WO2001051445A3 - Coproduction d'acides carboxyliques et/ou de leurs esters - Google Patents

Coproduction d'acides carboxyliques et/ou de leurs esters Download PDF

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Publication number
WO2001051445A3
WO2001051445A3 PCT/GB2000/004933 GB0004933W WO0151445A3 WO 2001051445 A3 WO2001051445 A3 WO 2001051445A3 GB 0004933 W GB0004933 W GB 0004933W WO 0151445 A3 WO0151445 A3 WO 0151445A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon atoms
carboxylic acids
methanol
esters
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2000/004933
Other languages
English (en)
Other versions
WO2001051445A2 (fr
Inventor
Stephen David Cook
Lesley Ann Key
John Glenn Sunley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0000936A external-priority patent/GB0000936D0/en
Priority claimed from GB0000935A external-priority patent/GB0000935D0/en
Priority claimed from GB0000934A external-priority patent/GB0000934D0/en
Priority claimed from GB0000933A external-priority patent/GB0000933D0/en
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Priority to AU2001222065A priority Critical patent/AU2001222065A1/en
Publication of WO2001051445A2 publication Critical patent/WO2001051445A2/fr
Publication of WO2001051445A3 publication Critical patent/WO2001051445A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé de co-carbonylation de méthanol et d'un réactif insaturé en oléfine, se prêtant à la carbonylation et comprenant au moins deux atomes de carbone, et/ou de dérivés réactifs de ceux-ci, afin de produire un mélange d'acide acétique et d'un acide carboxylique comprenant au moins trois atomes de carbone, et/ou un ester d'un ou des deux acides carboxyliques. Ce procédé consiste à faire entrer en contact à une pression et à une température élevées (i) du monoxyde de carbone, (ii) du méthanol et/ou un dérivé réactif de celui-ci, (iii) un réactif insaturé en oléfine se prêtant à la carbonylation et comprenant au moins deux atomes de carbone et/ou un dérivé réactif de celui-ci, et (iv) de l'eau, dans une composition réactionnelle liquide à l'intérieur d'un réacteur de carbonylation. La composition réactionnelle liquide comprend (a) une concentration finie en eau, (b) un halogénure d'hydrocarbyle, (c) un catalyseur à base de rhodium et (d) du ruthénium et/ou de l'osmium en tant que promoteurs.
PCT/GB2000/004933 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters Ceased WO2001051445A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001222065A AU2001222065A1 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
GB0000936A GB0000936D0 (en) 2000-01-14 2000-01-14 Process
GB0000934.0 2000-01-14
GB0000935A GB0000935D0 (en) 2000-01-14 2000-01-14 Process
GB0000935.7 2000-01-14
GB0000936.5 2000-01-14
GB0000933.2 2000-01-14
GB0000934A GB0000934D0 (en) 2000-01-14 2000-01-14 Process
GB0000933A GB0000933D0 (en) 2000-01-14 2000-01-14 Process

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/178,667 Continuation US6770643B2 (en) 1999-12-24 2002-06-24 Azaindoles

Publications (2)

Publication Number Publication Date
WO2001051445A2 WO2001051445A2 (fr) 2001-07-19
WO2001051445A3 true WO2001051445A3 (fr) 2002-05-10

Family

ID=27447750

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/GB2000/004933 Ceased WO2001051445A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters
PCT/GB2000/004943 Ceased WO2001051446A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters
PCT/GB2000/004944 Ceased WO2001051447A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters
PCT/GB2000/004924 Ceased WO2001051444A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters

Family Applications After (3)

Application Number Title Priority Date Filing Date
PCT/GB2000/004943 Ceased WO2001051446A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters
PCT/GB2000/004944 Ceased WO2001051447A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters
PCT/GB2000/004924 Ceased WO2001051444A2 (fr) 2000-01-14 2000-12-21 Coproduction d'acides carboxyliques et/ou de leurs esters

Country Status (2)

Country Link
AU (4) AU2001223818A1 (fr)
WO (4) WO2001051445A2 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7053241B1 (en) * 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
CN108003022B (zh) * 2016-11-02 2020-01-07 中国科学院大连化学物理研究所 一种制备酯类化合物的方法
CN108003023B (zh) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 一种制备丙酸甲酯的方法
CN108003024B (zh) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 一种丙酸甲酯的制备方法
CN116157380A (zh) * 2020-08-04 2023-05-23 伊士曼化工公司 丙酸方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0618183A1 (fr) * 1993-03-31 1994-10-05 Pardies Acetiques Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium
GB2298200A (en) * 1995-02-21 1996-08-28 Bp Chem Int Ltd Catalyst system comprising iridium and rhodium catalyst, alkyl halide and at least one ruthenium, osmium or rhenium promoter for use in alcohol carbonylation
GB2327420A (en) * 1997-07-22 1999-01-27 Bp Chem Int Ltd Production of oxygenated compounds
EP1085004A1 (fr) * 1999-09-20 2001-03-21 Dsm N.V. Procédé de carbonylation de butadiène et/ou de dérivés de butadiène

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4132734A (en) * 1976-05-03 1979-01-02 Monsanto Company Synthesis of carboxylic acids
US4111982A (en) * 1976-07-26 1978-09-05 Monsanto Company Coproduction of acetic and propionic acids
ZA833528B (en) * 1982-05-22 1984-12-24 Bp Chem Int Ltd Process for the production of one or more carboxylic acid anhydrides
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
GB8406126D0 (en) * 1984-03-08 1984-04-11 Bp Chem Int Ltd Esters
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
GB9503382D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
GB9504708D0 (en) * 1995-03-08 1995-04-26 Bp Chem Int Ltd Process
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0618183A1 (fr) * 1993-03-31 1994-10-05 Pardies Acetiques Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium
GB2298200A (en) * 1995-02-21 1996-08-28 Bp Chem Int Ltd Catalyst system comprising iridium and rhodium catalyst, alkyl halide and at least one ruthenium, osmium or rhenium promoter for use in alcohol carbonylation
GB2327420A (en) * 1997-07-22 1999-01-27 Bp Chem Int Ltd Production of oxygenated compounds
EP1085004A1 (fr) * 1999-09-20 2001-03-21 Dsm N.V. Procédé de carbonylation de butadiène et/ou de dérivés de butadiène

Also Published As

Publication number Publication date
WO2001051447A2 (fr) 2001-07-19
WO2001051445A2 (fr) 2001-07-19
WO2001051446A2 (fr) 2001-07-19
WO2001051444A2 (fr) 2001-07-19
AU2001220161A1 (en) 2001-07-24
WO2001051444A3 (fr) 2002-02-28
AU2001222065A1 (en) 2001-07-24
AU2001222071A1 (en) 2001-07-24
WO2001051446A3 (fr) 2002-03-14
AU2001223818A1 (en) 2001-07-24
WO2001051447A3 (fr) 2002-03-14

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