WO2005016873A3 - 4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide - Google Patents

4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide Download PDF

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Publication number
WO2005016873A3
WO2005016873A3 PCT/EP2004/008638 EP2004008638W WO2005016873A3 WO 2005016873 A3 WO2005016873 A3 WO 2005016873A3 EP 2004008638 W EP2004008638 W EP 2004008638W WO 2005016873 A3 WO2005016873 A3 WO 2005016873A3
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WO
WIPO (PCT)
Prior art keywords
dione derivatives
pyrazolidin
biphenylsubstituted
biphenyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2004/008638
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English (en)
French (fr)
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WO2005016873A2 (de
Inventor
Reiner Fischer
Thomas Bretschneider
Ernst Rudolf F Gesing
Dieter Feucht
Karl-Heinz Kuck
Peter Loesel
Olga Malsam
Christian Arnold
Thomas Auler
Martin Jeffrey Hills
Heinz Kehne
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Bayer CropScience AG
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Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2006522945A priority Critical patent/JP5432432B2/ja
Priority to CA002535512A priority patent/CA2535512A1/en
Priority to US10/567,788 priority patent/US8119566B2/en
Priority to CN2004800293416A priority patent/CN1863806B/zh
Priority to AU2004265089A priority patent/AU2004265089B2/en
Priority to BRPI0413531-8A priority patent/BRPI0413531A/pt
Priority to KR1020067002980A priority patent/KR101110112B1/ko
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP04763708A priority patent/EP1656382A2/de
Publication of WO2005016873A2 publication Critical patent/WO2005016873A2/de
Publication of WO2005016873A3 publication Critical patent/WO2005016873A3/de
Anticipated expiration legal-status Critical
Priority to US13/017,194 priority patent/US8168566B2/en
Priority to US13/347,931 priority patent/US8586783B2/en
Priority to US13/952,858 priority patent/US8987500B2/en
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/616Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety polycyclic
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28Two oxygen or sulfur atoms
    • C07D231/30Two oxygen or sulfur atoms attached in positions 3 and 5
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/581,2-Diazines; Hydrogenated 1,2-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00Antiparasitic agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00Antiparasitic agents
    • A61P33/14Ectoparasiticides, e.g. scabicides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/56Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups bound to carbon atoms of six-membered aromatic rings and carboxyl groups bound to acyclic carbon atoms of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • C07C317/44Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28Two oxygen or sulfur atoms
    • C07D231/30Two oxygen or sulfur atoms attached in positions 3 and 5
    • C07D231/32Oxygen atoms
    • C07D231/36Oxygen atoms with hydrocarbon radicals, substituted by hetero atoms, attached in position 4
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04Ortho-condensed systems
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08Bridged systems

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmacology & Pharmacy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)

Abstract

Die vorliegende Erfindung betrifft neue 4-Biphenylsubstituierte Pyrazolidin-3,5-dion-Derivate, der Formel (I) in welcher A, D, G, W, X, Y und Z die oben angegebenen Bedeutungen haben, mehrere Verfahren zu ihrer Herstellung und ihre Verwendung als Schädlingsbekämpfungsmittel und/oder Herbizide und/oder Mikrobizide. Außerdem betrifft die Erfindung selektiv herbizide Mittel, die 4-Biphenylsubstituierte Pyrazolidin-3,5-dion-Derivate der Formel (I) einerseits und eine die Kulturpflanzenverträglichkeit verbessernde Verbindung andererseits enthalten.
PCT/EP2004/008638 2003-08-14 2004-08-02 4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide Ceased WO2005016873A2 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
BRPI0413531-8A BRPI0413531A (pt) 2003-08-14 2004-08-02 derivados de órazpçodoma-3.5-diona substituìda com 4-bifenila
CA002535512A CA2535512A1 (en) 2003-08-14 2004-08-02 4-biphenylsubstituted pyrazolidin-3,5-dione derivatives
US10/567,788 US8119566B2 (en) 2003-08-14 2004-08-02 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
CN2004800293416A CN1863806B (zh) 2003-08-14 2004-08-02 4-联苯基取代的吡唑烷-3,5-二酮衍生物
AU2004265089A AU2004265089B2 (en) 2003-08-14 2004-08-02 4-biphenylsubstituted pyrazolidin-3,5-dione derivatives
KR1020067002980A KR101110112B1 (ko) 2003-08-14 2004-08-02 4-비페닐 치환된 피라졸리딘-3,5-디온 유도체
EP04763708A EP1656382A2 (de) 2003-08-14 2004-08-02 4-biphenylsubstituierte pyrazolidin-3,5-dion-derivate als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide
JP2006522945A JP5432432B2 (ja) 2003-08-14 2004-08-02 4−ビフェニル置換ピラゾリジン−3,5−ジオン誘導体
US13/017,194 US8168566B2 (en) 2003-08-14 2011-01-31 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/347,931 US8586783B2 (en) 2003-08-14 2012-01-11 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/952,858 US8987500B2 (en) 2003-08-14 2013-07-29 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10337497A DE10337497A1 (de) 2003-08-14 2003-08-14 4-Biphenylsubstituierte-Pyrazolidin-3,5-dion-Derivate
DE10337497.3 2003-08-14

