WO2008072482A1 - 半導体装置の製造方法 - Google Patents
半導体装置の製造方法 Download PDFInfo
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- WO2008072482A1 WO2008072482A1 PCT/JP2007/073078 JP2007073078W WO2008072482A1 WO 2008072482 A1 WO2008072482 A1 WO 2008072482A1 JP 2007073078 W JP2007073078 W JP 2007073078W WO 2008072482 A1 WO2008072482 A1 WO 2008072482A1
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- ion implantation
- implantation mask
- etching
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/64—Double-diffused metal-oxide semiconductor [DMOS] FETs
- H10D30/66—Vertical DMOS [VDMOS] FETs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P30/00—Ion implantation into wafers, substrates or parts of devices
- H10P30/20—Ion implantation into wafers, substrates or parts of devices into semiconductor materials, e.g. for doping
- H10P30/22—Ion implantation into wafers, substrates or parts of devices into semiconductor materials, e.g. for doping using masks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D12/00—Bipolar devices controlled by the field effect, e.g. insulated-gate bipolar transistors [IGBT]
- H10D12/01—Manufacture or treatment
- H10D12/031—Manufacture or treatment of IGBTs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/028—Manufacture or treatment of FETs having insulated gates [IGFET] of double-diffused metal oxide semiconductor [DMOS] FETs
- H10D30/0281—Manufacture or treatment of FETs having insulated gates [IGFET] of double-diffused metal oxide semiconductor [DMOS] FETs of lateral DMOS [LDMOS] FETs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
- H10D62/832—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge being Group IV materials comprising two or more elements, e.g. SiGe
- H10D62/8325—Silicon carbide
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/69—Inorganic materials
- H10P14/692—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
- H10P14/6921—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses containing silicon
- H10P14/69215—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses containing silicon the material being a silicon oxide, e.g. SiO2
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P32/00—Diffusion of dopants within, into or out of wafers, substrates or parts of devices
- H10P32/10—Diffusion of dopants within, into or out of semiconductor bodies or layers
- H10P32/14—Diffusion of dopants within, into or out of semiconductor bodies or layers within a single semiconductor body or layer in a solid phase; between different semiconductor bodies or layers, both in a solid phase
- H10P32/1404—Diffusion of dopants within, into or out of semiconductor bodies or layers within a single semiconductor body or layer in a solid phase; between different semiconductor bodies or layers, both in a solid phase using predeposition followed by drive-in of impurities into the semiconductor surface, e.g. predeposition from a gaseous phase
- H10P32/1406—Diffusion of dopants within, into or out of semiconductor bodies or layers within a single semiconductor body or layer in a solid phase; between different semiconductor bodies or layers, both in a solid phase using predeposition followed by drive-in of impurities into the semiconductor surface, e.g. predeposition from a gaseous phase by ion implantation
Definitions
- the present invention relates to a method for manufacturing a semiconductor device, and more particularly to a method for manufacturing a semiconductor device capable of miniaturizing the semiconductor device and reducing variations in characteristics of the semiconductor device.
- MOSFET Metal Oxide Semiconductor Field Effect Transistor
- SiC-MOSFET Metal Oxide Semiconductor Field Effect Transistor
- an n-type SiC film 202 is epitaxially grown on the surface of a SiC substrate 201.
- an ion implantation mask 203 is formed on the entire surface of the SiC film 202.
- a resist 204 having a predetermined opening 205 is formed on the ion implantation mask 203 by using a photolithography technique. Then, as shown in Figure 23
- a portion of the ion implantation mask 203 located below the opening 205 is removed by etching, and a part of the surface of the SiC film 202 is exposed.
- the resist 204 is removed, and ions of an n-type dopant such as phosphorus are ion-implanted into the exposed surface of the SiC film 202, so that the n-type is implanted into the surface of the SiC film 202.
- a dopant implantation region 206 is formed.
- a photolithography technique is formed on the surface of the ion implantation mask 203.
- the resist 204 is partially formed using
- the formation position of the resist 204 may deviate from the set position depending on the accuracy of the photolithography apparatus.
- a portion of the surface of the SiC film 202 is exposed by removing the portion of the ion implantation mask 203 where the resist 204 is not formed by etching.
