WO2005009934A3 - Zweistufiges hydroformylierungsverfahren - Google Patents

Zweistufiges hydroformylierungsverfahren Download PDF

Info

Publication number
WO2005009934A3
WO2005009934A3 PCT/EP2004/008209 EP2004008209W WO2005009934A3 WO 2005009934 A3 WO2005009934 A3 WO 2005009934A3 EP 2004008209 W EP2004008209 W EP 2004008209W WO 2005009934 A3 WO2005009934 A3 WO 2005009934A3
Authority
WO
WIPO (PCT)
Prior art keywords
reaction zone
reacted
fed
hydrogen
carbon monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2004/008209
Other languages
English (en)
French (fr)
Other versions
WO2005009934A2 (de
Inventor
Wolfgang Ahlers
Rocco Paciello
Edgar Zeller
Martin Volland
Miguel Angel Flores
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of WO2005009934A2 publication Critical patent/WO2005009934A2/de
Publication of WO2005009934A3 publication Critical patent/WO2005009934A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Hydroformylie- rungsprodukten von Olefinen, bei dem man a) in eine erste Reaktionszone einen olefinhaltigen Zulauf sowie Kohlenmonoxid und Wasserstoff einspeist und in Gegenwart eines ersten Katalysatorsystems umsetzt, 10 b) vom Austrag aus der ersten Reaktionszone einen im Wesentlichen aus nicht um gesetzten Olefinen und gegebenenfalls gesättigten Kohlenwasserstoffen bestehenden flüssigen Strom abtrennt, c) den in Schritt b) erhaltenen füssigen Strom sowie Kohlenmonoxid und Wasserstoff in eine zweite Reaktionszone einspeist und in Gegenwart eines zweiten Katalysatorsystems umsetzt.
PCT/EP2004/008209 2003-07-23 2004-07-22 Zweistufiges hydroformylierungsverfahren Ceased WO2005009934A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10333519A DE10333519A1 (de) 2003-07-23 2003-07-23 Zweistufiges Hydroformylierungsverfahren
DE10333519.6 2003-07-23

Publications (2)

Publication Number Publication Date
WO2005009934A2 WO2005009934A2 (de) 2005-02-03
WO2005009934A3 true WO2005009934A3 (de) 2005-04-07

Family

ID=34071851

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/008209 Ceased WO2005009934A2 (de) 2003-07-23 2004-07-22 Zweistufiges hydroformylierungsverfahren

Country Status (2)

Country Link
DE (1) DE10333519A1 (de)
WO (1) WO2005009934A2 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004041850A1 (de) * 2004-08-27 2006-03-02 Basf Ag Verfahren zur Herstellung von C5-Aldehyden und Propen aus einem 1-Buten- und 2-Buten-haltigen C4-Strom
EP2740535A1 (de) * 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentat-Liganden für die Hydroformylation von Ethylen
PL3319951T3 (pl) 2015-07-10 2022-02-28 Basf Se Sposób hydroformylowania 2-podstawionych butadienów oraz wytwarzania ich produktów pochodnych, w szczególności ambroksu
WO2017064064A1 (en) 2015-10-12 2017-04-20 Basf Se Hydroformylation process for producing 1,6-disubstituted hexane derivatives
CN108350010B (zh) * 2015-11-09 2020-09-04 赢创运营有限公司 2-丙基庚醇的经济制备
JP2020523297A (ja) 2017-06-13 2020-08-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ １，６−ヘキサンジオール誘導体を製造するためのヒドロホルミル化方法
EP4161696A4 (de) * 2020-06-05 2025-05-28 Scion Holdings LLC Verzweigte alkohole
WO2021247516A1 (en) 2020-06-05 2021-12-09 SCION Holdings LLC Branched alcohols
US11680032B2 (en) 2020-06-05 2023-06-20 SCION Holdings LLC Alcohols production
US12221404B2 (en) 2020-06-05 2025-02-11 SCION Holdings LLC Composition comprising branched aldehydes
US12145904B2 (en) 2020-12-17 2024-11-19 SCION Holdings LLC Branched products
CN112851708B (zh) * 2021-01-19 2023-05-05 成都欣华源科技有限责任公司 催化端炔或端位共轭烯炔制备烯醛的方法及其使用的双膦配体
CN112898140B (zh) * 2021-01-21 2022-07-22 四川大学 一种基于亚膦酰胺膦配体催化内烯烃制备醛的方法
CN115646552B (zh) * 2022-11-15 2024-01-26 中国海洋石油集团有限公司 一种用于烯烃加氢甲酰化的催化剂及其制备方法和用途