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US10/567,788 A-371-Of-International US8119566B2 (en) 2003-08-14 2004-08-02 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/017,194 Division US8168566B2 (en) 2003-08-14 2011-01-31 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/347,931 Division US8586783B2 (en) 2003-08-14 2012-01-11 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/952,858 Division US8987500B2 (en) 2003-08-14 2013-07-29 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives

Publications (2)

Publication Number Publication Date
WO2005016873A2 WO2005016873A2 (de) 2005-02-24
WO2005016873A3 true WO2005016873A3 (de) 2005-04-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/008638 Ceased WO2005016873A2 (de) 2003-08-14 2004-08-02 4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide

Country Status (11)

Country Link
US (4) US8119566B2 (de)
EP (1) EP1656382A2 (de)
JP (2) JP5432432B2 (de)
KR (1) KR101110112B1 (de)
CN (3) CN1863806B (de)
AR (1) AR045246A1 (de)
AU (1) AU2004265089B2 (de)
BR (1) BRPI0413531A (de)
CA (1) CA2535512A1 (de)
DE (1) DE10337497A1 (de)
WO (1) WO2005016873A2 (de)

Cited By (2)

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US8013172B2 (en) 2006-02-21 2011-09-06 Bayer Cropscience Ag Cycloalkylphenyl substituted cyclic ketoenols
US8993782B2 (en) 2006-12-04 2015-03-31 Bayer Cropscience Ag Cis-alkoxyspirocyclic biphenyl-substituted tetramic acid derivatives