- a p-type dopant implantation region 207 is formed on the surface of the SiC film 202.
- the ion implantation mask 203 and the resist 204 are removed, and an activation annealing is performed to recover the crystallinity of the wafer after the removal of the ion implantation mask 203 and the resist 204.
- a gate oxide film 208, a source electrode 209, and a drain electrode 211 are formed on the surface of the SiC film 202, and a gate electrode 210 is formed on the surface of the gate oxide film 208.
- wiring is provided to the source electrode 209, the gate electrode 210, and the drain electrode 211, and then the wafer is divided into chips, thereby completing the SiC-MOSFET.
- Non-Patent Document 1 edited by Hiroyuki Matsunami, “Semiconductor SiC Technology and Applications”, Nikkan Kogyo Shimbun, March 2003
- SiC has a small diffusion coefficient of dopant, it is necessary to introduce an n-type dopant and a p-type dopant by an ion implantation method that is different from the diffusion method.
- an object of the present invention is to provide a method for manufacturing a semiconductor device that can miniaturize the semiconductor device and reduce variations in characteristics of the semiconductor device.
- the present invention includes a first step of forming an ion implantation mask on a part of the semiconductor surface, and a first dopant in at least a part of the exposed region of the semiconductor surface other than the region where the ion implantation mask is formed.
- a second step in which a first dopant implantation region is formed by implanting ions, and a third step in which the exposed region of the semiconductor surface is enlarged by removing a portion of the ion implantation mask after the formation of the first dopant implantation region.
- the ion implantation mask for forming the first dopant implantation region can also be used for the formation of the second dopant implantation region.
- the ion implantation mask for forming the first dopant implantation region can also be used for the formation of the second dopant implantation region.
- the ion implantation mask preferably includes at least one selected from the group consisting of tandasten, kaen, aluminum, nickel, and titanium.
- the ion implantation mask functions as a mask for ion implantation of the first dopant and the second dopant, and suppresses etching of the semiconductor surface with an adhesion improving layer that improves adhesion between the ion implantation mask and the semiconductor surface.
- An etch stop layer can be included.
- each of the above tungsten, silicon, aluminum, nickel, and titanium may be included in the ion implantation mask in a single form, or may be included in the ion implantation mask in the form of a compound! / Well! /
- the ion implantation mask may be composed of two or more layers. If the ion implantation mask consists of two or more layers, When the exposed area of the semiconductor surface is enlarged by removing a part of the ion implantation mask after forming the ion implantation area, the width of the ion implantation mask can be reduced while suppressing the decrease in the thickness. This improves the reliability of the ion implantation mask during ion implantation of the second dopant.
- the ion implantation mask includes two layers of a first ion implantation mask and a second ion implantation mask formed on the first ion implantation mask. It may be.
- the thickness of the first ion implantation mask is reduced. Since the width of the first ion implantation mask can be reduced while suppressing, the reliability of the first ion implantation mask during ion implantation of the second dopant is improved.
- the first ion implantation mask has tungsten as a main component and the second ion implantation mask has silicon oxide as a main component.
- the second ion implantation mask is difficult to be etched.
- the first ion implantation mask tends to be difficult to etch. Since the width of the first ion implantation mask can be reduced while suppressing a decrease in the thickness of the implantation mask, the reliability of the first ion implantation mask during ion implantation of the second dopant is improved.
- the first step is to form an ion implantation mask by stacking a first ion implantation mask and a second ion implantation mask in this order on the surface of the semiconductor.
- the etching is performed by exposing a part of the semiconductor surface by etching a part of the ion implantation mask, and the third step etches the first ion implantation mask at least in the width direction after the formation of the first dopant implantation region.
- the step of removing the second ion implantation mask by etching is included between the third step and the fourth step, and the step of removing the first ion implantation mask by etching after the fourth step. May be included. In this case, miniaturization of the semiconductor device and reduction in variation in characteristics of the semiconductor device can be achieved, and the number of processes can be reduced as compared with the conventional method.
