WO2008127084A2 - Un tubo de acero sin costura para la aplicación como columnas ascendientes de work-over y método para fabricar el mismo - Google Patents
Un tubo de acero sin costura para la aplicación como columnas ascendientes de work-over y método para fabricar el mismo Download PDFInfo
- Publication number
- WO2008127084A2 WO2008127084A2 PCT/MX2008/000054 MX2008000054W WO2008127084A2 WO 2008127084 A2 WO2008127084 A2 WO 2008127084A2 MX 2008000054 W MX2008000054 W MX 2008000054W WO 2008127084 A2 WO2008127084 A2 WO 2008127084A2
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- WO
- WIPO (PCT)
- Prior art keywords
- max
- tube
- test
- tempered
- seamless steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
- C21D9/085—Cooling or quenching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B17/00—Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
- E21B17/01—Risers
Definitions
- This invention relates to a seamless steel tube for risers (rising columns) used in conditioning operations.
- the requirements to operate a well on the seabed involve a plurality of systems and equipment that includes risers (ascending columns) for drilling, production and conditioning.
- a riser (ascending column) for drilling is a pipe between a seabed anti-suppression device (BOP) and a floating drilling carriage that is a drilling unit not permanently fixed to the seabed as a drilling unit, a semi-submersible unit or a unit of cats. It is assumed that the floating drilling car is the mobile arm crane and its associated machinery.
- BOP seabed anti-suppression device
- a production riser (rising column) is a pipeline that transports oil or gas that joins a marine wellhead to a production platform or a tank loading platform.
- a riser (ascending column) for conditioning is a flow line that is used to perform a well conditioning, which is done in an existing well and may involve re-evaluating the production formation, cleaning the sand of the production areas, jetting, replacement of equipment at the bottom of the well, deepening wells, acidification or fracturing or improvement of the impulse mechanism.
- the pipes need to have a good welding performance to be welded to welded connectors to build the column.
- a first object of the invention is to provide a seamless access pipe that will be used as a riser (ascending column) in conditioning operations with a specific chemical design and microstructure consisting of a geometry in which the ends of the tube have a increased wall thickness and external diameter to reduce the weight of the riser column (ascending column).
- a second object will provide a seamless steel tube for the application as a riser (ascending column) of conditioning with a specific chemistry design and a microstructure consisting of a geometry in which the ends of the tube have a wall thickness and an increased external diameter to reduce bending loads at the head of the well and at the interface of the platform.
- a third object of the invention is to provide a method for manufacturing a seamless steel tube for Ia application as a riser (ascending column) of conditioning with a specific chemical design and microstructure consisting of a geometry in which the ends of the tube have an increased wall thickness and an external diameter using alteration techniques.
- a fourth object of the invention is to provide a method for manufacturing a seamless steel tube for the application as a riser (ascending column) of conditioning with a specific chemical design and microstructure consisting of a geometry in which the ends of the tube have a wall thickness and external diameter increased using machining techniques.
- a fifth object of the invention is to provide a method for manufacturing a seamless steel tube for application as a riser (ascending column) of conditioning with a specific chemical design and microstructure consisting of a geometry in which the ends of the tube have a increased wall thickness and external diameter capable of guaranteeing the mechanical characteristics to have a high resistance to wear and corrosion and good welding performance.
- Figure 1 illustrates a preferred embodiment of the riser (ascending column) for conditioning the present invention with pointed ends.
- Figure 2 shows a graphical representation of the results of the Tensile Test (YS and UTS) of the sections of the stressed pipe body of the material in the tempering and tempering condition of the different industrial tests.
- Figure 3 shows a graphical representation of the HRC hardness values of the body sections of cutlery and highlighting that show the achievement of the minimum percentage of martensitic transformation of the material in the temperate condition of the production of both dimensions.
- Figures 4 and 5 show a graphical representation of the HRC hardness values of the rework sections and pipe body that show the dispersion of individual hardness readings as a function of the location across the thickness (OD, MW & ID) of the material in the condition of overheating of the production of the WT dimension of 7 "OD x 17.5 mm WT and the WT dimension of 8 5/8" OD x 15.9mm, respectively.
- Figure 6 shows the graphic representation of the results of the CVN cross-sectional impact test at -20 ° C from the highlighting and tube body sections of Ia production of both dimensions that show the dispersion of individual hardness values according to the specification of the material in the temperate condition.
- Figure 7 shows the austenitic grain size reported in ASTM 9/10 in the tube body and ASTM 8/9 at the stressed end.
