WO2005009934A3 - Procede d'hydroformylation en deux etapes - Google Patents

Procede d'hydroformylation en deux etapes Download PDF

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Publication number
WO2005009934A3
WO2005009934A3 PCT/EP2004/008209 EP2004008209W WO2005009934A3 WO 2005009934 A3 WO2005009934 A3 WO 2005009934A3 EP 2004008209 W EP2004008209 W EP 2004008209W WO 2005009934 A3 WO2005009934 A3 WO 2005009934A3
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WO
WIPO (PCT)
Prior art keywords
reaction zone
reacted
fed
hydrogen
carbon monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/EP2004/008209
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German (de)
English (en)
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WO2005009934A2 (fr
Inventor
Wolfgang Ahlers
Rocco Paciello
Edgar Zeller
Martin Volland
Miguel Angel Flores
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BASF SE
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BASF SE
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Publication of WO2005009934A2 publication Critical patent/WO2005009934A2/fr
Publication of WO2005009934A3 publication Critical patent/WO2005009934A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne un procédé d'obtention de produits d'hydroformylation d'oléfines, procédé selon lequel : a) on introduit, dans une première zone de réaction, une charge contenant des oléfines, ainsi que du monoxyde de carbone et de l'hydrogène, que l'on fait réagir en présence d'un premier système catalyseur ; b) on sépare, du produit extrait de la première zone de réaction, un courant de liquide constitué essentiellement d'oléfines n'ayant pas réagi et éventuellement d'hydrocarbures saturés ; c) et l'on introduit le courant de liquide obtenu à l'étape b), ainsi que du monoxyde de carbone et de l'hydrogène, dans une seconde zone de réaction, et on les fait réagir en présence d'un second système catalyseur.
PCT/EP2004/008209 2003-07-23 2004-07-22 Procede d'hydroformylation en deux etapes Ceased WO2005009934A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10333519A DE10333519A1 (de) 2003-07-23 2003-07-23 Zweistufiges Hydroformylierungsverfahren
DE10333519.6 2003-07-23

Publications (2)

Publication Number Publication Date
WO2005009934A2 WO2005009934A2 (fr) 2005-02-03
WO2005009934A3 true WO2005009934A3 (fr) 2005-04-07

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ID=34071851

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/008209 Ceased WO2005009934A2 (fr) 2003-07-23 2004-07-22 Procede d'hydroformylation en deux etapes

Country Status (2)

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DE (1) DE10333519A1 (fr)
WO (1) WO2005009934A2 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004041850A1 (de) * 2004-08-27 2006-03-02 Basf Ag Verfahren zur Herstellung von C5-Aldehyden und Propen aus einem 1-Buten- und 2-Buten-haltigen C4-Strom
EP2740535A1 (fr) * 2012-12-04 2014-06-11 Dow Technology Investments LLC Ligands bidentates pour hydroformylation d'éthylène
PL3319951T3 (pl) 2015-07-10 2022-02-28 Basf Se Sposób hydroformylowania 2-podstawionych butadienów oraz wytwarzania ich produktów pochodnych, w szczególności ambroksu
WO2017064064A1 (fr) 2015-10-12 2017-04-20 Basf Se Procédé d'hydroformylation pour produire des dérivés 1,6-disubstitués d'hexane
CN108350010B (zh) * 2015-11-09 2020-09-04 赢创运营有限公司 2-丙基庚醇的经济制备
JP2020523297A (ja) 2017-06-13 2020-08-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ １，６−ヘキサンジオール誘導体を製造するためのヒドロホルミル化方法
EP4161696A4 (fr) * 2020-06-05 2025-05-28 Scion Holdings LLC Alcools ramifiés
WO2021247516A1 (fr) 2020-06-05 2021-12-09 SCION Holdings LLC Alcools ramifiés
US11680032B2 (en) 2020-06-05 2023-06-20 SCION Holdings LLC Alcohols production
US12221404B2 (en) 2020-06-05 2025-02-11 SCION Holdings LLC Composition comprising branched aldehydes
US12145904B2 (en) 2020-12-17 2024-11-19 SCION Holdings LLC Branched products
CN112851708B (zh) * 2021-01-19 2023-05-05 成都欣华源科技有限责任公司 催化端炔或端位共轭烯炔制备烯醛的方法及其使用的双膦配体
CN112898140B (zh) * 2021-01-21 2022-07-22 四川大学 一种基于亚膦酰胺膦配体催化内烯烃制备醛的方法
CN115646552B (zh) * 2022-11-15 2024-01-26 中国海洋石油集团有限公司 一种用于烯烃加氢甲酰化的催化剂及其制备方法和用途

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0562451A2 (fr) * 1992-03-27 1993-09-29 Hoechst Aktiengesellschaft Mélanges d'alcools décycliques, esters de l'acide phtalique obtenus de ceux-ci et leur utilisation comme agents plastifiants
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
WO2003018192A2 (fr) * 2001-08-24 2003-03-06 Basf Aktiengesellschaft Procede de preparation de 2-propylheptanol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0562451A2 (fr) * 1992-03-27 1993-09-29 Hoechst Aktiengesellschaft Mélanges d'alcools décycliques, esters de l'acide phtalique obtenus de ceux-ci et leur utilisation comme agents plastifiants
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
WO2003018192A2 (fr) * 2001-08-24 2003-03-06 Basf Aktiengesellschaft Procede de preparation de 2-propylheptanol

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Publication number Publication date
WO2005009934A2 (fr) 2005-02-03
DE10333519A1 (de) 2005-02-17

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