- the second ion implantation mask may be It is preferable that the selection ratio of the second ion implantation mask to the first ion implantation mask by the etching solution or etching gas for etching is 2 or more. In this case, etching of the second ion implantation mask can be suppressed before ion implantation of the second dopant, and the first ion implantation mask can be removed while suppressing a decrease in the thickness of the first ion implantation mask. Since the etching can be performed in the width direction, the reliability of the first ion implantation mask during ion implantation of the second dopant is improved.
- the etching in the first step and the etching in the third step are each performed by dry etching.
- the etching in the thickness direction of the first ion implantation mask and the second ion implantation mask tends to proceed, and the exposed area of the semiconductor surface is enlarged.
- the third step since the etching control in the width direction of the first ion implantation mask and the second ion implantation mask tends to be easy, the on implantation mask can be prevented from being unnecessarily etched.
- a part of the ion implantation mask in the third step is removed by etching, and the thickness of the ion implantation mask after the etching in the third step is set to the first.
- the thickness can function as an ion implantation mask for the second dopant in the four steps.
- the force S can be used to prevent the second dopant implantation region from being formed to an unnecessary portion.
- the ion implantation mask may contain tungsten as a main component.
- tungsten is a high-density material and has a high ability to prevent ion implantation! Therefore, the ion implantation mask can be formed thinner than other materials. This is preferable in that the process tends to be simple.
- the first step forms a part of the surface of the semiconductor by etching a part of the ion implantation mask after forming the ion implantation mask on the surface of the semiconductor.
- the third step is the first dopant injection. This is performed by etching the ion implantation mask at least in the width direction after forming the entrance region, and the step of removing the ion implantation mask may be included after the fourth step. In this case, miniaturization of the semiconductor device and reduction in variation in characteristics of the semiconductor device can be achieved, and the number of processes can be reduced as compared with the prior art.
- the etching in the first step and the etching in the third step are each preferably performed by dry etching.
- etching in the thickness direction of the ion implantation mask tends to proceed
- ion implantation is performed. Since the etching control in the mask width direction tends to be easy, it is possible to prevent unnecessary etching of the ion implantation mask when etching the ion implantation mask.
- the semiconductor preferably has a band gap energy of 2.5 eV or more.
- a semiconductor device having a high withstand voltage and a low loss and excellent in heat resistance and environmental resistance tends to be manufactured.
- the semiconductor is mainly composed of silicon carbide.
- the activation annealing temperature after dopant implantation becomes high, the self-alignment method as in the conventional Si device cannot be used, so the present invention is particularly preferably used. be able to. The invention's effect
- FIG. 1 is a schematic cross-sectional view illustrating a part of an example of a method for manufacturing a semiconductor device of the present invention.
- FIG. 2 is a schematic cross-sectional view illustrating a part of an example of a method for manufacturing a semiconductor device of the present invention.
- FIG. 3 is a schematic cross-sectional view illustrating a part of an example of a method for manufacturing a semiconductor device of the present invention.
- FIG. 4 is a schematic cross-sectional view illustrating a part of an example of a method for manufacturing a semiconductor device of the present invention.
- FIG. 5 is a schematic cross-sectional view illustrating a part of an example of a method for manufacturing a semiconductor device of the present invention.
- FIG. 6 is a schematic cross-sectional view illustrating a part of an example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 7 is a schematic cross-sectional view illustrating a part of an example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 8 is a schematic cross-sectional view illustrating a part of an example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 9 is a schematic cross-sectional view illustrating a part of an example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 10 is a schematic cross-sectional view illustrating a part of an example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 11 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 12 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 13 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 14 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 15 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 16 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 17 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 18 is a schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 19 A schematic cross-sectional view illustrating a part of another example of the method for manufacturing a semiconductor device of the present invention.
- FIG. 20 is a schematic cross-sectional view illustrating a part of an example of a conventional method for manufacturing a SiC-MOSFET.
- FIG. 21 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- FIG. 22 is a schematic cross-sectional view illustrating a part of an example of a conventional method for manufacturing a SiC-MOSFET.
- FIG. 23 is a schematic cross-sectional view illustrating a part of an example of a conventional method for manufacturing a SiC-MOSFET.
- FIG. 24 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- FIG. 25 is a schematic cross-sectional view illustrating a part of an example of a conventional method for manufacturing a SiC-MOSFET.
