WO2009107687A1 - Composition adhésive sensible à la pression pour piéger de petits organismes - Google Patents

Composition adhésive sensible à la pression pour piéger de petits organismes Download PDF

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Publication number
WO2009107687A1
WO2009107687A1 PCT/JP2009/053467 JP2009053467W WO2009107687A1 WO 2009107687 A1 WO2009107687 A1 WO 2009107687A1 JP 2009053467 W JP2009053467 W JP 2009053467W WO 2009107687 A1 WO2009107687 A1 WO 2009107687A1
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WO
WIPO (PCT)
Prior art keywords
adhesive composition
mass
pressure
composition
small organisms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2009/053467
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English (en)
Japanese (ja)
Inventor
伊田領二
合志義広
佐藤浩一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Priority to CN2009801066484A priority Critical patent/CN101959986B/zh
Publication of WO2009107687A1 publication Critical patent/WO2009107687A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

Definitions

  • the present invention relates to an adhesive composition suitable for capturing small organisms such as mice, cockroaches and flies.
  • Exterminating harmful small organisms such as rats, cockroaches and flies is an important issue from the viewpoint of improving the living environment.
  • the damage caused by rodents is enormous.
  • rats can eat not only agricultural products and food, but also lead to gas leaks by breaking lead pipes, and can cause fires by exposing power lines.
  • Several methods have been proposed and implemented to combat these small organisms. The simplest of these methods is to use sticky capture agents such as cardboard, cardboard, wood board, and plastic foam.
  • There is a method of applying to the material to be coated such as film, sheet, etc. and installing it in the passage of small organisms. In this case, it is necessary to satisfy the requirement that the scavenger is excellent in application workability and adhesiveness.
  • the trapping agent when pre-applied to the material to be coated, etc., the trapping agent may flow out of the material to be coated during storage or use, or may penetrate and ooze out from the material to be coated and cannot be used. There should be no such thing as becoming or soiling the floor.
  • a composition comprising 86% polybutene, 10% butyl rubber and 4% paraffin as an anti-sagging agent (Patent Document 1), 80 parts polybutene, 10 parts butyl rubber and rosin A composition comprising 40 parts of silica gel, polyethylene (Patent Document 2), polyisobutene (viscosity at 100 ° C.
  • Patent Document 3 Patent Document 4
  • Patent Document 5 also butyl rubber 5 mass 0/0, polybutene 3 5 mass 0/0, and mouth gin esters, toluene, xylene such as six 0 mass 0/0 than made composition
  • polybutene 8 0 mass 0/0, butyl rubber 1 6 mass%, and polyethylene 4 consisting wt% composition Patent Document 6
  • the mixture 8 0-9 8 liquid polybutene two ⁇ different molecular weight mass Patent Document 6
  • a composition comprising butyl rubber, polybutene, rosin ester, toluene, and xylene has a problem of odor because it uses a volatile aromatic solvent. Furthermore, the coating film coated with the adhesive composition is installed for capturing small organisms, and the solvent is volatilized over a long period of time, the coating film is cured, and the capture capability is inevitably reduced. In addition, a composition comprising polybutene, butyl rubber and polyethylene cannot satisfy both the tackiness of the tacky composition and the workability during the coating operation.
  • the one using polyisobutylene rubber disclosed in Japanese Patent Application Laid-Open No. 2 0 0 7-1 7 7 1 0 4 has excellent adhesion, but the molecular weight of polyisobutylene rubber is very large. It has the disadvantage that it takes time to knead and dissolve in polybutene.
  • polyisobutylene rubber has a limited supply source and is expensive. There is a problem with stable supply.
  • the use of two types of liquid polybutene is very labor-intensive.
  • Patent Document 1 Japanese Patent Publication No. 48-16617
  • Patent Document 2 JP-A 52-105217
  • Patent Document 3 Japanese Patent Application Laid-Open No. 51-125123
  • Patent Document 4 Japanese Patent Publication No. 53-18586
  • Patent Document 5 Japanese Patent Laid-Open No. 52-98161
  • Patent Document 6 Japanese Patent Publication No. 2-57521
  • Patent Document 7 Japanese Unexamined Patent Publication No. 2007-177104 Disclosure of Invention
  • An object of the present invention is excellent in tackiness for capturing small organisms, excellent in workability during the production of the adhesive composition or in the application work of the produced adhesive composition, and moreover, after application It is an object of the present invention to provide an adhesive composition for capturing small organisms that has excellent performance in response to various demands such as no flow-out of an adhesive composition, is easy to obtain raw materials, and is inexpensive.
  • the present invention is a.
