WO2010089395A3 - Procédé et kit de séparation de nanotubes de carbone métalliques et semi-conducteurs - Google Patents

Procédé et kit de séparation de nanotubes de carbone métalliques et semi-conducteurs Download PDF

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Publication number
WO2010089395A3
WO2010089395A3 PCT/EP2010/051510 EP2010051510W WO2010089395A3 WO 2010089395 A3 WO2010089395 A3 WO 2010089395A3 EP 2010051510 W EP2010051510 W EP 2010051510W WO 2010089395 A3 WO2010089395 A3 WO 2010089395A3
Authority
WO
WIPO (PCT)
Prior art keywords
swnts
kit
grafted
carbon nanotubes
separating metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/051510
Other languages
English (en)
Other versions
WO2010089395A2 (fr
Inventor
Pascale Chenevier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to EP10703843A priority Critical patent/EP2393752A2/fr
Priority to US13/147,140 priority patent/US9206040B2/en
Publication of WO2010089395A2 publication Critical patent/WO2010089395A2/fr
Publication of WO2010089395A3 publication Critical patent/WO2010089395A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • C01B32/172—Sorting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/22—Electronic properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/34—Length
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/36—Diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

La présente invention concerne un procédé de séparation des nanotubes de carbone à une seule couche de graphène métalliques (m-SWNT) et des nanotubes à une seule couche de graphène semi-conducteurs (sc-SWNT) comprenant une étape de greffage, notamment par greffage chimique radicalaire, d'un dérivé de sel de diazonium sur un mélange de m-SWNT et de sc-SWNT de façon à obtenir un mélange de m-SWNT greffés et de sc-SWNT non-greffés, moyennant quoi les m-SWNT greffés et les sc-SWNT non-greffés se séparent du fait de propriétés chimiques et/ou physiques différentielles causées par ledit greffage. La présente invention concerne également un kit pour la séparation des m-SWNT et des sc-SWNT.
PCT/EP2010/051510 2009-02-06 2010-02-08 Procédé et kit de séparation de nanotubes de carbone métalliques et semi-conducteurs Ceased WO2010089395A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP10703843A EP2393752A2 (fr) 2009-02-06 2010-02-08 Procédé et kit de séparation de nanotubes de carbone métalliques et semi-conducteurs
US13/147,140 US9206040B2 (en) 2009-02-06 2010-02-08 Method and kit for separating metal and semiconductor carbon nanotubes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0950757A FR2941938B1 (fr) 2009-02-06 2009-02-06 Procede de kit de separation de nanotubes de carbone metalliques et semi-conducteurs.
FR0950757 2009-02-06

Publications (2)

Publication Number Publication Date
WO2010089395A2 WO2010089395A2 (fr) 2010-08-12
WO2010089395A3 true WO2010089395A3 (fr) 2010-10-07

Family

ID=41116772

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/051510 Ceased WO2010089395A2 (fr) 2009-02-06 2010-02-08 Procédé et kit de séparation de nanotubes de carbone métalliques et semi-conducteurs

Country Status (4)

Country Link
US (1) US9206040B2 (fr)
EP (1) EP2393752A2 (fr)
FR (1) FR2941938B1 (fr)
WO (1) WO2010089395A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG187760A1 (en) 2010-08-06 2013-03-28 Hitachi Chemical Co Ltd Liquid composition, and resistor film, resistor element and circuit board using same
US8980216B2 (en) * 2011-04-04 2015-03-17 University Of Maryland, College Park Covalently functionalized carbon nanostructures and methods for their separation
FR2976279B1 (fr) * 2011-06-10 2014-07-04 Commissariat Energie Atomique Procede de fonctionnalisation selective de nanotubes de carbone monoparois

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002060812A2 (fr) * 2001-01-29 2002-08-08 William Marsh Rice University Processus de derivatisation de nanotubes de carbone avec des especes chimiques diazonium et compositions de celles-ci
US20040040834A1 (en) * 2002-03-04 2004-03-04 Smalley Richard E. Method for separating single-wall carbon nanotubes and compositions thereof
WO2006096200A1 (fr) * 2004-07-29 2006-09-14 William Marsh Rice University Separation en vrac de nanotubes de carbone par une bande interdite