- Figure 8 shows photomicrographs in cross-section showing a microstructure constituted by martensite through the wall thickness of the section of the body of the tube of tempered material for Nital 2% in magnification at 300X.
- Figure 9 shows cross-sectional photomicrographs showing a microstructure consisting of martensite at the pointed end of the 2% Nital tempered material in 300X magnification.
- Figure 10 shows cross-sectional photomicrographs, showing a microstructure consisting of tempered martensite in the body of the tempered and tempered tube for 2% Nital in magnification of 300X.
- Figure 10 shows cross-sectional photomicrographs, showing a microstructure consisting of tempered martensite at the stressed end of the tempered and tempered material for 2% Nital in 300X magnification.
- Figure 12 shows microstructural observations of tempered material in the mechanized body of the tube and the end areas that relieve an austenitic grain size of 8/9 in both zones measured by the saturation method according to ASTM E-112.
- Figure 13 shows cross-sectional photomicrographs showing a microstructure constituted by martensite through the wall thickness of the body section of the machined tube of tempered material for Nital 2% in magnification at 300X.
- Figure 14 shows photomicrographs in cross-section showing a microstructure constituted by martensite through the wall thickness of the end section of the tube of tempered material for Nital 2% in magnification at 300X.
- Figure 15 shows cross-sectional photomicrographs showing a microstructure constituted by tempered martensite through the thickness of the tempered and tempered pipe body section for 2% of Nital in magnification at 300X.
- Figure 16 shows cross-sectional photomicrographs showing a microstructure constituted by tempered martensite through the thickness of the pipe end section of tempered and tempered material for 2% Nital in magnification at 300X.
- the present invention describes a seamless steel tube to be used as a riser (rising column) in conditioning operations with a specific chemical design and a microstructure consisting of a geometry in which the ends of the tube have a wall thickness and external diameter increased.
- the alloy design is based on high strength requirements.
- the main characteristics of the chemical composition of the tube include 0.23-0.28% by weight of Carbon, 0.45 -0.65% by weight of Mn, and other alloy elements such as Mo, and Cr to achieve the required percentage of martensitic transformation.
- microalloy element such as Ti and Nb are used as grain refiners.
- the low content of residual elements such as S and residual elements such as Cu and P are used to avoid the corrosion problem related to the promotion of inclusions and segregation in grain boundaries that decrease the corrosion performance, the hydrogen content was maintained by below 2.4 ppm to avoid any problem related to the inclusion of hydrogen and the decrease in corrosion performance.
- the production route to manufacture the seamless seamless pipe for the application of the riser (rising column) Conditioning includes the following steps: steel molding (continuous molding bar, pipe lamination without sewing (MPM process), highlighting of pipe ends, heat treatment, destructive tests (including microlleaning, austenitic grain size, calculation of the percentage of martensitic transformation, tensile tests, hardness, resistance, SSC), dimensional control of the body of pipe and pointed ends (external diameter, roundness defect, eccentricity, straight edge, internal diameter, length), external and internal highlighting end machining, dimensional control (internal diameter, external diameter and machining length), drag tests at the ends of highlighting, non-destructive tests (NDT) of ends of highlighting, weight, measurement and marking, visual inspection of external surface, UT inspection of the tube body and UT inspection of the stressed ends (cylindrical section only).
- the production route for manufacturing the seamless machining pipe for the application of riser (rising column) Conditioning includes the following steps: steel molding (continuous molding bar), seamless pipe rolling (MPM process), treatment thermal, destructive tests (including microlleaning, austenitic grain size, calculation of the percentage of martensitic transformation, tensile tests, hardness, resistance, SSC), dimensional control of the pipe body (external diameter, roundness defect, straightness in edges, diameter internal, length), machining of the external surface of the entire length of the pipe when programming the CNC lattice machine in order to achieve the final dimensions at the ends, dimensional control (internal diameter, external diameter, roundness defect, straightness in edges and long itud) of the pipe body and machining ends, drag tests at the ends, non-destructive tests (NDT) of ends, weight, measurement and marking, visual inspection of external surface, UT inspection of machined tube body e UT end inspection (cylindrical section only).
- the present invention comprises percentage by weight: carbon 0.23-0.29, manganese 0.45-0.65, silicone 0.1 5-0.35, chromium 0.90-1 .20, ibidine mol 0.70-0.90, ID No. 0.20 max, nitrogen 0.01 0 max, boron 0.0010 -0.0030, alum inio 0.010-0.045, sulfur 0.005 max, phosphorus 0.01 5 max, titanium 0.005-0.030, niobium 0.020- 0.035, copper 0.15 max, arsenic 0.020 max, calcium 0.0040 max, tin 0.020 max, hydrogen 2.4 ppm max, the rest are iron and inevitable impurities.
