WO2012045680A2 - Combinaisons de substances actives insecticides et fongicides - Google Patents

Combinaisons de substances actives insecticides et fongicides Download PDF

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Publication number
WO2012045680A2
WO2012045680A2 PCT/EP2011/067137 EP2011067137W WO2012045680A2 WO 2012045680 A2 WO2012045680 A2 WO 2012045680A2 EP 2011067137 W EP2011067137 W EP 2011067137W WO 2012045680 A2 WO2012045680 A2 WO 2012045680A2
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methyl
chloro
spp
amino
phenyl
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WO2012045680A3 (fr
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Peter Jeschke
Heike Hungenberg
Robert Velten
Leonardo PITTÁ
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Bayer CropScience AG
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Bayer CropScience AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

Definitions

  • This application relates to mixtures of halogen-substituted compounds of formula (I) explained below with at least one further active ingredient, which may preferably be an insecticide or an acaricide or a nematicide or an antimicrobial compound.
  • these mixtures are suitable for controlling animal or microbial pests and as a plant tonic.
  • halogen-substituted compounds are known from WO 2008/009360, where their use for controlling animal pests is described.
  • the acaricidal and / or insecticidal and / or nematicidal activity and / or range of action and / or the plant tolerance, in particular to crops, of these compounds is not always sufficient.
  • drug combinations comprising one or more compounds of the formula (I) and one or more compounds from the groups (1-1) to (1-29) described below and / or one or more compounds the groups (Fl) to (F-14) described below are synergistically effective and are suitable for controlling animal and microbial pests and as a plant tonic.
  • the active compound combinations according to the invention contain at least one and preferably exactly one compound of the formula (I),
  • A is in each case optionally substituted aryl, heterocyclyl or hetaryl which is optionally substituted by fluorine, chlorine, bromine, iodine, cyano, nitro, alkyl (which is optionally substituted by fluorine and / or chlorine), alkylthio (which is optionally substituted by fluorine and / or Chlorine is substituted), or alkylsulfonyl (which is optionally substituted by fluorine and / or chlorine) are substituted,
  • R 1 is in each case halogen-substituted C 2 -C 4 -alkyl, C 2 -C 5 -alkenyl or C 3 -C 5 -cycloalkyl,
  • R 2 is in each case optionally halogen-substituted alkyl or cycloalkyl, represents optionally substituted methylene or in each case optionally substituted alkylene or alkylidene having in each case 2 to 6 carbon atoms, or denotes a bond between A and NR 1 .
  • X is halogen, C 1 -C 4 -alkyl or C 1 -C -haloalkyl
  • Y represents halogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, azido or cyano.
  • A is also preferably a radical from the series consisting of 5,6-difluoropyrid-3-yl, 5-chloro-6-fluoropyrid-3-yl, 5-bromo-6-fluoropyrid-3-yl, 5-iodo-6-fluoro-pyrid-3-yl, 5-fluoro-6-chloro-pyrid-3-yl, 5,6-dichloro-pyrid-3-yl, 5-bromo-6-chloro-pyrid 3-yl, 5-iodo-6-chloro-pyrid-3-yl, 5-fluoro-6-bromo-pyrid-3-yl, 5-chloro-6-bromo-pyrid-3-yl, 5,6- Dibromo-pyrid-3-yl, 5-iodo-6-bromo-pyrid-3-yl, 5-fluoro-6-iodo-pyrid-3-yl, 5-chloro-6-iodo-pyrid
  • R 1 is preferably 2,2,2-trifluoroethyl or 2,2-difluoroethyl.
  • R 2 preferably represents in each case optionally fluorine-, chlorine- or bromine-substituted methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, cyclopropyl or cyclobutyl.
  • B is preferably -CR 3 R 4 - or -H 2 C-CR 3 R 4 -, in which
  • R 3 and R 4 independently of one another represent hydrogen, in each case optionally substituted by halogen, in particular fluorine, substituted methyl, ethyl or Ca-Ce-cycloalkyl (in particular cyclopropyl) or for halogen, in particular fluorine, or for C 1 -C 4 -alkoxy-C C4-alkyl, in particular methoxymethyl, or
  • R 3 and R 4 together with the carbon atom to which they are attached form a 3- to 6-membered carbon ring.
  • the active compound combinations according to the invention preferably contain one or more and in particular one of the compounds of the formula (I) listed in the following table.
  • the active compound combinations according to the invention also contain one or more compounds from the groups (1-1) to (1-29) described below and / or one or more compounds from the groups (Fl) to (F-14).
  • Acetylcholinesterase (AChE) inhibitors such as
  • Carbamates e.g. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxime, Butoxycarboxime, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC and xylylcarb; or
  • Organophosphates e.g. B. Acephate, Azamethiphos, Azinphos-ethyl, Azinophos-methyl, Cadusafos, Chloroethoxyfos, Chlorfenvinphos, Chlormephos, Chlo ⁇ yrifos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinone, Dichlorvos / DDVP, Dicrotophos, Dimethoates, Dimethylvinphos, Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl O- (methoxyaminothio-phosphoryl) salicylate, Isoxathione, Malathion, Mecarbam, Methamidophos
  • Cyclodiene organochlorines e.g. Chlordane and endosulfan
  • Phenylpyrazoles e.g. Ethiprole and fipronil.
  • Pyrethroids eg acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin , alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) -trans isomers], deltamethrin, empenthrin [(EZ) - (IR) -isomers]], esfenvalerates, e
  • nicotinergic acetylcholine receptor (nAChR) agonists such as neonicotinoids, e.g. Acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam; or
  • nicotinergic acetylcholine receptor (nAChR) allosteric activators such as spinosines, e.g. Spinetoram and spinosad.
  • chloride channel activators such as
  • Avermectins / milbemycins e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin. (7) juvenile hormone mimics, such as
  • Juvenile hormone analogs e.g. Hydroprene, kinoprene and methoprene; or fenoxycarb; or pyriproxyfen.
  • agents with unknown or nonspecific modes of action such as alkyl halides, e.g. Methyl bromide and other alkyl halides; or chloropicrin; or sulfuryl fluoride; or borax; or tartar emetic.
  • mite growth inhibitors e.g. Clofentezine, hexythiazox and diflovidazine; or Etoxazole.
  • Microbial disruptors of the insect intestinal membrane eg Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.
  • Microbial disruptors of the insect intestinal membrane eg Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylF
  • inhibitors of oxidative phosphorylation, ATP disruptors such as diafenthiuron; or organotin compounds, e.g. Azocyclotine, cyhexatin and fenbutatin oxide; or propargite; or tetradifon.
  • Nicotinergic acetylcholine receptor antagonists such as Bensultap, Cartap hydrochloride, thiocyclam and thiosultap sodium.
  • Type 0 inhibitors of chitin biosynthesis such as bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
  • inhibitors of chitin biosynthesis type 1, such as buprofezin.
  • Moulting agents dipteran, such as cyromazine.
  • ecdysone receptor agonists such as chromafenozides, halofenozides, methoxyfenozides, and tebufenozides.
  • Octopaminergic agonists such as amitraz.
  • complex III electron transport inhibitors such as hydramethylnone; or acequinocyl; or fluacrypyrim.
  • complex I electron transport inhibitors for example
  • METI acaricides e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad; or
  • Tetronic and tetramic acid derivatives e.g. Spirodiclofen, spiromesifen and spirotetramat.
  • Phosphines e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide; or cyanide.
  • ryanodine receptor effectors such as diamides, e.g. Chlorantraniliprole and flubendiamide.
  • (F-1) inhibitors of nucleic acid synthesis such as benalaxyl, benalaxyl-M, bupirimate, clozylacone, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M, ofurace, oxadixyl and oxolic acid.
  • F-2 Inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fuberidazole, pencycuron, thiabendazole, thiophanate, thiophanate-methyl and zoxamide.
  • (F-3) inhibitors of respiration such as diflumetorim as an inhibitor at complex I of the respiratory chain; Bixafen, boscalid, carboxin, fenfuram, flutolanil, fluopyram, furametpyr, furmecyclox, isopyrazam (mixture of the sy-epimeric racemate ⁇ RS, 4SR, 9RS and the ßwft 'epimers racemate IRS, 4SR, 9SR) Isopyrazam (sy "-epimeres racemate IRS, 4SR, 9RS) Isopyrazam (syn epimeric enantiomer 1R, 4S, 9R), Isopyrazam (sy" -epimeres enantiomer ⁇ S, 4 R , 9S), isopyrazam (anti- epimeric racemate ⁇ RS, 4SR, 9SR), isopyrazam (awfr ' epimeric en
  • Pyraclostrobin Pyraoxystrobin, Pyrametostrobin, Pyribencarb, Trifloxystrobin as inhibitors of the complex III of the respiratory chain.
  • decouplers such as binapacryl, dinocap, fluazinam and meptyldinocap.
  • F-5 Inhibitors of ATP Production such as Fentin Acetate, Fentin Chloride, Fentin Hydroxide and Silthiofam.
  • F-6 Inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S ', cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil.
  • F-7 signal transduction inhibitors such as fenpiclonil, fludioxonil, fluxapyroxad and quinoxyfen.
  • Inhibitors of lipid and membrane synthesis such as biphenyl, chlozolinate, edifenphos, etridiazole, iodocarb, Iprobenfos, iprodione, isoprothiolane, procymidone, propamocarb, propamocarb hydrochloride, pyrazophos, tolclofos-methyl and vinclozolin.
  • (F-9) inhibitors of ergosterol biosynthesis such as aldimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fenhexamide, fenpropidin, Fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole cis, hexaconazole, imazalil, imazalil sulfate, imibenconazole, ipconazole, metconazole, myclobutanil, naftifine, nuarimol, oxpoconazole, paclobutrazole
  • (F-10) inhibitors of cell wall synthesis such as benthiavalicarb, dimethomo h, flumo h, iprovalicarb, mandipropamide, polyoxins, polyoxorim, prothiocarb, validamycin A and valefenalate.
  • (F-1) Inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, fthalide, pyroquilone and tricyclazole.
  • (F-13) compounds with multisite activity such as Bordeaux mixture, captafol, captan, chlorothalonil, copper naphthenate, copper oxide, copper oxychloride, copper preparations, such as copper hydroxide, copper sulfate, dichlofluanid, dithianone, dodine and its free base, Ferbam, Fluorofolpet, Folpet, Guazatine, guazatine acetate, iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram.
  • Preferred compounds from these groups are: Acrinathrin, alpha-cypermethrin, beta-cyfluthrin, cyhalothrin, cypermethrin, deltamethrin
  • Preferred compounds from these groups are furthermore:
  • Azoxystrobin Boscalid, Penflufen, Bixafen, Fluopyram, Carpropamid, Spiroxamine, Fluxapyroxad, Carbendazim, Carboxin, Fenamidone, Fludioxonil, Fluopicolide, Fluoxastrobin, Fluquinconazole, Flutriafol, Ipconazole, Iprodione, Isotianil, Mefenoxam, Metalaxyl, Metominostrobin, Pencycuron, Prochloraz, Prothioconazole, Pyraclostrobin, Pyrimethanil, Sedaxane, Silthiopham, Tebuconazole, Thiram, Tolylfluanid, Triadimenol, Triazoxide, Trifloxystrobin, Triflumuron and Triticonazole.
  • Alpha-Cypermethrin 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Beta-Cyfluthrin 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Tefluthrin 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Tebufenozide 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Endosulfan 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Ethiprole 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Cyenopyrafen 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Metaflumizone 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Methiocarb 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Fluquinconazole 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Ipconazole 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Isotianil 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Metalaxyl 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Tebuconazole 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Triadimenol 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Trifloxystrobin 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • Triticonazole 125 1 to 1: 125 25: 1 to 1:25 5: 1 to 1: 5
  • the mixture listed in No.105 in the above table is preferably in a ratio of from 85:15 to 97: 3 for the first to the second named compound, these corner points being included.
  • a preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-1) is present and as mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios as indicated above are.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-2) is present and as mixing partners of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-3) is present and as mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios as above are indicated.
  • Another particularly preferred embodiment of the present invention relates Active ingredient combinations in which the compound of the formula (1-4) is present and as a mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios are as indicated above.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-5) is present and as mixing partners of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and most particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-6) is present and as mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and most particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-7) is present and as a mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-8) is present and as mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and most particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-9) is present and as a mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (1-10) is present and as mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, wherein the preferred, particularly preferred and very particularly preferred mixing ratios as above are indicated.
  • a further preferred embodiment of the present invention relates to active ingredient combinations in which the compound of the formula (I-1 1) is present and as mixing partner of one of the abovementioned mixing partners of the numbers 1 to 150, the preferred, particularly preferred and very particular preferred mixing ratios are as indicated above.
  • Further preferred active ingredient combinations are selected from combinations which contain the compound of the formula (1-4) and a further active compound from Table A selected from the compounds with the numbers 1, 2, 3, 5, 6, 12b, 15, 18 , 19, 24, 26, 28, 29, 30, 34, 36, 37, 38, 44, 45, 49, 50, 53, 54, 55, 57, 58, 62, 63, 74, 77, 87, 90 , 92, 93, 94, 95, 96, 97, 98, 99, 100, 101, 102, 103, 104, 105, 106, 108, 109, 111, 112, 113, 114, 148, 149 and 150.
  • the active compound combinations according to the invention are very suitable for controlling animal pests or undesired microorganisms.
  • the insecticides and / or acaricidal and / or antimicrobial action, or the fungicidal action and / or the plant-strengthening and / or yield-increasing action of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unpredictable true synergistic effect and not just an effect supplement.
  • the compounds of the formula (I) may be mixed with the following herbicides.
  • Fruit / Vegetable Herbicides Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam; Cereal Herbicides: Isoproturon, Bromoxynil, Ioxynil, Phenoxies, Chlorsulfuron, Clodinafop, Diclofop, Diflufenican, Fenoxaprop, Florasulam, Fluroxypyr, Metsulfuron, Triasulfuron, Flucarbazone, Iodosulfuron, Propoxycarbazone, Picolinafen, Mesosulfuron, Beflubutamide, Pinoxaden, Amidosulfuron, Thifensulfuron, Tribenuron, Flupyrsul
  • Corn herbicides Atrazine. Alachlor, bromoxynil, acetochlor, dicamba, clopyralid, (5) -dimethenamid, glufosinate, glyphosate, isoxaflutole, (5) -metolachlor, mesotrione, nicosulfuron, primisulfuron, rimsulfuron, sulcotrione, foramsulfuron, toramezone, tembotrione, saflufenacil, thien arbazone, flufenacet , Pyroxasulfone; Rice herbicides: Butachlor.
  • Soy herbicides alachlor, bentazone, trifluralin, chlorimuron-ethyl, cloransulam-methyl, fenoxaprop, fomesafen, fluazifop, glyphosate, imazamox, imazaquin, imazethapyr, ( ⁇ S) -metolachlor, metribuzin, pendimethalin, tepraloxydim, glufosinate;
  • Sugar beet herbicides Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Lenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop;
  • Rape herbicides Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim; Particular preference is given to mixtures of compounds of the formula (I) with glyphosate. Further preferred are mixtures of the compound of the formula (I) with glufosinate.
  • insects in particular insects, arachnids, helminths, nematodes and molluscs, found in agriculture, horticulture, livestock, forestry, gardens and recreational facilities, in storage and materials protection and in the hygiene sector.
  • Pests in particular insects, arachnids, helminths, nematodes and molluscs, found in agriculture, horticulture, livestock, forestry, gardens and recreational facilities, in storage and materials protection and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the above mentioned pests include:
  • Anoplura e.g. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.
  • Arachnids e.g. Acarus spp., Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri , Eutetranychus spp., Eriophyes spp., Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Nuphersa spp., Oligonychus spp., Ornithodoros
  • Atomaria spp. Atomaria spp., Attagenus spp., Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Diloboderus spp., Epilachna spp., Epitrix spp., Faustinus spp., Gibbium psylloides, Hellula and alis, Heteronychus arator, Heteronyx spp
  • Hylamorpha elegans Hylotrupes bajulus, Hypera postica, Hypo- noemus spp., Lachnosterna consanguinea, Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Lixus spp., Luperodes spp., Lyctus spp., Megascelis spp.
  • Melanoms spp. Melig Ethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus spp., Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllotreta spp., Popillia japonica, Premnotrypes spp., Psylliodes spp., Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Starchus spp., Symphyletes spp., Tan
  • Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.
  • helminths e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.
  • helminths e.g.
  • Hymenoptera e.g. Athalia spp., Diprion spp., Hoplocampa spp., Lasius spp., Monorium pharaonis, Vespa spp.
  • Lepidoptera From the order of Lepidoptera, for example, Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Barathra brassicae, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius , Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocerus spp., Cnephasia spp., Conopomorph
  • Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Dichroplus spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
  • siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.
  • Thysanoptera e.g. Anaphothrips obscurus, Baliothrips biformis, Drepanothris reuteri, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
  • Anaphothrips obscurus e.g. Anaphothrips obscurus, Baliothrips biformis, Drepanothris reuteri, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
  • Thysanura e.g. Lepisma saccharina.
  • the plant parasitic nematodes include, for example, Aphelenchoides spp., Bursaphelenchus spp., Ditylenchus spp., Globodera spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Trichodorus spp., Tylenchulus semipenetrans, Xiphinema spp
  • the present invention further relates to formulations and application forms prepared therefrom Plant protection products and / or pesticides such. B. drench, drip and spray, comprising at least one of the active compounds according to the invention.
  • the use forms contain other crop protection agents and / or pesticides and / or the effect of improving adjuvants such as penetration enhancers, eg.
  • vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetable fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts z.
  • organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such.
  • dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such as dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such.
  • glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.
  • Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ;
  • SL water-soluble liquids
  • EC emulsion concentrates
  • EW emulsions in water
  • SC suspension concentrates
  • SC SE, SE, FS, OD
  • WG water-dispersible granules
  • GR granules
  • capsule concentrates CS
  • the formulations contain, in addition to one or more active compounds according to the invention, further agrochemical active substances.
  • auxiliaries such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, for example adjuvants.
  • An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect.
  • Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.
  • formulations are prepared in a known manner, e.g. by mixing the active ingredients with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • the preparation of the formulations is carried out either in suitable systems or before or during use.
  • polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes
  • alcohols and polyols which may also be substituted, etherified and / or esterified
  • ketones such as
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • alcohols such as butanol or glycol and their ethers and esters
  • ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons, e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, e.g. Methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents, such as dimethyl sulfoxide, and water.
  • aromatic hydrocarbons e.g. Xylene, toluene or alkylnaphthalenes
  • chlorinated aromatic or aliphatic hydrocarbons
  • Suitable carriers are in particular: for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals, such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes and / or solid Fertilizer. Mixtures of such carriers can also be used.
  • Suitable carriers for granules are: eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.
  • liquefied gaseous diluents or solvents can be used.
  • Particularly suitable are those extenders or carriers which are gaseous at normal temperature and under atmospheric pressure, for example aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
  • Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or nonionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with Fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyltaurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, for example alkylarylpolyglycol ethers, Alkyl sulfonates, alkyl sulfates, arylsulfonates, protein
  • dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes, and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers.
  • formulations and applications derived therefrom may also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins, and synthetic phospholipids.
  • additional auxiliaries may be mineral and vegetable oils.
  • auxiliaries may be present in the formulations and in the use forms derived therefrom.
  • additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents.
  • the Active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.
  • retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.
  • Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants.
  • Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle.
  • the method described in the literature can be used to determine this property.
  • Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • alcohol alkoxylates such as coconut oil ethoxylate (10) or isotridecyl ethoxylate (12)
  • fatty acid esters such as rapeseed oil or soybean oil
  • fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • the plants which can be treated with the active compound combinations according to the invention include, for.
  • turf vines, cereals, for example wheat, barley, rye, oats, rice, maize and millet
  • Beets for example sugar beets and fodder beets
  • Fruits such as pome fruit, stone fruit and soft fruit, such as apples, pears, plums, peaches, almonds, cherries and berries, eg.
  • Legumes such as beans, lentils, peas and soybeans
  • Oil crops such as rapeseed, mustard, poppy
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and Roots, tubers and rhizomes are listed.
  • the plant parts also include crops as well as vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active ingredient combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, eg by dipping, spraying, evaporating, casting, atomizing, spreading, brushing and in propagation material, in particular in seeds, furthermore by single or multi-layer wrapping.
  • all plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the terms "parts” or “parts of plants” or “plant parts” have been explained above.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted.
  • Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants”).
  • trasits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • herbicidally active compounds for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • the genes which confer the desired properties can also occur in combinations with one another in the transgenic plants.
  • Bt plants are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ® (for example maize, cotton, soya beans), KnockOut ® (for example maize), StarLink ® (for example maize), Bollgard ® ( cotton), NuCOTN ® (cotton) and NewLeaf ® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are resistant under the trade names Roundup Ready ® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ® (tolerance to phosphinotricin, for example oilseed rape), IMI ® (tolerance Imidazolinone) and STS ® (tolerance to sulfonylureas such as corn) are sold.
  • Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield ® (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
  • the listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention.
  • the preferred ranges given above for the active substance combinations also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the active ingredient combinations specifically mentioned in the present text.
  • the active compound combinations according to the invention have an increased microbicidal action (in comparison to the microbially active compounds within the groups F1 to F14) and can be used for controlling unwanted microorganisms, such as fungi and bacteria, in crop protection and in the protection of materials.
  • Fungicides can be used for the control of Plasmodiophoromycetes, Oomycetes, Chytriomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
  • Blumeria species such as Blumeria graminis
  • Podosphaera species such as Podosphaera leucotricha
  • Sphaerotheca species such as Sphaerotheca fuliginea
  • Uncinula species such as Uncinula necator
  • Gymnosporangium species such as Gymnosporangium sabinae
  • Hemileia species such as Hemileia vastatrix
  • Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae
  • Puccinia species such as Puccinia recondita
  • Uromyces species such as Uromyces appendiculatus
  • Bremia species such as Bremia lactucae
  • Peronospora species such as Peronospora pisi or P. brassicae;
  • Phytophthora species such as Phytophthora infestans
  • Plasmopara species such as Plasmopara viticola
  • Pseudoperonospora species such as Pseudoperonospora humuli or
  • Pseudoperonospora cubensis Pythium species such as Pythium ultimum;
  • Alternaria species such as Alternaria solani;
  • Cercospora species such as Cercospora beticola
  • Cladosporium species such as Cladosporium cucumerinum
  • Cochliobolus species such as Cochliobolus sativus
  • Colletotrichum species such as Colletotrichum lindemuthanium
  • Cycloconium species such as cycloconium oleaginum
  • Diaporthe species such as Diaporthe citri;
  • Elsinoe species such as Elsinoe fawcettii
  • Gloeosporium species such as, for example, Gloeosporium laeticolor
  • Glomerella species such as Glomerella cingulata
  • Guignardia species such as Guignardia bidwelli;
  • Leptosphaeria species such as Leptosphaeria maculans
  • Magnaporthe species such as Magnaporthe grisea
  • Mycosphaerella species such as Mycosphaerella graminicola and Mycosphaerella fijiensis;
  • Phaeosphaeria species such as Phaeosphaeria nodorum
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramularia species such as Ramularia collo-cygni
  • Rhynchosporium species such as Rhynchosporium secalis
  • Septoria species such as Septoria apii
  • Typhula species such as Typhula incarnata
  • Venturia species such as Venturia inaequalis
  • Corticium species such as Corticium graminearum
  • Fusarium species such as Fusarium oxysporum
  • Gaeumannomyces species such as Gaeumannomyces graminis
  • Rhizoctonia species such as Rhizoctonia solani
  • Tapesia species such as Tapesia acuformis
  • Thielaviopsis species such as Thielaviopsis basicola
  • Ear and panicle diseases caused by e.g.
  • Alternaria species such as Alternaria spp .
  • Aspergillus species such as Aspergillus flavus
  • Cladosporium species such as Cladosporium cladosporioides
  • Claviceps species such as Claviceps purpurea
  • Fusarium species such as Fusarium culmorum
  • Gibberella species such as Gibberella zeae
  • Monographella species such as Monographella nivalis
  • Sphacelotheca species such as Sphacelotheca reiliana
  • Tilletia species such as Tilletia caries
  • Urocystis species such as Urocystis occulta
  • Ustilago species such as Ustilago nuda
  • Aspergillus species such as Aspergillus flavus
  • Botrytis species such as Botrytis cinerea
  • Penicillium species such as Penicillium expansum and Penicillium pu ⁇ urogenum;
  • Sclerotinia species such as Sclerotinia sclerotiorum
  • Verticilium species such as Verticilium alboatrum
  • Fusarium species such as Fusarium culmorum
  • Phytophthora species such as Phytophthora cactorum
  • Pythium species such as Pythium ultimum
  • Rhizoctonia species such as Rhizoctonia solani
  • Sclerotium species such as Sclerotium rolfsii
  • Nectria species such as Nectria galligena
  • Monilinia species such as Monilinia laxa
  • Taphrina species such as Taphrina deformans
  • Esca species such as Phaeomoniella chlamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea;
  • Botrytis species such as Botrytis cinerea
  • Rhizoctonia species such as Rhizoctonia solani
  • Helminthosporium species such as Helminthosporium solani
  • Xanthomonas species such as Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as Pseudomonas syringae pv. Lachrymans;
  • Erwinia species such as Erwinia amylovora
  • the following diseases of soybean beans can be controlled:
  • Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Pod and Stem Blight (Phomopsis sojae), Powdery Milde
  • Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregular, Pythium Debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).
  • X is the degree of killing, expressed in% of the untreated control, when using the active ingredient A at a rate of m g / ha or in a concentration of m ppm,
  • Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm
  • E is the killing degree, expressed in% of the untreated control, when using the active compounds A and B in application rates of m and n g / ha or in a concentration of m and n ppm, then is
  • the combination is over-additive in its kill, i. there is a synergistic effect.
  • the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves ⁇ Brassica oleracea) which are heavily infested with the green peach aphid (Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Bacillus firmus 1-1582 (1: 12.5) 20 + 250 100 80
  • Tebufenozide (1: 1) 0.8 + 0.8 70 0
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica oleraceä) are by spraying with the active ingredient preparation in the desired Concentrated and treated with larvae of the horseradish leaf beetle ⁇ Phaedon cochleariae), as long as the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves ⁇ Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and are infested with the armyworm ⁇ Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • dimethylformamide emulsifier 1.5 parts by weight of dimethylformamide emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Bean leaf discs Phaseolus vulgaris
  • Triticae Tricholine
  • the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.
  • Cyfluthrin (25: 1) 20 + 0.8 70 0 Active substance concentration killing in g / ha in% after 6 d
  • Seed of the soybean (Glycine max) is mixed with the desired amount of active ingredient and spores and water. After drying, 25 seeds each are sown in a pot of sandy loam soil.
  • the effect is determined in%.
  • the effect is calculated on the basis of the number of accumulated soybean plants compared to the untreated control.
  • the following active - spore combination showed a better start - up rate than the individually applied components and the control:

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Abstract

La présente invention concerne des combinaisons de substances actives contenant un composé à substitution halogène de formule (I) et une ou plusieurs autres substances actives pesticides, lesquelles combinaisons sont conçues pour lutter contre les parasites animaux et microbiens.
PCT/EP2011/067137 2010-10-04 2011-09-30 Combinaisons de substances actives insecticides et fongicides Ceased WO2012045680A2 (fr)

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CN103478161A (zh) * 2013-09-05 2014-01-01 江苏龙灯化学有限公司 一种含氯噻啉和甲氧虫酰肼的农药杀虫组合物
CN103518773A (zh) * 2012-12-05 2014-01-22 江苏辉丰农化股份有限公司 具有增效作用的杀虫组合物
CN105746523A (zh) * 2012-05-16 2016-07-13 陕西韦尔奇作物保护有限公司 一种含吡丙醚的杀虫组合物
CN106818149A (zh) * 2017-01-13 2017-06-13 和县聂兴圩蔬菜种植有限责任公司 一种抱子甘蓝的种植培育方法
US10233134B2 (en) 2017-01-24 2019-03-19 Germains Seed Technology, Inc. Anti-fungal seed treatment formulations, treated seeds, and methods

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CN105746523B (zh) * 2012-05-16 2018-06-26 陕西韦尔奇作物保护有限公司 一种含吡丙醚的杀虫组合物
CN103518773A (zh) * 2012-12-05 2014-01-22 江苏辉丰农化股份有限公司 具有增效作用的杀虫组合物
CN103478161A (zh) * 2013-09-05 2014-01-01 江苏龙灯化学有限公司 一种含氯噻啉和甲氧虫酰肼的农药杀虫组合物
CN106818149A (zh) * 2017-01-13 2017-06-13 和县聂兴圩蔬菜种植有限责任公司 一种抱子甘蓝的种植培育方法
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