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DE10337497A1 (de) 2003-08-14 2005-03-10 Bayer Cropscience Ag 4-Biphenylsubstituierte-Pyrazolidin-3,5-dion-Derivate
DE102004011006A1 (de) * 2004-03-06 2005-09-22 Bayer Cropscience Ag Suspensionskonzentrate auf Ölbasis
DE102004044827A1 (de) 2004-09-16 2006-03-23 Bayer Cropscience Ag Jod-phenylsubstituierte cyclische Ketoenole
DE102004049041A1 (de) * 2004-10-08 2006-04-13 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE102004053191A1 (de) 2004-11-04 2006-05-11 Bayer Cropscience Ag 2,6-Diethyl-4-methyl-phenyl substituierte Tetramsäure-Derivate
DE102004053192A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2-Alkoxy-6-alkyl-phenyl substituierte spirocyclische Tetramsäure-Derivate
DE102005057250A1 (de) * 2005-11-29 2007-06-06 Bayer Cropscience Gmbh Wirkstoffe zur Steigerung der Stressabwehr in Pflanzen gegenüber abiotischem Stress und Methoden zu ihrer Auffindung
DE102005059469A1 (de) 2005-12-13 2007-06-14 Bayer Cropscience Ag Insektizide Zusammensetzungen mit verbesserter Wirkung
JO3598B1 (ar) 2006-10-10 2020-07-05 Infinity Discovery Inc الاحماض والاسترات البورونية كمثبطات اميد هيدروليز الحامض الدهني
DE102006057036A1 (de) * 2006-12-04 2008-06-05 Bayer Cropscience Ag Biphenylsubstituierte spirocyclische Ketoenole
WO2009088549A2 (en) 2007-10-19 2009-07-16 The Board Of Regents Of The University Of Texas System Methods of inhibiting bacterial virulence and compounds relating thereto
TW201000107A (en) * 2008-04-09 2010-01-01 Infinity Pharmaceuticals Inc Inhibitors of fatty acid amide hydrolase
US8524748B2 (en) 2008-10-08 2013-09-03 Panmira Pharmaceuticals, Llc Heteroalkyl biphenyl antagonists of prostaglandin D2 receptors
HUE015568T4 (en) * 2008-12-19 2017-10-30 Elanco Tiergesundheit Ag Isoxazoline derivatives and their use as pesticides
CN102348684B (zh) 2009-03-11 2014-11-12 拜尔农作物科学股份公司 被卤代烷基亚甲基氧基苯基取代的酮烯醇
CA2757622A1 (en) 2009-04-07 2010-10-14 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
WO2010118155A1 (en) 2009-04-07 2010-10-14 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
BR112012000244B1 (pt) 2009-07-07 2019-01-08 Bayer Cropscicence Ag método para a produção de ácidos (2,4-dimentilbifenil-3-il) acéticos, os seus ésteres e compostos intermediários.
MX361692B (es) 2010-02-03 2018-12-13 Infinity Pharmaceuticals Inc Inhibidores de amida hidrolasa de ácido graso.
WO2011098440A2 (de) 2010-02-10 2011-08-18 Bayer Cropscience Ag Biphenylsubstituierte cyclische ketoenole
DE102010008644A1 (de) 2010-02-15 2011-08-18 Bayer Schering Pharma Aktiengesellschaft, 13353 Zyklische Ketoenole zur Therapie
JP5842594B2 (ja) 2010-12-27 2016-01-13 住友化学株式会社 ピリダジノン化合物、それを含有する除草剤及び有害節足動物防除剤
AR087008A1 (es) 2011-06-22 2014-02-05 Syngenta Participations Ag Derivados de n-oxi-pirazolo-triazepina-diona
KR102030337B1 (ko) 2012-01-26 2019-10-10 바이엘 인텔렉쳐 프로퍼티 게엠베하 어류 기생충 방제용의 페닐-치환된 케토에놀
DK3362462T3 (da) 2015-10-12 2021-10-11 Advanced Cell Diagnostics Inc In situ-detektion af nukleotidvarianter i prøver med højt støjniveau, og sammensætninger og fremgangsmåder relateret dertil
CN109180667B (zh) * 2018-09-10 2021-08-06 湖南大学 8-(苯并呋喃-5-基)苯并噁嗪酮衍生物及其应用
CA3214787A1 (en) 2021-03-30 2022-10-06 Stepan Company Agricultural formulations

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CN101323622A (zh) 2008-12-17
US20120040963A1 (en) 2012-02-16
AR045246A1 (es) 2005-10-19
US8586783B2 (en) 2013-11-19
CN1863806B (zh) 2010-06-16
AU2004265089B2 (en) 2011-07-28
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US20130018202A1 (en) 2013-01-17
US8168566B2 (en) 2012-05-01
JP5432432B2 (ja) 2014-03-05
WO2005016873A2 (de) 2005-02-24
CN102050722B (zh) 2014-08-13
CA2535512A1 (en) 2005-02-24
US8119566B2 (en) 2012-02-21
AU2004265089A1 (en) 2005-02-24
BRPI0413531A (pt) 2006-10-10
KR101110112B1 (ko) 2012-01-31
KR20060065681A (ko) 2006-06-14
US8987500B2 (en) 2015-03-24
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