- FIG. 26 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- FIG. 27 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- FIG. 28 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- FIG. 29 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- FIG. 30 is a schematic cross-sectional view illustrating a part of an example of a conventional method for producing a SiC-MOSFET.
- an n-type SiC film 102 is epitaxially grown on the surface of a SiC substrate 101 to form a wafer.
- a first ion implantation mask 103a made of tungsten is formed on the entire surface of the SiC film 102, and a second ion implantation made of silicon oxide is formed on the surface of the first ion implantation mask 103a.
- a mask 103b is formed.
- an ion implantation mask 103 composed of a stacked body of the first ion implantation mask 103a and the second ion implantation mask 103b is formed.
- the first ion implantation mask 103a made of tungsten and the second ion implantation mask 103b made of silicon oxide are each formed by, for example, a sputtering method or a CVD (Chemical Vapor D mark osition) method. Can do.
- the first ion implantation mask 103a made of tungsten is preferably formed to a thickness of 2 ⁇ m or less; more preferably, a thickness of m or less.
- the second ion implantation mask 103b made of silicon oxide is preferably formed to a thickness of 0.5 m or less, more preferably 0.3 m or less.
- a resist 104 having a predetermined opening 105 is formed on the second ion implantation mask 103b by using, for example, a photolithography technique.
- the portions of the first ion implantation mask 103a and the second ion implantation mask 103b located below the opening 105 are removed by etching in the thickness direction, and the SiC film 10 Expose part of the surface of 2.
- the resist 104 is removed and ions of an n-type dopant such as phosphorus are ion-implanted into the exposed surface of the SiC film 102 to thereby form an n-type dopant on the surface of the SiC film 102.
- Implant region 106 is formed.
- the first ion implantation mask 103a is etched in the width direction to reduce the width of the first ion implantation mask 103a.
- a region other than the region where the n-type dopant implantation region 106 is formed is exposed on the surface of the SiC film 102, and Si
- the exposed area on the surface of the C film 102 is enlarged.
- the first ion implantation mask 103a is etched more than the second ion implantation mask 103b. It is done.
- the second ion implantation mask 103 b on the first ion implantation mask 103a is removed by etching.
- an etching solution or etching gas for etching the second ion implantation mask 103b a material that etches the second ion implantation mask 103b rather than the first ion implantation mask 103a is used.
- the first ion implantation mask 103a is removed. Thereafter, the crystallinity of the wafer after the removal of the first ion implantation mask 103a is restored, and an activation canal for activating the ions of the n-type dopant and the p-type dopant that have been ion-implanted is used. Do.
- a gate oxide film 108, a source electrode 109 and a drain electrode 111 are formed on the surface of the SiC film 102, and a gate electrode 110 is formed on the surface of the gate oxide film 108.
- the SiC-MOSFET is completed by dividing the wafer into chips.
- the ion implantation mask for forming the n-type dopant implantation region can be used also for the formation of the p-type dopant implantation region, the n-type dopant is conventionally formed. Ion implantation mask for forming dopant implantation region and p-type dopant implantation region There is no need to separately form an ion implantation mask for forming the film.
- ion implantation mask 103 includes a layer made of, for example, titanium, nickel, silicon oxide, or nitride nitride between first ion implantation mask 103a made of tungsten and the surface of SiC film 102. You may go out. This is because such a layer improves the adhesion between the ion implantation mask 103 and the SiC film 102 and can also function as an etching stop layer on the surface of the SiC film 102. This layer can be formed to a thickness of, for example, lOOnm or less.
- the present invention is not limited to this configuration in which tungsten is used as the first ion implantation mask 103a and silicon oxide is used as the second ion implantation mask 103b.
- a key compound such as silicon oxide, nitride nitride, or oxynitride can be used for the first ion implantation mask 103a, and a metal such as aluminum or titanium can be used for the second ion implantation mask 103b.
- the first ion implantation mask 103a is made of a material that is harder to etch than the second ion implantation mask 103b with respect to an etching solution or etching gas for etching the second ion implantation mask 103b.
- the second ion implantation mask 103b can be used as an etching solution or etching gas for etching the first ion implantation mask 103a. Can be used.
