeltes kompositvlies aus stapel- und endlosfasern und verfahren zur herstellung
FR2827313A1 (fr) * 2001-07-10 2003-01-17 Rieter Perfojet Non tisse comprenant une nappe en filaments continus, son procede de fabrication et son application en tant que chiffon d'essuyage
EP1275764A1 (de) * 2001-07-10 2003-01-15 Rieter Perfojet (S.A.) Vliesstoff mit einer Schicht aus endlosen Filamenten, Verfahren zur dessen Herstellung und Verwendung als Reinigungstuch
EP1743971A3 (de) * 2001-07-10 2009-08-05 Rieter Perfojet (S.A.) Vliesstoff mit einer Schicht aus endlosen Filamenten, Verfahren zu dessen Herstellung und Verwendung als Reinigungstuch
US7311792B2 (en) 2001-12-31 2007-12-25 Kimberly-Clark Worldwide, Inc. Process for making a splice for a stabilized absorbent
US6863945B2 (en) 2001-12-31 2005-03-08 Kimberly-Clark Worldwide, Inc. Usable splice for a stabilized absorbent
US7273646B2 (en) 2001-12-31 2007-09-25 Kimberly-Clark Worldwide, Inc. Personal care absorbent article having spliced absorbent material
US6737141B2 (en) 2002-03-20 2004-05-18 Kimberly-Clark Worldwide, Inc. Usable splice for a stabilized absorbent and method for making the splice
US7331090B2 (en) 2002-12-27 2008-02-19 Unilever Home & Personal Care Usa, Division Of Conopco Hydroentangled textile and use in a personal cleansing implement
US7381667B2 (en) 2002-12-27 2008-06-03 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Hydroentangled textile and use in a personal cleansing implement
CN100507123C (zh) * 2002-12-27 2009-07-01 荷兰联合利华有限公司 水力缠结纺织品和在个人清洁用具中的用途
WO2004059062A1 (en) * 2002-12-27 2004-07-15 Unilever Plc Hydroentangled textile and use in a personal cleansing implement
KR101063050B1 (ko) * 2002-12-27 2011-09-15 유니레버 엔.브이. 수력얽힘에 의한 직물 및 개인 세정 물품에의 용도
US11136699B2 (en) 2018-05-14 2021-10-05 Fitesa Simpsonville, Inc. Composite sheet material, system, and method of preparing same

Also Published As

Publication number Publication date
EP1192306B1 (de) 2006-08-16
IL146867A0 (en) 2002-08-14
AU4932000A (en) 2001-01-02
DE60030120D1 (de) 2006-09-28
DK1192306T3 (da) 2006-12-11
CN1355864A (zh) 2002-06-26
FR2794776B1 (fr) 2001-10-05
FR2794776A1 (fr) 2000-12-15
ATE336611T1 (de) 2006-09-15
ES2270833T3 (es) 2007-04-16
US20020157766A1 (en) 2002-10-31
TR200103471T2 (tr) 2002-07-22
JP4546010B2 (ja) 2010-09-15
PL352192A1 (en) 2003-08-11
JP2003502515A (ja) 2003-01-21
EP1192306A1 (de) 2002-04-03
DE60030120T2 (de) 2007-02-15

Similar Documents

Publication Publication Date Title
EP1192306B1 (de) Verfahren zur herstellung eines vliesstoffes, anlage zur durchführung dieses verfahren, hergestellter vliesstoff
EP1246958B1 (de) Verfahren zur herstellung eines verbundvliesmaterials und hergestelltes material
EP0403403B1 (de) Textil-Schichtstoff aus Faserbahnen mit verschiedenen Eigenschaften und dessen Verfahren zur Herstellung
EP0681620B1 (de) Verfahren zur herstellung eines vliesstoffs und dadurch erhaltener vliesstoff
EP0972102B1 (de) Verfahren zur Herstellung von multiaxialen Vliesstoffen
EP1226297B1 (de) Verfahren zur herstellung eines vliesstoffes mit hydrodynamischer vernadelung
EP1117860A1 (de) Verfahren zur herstellung von komplexen vliesen und hergestellte vliese
FR2711151A1 (fr) Support pour entoilage comportant une nappe de fibres entremêlées dans des fils de trame et son procédé de fabrication.
EP0772705B1 (de) Vorrichtung zur herstellung von vliesstoffen wovon die kohäsion durch flüssigkeitsstrahl hergestellt ist
FR2686628A1 (fr) Structure textile complexe a base de nappes fibreuses non tissees et procede et installation pour son obtention.
EP0745716B1 (de) Verfahren zur Herstellung einer textilen Verstärkungseinlage für die Herstellung von Kompositmaterialien
WO1993000465A1 (fr) Procede pour realiser un non-tisse, non-tisse obtenu notamment par ce procede et installation pour la fabrication de ce non-tisse
EP0501842A1 (de) Einlageverbundvliesstoff
EP2113041A2 (de) Vorrichtung und verfahren zur herstellung einer matte aus faser- oder filamentbasis
EP1554421A2 (de) Verfahren und vorrichtung zur herstellung von vliesstoffen unter verminderung der bewegungsgeschwindigkeit der verdichteten faserbahn
WO2001068966A2 (fr) Installation pour la realisation de nappes non tissees dont la cohesion est obtenue par l'action de jets de fluide
FR2881758A1 (fr) Carde et machine de production d'un non-tisse

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 00808757.1

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: IN/PCT/2001/01054/DE

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 2000931356

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2001 503723

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 09997069

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2001/03471

Country of ref document: TR

WWP Wipo information: published in national office

Ref document number: 2000931356

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWG Wipo information: grant in national office

Ref document number: 2000931356

Country of ref document: EP