WO2009130075A3 - Katalysator zur umsetzung von carbonsäurenitrilen - Google Patents

Katalysator zur umsetzung von carbonsäurenitrilen Download PDF

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Publication number
WO2009130075A3
WO2009130075A3 PCT/EP2009/052239 EP2009052239W WO2009130075A3 WO 2009130075 A3 WO2009130075 A3 WO 2009130075A3 EP 2009052239 W EP2009052239 W EP 2009052239W WO 2009130075 A3 WO2009130075 A3 WO 2009130075A3
Authority
WO
WIPO (PCT)
Prior art keywords
carboxylic acid
catalyst
reacting carboxylic
acid nitriles
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2009/052239
Other languages
English (en)
French (fr)
Other versions
WO2009130075A2 (de
Inventor
Alexander May
Bernd Vogel
Hermann Siegert
Kurt-Alfred Gaudschun
Thomas Quandt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm GmbH Darmstadt
Original Assignee
Evonik Roehm GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2011505440A priority Critical patent/JP5377628B2/ja
Application filed by Evonik Roehm GmbH filed Critical Evonik Roehm GmbH
Priority to RU2010147293/04A priority patent/RU2496575C9/ru
Priority to CA2722334A priority patent/CA2722334A1/en
Priority to CN2009801141659A priority patent/CN102015099A/zh
Priority to BRPI0910762A priority patent/BRPI0910762A2/pt
Priority to US12/937,659 priority patent/US9289752B2/en
Priority to MX2010011667A priority patent/MX2010011667A/es
Priority to EP09734323A priority patent/EP2268396A2/de
Publication of WO2009130075A2 publication Critical patent/WO2009130075A2/de
Publication of WO2009130075A3 publication Critical patent/WO2009130075A3/de
Priority to EG2010101752A priority patent/EG26411A/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/06—Preparation of carboxylic acid amides from nitriles by transformation of cyano groups into carboxamide groups
    • C07C231/065—By hydration using metals or metallic ions as catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft einen Katalysator zur Umsetzung von Carbonsäurenitrilen mit Wasser, wobei der Katalysator mindestens 60 Gew.-% Mangandioxid mit einer Summenformel MnOx, wobei x im Bereich von 1,7 bis 2,0 liegt, und mindestens ein Plastifizierungsmittel umfasst. Weiterhin betrifft die vorliegende Erfindung ein Verfahren zur Herstellung der zuvor dargelegten Katalysatoren sowie ein Verfahren zur Herstellung von Carbonsäureamiden durch Umsetzung von Carbonsäurenitrilen mit Wasser in Gegenwart des vorliegenden Katalysators.
PCT/EP2009/052239 2008-04-22 2009-02-26 Katalysator zur umsetzung von carbonsäurenitrilen Ceased WO2009130075A2 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
EP09734323A EP2268396A2 (de) 2008-04-22 2009-02-26 Katalysator zur umsetzung von carbonsäurenitrilen
RU2010147293/04A RU2496575C9 (ru) 2008-04-22 2009-02-26 Катализатор для превращения нитрилов карбоновых кислот
CA2722334A CA2722334A1 (en) 2008-04-22 2009-02-26 Catalyst for reacting carboxylic acid nitriles
CN2009801141659A CN102015099A (zh) 2008-04-22 2009-02-26 用于使腈反应的催化剂
BRPI0910762A BRPI0910762A2 (pt) 2008-04-22 2009-02-26 Catalisador para reagir nitrilas de ácido carboxílico, processo para preparar o dito catalisador e processo para preparar carboxamidas reagindo carbonitrilas com água
JP2011505440A JP5377628B2 (ja) 2008-04-22 2009-02-26 カルボン酸ニトリルを反応させるための触媒
MX2010011667A MX2010011667A (es) 2008-04-22 2009-02-26 Catalizador para hacer reaccionar nitrilos de acido carboxilico.
US12/937,659 US9289752B2 (en) 2008-04-22 2009-02-26 Catalyst for reacting carboxylic acid nitriles
EG2010101752A EG26411A (en) 2008-04-22 2010-10-19 Catalyst for reacting carboxylic acid nitriles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008001319A DE102008001319A1 (de) 2008-04-22 2008-04-22 Katalysator zur Umsetzung von Carbonsäurenitrilen
DE102008001319.6 2008-04-22

Publications (2)

Publication Number Publication Date
WO2009130075A2 WO2009130075A2 (de) 2009-10-29
WO2009130075A3 true WO2009130075A3 (de) 2010-01-14

Family

ID=41111421

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/052239 Ceased WO2009130075A2 (de) 2008-04-22 2009-02-26 Katalysator zur umsetzung von carbonsäurenitrilen

Country Status (15)