- the first ion implantation mask 103a it is preferable to use tungsten as the first ion implantation mask 103a. It is preferable to use silicon oxide as the second ion implantation mask 103b. In this case, when the second ion implantation mask 103b that is difficult to be etched is etched, the first ion implantation mask 103a tends to be difficult to etch. Since the width of the first ion implantation mask 103a can be reduced while suppressing the decrease in thickness, the reliability of the first ion implantation mask 103a during ion implantation of the second dopant can be improved with the force S. .
- the ion implantation mask 103 is not limited to the two-layer structure described above, and may be a single layer or three or more layers.
- the selection ratio of the second ion implantation mask 103b to the first ion implantation mask 103a by the etching solution or the etching gas for etching the second ion implantation mask 103b is 2 or more.
- the etching of the second ion implantation mask 103b can be suppressed before the ion implantation of the p-type dopant, and the first ion implantation mask can be suppressed while reducing the thickness of the first ion implantation mask 103a. Since 103a can be etched in the width direction, the reliability of the first ion implantation mask 103a during p-type dopant ion implantation is improved.
- the above selection ratio is determined by etching the first ion implantation mask 103a and the second ion implantation mask 103b with an etching solution or an etching gas under the same conditions, and the etching rate of the first ion implantation mask 103a and the first ion implantation mask 103a. It can be calculated by obtaining the ratio of the etching rate of the two ion implantation mask 103b (the etching rate of the first ion implantation mask 103a / the etching rate of the second ion implantation mask 103b).
- the etching in the thickness direction of the first ion implantation mask 103a and the second ion implantation mask 103b shown in FIG. 4 is preferably performed by dry etching using an etching gas. Further, the etching in the width direction of the first ion implantation mask 103a shown in FIG. 6 is preferably performed by dry etching using a force etching gas that can be performed by wet etching using an etchant.
- etching in the thickness direction of the first ion implantation mask 103a and the second ion implantation mask 103b tends to proceed easily.
- isotropic etching is likely to proceed, and therefore, in the width direction of the first ion implantation mask 103a, compared to dry etching.
- Etching force tends to be advanced S. From the viewpoint of facilitating etching control, it is preferable to perform etching in the width direction of the first ion implantation mask 103a by dry etching using an etching gas.
- a semiconductor using SiC as the semiconductor may be a semiconductor other than SiC.
- the semiconductor for example, gallium nitride, diamond, zinc oxide, aluminum nitride, or the like can be used.
- a semiconductor having a band gap energy of 2.5 eV or more it is preferable to use.
- a semiconductor device having high withstand voltage and low loss and excellent in heat resistance and environmental resistance can be manufactured.
- an n-type SiC film 102 is epitaxially grown on the surface of the SiC substrate 101 to form a wafer.
- an ion implantation mask 103 made of tungsten is formed on the entire surface of the SiC film 102.
- a resist 104 having a predetermined opening 105 is formed on the surface of the ion implantation mask 103 by using, for example, a photolithography technique. Subsequently, as shown in FIG. 14, the portion of the implantation mask 103 located below the opening 105 is removed by etching, and a part of the surface of the SiC film 102 is exposed.
- the resist 104 is removed, and ions of an n-type dopant such as phosphorus are ion-implanted into the exposed surface of the SiC film 102 to thereby form an n-type on the surface of the SiC film 102.
- a dopant implantation region 106 is formed.
- isotropic etching of the ion implantation mask 103 is performed, and The ion implantation mask 103 is removed in the width direction to reduce the width of the ion implantation mask 103.
- a p-type dopant implantation region 107 is formed on the surface of 102.
- the ion implantation mask 103 is removed. Thereafter, activation annealing for recovering the crystallinity of the wafer after the ion implantation mask 103 is removed is performed.
- a gate oxide film 108, a source electrode 109 and a drain electrode 111 are formed on the surface of the SiC film 102, and a gate electrode 110 is formed on the surface of the gate oxide film 108.
- the SiC-MOSFET is completed by dividing the wafer into chips.
- the ion implantation mask for forming the n-type dopant implantation region can also be used for the formation of the p-type dopant implantation region, and for forming the n-type dopant implantation region. There is no need to form a separate ion implantation mask and an ion implantation mask for forming a P-type dopant implantation region.
- the resist for patterning of the ion implantation mask 103 needs to be formed only once, the number of processes can be reduced as compared with the conventional case.