- a more preferred composition comprises: carbon 0.25-0.28, manganese 0.48-0.58, silicone 0.20-0.30, chromium 1.05-1.15, molybdenum 0.80-0.83, nickel 0.10 max, nitrogen 0.008 max, boron 0.0016-0.0026, aluminum 0.015-0.045, sulfur 0.0030 max, phosphorus 0.010 max, titanium 0.016-0.026, niobium 0.025-0.030, copper 0.10 max, arsenic 0.020 max, calcium 0.0040 max, tin 0.015 max, hydrogen 2.0 ppm max, the rest are iron and inevitable impurities.
- Seamless steel tubes have a geometry, in which the ends of the tubes have an increased wall thickness and external diameter, and the following mechanical properties:
- API 5CT means average per row
- the geometry of the seamless steel tube of the present invention and the mechanical characteristics are obtained by two manufacturing methods: highlighting and machining.
- the method of highlighting manufacturing comprises the following steps:
- (a) provide a steel tube containing a composition in percentage by weight of carbon 0.23-0.29, manganese 0.45-0.65, silicone 0.15-0.35, chromium 0.90-1.20, molybdenum 0.70-0.090, nickel 0.20 max, nitrogen 0.010 max, boron 0.0010-0.0030, aluminum 0.010-0.045, sulfur 0.005 max, phosphorus 0.015 max, titanium 0.005-0.030, niobium 0.020-0.035, copper 0.15 max, arsenic 0.020, calcium 0.0040 max, tin 0.020 max, hydrogen 2.4 ppm max, the rest are iron and inevitable impurities, obtained by the rolling process (MPM process);
- the method of manufacturing upsetting comprises the following steps: (a) provide a steel tube containing a composition in percentage by weight of carbon 0.23-0.29, manganese 0.45-0.65, silicone 0.15-0.35, chromium 0.90-1.20, molybdenum 0.70 - 0.90, nickel 0.20 max, nitrogen 0.010 max, boron 0.0010-0.0030, aluminum 0.010-0.045, sulfur 0.005 max, phosphorus 0.015 max, titanium 0.005-0.030, niobium 0.020-0.035, copper 0.15 max, arsenic 0.020, calcium 0.0040 max, tin 0.020 max, hydrogen 2.4 ppm max, the rest are iron and unavoidable impurities, obtained by the rolling process (MPM process); (b) heat treatment of pipes (austenitization between
- NDT non-destructive tests
- Both methods are also performed by providing a seamless steel pipe with the preferred composition, as disclosed above.
- the seamless steel pipe of the present invention can be divided into two zones. As shown in Figure
- both the entire tube body and the ends have the same elasticity limit of at least 620 MPa (90 ksi) (YS) and at much
- the pipes can be used in corrosive and non-corrosive service.
- the nominal diameter of the tubes that are going to be stressed ends can be from 414 "up to 10%”.
- the thickness of the tubes varies from 10 mm to 50 mm.
- the highlighting manufacturing operation was carried out following the steps of: a) The pipe ends in the rolled up condition were heated to the suitable floor temperature by heating the calculated pipe length. The highlighting operation occurs at a minimum temperature of 1000 c C; b) Once the heating cycle was achieved, the pipe ends were emphasized with the appropriate die and design. tools for each particular dimension; c) Then, the inspection of surfaces of external and internal pipes was made after each stroke in order to find any possible defect generated by the highlighting operation.
- the heating cuvette was designed to be used during the heat treatment process in the ustenitization furnace (860-940 0 C) and the tempering furnace (640-720 0 C) for the ends Highlights of the 8 5/8 "OD product.
- the pipe After the austenitization heat treatment process, the pipe must enter the tempering process above AC3 to guarantee the transformation through the guaranteed wall. Then, for the product 7 "OD, a few heat treatment adjustments were made in the heating curves based on the results obtained from the other OD 5 8/8" pipe.
- the actual temperatures of the pipe body and external surface of the highlighting ends were carefully measured through the test stages just at the entrance of the pipes into the tempering head using a manual pyrometer in addition to the oven pyrometers.
- Austenitic grain size in tempered material was measured by the saturation method according to ASTM E-112. As shown in Figure 6, the grain size reported in the samples was 9/10 in the body of the pipe which was above the required size because the minimum required was 5. The highlighting samples showed a grain size of 8/9 and 9/10 complying with the specifications illustrated in Figure 6.