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1186572A1 (fr) * 2000-09-06 2002-03-13 Facultés Universitaires Notre-Dame de la Paix Nanotubes de carbone de faible longueur et leur procédé de préparation
US6878361B2 (en) 2001-07-10 2005-04-12 Battelle Memorial Institute Production of stable aqueous dispersions of carbon nanotubes
KR20040050069A (ko) * 2001-10-01 2004-06-14 로세터 홀딩스 엘티디 단축된 탄소 나노튜브
US6974926B2 (en) 2002-03-26 2005-12-13 Intel Corporation Sorting of single-walled carbon nanotubes using optical dipole traps
SE0203377L (sv) 2002-11-13 2004-05-14 Kim Bolton Hantering av derivatiserade kolnanorör
US7374649B2 (en) 2002-11-21 2008-05-20 E. I. Du Pont De Nemours And Company Dispersion of carbon nanotubes by nucleic acids
US6921684B2 (en) 2003-10-17 2005-07-26 Intel Corporation Method of sorting carbon nanotubes including protecting metallic nanotubes and removing the semiconducting nanotubes
KR100847068B1 (ko) 2004-02-16 2008-07-18 도쿠리쓰교세이호징 가가쿠 기주쓰 신코 기코 카본 나노튜브의 구조선택분리 및 표면고정
KR100773369B1 (ko) 2004-05-12 2007-11-05 삼성코닝 주식회사 반도체성 탄소나노튜브의 선별 방법
KR100875392B1 (ko) 2004-08-02 2008-12-23 고쿠리쯔 다이가쿠 호징 츠쿠바 다이가쿠 카본 나노튜브의 분리방법 및 분산액
CA2590684A1 (fr) * 2004-12-16 2006-06-22 Nantero, Inc. Liquide aqueux applicateurs de nanotubes de carbone et leur procede de production
US20060223068A1 (en) 2005-03-30 2006-10-05 Yuegang Zhang Sorting of Carbon nanotubes through selective DNA delamination of DNA/Carbon nanotube hybrid structures
JP4982980B2 (ja) 2005-07-29 2012-07-25 ソニー株式会社 金属的カーボンナノチューブの分離方法、半導体的カーボンナノチューブ薄膜の製造方法、薄膜トランジスタの製造方法および電子素子の製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002060812A2 (fr) * 2001-01-29 2002-08-08 William Marsh Rice University Processus de derivatisation de nanotubes de carbone avec des especes chimiques diazonium et compositions de celles-ci
US20040040834A1 (en) * 2002-03-04 2004-03-04 Smalley Richard E. Method for separating single-wall carbon nanotubes and compositions thereof
WO2006096200A1 (fr) * 2004-07-29 2006-09-14 William Marsh Rice University Separation en vrac de nanotubes de carbone par une bande interdite

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
C. HEALD, G. WILDGOOSE, L. JANG, T. JONES, R. COMPTON: "Chemical Derivatisation of Multiwalled Carbon Nanotubes Using Diazonium Salts", CHEMICAL PHYSICS AND PHYSICAL CHEMISTRY, vol. 5, no. 11, 5 November 2004 (2004-11-05), pages 1794 - 1799, XP002549553 *
FRÃ CR DÃ CR RIC BARRIÃRE ET AL: "Covalent modification of graphitic carbon substrates by non-electrochemical methods", JOURNAL OF SOLID STATE ELECTROCHEMISTRY ; CURRENT RESEARCH AND DEVELOPMENT IN SCIENCE AND TECHNOLOGY, SPRINGER, BERLIN, DE, vol. 12, no. 10, 14 March 2008 (2008-03-14), pages 1231 - 1244, XP019593274, ISSN: 1433-0768 *
M. GOMBERG, W.E. BACHMANN: "The Synthesis of Biaryl Compounds by Means of the Diazo Reaction", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 46, 1 October 1924 (1924-10-01), pages 2340 - 2343, XP002549552 *

Also Published As

Publication number Publication date
US20120114549A1 (en) 2012-05-10
US9206040B2 (en) 2015-12-08
EP2393752A2 (fr) 2011-12-14
WO2010089395A2 (fr) 2010-08-12
FR2941938A1 (fr) 2010-08-13
FR2941938B1 (fr) 2011-05-06

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