- the thickness of the ion implantation mask 103 after etching shown in FIG. 16 is a certain thickness. This is because the post-etching ion implantation mask 103 shown in FIG. 16 does not function as an ion implantation mask for ion implantation, which will be described later. In this case, the p-type dopant implantation region 107 is formed even in an unnecessary portion. .
- the thickness that functions as an ion implantation mask means a thickness that is obtained by a force S that prevents implantation of 99.9% or more of ions to be implanted.
- the thickness of the ion implantation mask 103 may be reduced by X or more. After that, the thickness of the ion implantation mask 103 should be more than the thickness that functions as an ion implantation mask! /.
- the etching in the thickness direction of the ion implantation mask 103 shown in FIG. 14 is preferably performed by dry etching using an etching gas.
- the etching of the ion implantation mask 103 shown in FIG. 16 is preferably performed by dry etching using a force etching gas that can be performed by wet etching using an etchant.
- the etching gas proceeds with a certain degree of directivity toward the SiC substrate 101. Etching in the thickness direction tends to proceed easily. In addition, in wet etching using an etchant, isotropic etching is likely to proceed. Therefore, etching in the width direction of the ion implantation mask 103 tends to proceed more easily than dry etching. S, etching control From the viewpoint of facilitating the etching, it is preferable to etch the ion implantation mask 103 in the width direction by dry etching using an etching gas.
- a wafer was fabricated by epitaxially growing an n-type SiC film on the surface of the SiC substrate. did.
- the epitaxially grown n-type SiC film had a thickness of 10 m, and the n-type dopant concentration was 1 ⁇ 10 15 cm ⁇ 3 .
- a first ion implantation mask made of tungsten is formed by sputtering on the entire surface of the SiC film, and a second ion implantation mask made of silicon oxide is formed by sputtering on the first ion implantation mask.
- the thickness of the first ion implantation mask was 800 nm
- the thickness of the second ion implantation mask was lOOnm.
- a resist patterned to have an opening at the location where the n-type dopant implantation region is to be formed was formed on the second ion implantation mask.
- the second ion implantation mask of the portion to be exposed is CF gas.
- the surface of the SiC film located below the opening of the dies was exposed.
- the CF gas is made of silicon oxide rather than the first ion implantation mask made of tungsten.
- etching gas for greatly etching the second ion implantation mask.
- SF gas is used for the first ion made of tungsten rather than the second ion implantation mask made of silicon oxide.
- the resist was removed, and phosphorus ions were implanted into the exposed surface of the SiC film, thereby forming an n-type dopant implantation region on a part of the surface of the SiC film.
- the n-type dopant implantation region was formed by implanting phosphorus ions under the condition of a dose of 1 ⁇ 10 15 cm ⁇ 2 .
- the side surface of the first ion implantation mask made of tungsten is made to have a thickness of 0.5 ⁇ ⁇ ⁇ by immersing in an etching solution made of a mixed solution of an aqueous ammonia solution and a hydrogen peroxide solution for 2 minutes. Etching was performed in the width direction. As a result, a region other than the region where the ⁇ -type dopant implantation region was formed was exposed on the surface of the SiC film.
- an etching solution made of a mixed solution of an aqueous ammonia solution and a hydrogen peroxide solution etches the first ion implantation mask made of tungsten larger than the second ion implantation mask made of oxide silicon.
- Etching solution etches the second ion implantation mask made of silicon oxide.
- notched hydrofluoric acid is an etching solution that etches the second ion implantation mask made of silicon oxide more than the first ion implantation mask made of tungsten.
- a p-type dopant implantation region was formed on the surface of the SiC film by implanting aluminum ions into the surface of the exposed SiC film.
- the p-type dopant implantation region is formed by implanting aluminum ions under the condition of a dose amount of 1 ⁇ 10 14 cm ⁇ 2 .
- the first ion implantation mask made of tungsten was completely removed by etching using an etching solution made of a mixed solution of an ammonia aqueous solution and a hydrogen peroxide solution. After that, the wafer was heated to 1700 ° C for activation annealing to restore crystallinity and to activate the ion-implanted dopant.