Country Link
US (1) US9289752B2 (de)
EP (1) EP2268396A2 (de)
JP (1) JP5377628B2 (de)
KR (1) KR101551994B1 (de)
CN (2) CN105148905A (de)
BR (1) BRPI0910762A2 (de)
CA (1) CA2722334A1 (de)
DE (1) DE102008001319A1 (de)
EG (1) EG26411A (de)
HK (1) HK1213217A1 (de)
MX (1) MX2010011667A (de)
MY (1) MY158755A (de)
RU (1) RU2496575C9 (de)
TW (1) TWI460013B (de)
WO (1) WO2009130075A2 (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101365790B1 (ko) * 2006-05-15 2014-02-20 에보니크 룀 게엠베하 알파-히드록시카르복실 에스테르의 제조 방법
DE102006055430A1 (de) 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur Herstellung von Carbonsäureamiden durch Hydrolyse von Carbonsäurenitrilen in Gegenwart eines Mangandioxid umfassenden Katalysators
DE102006055428A1 (de) * 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur Herstellung von (Meth)acrylsäure
DE102008044218A1 (de) 2008-12-01 2010-06-02 Evonik Röhm Gmbh Verfahren zur Herstellung von einem Carbonsäureamid aus einer Carbonylverbindung und Blausäure
DE102011081256A1 (de) 2011-08-19 2013-02-21 Evonik Röhm Gmbh Verfahren zur Herstellung von Alpha-Hydroxycarbonsäureestern
CN103252233B (zh) * 2013-04-18 2015-03-18 兄弟科技股份有限公司 一种水解催化剂及其制备方法和用于制备烟酰胺的方法
DE102013213699A1 (de) 2013-07-12 2015-01-15 Evonik Industries Ag Verfahren zur Herstellung von alpha-Hydroxycarbonsäureestern
DE102016210285A1 (de) 2016-06-10 2017-12-14 Evonik Röhm Gmbh Verfahren zur Herstellung von Methacrylaten und Methacrylsäure
CN111153825A (zh) * 2019-06-19 2020-05-15 浙江大学 利用负载型金属氧化物催化材料制备酰胺类化合物的方法
RU2766555C1 (ru) * 2021-05-21 2022-03-15 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для селективного окисления сероводорода и способ его применения

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5232886A (en) * 1988-11-28 1993-08-03 Sakai Chemical Industry Co., Ltd. Catalysts and methods for ozone decomposition
US5721037A (en) * 1994-08-02 1998-02-24 Ngk Insulators, Ltd. Honeycomb structural bodies and method of producing the same
EP0956898A2 (de) * 1998-05-13 1999-11-17 Mitsubishi Gas Chemical Company, Inc. Mn und Si-enthaltender Katalysator zur Hydratisierung von Cyanhydrin
EP1300192A2 (de) * 1995-06-15 2003-04-09 Engelhard Corporation Geformter Hydrierkatalysator, Verfahren zu seiner Herstellung und seiner Verwendung
WO2007039536A1 (de) * 2005-10-05 2007-04-12 Evonik Degussa Gmbh Mangandioxid-katalysator zur hydrolyse von carbonsäurenitrilen
WO2008061822A1 (de) * 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur herstellung von carbonsäureamiden durch hydrolyse von carbonsäurenitrilen in gegenwart eines mangandioxid umfassenden katalysators