- the transverse side of the winding axis was prepared metallographically and recorded with Nital 2% to perform microstructural observations with an optical microscope. (Nital: 2% solution of nitric acid in ethyl alcohol).
- Nital 2% solution of nitric acid in ethyl alcohol.
- a martensitic structure was observed in OD, ID and MW sections through the thickness, achieving a martensitic transformation of more than 90% measured from the HRC hardness values as shown in Figures 8 and 9.
- a microstructure consisting of tempered martensite was observed through the thickness as shown in Figures 10 and 11.
- the microstructures observed in the tempered material were mainly martensitic with a martensitic transformation of more than 95% throughout the entire thickness of the pipe both in the pipe body and the highlighting, which indicates that the temperature at which the pipe entered the tempering stage and the tempering itself were homogeneous.
- the microstructures observed in the tempered material the tempered martensite was present through the thickness.
- the material passed the A test of the SSC Method at 85% SMYS according to NACE TM0177-96 reaching 720 hours.
- the pipe was laminated in a heavy wall condition.
- the thickness of the wall was approximately 44 mm. After rolling, the heat treatment is performed.
- Example 1 The dimensional control of the external diameter (OD), roundness defect, internal diameter (ID) and the length of pipes was performed after the UT inspection.
- the entire length of the pipe body was machined from the external surface Ia to program the CNC lattice machine.
- Example 1 a mechanical characterization was performed, calculating the percentage of martensitic transformation from the tempered material.
- microstructural observations of tempered material in the mechanized body of the tube and the end areas reveal an austenitic grain size of 8/9 in both areas measured by the saturation method according to ASTM E-112.
- the modified end of the analyzed sample showed a grain size of 8/9 complying with the specifications as shown in Figure 12.
- the transverse side of the rolling axis was prepared in a metallographic manner and recorded with Nital 2% to perform microstructural observations with an optical microscope. (Nital: 2% solution of nitric acid in ethyl alcohol).
- the material passed the A test of the SSC method to 85% SMYS according to NACE TM0177-2005 achieving 720 hours.
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Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002682959A CA2682959A1 (en) | 2007-04-17 | 2008-04-17 | A seamless steel tube for the application as work-over riser |
| EP08753716A EP2143817A2 (en) | 2007-04-17 | 2008-04-17 | A seamless steel tube for work-over riser and method of manufacturing |
| US12/595,167 US20100193085A1 (en) | 2007-04-17 | 2008-04-17 | Seamless steel pipe for use as vertical work-over sections |
| BRPI0810005A BRPI0810005A2 (pt) | 2007-04-17 | 2008-04-17 | tubo de aço sem costura para risers de acomodamento e método para fabricar o mesmo |
| NO20093069A NO20093069L (no) | 2007-04-17 | 2009-09-28 | Et somlost stalror for en ettermater og metode for fremstilling av dette. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX2007004600A MX2007004600A (es) | 2007-04-17 | 2007-04-17 | Un tubo sin costura para la aplicación como secciones verticales de work-over. |
| MXMX/A/2007/004600 | 2007-04-17 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO2008127084A2 true WO2008127084A2 (es) | 2008-10-23 |
| WO2008127084A3 WO2008127084A3 (es) | 2008-12-31 |
| WO2008127084A4 WO2008127084A4 (es) | 2009-03-19 |
Family
ID=39673395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/MX2008/000054 Ceased WO2008127084A2 (es) | 2007-04-17 | 2008-04-17 | Un tubo de acero sin costura para la aplicación como columnas ascendientes de work-over y método para fabricar el mismo |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20100193085A1 (es) |
| EP (1) | EP2143817A2 (es) |
| AR (1) | AR066080A1 (es) |
| BR (1) | BRPI0810005A2 (es) |
| CA (1) | CA2682959A1 (es) |
| MX (1) | MX2007004600A (es) |
| NO (1) | NO20093069L (es) |
| WO (1) | WO2008127084A2 (es) |
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| US8002910B2 (en) | 2003-04-25 | 2011-08-23 | Tubos De Acero De Mexico S.A. | Seamless steel tube which is intended to be used as a guide pipe and production method thereof |
| US8007603B2 (en) | 2005-08-04 | 2011-08-30 | Tenaris Connections Limited | High-strength steel for seamless, weldable steel pipes |