- a gate oxide film made of silicon oxide was formed to a thickness of 100 ⁇ m on the surface of the SiC film by a thermal oxidation method.
- a source electrode and a drain electrode are formed, and further, a gate electrode is formed on the surface of the gate oxide film, and then the wafer is divided into chips to obtain SiC-MOS.
- a wafer was fabricated by epitaxially growing an n-type SiC film on the surface of a SiC substrate.
- the epitaxially grown n-type SiC film had a thickness of 10 m, and the n-type dopant concentration was 1 ⁇ 10 15 cm ⁇ 3 .
- an ion implantation mask made of tungsten was formed on the entire surface of the SiC film with a thickness of 1600 by sputtering.
- a resist patterned to have an opening at a position where an n-type dopant implantation region is to be formed was formed on the ion implantation mask.
- the resist was removed, and phosphorus ions were ion-implanted into the exposed surface of the SiC film, thereby forming an n-type dopant implantation region on a part of the surface of the SiC film.
- the n-type dopant implantation region was formed by implanting phosphorus ions under the condition of a dose of 1 ⁇ 10 15 cm ⁇ 2 .
- a p-type dopant implantation region was formed on the surface of the SiC film by implanting aluminum ions into the surface of the exposed SiC film.
- the p-type dopant implantation region is formed by implanting aluminum ions under the condition of a dose amount of 1 ⁇ 10 14 cm ⁇ 2 . It was 800nm. Therefore, it was confirmed that the ion implantation mask after the dry etching had a sufficient thickness.
- the ion implantation mask made of tungsten was completely removed by etching using an etching solution made of a mixed solution of an ammonia aqueous solution and a hydrogen peroxide solution. afterwards
- the wafer was heated to 1700 ° C for activation annealing to restore crystallinity and to activate the ion-implanted dopant.
- a gate oxide film made of silicon oxide was formed to a thickness of 100 ⁇ m on the surface of the SiC film by a thermal oxidation method.
- a source electrode and a drain electrode were formed. Further, after forming a gate electrode on the surface of the gate oxide film, the wafer was divided into chips to complete a SiC-MOS FET.
- the manufacturing method of the semiconductor device which can reduce the dispersion
Landscapes
- Electrodes Of Semiconductors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
- Drying Of Semiconductors (AREA)
- Bipolar Transistors (AREA)
- Junction Field-Effect Transistors (AREA)
- Formation Of Insulating Films (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002672259A CA2672259A1 (en) | 2006-12-13 | 2007-11-29 | Method of manufacturing semiconductor device |
| US12/517,735 US20100035420A1 (en) | 2006-12-13 | 2007-11-29 | Method of manufacturing semiconductor device |
| EP07832793A EP2092552A4 (en) | 2006-12-13 | 2007-11-29 | MANUFACTURING METHOD FOR SEMICONDUCTOR COMPONENTS |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006336000A JP2008147576A (ja) | 2006-12-13 | 2006-12-13 | 半導体装置の製造方法 |
| JP2006-336000 | 2006-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008072482A1 true WO2008072482A1 (ja) | 2008-06-19 |
Family
ID=39511506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/073078 Ceased WO2008072482A1 (ja) | 2006-12-13 | 2007-11-29 | 半導体装置の製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20100035420A1 (ja) |
| EP (1) | EP2092552A4 (ja) |
| JP (1) | JP2008147576A (ja) |
| KR (1) | KR20090098832A (ja) |
