WO2009141564A3 - Procédé de préparation d'un mélange de biocarburants - Google Patents

Procédé de préparation d'un mélange de biocarburants Download PDF

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Publication number
WO2009141564A3
WO2009141564A3 PCT/FR2009/050834 FR2009050834W WO2009141564A3 WO 2009141564 A3 WO2009141564 A3 WO 2009141564A3 FR 2009050834 W FR2009050834 W FR 2009050834W WO 2009141564 A3 WO2009141564 A3 WO 2009141564A3
Authority
WO
WIPO (PCT)
Prior art keywords
glycerol
mixture
biofuels
preparing
ethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2009/050834
Other languages
English (en)
Other versions
WO2009141564A2 (fr
Inventor
Nadine Essayem
Rodrigo Lopes De Souza
Berna Hamad
Gilbert Sapaly
Paulo Pries De Oliveira
Wilma Gonzalez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to BRPI0912220A priority Critical patent/BRPI0912220A2/pt
Priority to US12/991,314 priority patent/US8704003B2/en
Priority to EP09750045A priority patent/EP2291495A2/fr
Publication of WO2009141564A2 publication Critical patent/WO2009141564A2/fr
Publication of WO2009141564A3 publication Critical patent/WO2009141564A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L'invention concerne un procédé de préparation d'un mélange de biocarburants comprenant des esters d'acides gras et au moins un mélange d'éthers de glycérol à partir de matières grasses pouvant contenir des acides gras libres et d'éthanol comprenant : a) une étape de transestérification d'une l'huile végétale ou animale par de l'éthanol en présence d'un catalyseur à base d'au moins un sel alcalin ou d'ammonium d'hétéropolyacide caractérisé par une chaleur différentielle d'absorption d'ammoniac supérieure ou égale à 150 KJ/mol, stable à T>150°C, pour obtenir des esters d'acides gras et du glycérol, et, b) une étape d'éthérification du glycérol formé lors de l'étape a) par l'alcool mis en jeu à l'étape a) en présence du catalyseur de l'étape a) pour obtenir au moins un éther du glycérol, les dites étapes a) et b) ayant lieu simultanément, dans un seul et même réacteur.
PCT/FR2009/050834 2008-05-05 2009-05-05 Procédé de préparation d'un mélange de biocarburants Ceased WO2009141564A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BRPI0912220A BRPI0912220A2 (pt) 2008-05-05 2009-05-05 processos de preparação de uma mistura de biocombustíveis e de eterificação do glicerol pelo etanol, utilização de um catalisador à base de pelo menos um sal alcalino ou de amônio de heteropoliácido, e, biocombustível.
US12/991,314 US8704003B2 (en) 2008-05-05 2009-05-05 Method for preparing a mixture of biofuels
EP09750045A EP2291495A2 (fr) 2008-05-05 2009-05-05 Procédé de préparation d'un mélange de biocarburants

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0802491 2008-05-05
FR0802491A FR2930779B1 (fr) 2008-05-05 2008-05-05 Procede de preparation d'un melange de biocarburants

Publications (2)

Publication Number Publication Date
WO2009141564A2 WO2009141564A2 (fr) 2009-11-26
WO2009141564A3 true WO2009141564A3 (fr) 2010-01-21

Family

ID=40134067

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/050834 Ceased WO2009141564A2 (fr) 2008-05-05 2009-05-05 Procédé de préparation d'un mélange de biocarburants

Country Status (5)

