WO2004013236A3 - Composition de gel de revetement pour procede de finition dans le moule - Google Patents

Composition de gel de revetement pour procede de finition dans le moule Download PDF

Info

Publication number
WO2004013236A3
WO2004013236A3 PCT/US2003/022677 US0322677W WO2004013236A3 WO 2004013236 A3 WO2004013236 A3 WO 2004013236A3 US 0322677 W US0322677 W US 0322677W WO 2004013236 A3 WO2004013236 A3 WO 2004013236A3
Authority
WO
WIPO (PCT)
Prior art keywords
gel coat
laminate
mold
preferred
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/022677
Other languages
English (en)
Other versions
WO2004013236A2 (fr
Inventor
Sheila F Kia
Devi N Rai
Hamid G Kia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Motors Liquidation Co
Original Assignee
General Motors Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Motors Corp filed Critical General Motors Corp
Priority to AU2003261197A priority Critical patent/AU2003261197A1/en
Priority to EP03766882A priority patent/EP1539452A4/fr
Publication of WO2004013236A2 publication Critical patent/WO2004013236A2/fr
Publication of WO2004013236A3 publication Critical patent/WO2004013236A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/08—Glass
    • B32B2315/085—Glass fiber cloth or fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00—Polyureas; Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2220/00—Compositions for preparing gels other than hydrogels, aerogels and xerogels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31565—Next to polyester [polyethylene terephthalate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/31794—Of cross-linked polyester

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Des articles composites sont préparés par une opération de pulvérisation. Une première étape consiste à appliquer un gel de revêtement sur une surface de moule ayant été éventuellement prétraitée par un revêtement de détachement du moule. Ceci consiste ensuite à appliquer une couche barrière au-dessus du gel dans le moule et, ensuite, une formulation de laminé au-dessus de cette couche barrière. Ce laminé contient 20-60 % en poids de fibre de renforcement. Dans un mode de réalisation préféré, ce composite multicouche possède une épaisseur égale ou inférieure à 15 mm et est utile sous forme de panneau pour carrosserie automobile. Ce gel de revêtement contient une résine durcissante d'acrylate de polyuréthanne de polyester et l'article composite présente une surface possédant d'excellentes caractéristiques de brillance et de conservation de couleur après une exposition prolongée à un rayonnement ultraviolet. Le laminé est, de préférence, composé d'une résine de polyester peu rétrécissante basse densité remplie de fibre de verre. Dans un mode de réalisation préféré, la pâte du laminé contient une résine de polyester insaturé de dicyclopentadiène, des microsphères polymères creuses et un initiateur capable de déclencher le durcissement à température ambiante ou à une température égale ou inférieure à 50° C.
PCT/US2003/022677 2002-08-01 2003-07-21 Composition de gel de revetement pour procede de finition dans le moule Ceased WO2004013236A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2003261197A AU2003261197A1 (en) 2002-08-01 2003-07-21 Gel coat composition for in mold finish process
EP03766882A EP1539452A4 (fr) 2002-08-01 2003-07-21 Composition de gel de revetement pour procede de finition dans le moule

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US40032402P 2002-08-01 2002-08-01
US40009502P 2002-08-01 2002-08-01
US60/400,095 2002-08-01
US60/400,324 2002-08-01
US40245902P 2002-08-09 2002-08-09
US60/402,459 2002-08-09
US40278402P 2002-08-12 2002-08-12
US60/402,784 2002-08-12

Publications (2)

Publication Number Publication Date
WO2004013236A2 WO2004013236A2 (fr) 2004-02-12
WO2004013236A3 true WO2004013236A3 (fr) 2004-05-27

Family

ID=31499551

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/022677 Ceased WO2004013236A2 (fr) 2002-08-01 2003-07-21 Composition de gel de revetement pour procede de finition dans le moule

Country Status (5)

Country Link
US (1) US7150915B2 (fr)
EP (1) EP1539452A4 (fr)
CN (1) CN100402261C (fr)
AU (1) AU2003261197A1 (fr)
WO (1) WO2004013236A2 (fr)

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US7150915B2 (en) * 2002-08-01 2006-12-19 General Motors Corporation Gel coat composition for in mold finish process
ATE386785T1 (de) * 2003-07-22 2008-03-15 Omnova Solutions Inc Basislackhinterspritzung
US20060073346A1 (en) * 2004-10-04 2006-04-06 Super Michael S Polyester-polyurethane composites
US7520217B2 (en) 2005-02-02 2009-04-21 Design Imaging, Llc Method and system for printing onto a deformable cast polymer article
US20070088115A1 (en) * 2005-10-17 2007-04-19 Horn Donald R Surface coat formula for solid surface composites
US20070098997A1 (en) 2005-11-02 2007-05-03 Bayer Materialscience Llc Composite articles and a process for their production
DE102006029423A1 (de) * 2006-06-27 2008-01-03 Wacker Chemie Ag Cokatalysatoren mit verbesserter Lagerstabilität
US8641957B2 (en) 2006-07-05 2014-02-04 GM Global Technology Operations LLC Molding cosmetic composite panels with visible fibers from ultraviolent light resistant epoxy compositions
US8906502B2 (en) * 2006-12-29 2014-12-09 Ccp Composites Us Llc Organic powder useful as the replacement of mineral filler in composites
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EP1988068B1 (fr) * 2007-05-02 2017-04-12 SGL Carbon SE Procédé de fabrication des corps renforcés par fibres
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US8221874B1 (en) * 2009-09-23 2012-07-17 Crane Composites Inc. Durable glass fiber reinforced panel
EP2301645A1 (fr) * 2009-09-28 2011-03-30 Cytec Surface Specialties Austria GmbH Antimoussant pour la pulvérisation sans air
US20110086975A1 (en) * 2009-10-09 2011-04-14 Thomas Melnyk Colored gel coat composition and article
US20110136985A1 (en) * 2009-12-09 2011-06-09 Moon Douglas E Molded article having a mold imparted release layer coating
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Also Published As

Publication number Publication date
US20040023050A1 (en) 2004-02-05
EP1539452A4 (fr) 2006-04-05
US7150915B2 (en) 2006-12-19
EP1539452A2 (fr) 2005-06-15
CN1684806A (zh) 2005-10-19
WO2004013236A2 (fr) 2004-02-12
AU2003261197A1 (en) 2004-02-23
AU2003261197A8 (en) 2004-02-23
CN100402261C (zh) 2008-07-16

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