| CN (1) | CN101558475A (ja) |
| CA (1) | CA2672259A1 (ja) |
| TW (1) | TW200842952A (ja) |
| WO (1) | WO2008072482A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012060248A1 (ja) * | 2010-11-01 | 2012-05-10 | 住友電気工業株式会社 | 半導体装置およびその製造方法 |
| EP2497116A4 (en) * | 2009-11-03 | 2014-06-18 | Cree Inc | SEMICONDUCTOR SIGNALING DEVICES WITH SELECTIVELY DOCKED JFET REGIONS AND CORRESPONDING METHOD FOR FORMING SUCH DEVICES |
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| JP5564890B2 (ja) | 2008-12-16 | 2014-08-06 | 住友電気工業株式会社 | 接合型電界効果トランジスタおよびその製造方法 |
| US8350365B1 (en) * | 2011-01-13 | 2013-01-08 | Xilinx, Inc. | Mitigation of well proximity effect in integrated circuits |
| KR20130139738A (ko) | 2011-01-17 | 2013-12-23 | 스미토모덴키고교가부시키가이샤 | 탄화규소 반도체 장치의 제조방법 |
| JP5883563B2 (ja) | 2011-01-31 | 2016-03-15 | ルネサスエレクトロニクス株式会社 | 半導体装置の製造方法 |
| JP2013021219A (ja) * | 2011-07-13 | 2013-01-31 | Shindengen Electric Mfg Co Ltd | 半導体装置およびその製造方法 |
| JP2013021242A (ja) * | 2011-07-14 | 2013-01-31 | Sumitomo Electric Ind Ltd | 半導体装置の製造方法 |
| CN102507704A (zh) * | 2011-10-18 | 2012-06-20 | 重庆邮电大学 | 基于碳化硅的肖特基势垒二极管氧传感器及制造方法 |
| CN102496559A (zh) * | 2011-11-25 | 2012-06-13 | 中国科学院微电子研究所 | 一种三层复合离子注入阻挡层及其制备、去除方法 |
| EP3176812A1 (en) * | 2015-12-02 | 2017-06-07 | ABB Schweiz AG | Semiconductor device and method for manufacturing such a semiconductor device |
| JP7187808B2 (ja) * | 2018-04-12 | 2022-12-13 | 富士電機株式会社 | 窒化物半導体装置および窒化物半導体装置の製造方法 |
| US10937869B2 (en) * | 2018-09-28 | 2021-03-02 | General Electric Company | Systems and methods of masking during high-energy implantation when fabricating wide band gap semiconductor devices |
| CN109309009B (zh) * | 2018-11-21 | 2020-12-11 | 长江存储科技有限责任公司 | 一种半导体器件及其制造方法 |
| CN114628416B (zh) * | 2020-12-11 | 2026-03-03 | 联合微电子中心有限责任公司 | 一种cmos图像传感器制作方法 |
| CN115020239A (zh) * | 2022-06-30 | 2022-09-06 | 鸿海精密工业股份有限公司 | 半导体装置与其制造方法 |
| CN116504612B (zh) * | 2023-02-09 | 2023-11-21 | 长鑫存储技术有限公司 | 半导体结构及其形成方法 |
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- 2007-11-29 KR KR1020097012675A patent/KR20090098832A/ko not_active Ceased
- 2007-11-29 WO PCT/JP2007/073078 patent/WO2008072482A1/ja not_active Ceased
- 2007-11-29 US US12/517,735 patent/US20100035420A1/en not_active Abandoned
- 2007-11-29 CN CNA2007800462579A patent/CN101558475A/zh active Pending
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- 2007-12-05 TW TW096146359A patent/TW200842952A/zh unknown
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2497116A4 (en) * | 2009-11-03 | 2014-06-18 | Cree Inc | SEMICONDUCTOR SIGNALING DEVICES WITH SELECTIVELY DOCKED JFET REGIONS AND CORRESPONDING METHOD FOR FORMING SUCH DEVICES |
| WO2012060248A1 (ja) * | 2010-11-01 | 2012-05-10 | 住友電気工業株式会社 | 半導体装置およびその製造方法 |
| JP2012099601A (ja) * | 2010-11-01 | 2012-05-24 | Sumitomo Electric Ind Ltd | 半導体装置およびその製造方法 |
| US9006745B2 (en) | 2010-11-01 | 2015-04-14 | Sumitomo Electric Industries, Ltd. | Semiconductor device and fabrication method thereof |
| US9443960B2 (en) | 2010-11-01 | 2016-09-13 | Sumitomo Electric Industries, Ltd. | Semiconductor device and fabrication method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008147576A (ja) | 2008-06-26 |
| KR20090098832A (ko) | 2009-09-17 |
| US20100035420A1 (en) | 2010-02-11 |
| CN101558475A (zh) | 2009-10-14 |
| TW200842952A (en) | 2008-11-01 |
| CA2672259A1 (en) | 2008-06-19 |
| EP2092552A1 (en) | 2009-08-26 |
| EP2092552A4 (en) | 2010-12-01 |
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