Country Link
US (1) US8704003B2 (fr)
EP (1) EP2291495A2 (fr)
BR (1) BRPI0912220A2 (fr)
FR (1) FR2930779B1 (fr)
WO (1) WO2009141564A2 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2011269085B2 (en) 2010-06-22 2014-09-18 Shell Internationale Research Maatschappij B.V. Diesel fuel formulation
IT1403085B1 (it) * 2010-10-27 2013-10-04 Eni Spa Composizione di gasolio comprendente eteri della glicerina contenenti catene alchiliche lineari o loro miscele
CN102093173A (zh) * 2010-12-21 2011-06-15 浙江大学 由甘油和乙醇直接酯化制备3-乙氧基-1,2-丙二醇的方法
CN105080606A (zh) * 2014-05-06 2015-11-25 东北师范大学 一种制备生物柴油的多金属氧酸盐催化剂
JP7664247B2 (ja) * 2019-11-28 2025-04-17 ペトロレオ ブラジレイロ ソシエダ アノニマ － ペトロブラス ディーゼル用セタン価向上剤としてのグリセロール及びエタノールのエーテルの硝酸エステル及びその製造方法
WO2022152742A1 (fr) 2021-01-12 2022-07-21 Momentive Performance Materials Gmbh Composés éther utilisés comme substances volatiles pour le traitement de substrats à base d'acides aminés, tels que la peau et les cheveux
US11944955B2 (en) 2021-06-25 2024-04-02 Petróleo Brasileiro S.A.—Petrobras Process of obtaining a catalyst, catalyst and pre-treatment process of acidic raw materials
BR102021016123A2 (pt) 2021-08-16 2023-02-23 Petróleo Brasileiro S.A. - Petrobras Processo para produção de biodiesel a partir de cargas ácidas

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000013792A1 (fr) * 1998-09-07 2000-03-16 The University Of York Preparation et utilisation de catalyseur supporte d'acide solide d'un complexe de bf¿3?
WO2007113776A2 (fr) * 2006-04-05 2007-10-11 The Procter & Gamble Company Processus de conversion de glycérol en éthers de glycérol
US20070260078A1 (en) * 2006-05-05 2007-11-08 Bhat Ramanath N Integrated process for the manufacture of biodiesel

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2752242B1 (fr) * 1996-08-08 1998-10-16 Inst Francais Du Petrole Procede de fabrication d'esters a partir d'huiles vegetales ou animales et d'alcools
US6015440A (en) * 1997-10-31 2000-01-18 Board Of Regents Of The University Of Nebraska Process for producing biodiesel fuel with reduced viscosity and a cloud point below thirty-two (32) degrees fahrenheit
US8419810B2 (en) * 2004-02-24 2013-04-16 IFP Energies Nouvelles Method for producing biofuels, transforming triglycerides into at least two biofuel families: fatty acid monoesters and ethers and/or soluble glycerol acetals
FR2890963A1 (fr) * 2005-09-16 2007-03-23 Inst Francais Du Petrole Procede de fabrication d'esters ethyliques d'acides gras a partir de triglycerides et d'alcools
FR2890961B1 (fr) * 2005-09-21 2007-11-23 Inst Francais Du Petrole Procede perfectionne de fabrication d'esters ethyliques a partir de corps gras d'origine naturelle
CA2670035C (fr) * 2005-11-17 2018-06-12 Cps Biofuels, Inc. Composition d'additif de carburant a base d'ether de glycerol
US8613780B2 (en) * 2007-11-20 2013-12-24 Board Of Trustees Of Michigan State University Process for producing mixed esters of fatty acids as biofuels

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000013792A1 (fr) * 1998-09-07 2000-03-16 The University Of York Preparation et utilisation de catalyseur supporte d'acide solide d'un complexe de bf¿3?
WO2007113776A2 (fr) * 2006-04-05 2007-10-11 The Procter & Gamble Company Processus de conversion de glycérol en éthers de glycérol
US20070260078A1 (en) * 2006-05-05 2007-11-08 Bhat Ramanath N Integrated process for the manufacture of biodiesel

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BOKADE V V ET AL: "Synthesis of Bio-Diesel and Bio-Lubricant by Transesterification of Vegetable Oil with Lower and Higher Alcohols Over Heteropolyacids Supported by Clay (K-10)", PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, INSTITUTION OF CHEMICAL ENGINEERS, RUGBY, GB, vol. 85, no. 5, 1 January 2007 (2007-01-01), pages 372 - 377, XP022618630, ISSN: 0957-5820, [retrieved on 20070101] *
MORIN ET AL: "Transesterification of rapeseed oil with ethanol", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 330, 17 September 2007 (2007-09-17), pages 69 - 76, XP022223119, ISSN: 0926-860X *

Also Published As

Publication number Publication date
FR2930779A1 (fr) 2009-11-06
FR2930779B1 (fr) 2011-12-09
US8704003B2 (en) 2014-04-22
WO2009141564A2 (fr) 2009-11-26
EP2291495A2 (fr) 2011-03-09
US20110146137A1 (en) 2011-06-23
BRPI0912220A2 (pt) 2015-10-06

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