| US8221562B2 (en) | 2008-11-25 | 2012-07-17 | Maverick Tube, Llc | Compact strip or thin slab processing of boron/titanium steels |
| US8328960B2 (en) | 2007-11-19 | 2012-12-11 | Tenaris Connections Limited | High strength bainitic steel for OCTG applications |
| US8328958B2 (en) | 2007-07-06 | 2012-12-11 | Tenaris Connections Limited | Steels for sour service environments |
| US8414715B2 (en) | 2011-02-18 | 2013-04-09 | Siderca S.A.I.C. | Method of making ultra high strength steel having good toughness |
| US8636856B2 (en) | 2011-02-18 | 2014-01-28 | Siderca S.A.I.C. | High strength steel having good toughness |
| US8821653B2 (en) | 2011-02-07 | 2014-09-02 | Dalmine S.P.A. | Heavy wall steel pipes with excellent toughness at low temperature and sulfide stress corrosion cracking resistance |
| US8926771B2 (en) | 2006-06-29 | 2015-01-06 | Tenaris Connections Limited | Seamless precision steel tubes with improved isotropic toughness at low temperature for hydraulic cylinders and process for obtaining the same |
| AU2013253775B2 (en) * | 2012-04-27 | 2015-10-15 | Nippon Steel Corporation | Seamless steel pipe and method for producing the same |
| US9187811B2 (en) | 2013-03-11 | 2015-11-17 | Tenaris Connections Limited | Low-carbon chromium steel having reduced vanadium and high corrosion resistance, and methods of manufacturing |
| US9340847B2 (en) | 2012-04-10 | 2016-05-17 | Tenaris Connections Limited | Methods of manufacturing steel tubes for drilling rods with improved mechanical properties, and rods made by the same |
| US9598746B2 (en) | 2011-02-07 | 2017-03-21 | Dalmine S.P.A. | High strength steel pipes with excellent toughness at low temperature and sulfide stress corrosion cracking resistance |
| US9644248B2 (en) | 2013-04-08 | 2017-05-09 | Dalmine S.P.A. | Heavy wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes |
| US9657365B2 (en) | 2013-04-08 | 2017-05-23 | Dalmine S.P.A. | High strength medium wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes |
| US9803256B2 (en) | 2013-03-14 | 2017-10-31 | Tenaris Coiled Tubes, Llc | High performance material for coiled tubing applications and the method of producing the same |
| US9970242B2 (en) | 2013-01-11 | 2018-05-15 | Tenaris Connections B.V. | Galling resistant drill pipe tool joint and corresponding drill pipe |
| US10844669B2 (en) | 2009-11-24 | 2020-11-24 | Tenaris Connections B.V. | Threaded joint sealed to internal and external pressures |
| US11105501B2 (en) | 2013-06-25 | 2021-08-31 | Tenaris Connections B.V. | High-chromium heat-resistant steel |
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| US20100319814A1 (en) * | 2009-06-17 | 2010-12-23 | Teresa Estela Perez | Bainitic steels with boron |
| RU2464327C1 (ru) * | 2011-07-27 | 2012-10-20 | ООО "Компания ИжТехМаш" | Способ изготовления трубы для технологических нужд нефтяных скважин |
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| US8926771B2 (en) | 2006-06-29 | 2015-01-06 | Tenaris Connections Limited | Seamless precision steel tubes with improved isotropic toughness at low temperature for hydraulic cylinders and process for obtaining the same |
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| US8221562B2 (en) | 2008-11-25 | 2012-07-17 | Maverick Tube, Llc | Compact strip or thin slab processing of boron/titanium steels |
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| US9644248B2 (en) | 2013-04-08 | 2017-05-09 | Dalmine S.P.A. | Heavy wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes |
| US9657365B2 (en) | 2013-04-08 | 2017-05-23 | Dalmine S.P.A. | High strength medium wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes |
| US11105501B2 (en) | 2013-06-25 | 2021-08-31 | Tenaris Connections B.V. | High-chromium heat-resistant steel |
| US12129533B2 (en) | 2015-04-14 | 2024-10-29 | Tenaris Connections B.V. | Ultra-fine grained steels having corrosion- fatigue resistance |
| US11124852B2 (en) | 2016-08-12 | 2021-09-21 | Tenaris Coiled Tubes, Llc | Method and system for manufacturing coiled tubing |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0810005A2 (pt) | 2015-10-27 |
| MX2007004600A (es) | 2008-12-01 |
| AR066080A1 (es) | 2009-07-22 |
| US20100193085A1 (en) | 2010-08-05 |
| EP2143817A2 (en) | 2010-01-13 |
| WO2008127084A4 (es) | 2009-03-19 |
| CA2682959A1 (en) | 2008-10-23 |
| NO20093069L (no) | 2009-12-30 |
| WO2008127084A3 (es) | 2008-12-31 |
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