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2400037A (en) * 1944-03-18 1946-05-07 Shell Dev Liquefied gas handling system
NL131718C (de) 1965-11-29
GB1351530A (en) * 1970-08-24 1974-05-01 Reynolds Tobacco Co R Process for converting nitriles to amides
DE2320060C2 (de) * 1973-04-19 1982-10-14 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Carbonsäureamiden
DE2527120A1 (de) 1975-06-18 1976-12-30 Roehm Gmbh Verfahren zur herstellung von alpha-hydroxyisobutyramid aus acetoncyanhydrin
US4290923A (en) 1979-02-01 1981-09-22 Carus Corporation Rare-earth-manganese oxidation catalysts and process of producing same
DE3346415C1 (de) * 1983-12-22 1984-09-13 Chemische Fabrik Stockhausen GmbH, 4150 Krefeld Verfahren zur Herstellung von ss-Hydroxypropionsaeureamid
JPS6164334A (ja) 1984-09-07 1986-04-02 Ube Ind Ltd 窒素酸化物浄化用触媒の製法
US4950801A (en) 1989-01-19 1990-08-21 Mitsubishi Gas Chemical Company, Inc. Process for producing alpha-hydroxycarboxylic acid amide
JP2893730B2 (ja) 1989-07-04 1999-05-24 三菱瓦斯化学株式会社 メタクリル酸メチルの製造法
JP2778131B2 (ja) 1989-07-14 1998-07-23 三菱瓦斯化学株式会社 メタクリル酸メチルの製造方法
JP2827368B2 (ja) 1989-12-19 1998-11-25 三菱瓦斯化学株式会社 α―ヒドロキシイソ酪酸アミドの製造法
KR940007527B1 (ko) * 1990-06-11 1994-08-19 미쯔이도오아쯔가가꾸 가부시기가이샤 아미드 화합물의 제조방법
US5387715A (en) 1991-12-03 1995-02-07 Mitsui Toatsu Chemicals, Inc. Process for producing α-hydroxy-isobutyramide
JP3525937B2 (ja) * 1992-11-09 2004-05-10 三菱瓦斯化学株式会社 α−ヒドロキシイソ酪酸アミドの製造法
JPH06340602A (ja) 1993-06-02 1994-12-13 Mitsui Toatsu Chem Inc α−ヒドロキシイソ酪酸アミドの製造方法
JPH0770020A (ja) * 1993-09-03 1995-03-14 Mitsui Toatsu Chem Inc アミド化合物の製造方法
KR960000850A (ko) 1994-06-06 1996-01-25 사토 아키오 메타크릴산메틸의 연속제조방법
US5578283A (en) * 1994-12-30 1996-11-26 Engelhard Corporation Catalytic oxidation catalyst and method for controlling VOC, CO and halogenated organic emissions
JPH09104665A (ja) 1995-10-09 1997-04-22 Daicel Chem Ind Ltd カルボン酸アミドの製造方法
US5756842A (en) 1995-11-07 1998-05-26 Mitsubishi Gas Chemical Company, Inc. Process for preparing lactamide
TW422724B (en) * 1997-07-03 2001-02-21 Takasago Thermal Engineering An air filter, the manufacturing method, and a high efficiency air cleaning apparatus
JPH11255710A (ja) 1998-03-11 1999-09-21 Mitsubishi Gas Chem Co Inc メタクリル酸メチルの製造方法
US6124501A (en) 1998-03-24 2000-09-26 Mitsubishi Gas Chemical Company, Inc. Process for preparing lactamide
DE102005023976A1 (de) 2005-05-20 2006-11-23 Röhm Gmbh Verfahren zur Umesterung
KR101365790B1 (ko) 2006-05-15 2014-02-20 에보니크 룀 게엠베하 알파-히드록시카르복실 에스테르의 제조 방법
DE102006055428A1 (de) 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur Herstellung von (Meth)acrylsäure
DE102008044218A1 (de) 2008-12-01 2010-06-02 Evonik Röhm Gmbh Verfahren zur Herstellung von einem Carbonsäureamid aus einer Carbonylverbindung und Blausäure

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5232886A (en) * 1988-11-28 1993-08-03 Sakai Chemical Industry Co., Ltd. Catalysts and methods for ozone decomposition
US5721037A (en) * 1994-08-02 1998-02-24 Ngk Insulators, Ltd. Honeycomb structural bodies and method of producing the same
EP1300192A2 (de) * 1995-06-15 2003-04-09 Engelhard Corporation Geformter Hydrierkatalysator, Verfahren zu seiner Herstellung und seiner Verwendung
EP0956898A2 (de) * 1998-05-13 1999-11-17 Mitsubishi Gas Chemical Company, Inc. Mn und Si-enthaltender Katalysator zur Hydratisierung von Cyanhydrin
WO2007039536A1 (de) * 2005-10-05 2007-04-12 Evonik Degussa Gmbh Mangandioxid-katalysator zur hydrolyse von carbonsäurenitrilen
WO2008061822A1 (de) * 2006-11-22 2008-05-29 Evonik Röhm Gmbh Verfahren zur herstellung von carbonsäureamiden durch hydrolyse von carbonsäurenitrilen in gegenwart eines mangandioxid umfassenden katalysators

Also Published As

Publication number Publication date
JP2011518039A (ja) 2011-06-23
MX2010011667A (es) 2011-02-18
KR101551994B1 (ko) 2015-09-09
EG26411A (en) 2013-10-22
CN105148905A (zh) 2015-12-16
RU2496575C2 (ru) 2013-10-27
RU2010147293A (ru) 2012-05-27
HK1213217A1 (zh) 2016-06-30
RU2496575C9 (ru) 2014-08-20
MY158755A (en) 2016-11-15
EP2268396A2 (de) 2011-01-05
CA2722334A1 (en) 2009-10-29
KR20110008049A (ko) 2011-01-25
BRPI0910762A2 (pt) 2017-08-29
US20110034728A1 (en) 2011-02-10
DE102008001319A1 (de) 2009-10-29
TWI460013B (zh) 2014-11-11
US9289752B2 (en) 2016-03-22
TW201004699A (en) 2010-02-01
CN102015099A (zh) 2011-04-13
JP5377628B2 (ja) 2013-12-25
WO2009130075A2 (de) 2009-10-29

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