  • the present invention relates to an adhesive composition for capturing small organisms, characterized by comprising 5 to 29% by mass of an alicyclic hydrocarbon resin (the total is 100% by mass).
  • an alicyclic hydrocarbon resin to a composition comprising liquid polybutene, polyethylene, and butyl rubber, conventional polybutene, Compared to compositions composed of ethylene, butyl rubber, rosin or silica gel, it has superior adhesion to small organisms, excellent workability during manufacturing and application of adhesive composition, and adhesion after application It is possible to provide a sticky composition for capturing small organisms which is free from defects such as flowing out of the composition, inexpensive and has excellent performance.
  • the (A) liquid polybutene used in the present invention has a number average molecular weight in the range of 2100 to 1200. A more preferred range of number average molecular weight is from 400 to 120.
  • This liquid polybutene can be produced, for example, by polymerizing a butane-butene fraction excluding butadiene in a so-called C4 fraction produced by naphtha decomposition.
  • These polybutenes are commercially available, for example, under the trade name Nisseki Polybutene (Shin Nippon Oil Co., Ltd.).
  • the number average molecular weight of polybutene is less than 200, the flash point will be low, so the safety when using the adhesive composition in production or in a place where there is a fire such as a laboratory is reduced. . Moreover, since the adhesive force of the obtained adhesive composition falls, it is not preferable. On the other hand, when the number average molecular weight is larger than 1 200, the melt viscosity of the pressure-sensitive adhesive composition becomes too high, and a smooth coating operation becomes impossible.
  • High-pressure polyethylene is a polymer obtained by polymerizing ethylene alone or ethylene and other olefins (eg, butene, pentene, hexene, etc.) in a high-pressure polymerization method, and having a density of 0.92 to 0.93. Means.
  • the high pressure polyethylene (B) used in the present invention has a melt index of 0.04 to 35, preferably 0.1 to 20. Those with a melt index of less than 0.04 require a high temperature and a long time to dissolve in liquid polybutene, and those with a melt index greater than this range are sufficient for tackiness, prevention of trapping agent flow and prevention of bleeding. You can't get anything.
  • High-pressure polyethylene can be obtained by using, for example, the trade name Novatec LJ 600 (Nippon Polyethylene Co., Ltd.). High pressure method polyester Tylene may be used alone or in combination.
  • butyl rubber used in the present invention is one-by-one viscosity ML 1 + 8 (125 ° C) 30 ⁇
  • butyl rubber preferably 45-55 butyl rubber.
  • these butyl rubbers are commercially available under the trade name BUTYL 268 (manufactured by JSR Corporation).
  • BUTYL 268 manufactured by JSR Corporation.
  • the viscosity of ML 1 + 8 (1 25 ° C) is less than 30, the adhesive composition produced has insufficient adhesive strength, and the trapping ability against small organisms is reduced.
  • it is larger than 60 it takes time to dissolve in polybutene, and the melt viscosity of the produced adhesive composition becomes very high, so that it is difficult to smoothly apply to the surface of the material to be coated.
  • the (D) alicyclic hydrocarbon resin used in the present invention is a resin or alkenyl aromatic hydrocarbon obtained by polymerizing an alicyclic olefin compound such as cyclopentagen or alkylcyclopentagen using an acid catalyst.
  • an alicyclic olefin compound such as cyclopentagen or alkylcyclopentagen using an acid catalyst.
  • examples thereof include resins obtained by polymerizing an acid with an acid catalyst and then hydrogenating an aromatic ring.
  • These alicyclic hydrocarbon hydrocarbons can be obtained from the market under, for example, the trade name E s cor e z 5300 (manufactured by Exxon Mobil Chemical).
  • the blending ratio of the liquid polybutene in the present invention is 70 to 98% by mass, preferably 75 to 85% by mass with respect to the whole composition.
  • the blending ratio of liquid polybutene is
  • the extensibility of the coating film is lowered, and the coating processability tends to be inferior, such as the formation of surface irregularities. Further, if it exceeds 98% by mass, the flow resistance of the coating film tends to be inferior.
  • the blending ratio of the high pressure polyethylene in the present invention is 1.0 to 8.0% by mass, preferably 2.0 to 6.0% by mass, more preferably 3.0 to 4.5% by mass, based on the entire composition. Range.
  • the blending ratio is less than 1.0% by mass, the flow resistance of the coated film is inferior.
  • it is more than 8.0% by mass, the film-forming property is lowered and the processability of the coating film is inferior, such as the formation of surface irregularities.
  • an alicyclic hydrocarbon resin as a component in addition to the above three components.
  • an alicyclic hydrocarbon resin By using an alicyclic hydrocarbon resin, it is possible to obtain a pressure-sensitive adhesive composition that is excellent in both adhesive strength and workability during coating.
  • an adhesive composition is produced without using an alicyclic hydrocarbon resin, when an attempt is made to obtain a composition having excellent workability at the time of application, the composition is only inferior in adhesive strength.
  • a composition satisfying the adhesive strength is produced without using an alicyclic hydrocarbon resin, the composition has an extremely high melt viscosity and is inferior in coating workability. Thus, it is not possible to obtain an adhesive composition excellent in both adhesive strength and workability during application.
  • the blending ratio of the alicyclic hydrocarbon resin is in the range of 5 to 29% by mass, preferably 7 to 20% by mass, and more preferably 9 to 15% by mass with respect to the entire composition. If the blending ratio is less than 5% by mass, the melt viscosity of the pressure-sensitive adhesive composition becomes too high, resulting in problems in applicability, and if it exceeds 29% by mass, the melt viscosity becomes too low. The flow resistance is inferior, which is not preferable. In addition, the adhesive strength of the coating film is low, causing problems in the capture performance of small organisms.
  • the pressure-sensitive adhesive composition of the present invention can be produced by melt-kneading the components (A) to (D).
  • the method of melt kneading is not particularly limited, and can be carried out using a known method.
  • a method of forcibly stirring using a kneader can be used under a temperature condition in which the components (A) to (D) are melted.
  • a known kettle with a stirring blade can be preferably used as the kneading apparatus.
  • a method for example, a method is preferably used in which liquid polybutene as a main component is heated, and other components are added thereto sequentially or simultaneously to knead.
  • a preferred temperature range for performing this series of operations is 1600 ° C to 1700 ° C.
  • the working time is appropriately adjusted according to the quantity, but 5-7 hours are preferred.
  • the method of applying the obtained adhesive composition to a substrate is a known doctor
  • the F method, the doctor blade method and the like can be preferably used.
  • the temperature of the adhesive composition at the time of application is preferably 160 to 170 ° C.
  • the composition of the present invention does not use an organic solvent and does not have a specific odor, it does not repel mice and does not inhibit the effect of the attractant. Further, since bentonite does not use a bulky filler such as silica, there is no problem that foaming occurs during the kneading operation, making it difficult to continue the manufacturing operation.
  • the adhesive composition of the present invention is effective not only for capturing rodent small organisms such as mice, but also for capturing other harmful small organisms such as cockroaches.
  • the pressure-sensitive adhesive composition of the present invention in the range not impairing the required performance, depending on the application to be applied, in addition to the above essential constituents, if necessary, process oil, animal and vegetable oil, polymer plasticizer, Softeners, colorants, antioxidants, anti-aging agents, fragrances, attractants, feeds, etc. can be added as appropriate.
  • Butyl rubber JSR Corporation BUTYL268, arm one hundred twenty-one viscosity ML 8 (125.C) 51 polyisobutylene Petit polyalkylene rubber; Exxon Mobi l Chemical Co. Vistanex L-120, weight average molecular weight 1.66 million
  • High-pressure polyethylene Nippon Polyethylene, Novatec LJ600, MFR5.5, density 0.93, melting point (DSC method) 108 ° C
  • Liquid polybutene A manufactured by Nippon Petrochemical Co., Ltd., Nisseki Polybutene HV-100, number average molecular weight 980
  • Liquid polybutene B Nippon Petrochemical Co., Ltd., Nisseki Polybutene HV-300, number average molecular weight 1400 Alicyclic hydrocarbon resin A: Escorez5300, Exxon Mobil Chemical Co., melting point 105 ° C Aliphatic hydrocarbon resin B: Escorezl304, Exxon Mobil Chemical Co., melting point 100 ° C
  • the preparation method of the adhesive composition is as follows: . That is, other components were sequentially added to the liquid polybutene heated to 1700C, and the temperature was maintained at 1700C and stirred until each component was uniformly dissolved.
  • Comparative Example 4 uses a polyisobutylene rubber disclosed in Japanese Patent Application Laid-Open No.
  • melt viscosity The melt viscosity at 160 ° C. was measured according to J IS _K 7 1 1 7. The melt viscosity affects the workability when the adhesive composition is applied to the surface to be applied. In the table, in addition to the numerical value of melt viscosity, the evaluation of coating performance is also shown. Evaluation was performed as follows. That is, the adhesive composition at 170 ° C. was applied to the surface of the mount with a thickness of 2 mm using a stainless steel mold punched out to a predetermined size. The adhesive composition was uniformly applied without being too hard, and the adhesive composition did not flow out during or after application ( ⁇ ). The adhesive composition was too hard to apply uniformly (X). The adhesive composition flowed out during or after the coating operation ( ⁇ ).
  • Finger touch tack A finger was brought into contact with the surface of the adhesive composition applied to the coated surface, and the finger touch tack was examined.
  • Evaluation X Almost no adhesion to fingers. Also, there is no elongation and no rubber elasticity.
  • Adhesive strength In accordance with the probe tack method (JIS-Z 0 2 3 7 Supplementary matter), the adhesive composition applied to the coated surface is brought into contact with the end face of a metal column with a diameter of 5 mm. The force required to pull away from the coated surface was measured with a tensile tester at 23 ° C. Adhesive strength affects the capture performance of small organisms.
  • the adhesive compositions of the present invention shown in Examples 1 to 3 comprising liquid polybutene, high-pressure polyethylene, ptyl rubber, and alicyclic hydrocarbon resin have an appropriate melt viscosity. It also has good finger touch and adhesive strength. In other words, it is excellent in both the capture of small organisms and the workability during application. Moreover, by comparing Examples 1 to 3, it can be seen that the desired adhesive strength and melt viscosity can be adjusted by adjusting the blending ratio of the alicyclic hydrocarbon resin. On the other hand, Comparative Example 1 in which no alicyclic hydrocarbon resin is blended is excellent in workability at the time of coating, but is inferior in adhesive strength.
  • Comparative Example 2 in which the blending ratio of butyl rubber is increased and liquid polybutene having a large viscosity is used in combination with Examples 1 and 2, the adhesive strength is excellent, but the melt viscosity is large. Inferior workability. Moreover, Comparative Example 3 using an aliphatic hydrocarbon resin instead of an alicyclic hydrocarbon resin as the hydrocarbon resin is excellent in workability at the time of coating, but is poor in adhesive strength. The odor of the sticky material that seems to be derived was also strong. Comparative Example 4 is currently marketed and is widely used as an adhesive composition for capturing small organisms, and has an excellent track record in both adhesive strength and coating workability.
  • Examples 1, 2 and 3 have adhesive strength and coating workability which are not inferior to those of Comparative Example 4.
  • Comparative Example 4 uses an ultra high molecular weight polyisobutylene rubber instead of the butyl rubber of the present application. Therefore, as shown in Table 1, it took a long time for the kneaded product to become uniform during the kneading operation, and there was a problem in workability during the production of the adhesive composition. Also, it was necessary to use two types of liquid polybutene, and the manufacturing work was complicated in this respect as well.
  • composition in which the proportion of the alicyclic hydrocarbon resin used was too small had a melt viscosity that was too high, and there was a problem in coating workability.
  • a compound (Comparative Example 6) in which the proportion of the alicyclic hydrocarbon resin used is too high the coated surface becomes too hard, and therefore there is no adhesive force, and the capture of small organisms is poor. Further, since the viscosity at the time of melting is too low, the spread becomes too large during the coating operation, and it is difficult to maintain the shape.
  • the pressure-sensitive adhesive composition of the present invention exemplified in Examples 1, 2 and 3 is excellent in both workability at the time of coating work and performance for capturing small organisms.
  • the time required for homogenization during the production of the adhesive composition is short, and the workability during production is also excellent.
  • the coating film after coating on the material to be coated does not flow out during installation at the small organism capture site, does not ooze out on the material to be coated, becomes unusable, and does not stain the surroundings. It was excellent. Industrial applicability
  • the present invention it is possible to provide a pressure-sensitive adhesive composition having excellent capture properties for rodent small organisms such as mice. Moreover, the adhesive composition for capturing small organisms of the present invention can be economically produced because of its excellent workability during production. Furthermore, since the adhesive composition is excellent in application workability, the application work to the material to be applied can be carried out economically.
  • the adhesive composition for capturing small organisms of the present invention can efficiently and economically eliminate rodents and other small organisms such as mice, thereby producing agricultural products from these rodents and small organisms. It can economically and effectively prevent damage to food, food, and lead pipes and power lines.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Catching Or Destruction (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paints Or Removers (AREA)