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0562451A2 (de) * 1992-03-27 1993-09-29 Hoechst Aktiengesellschaft Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
WO2003018192A2 (de) * 2001-08-24 2003-03-06 Basf Aktiengesellschaft Verfahren zur herstellung von 2-propylheptanol sowie dafür geeignete hydroformylierungskatalysatoren und deren weitere verwendung zur carbonylierung, hydrocyanierung und hydrierung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0562451A2 (de) * 1992-03-27 1993-09-29 Hoechst Aktiengesellschaft Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
WO2003018192A2 (de) * 2001-08-24 2003-03-06 Basf Aktiengesellschaft Verfahren zur herstellung von 2-propylheptanol sowie dafür geeignete hydroformylierungskatalysatoren und deren weitere verwendung zur carbonylierung, hydrocyanierung und hydrierung

Also Published As

Publication number Publication date
WO2005009934A2 (de) 2005-02-03
DE10333519A1 (de) 2005-02-17

Similar Documents

Publication Publication Date Title
WO2005009934A3 (de) Zweistufiges hydroformylierungsverfahren
TW200633967A (en) Process for the hydroformylation of olefins
AU2001281909A1 (en) Method for the hydroformylation of olefins comprising 2 to carbon atoms
MXPA03001238A (es) Proceso para la produccion continua de un oxido olefinico.
ES2258718T5 (es) Procedimiento para la epoxidación de olefinas
PL1931472T3 (pl) Sposób oddzielania organicznych katalizatorów kompleksowych z metalem przejściowym
WO2003078365A3 (de) Verfahren zur hydroformylierung von olefinen
MY131816A (en) Work-up of a liquid hydroformylation output
YU84002A (sh) Integrisani postupak za proizvodnju vinil acetata
WO2002096848A3 (en) Hydroformylation process
AU2003277856A1 (en) Fixed-bed method for production of chlorine by catalytic gas-phase oxidation of hydrogen chloride
CA2343272A1 (en) Process for the production of olefins
WO2004094355A3 (en) Selective dimethylether recovery and recycle in a methanol-to-olefin process
MY124674A (en) Process for producing aldehyde
AU2001267572A1 (en) Method for producing propylene hydroformylation products and acrylic acid and/oracrolein
AU2001287563A1 (en) Method for producing hydroformylation products of olefins with 2 to 8 carbon atoms
GB2389109B (en) A continuous process for the enantioselective catalytic hydrogenation of ß-ketoesters
WO2004060835A3 (en) Integrated gas to olefins process with recovery and conversion of by-products
CA2422477A1 (en) Recovery of metals by incineration of metal containing basic ion exchange resin
AU2003298364A1 (en) Hydroformylation process for the conversion of an ethylenically unsaturated compound to an alcohol
CN105164094A (zh) 具有多级冷凝的醛生产工艺
ATE331699T1 (de) Kontinuierliches hydroformylierungsverfahren
ATE390399T1 (de) Verfahren zur kontinuierlichen hydroformylierung
MY139327A (en) Method for the hydroformylation of olefins with 2 to 6 carbon atoms
WO2003093205A3 (de) Verfahren zur herstellung ungesättigter halogenhaltiger kohlenwasserstoffe sowie dafür geeignete vorrichtung

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase