WO2009118095A3 - Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators - Google Patents

Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators Download PDF

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Publication number
WO2009118095A3
WO2009118095A3 PCT/EP2009/001689 EP2009001689W WO2009118095A3 WO 2009118095 A3 WO2009118095 A3 WO 2009118095A3 EP 2009001689 W EP2009001689 W EP 2009001689W WO 2009118095 A3 WO2009118095 A3 WO 2009118095A3
Authority
WO
WIPO (PCT)
Prior art keywords
sulfur
ruthenium
contaminated
containing catalyst
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2009/001689
Other languages
English (en)
French (fr)
Other versions
WO2009118095A2 (de
Inventor
Timm Schmidt
Tim Loddenkemper
Frank Gerhartz
Walther Müller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Priority to ES09725694T priority Critical patent/ES2376413T3/es
Priority to EP09725694A priority patent/EP2257372B1/de
Priority to PL09725694T priority patent/PL2257372T3/pl
Priority to AT09725694T priority patent/ATE535304T1/de
Priority to RU2010143116/04A priority patent/RU2486008C2/ru
Priority to JP2011500072A priority patent/JP5577319B2/ja
Priority to CN2009801101670A priority patent/CN101977683B/zh
Publication of WO2009118095A2 publication Critical patent/WO2009118095A2/de
Publication of WO2009118095A3 publication Critical patent/WO2009118095A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/42—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/03—Preparation from chlorides
    • C01B7/04—Preparation of chlorine from hydrogen chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Die vorliegende Erfindung betrifft ein Verfahren, mit dem der Schwefelgehalt eines mit Schwefel in Form von Schwefelverbindungen vergifteten Ruthenium oder Rutheniumverbindungen enthaltenden Katalysators durch eine gezielte Behandlung mit einem Halogenwasserstoff, insbesondere Chlorwasserstoff enthaltenden Gasstrom unter nicht oxidativen Bedingungen gegebenenfalls bei erhöhter Temperatur soweit reduziert werden kann, dass dessen Aktivität auf die Aktivität eines gleichartigen Ruthenium oder Rutheniumverbindungen enthaltenden Katalysators ansteigt, der nicht durch Schwefel in Form von Schwefelverbindungen deaktiviert ist.
PCT/EP2009/001689 2008-03-22 2009-03-10 Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators Ceased WO2009118095A2 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES09725694T ES2376413T3 (es) 2008-03-22 2009-03-10 Procedimiento para la regeneración de un catalizador que contiene rutenio o compuestos de rutenio envenenado con azufre en forma de compuestos de azufre.
EP09725694A EP2257372B1 (de) 2008-03-22 2009-03-10 Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators
PL09725694T PL2257372T3 (pl) 2008-03-22 2009-03-10 Proces regeneracji katalizatora zawierającego ruten lub związki rutenu, zatrutego siarką w postaci związków siarki
AT09725694T ATE535304T1 (de) 2008-03-22 2009-03-10 Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators
RU2010143116/04A RU2486008C2 (ru) 2008-03-22 2009-03-10 Способ регенерации содержащего рутений или соединения рутения катализатора, отравленного серой в виде сернистых соединений
JP2011500072A JP5577319B2 (ja) 2008-03-22 2009-03-10 硫黄化合物の形態の硫黄で被毒したルテニウム含有またはルテニウム化合物含有触媒を再生する方法
CN2009801101670A CN101977683B (zh) 2008-03-22 2009-03-10 用于再生被以硫化合物形式的硫毒化的含钌或钌化合物的催化剂的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008015406.7 2008-03-22
DE102008015406A DE102008015406A1 (de) 2008-03-22 2008-03-22 Verfahren zur Regeneration eines mit Schwefel in Form von Schwefelverbindungen vergifteten, Ruthenium oder Rutheniumverbindungen enthaltenden Katalysators

Publications (2)

Publication Number Publication Date
WO2009118095A2 WO2009118095A2 (de) 2009-10-01
WO2009118095A3 true WO2009118095A3 (de) 2009-12-03

Family

ID=40886545

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/001689 Ceased WO2009118095A2 (de) 2008-03-22 2009-03-10 Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators

Country Status (13)

Country Link
US (1) US8889578B2 (de)
EP (1) EP2257372B1 (de)
JP (1) JP5577319B2 (de)
KR (1) KR101605212B1 (de)
CN (1) CN101977683B (de)
AT (1) ATE535304T1 (de)
DE (1) DE102008015406A1 (de)
ES (1) ES2376413T3 (de)
PL (1) PL2257372T3 (de)
PT (1) PT2257372E (de)
RU (1) RU2486008C2 (de)
TW (1) TW201004702A (de)
WO (1) WO2009118095A2 (de)

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KR101747974B1 (ko) * 2008-12-30 2017-06-15 바스프 에스이 염화수소의 산화를 위한 산화루테늄 포함 촉매의 재생 방법
DE102010039734A1 (de) * 2010-08-25 2012-03-01 Bayer Materialscience Aktiengesellschaft Katalysator und Verfahren zur Herstellung von Chlor durch Gasphasenoxidation
DE102010039735A1 (de) * 2010-08-25 2012-03-01 Bayer Materialscience Aktiengesellschaft Katalysator und Verfahren zur Herstellung von Chlor durch Gasphasenoxidation
US9352270B2 (en) 2011-04-11 2016-05-31 ADA-ES, Inc. Fluidized bed and method and system for gas component capture
CN104812467B (zh) 2012-09-20 2017-05-17 Ada-Es股份有限公司 用于恢复被热稳定盐污染的吸附剂上的功能位置的方法和系统
JP2014200775A (ja) * 2013-04-09 2014-10-27 株式会社ダイセル 触媒の再生方法、及び多価アルコールの水素化物の製造方法
JP6161508B2 (ja) 2013-10-23 2017-07-12 三菱重工業株式会社 Ｃｏｓ転換触媒の触媒再生方法
GB201407158D0 (en) * 2014-04-23 2014-06-04 Johnson Matthey Plc Precious metal recovery
US20160175774A1 (en) * 2014-12-18 2016-06-23 Uop Llc Process for adsorbing hydrogen chloride from a regenerator vent gas
US10118167B2 (en) * 2016-12-20 2018-11-06 Chevron Phillips Chemical Company Lp Methods for regenerating sulfur-contaminated aromatization catalysts
US10300476B2 (en) * 2017-05-17 2019-05-28 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition
EP3403723A1 (de) * 2017-05-19 2018-11-21 Covestro Deutschland AG Verfahren zur regeneration eines vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators
CN107290337B (zh) * 2017-06-14 2020-03-27 江南大学 一种基于钌纳米粒子比色法检测硫化氢的方法
KR102262496B1 (ko) * 2018-12-21 2021-06-07 한화솔루션 주식회사 염소 제조용 산화루테늄 담지 촉매의 제조방법 및 이에 의해 제조된 촉매
CN109607478B (zh) * 2018-12-25 2022-02-22 西安近代化学研究所 一种一步氧化氯化氢与氟化氢混合气制氯气的工艺
KR102709294B1 (ko) * 2019-12-31 2024-09-23 한화솔루션 주식회사 염화수소 산화반응 공정용 성형촉매 및 이의 제조방법
CN113275020B (zh) * 2020-02-19 2022-07-12 万华化学（宁波）有限公司 一种氯化氢氧化制氯催化剂的再生方法

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EP0743277A1 (de) * 1995-05-18 1996-11-20 Sumitomo Chemical Company Limited Verfahren zur Herstellung von Chlor
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EP0535619A1 (de) * 1991-10-03 1993-04-07 Idemitsu Kosan Company Limited Verfahren zur Regenerierung eines desaktivierten Katalysator
EP0743277A1 (de) * 1995-05-18 1996-11-20 Sumitomo Chemical Company Limited Verfahren zur Herstellung von Chlor
WO2007134721A2 (de) * 2006-05-23 2007-11-29 Bayer Materialscience Ag Verfahren zur herstellung von chlor durch gasphasenoxidation

Also Published As

Publication number Publication date
JP5577319B2 (ja) 2014-08-20
RU2486008C2 (ru) 2013-06-27
PL2257372T3 (pl) 2012-04-30
EP2257372B1 (de) 2011-11-30
PT2257372E (pt) 2012-02-06
WO2009118095A2 (de) 2009-10-01
ES2376413T3 (es) 2012-03-13
RU2010143116A (ru) 2012-04-27
EP2257372A2 (de) 2010-12-08
KR101605212B1 (ko) 2016-03-21
KR20100135239A (ko) 2010-12-24
TW201004702A (en) 2010-02-01
ATE535304T1 (de) 2011-12-15
US20090239736A1 (en) 2009-09-24
CN101977683B (zh) 2013-11-27
JP2011515208A (ja) 2011-05-19
CN101977683A (zh) 2011-02-16
DE102008015406A1 (de) 2009-09-24
US8889578B2 (en) 2014-11-18

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