Abstract

Selon l'invention, comme composition adhésive sensible à la pression pour piéger de petits organismes, utilisation est faite d'une composition comprenant : (A) 70 à 98 % en masse de polybutène liquide ayant une masse moléculaire moyenne en nombre de 200 à 1200 ; (B) 1,0 à 8,0 % en masse d'un polyéthylène de procédé haute pression ayant un indice de fusion de 0,04 à 35 ; (C) 1,0 à 8,0 % en masse de caoutchouc butyle ayant une viscosité Mooney ML1+8 (à 125 °C) de 30 à 60 ; et (D) 5 à 29 % en masse d'une résine hydrocarbonée alicyclique. On obtient ainsi une composition adhésive sensible à la pression pour piéger de petits organismes, qui a un caractère adhésif sensible à la pression élevée et de bonnes propriétés de revêtement sur une surface adhésive, et dans laquelle les matières de départ de la composition adhésive sensible à la pression peuvent être facilement obtenues et la composition sensible à la pression peut être obtenue avec une bonne aptitude à la mise en œuvre.
PCT/JP2009/053467 2008-02-29 2009-02-19 Composition adhésive sensible à la pression pour piéger de petits organismes Ceased WO2009107687A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009801066484A CN101959986B (zh) 2008-02-29 2009-02-19 小生物捕获用粘合性组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008050228A JP2009203446A (ja) 2008-02-29 2008-02-29 小生物捕獲用粘着性組成物
JP2008-050228 2008-02-29

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WO2009107687A1 true WO2009107687A1 (fr) 2009-09-03

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JP (1) JP2009203446A (fr)
CN (1) CN101959986B (fr)
TW (1) TWI449764B (fr)
WO (1) WO2009107687A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
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CN102850965A (zh) * 2012-08-13 2013-01-02 北京绿叶世纪日化用品有限公司 粘结剂、其制备方法以及涂覆其的害虫粘板
CN102850966A (zh) * 2012-08-13 2013-01-02 北京绿叶世纪日化用品有限公司 具有引诱效果的粘鼠胶、其制备方法以及涂覆其的粘鼠板
CN103497711A (zh) * 2013-08-07 2014-01-08 佛山力得高科技有限公司 粘鼠胶及其制备方法
JP2021105104A (ja) * 2019-12-26 2021-07-26 積水フーラー株式会社 ホットメルト組成物

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CN103709977B (zh) * 2013-12-04 2017-07-11 浙江固特热熔胶有限公司 环保无公害高效粘鼠胶及其生产方法
EP3601464A4 (fr) * 2017-03-31 2020-09-02 3M Innovative Properties Company Adhésif comprenant des polymères de polyisobutylène de faible poids moléculaire et des copolymères séquencés styrène-isobutylène
JP6984889B2 (ja) * 2018-03-30 2021-12-22 積水フーラー株式会社 ホットメルト組成物
JP2023086152A (ja) * 2021-12-10 2023-06-22 東洋インキＳｃホールディングス株式会社 小生物捕獲用粘着剤
CN116001127B (zh) * 2022-11-30 2024-10-01 苏州绿力士生物科技有限公司 一种在密炼机中的橡胶密炼方法

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JPS5626968A (en) * 1979-07-13 1981-03-16 Nichiban Co Ltd Adhesive tape for bundling raw vegetable of flower
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JPS58180401A (ja) * 1982-04-16 1983-10-21 Nippon Oil Co Ltd 小生物捕獲用粘着組成物
JPH1081856A (ja) * 1996-04-01 1998-03-31 Bridgestone Corp 接着テープ組成物および屋根を被覆する方法
JP2000262202A (ja) * 1999-03-18 2000-09-26 Nitta Gelatin Inc 小生物捕獲用粘着組成物およびこれを用いた小生物捕獲具
JP2007177105A (ja) * 2005-12-28 2007-07-12 Nippon Oil Corp 小生物捕獲用粘着剤
JP2007177104A (ja) * 2005-12-28 2007-07-12 Nippon Oil Corp 小生物捕獲用粘着性組成物

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JPH09143443A (ja) * 1995-11-22 1997-06-03 Nitto Denko Corp 粘着剤及び粘着捕獲具

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Publication number Priority date Publication date Assignee Title
JPS52154781A (en) * 1976-06-18 1977-12-22 Nitto Electric Ind Co Ltd Vermin adhesive collector
JPS5626968A (en) * 1979-07-13 1981-03-16 Nichiban Co Ltd Adhesive tape for bundling raw vegetable of flower
JPS58180402A (ja) * 1982-04-16 1983-10-21 Nippon Oil Co Ltd 改良された小生物捕獲用粘着組成物
JPS58180401A (ja) * 1982-04-16 1983-10-21 Nippon Oil Co Ltd 小生物捕獲用粘着組成物
JPH1081856A (ja) * 1996-04-01 1998-03-31 Bridgestone Corp 接着テープ組成物および屋根を被覆する方法
JP2000262202A (ja) * 1999-03-18 2000-09-26 Nitta Gelatin Inc 小生物捕獲用粘着組成物およびこれを用いた小生物捕獲具
JP2007177105A (ja) * 2005-12-28 2007-07-12 Nippon Oil Corp 小生物捕獲用粘着剤
JP2007177104A (ja) * 2005-12-28 2007-07-12 Nippon Oil Corp 小生物捕獲用粘着性組成物

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850965A (zh) * 2012-08-13 2013-01-02 北京绿叶世纪日化用品有限公司 粘结剂、其制备方法以及涂覆其的害虫粘板
CN102850966A (zh) * 2012-08-13 2013-01-02 北京绿叶世纪日化用品有限公司 具有引诱效果的粘鼠胶、其制备方法以及涂覆其的粘鼠板
CN102850965B (zh) * 2012-08-13 2014-07-23 北京绿叶世纪日化用品有限公司 粘结剂、其制备方法以及涂覆其的害虫粘板
CN103497711A (zh) * 2013-08-07 2014-01-08 佛山力得高科技有限公司 粘鼠胶及其制备方法
CN103497711B (zh) * 2013-08-07 2015-11-11 佛山力得高科技有限公司 粘鼠胶及其制备方法
JP2021105104A (ja) * 2019-12-26 2021-07-26 積水フーラー株式会社 ホットメルト組成物
JP7430059B2 (ja) 2019-12-26 2024-02-09 積水フーラー株式会社 ホットメルト組成物

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