WO2020078839A1 - Associations de principes actifs - Google Patents

Associations de principes actifs Download PDF

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Publication number
WO2020078839A1
WO2020078839A1 PCT/EP2019/077567 EP2019077567W WO2020078839A1 WO 2020078839 A1 WO2020078839 A1 WO 2020078839A1 EP 2019077567 W EP2019077567 W EP 2019077567W WO 2020078839 A1 WO2020078839 A1 WO 2020078839A1
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Prior art keywords
spp
plants
active
active ingredient
plant
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German (de)
English (en)
Inventor
Arnd Voerste
Silvia Cerezo-Galvez
Marita JOHN
Stefan Herrmann
Leonardo Pitta
Holger Weckwert
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Bayer AG
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Bayer AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P5/00—Nematocides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/02—Acaricides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/04—Insecticides

Definitions

  • the present application relates to mixtures of the compound of the formula (I) below with at least one further active ingredient or product, which is an insecticide or an acaricide or a nematicide. These mixtures (combinations of active ingredients) are suitable for controlling animal pests.
  • active substance combinations (synonymous with “active substance combinations” in the present application are the terms “active substance mixtures” and “mixtures”) containing the compound of the formula (I) and one or more active substances or products from the groups described below are synergistically effective and are suitable for controlling animal pests.
  • the present invention thus relates to active compound combinations comprising the compound of the formula (I)
  • the active compound combinations according to the invention contain, in addition to the compound of the formula (I), one or more mixing partners from the groups described below.
  • Acetylcholinesterase (AChE) inhibitors preferably carbamates selected from Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocomyl, Isocarbyl, Isoprocarb, Isoparboc Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC and Xylylcarb, or Organophosphate selected from Acephat, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos-Methylophifos, Chlorpyrosfos, Chlorpyrosfos
  • GABA-controlled chloride channel blockers preferably cyclodiene organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiprols) selected from ethiprol and fipronil.
  • sodium channel modulators preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta -Cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) -trans-isomerin], deltamine, deltamine (lR) -isomer], esfenvalerate, et
  • nAChR nicotinic acetylcholine receptor
  • nAChR nicotinic acetylcholine receptor
  • Allosteric modulators of the glutamate-dependent chloride channel preferably avermectine / milbemycine selected from abamectin, emamectin benzoate, lepimectin and milbemectin.
  • Juvenile hormone mimetics preferably juvenile hormone analogs selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen.
  • Non-specific (multi-site) inhibitors preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin or sulfuryl fluoride or borax or Brechweinstein or methyl isocyanate producers selected from diazomet and metam.
  • TRPV channel modulators of chordotonic organs selected from pymetrozine and pyrifluquinazone.
  • Mite growth inhibitors selected from clofentezine, hexythiazox, diflovidazine and etoxazole.
  • Microbial disruptors of the insect gut membrane selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subsp aizawai, Bacillus thuringiensis subsp kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bt plant proteins selected from CrylAb, CrylAc, CrylFa, CrylA.105, Cry2Ab, VIP3A , mCry3A, Cry3Ab, Cry3Bb and Cry34Ab 1/35 Abi.
  • Inhibitors of mitochondrial ATP synthase preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide, or propargite or tetradifone.
  • Blockers of the nicotinic acetylcholine receptor channel selected from bensultap, cartap hydrochloride, thiocyclam and thiosultap sodium.
  • Chitin biosynthesis inhibitors type 0, selected from bistrifluron, chlorofluorosuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, fufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
  • Inhibitors of chitin biosynthesis type 1 selected from buprofezin.
  • Molting disruptor (especially for dipteras, ie two-winged birds) selected from cyromazine.
  • Ecdysone receptor agonists selected from chromafenozide, halofenozid, methoxyfenozid and tebufenozid.
  • Octopamine receptor agonists selected from Amitraz.
  • Mitochondrial complex III electron transport inhibitors selected from hydramethylnon, acequinocyl and fluacrypyrim.
  • Mitochondrial complex I electron transport inhibitors preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad, or Rotenon (Derris).
  • Inhibitors of acetyl-CoA carboxylase preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen and spirotetramate.
  • Inhibitors of mitochondrial complex IV electron transport preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.
  • Inhibitors of mitochondrial complex II electron transport preferably beta-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from pyflubumide.
  • Preferred active compound combinations are those in which the compound of the formula (I) is combined with the mixing partners indicated in Table A.
  • the mixing ratios given in Table A are weight ratios. The ratio is to be understood in each case as a compound of formula (I) to mixed partner.
  • Compound (II) is the compound of the formula
  • the insecticidal and / or acaricidal and / or the nematicidal effect of the Active ingredient combinations according to the invention substantially higher than the sum of the effects of the individual active ingredients. There is an unforeseeable real synergistic effect and not just an addition.
  • the active compound combinations according to the invention can also be mixed with a further active compound, for example an insecticide / acaricide / nematicide.
  • the active compound combinations according to the invention are suitable with good plant tolerance, favorable warm-blood toxicity and good environmental compatibility for protecting plants and plant organs, for increasing crop yields, improving the quality of the crop and for combating animal pests, in particular insects, arachnids, helminths, nematodes and molluscs that occur in agriculture, horticulture, animal husbandry, in forests, in gardens and leisure facilities, in the protection of stored goods and materials as well as in the hygiene sector.
  • animal pests in particular insects, arachnids, helminths, nematodes and molluscs that occur in agriculture, horticulture, animal husbandry, in forests, in gardens and leisure facilities, in the protection of stored goods and materials as well as in the hygiene sector.
  • pesticides are preferably used to control animal pests in agriculture. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the pests mentioned above include:
  • Pests from the Arthropoda strain in particular from the Arachnida class, for example Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp.
  • Apogonia spp. Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferrugineus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerachna spp., Epicaerachna spp.
  • Melanotus spp. Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamynchisppy.
  • Idioscopus spp. Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Lopholeucaspis japonica, Lycorma americanula, Macrosiphum spp., Macrosteies facifrons, Mahanarva spp., Melanaphis saccharippium, dirosaphia, Monosaphi costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla s pp., Parabemisia myricae, Paratrioza spp., Parlatoria s
  • Paravespula spp. Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp .; from the order of the Isopoda, for example Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera, for example Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of the Lepidoptera, for example Achroia grisella, Acronic
  • Pseudaletia spp., Pseudaletia et al nipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Ontario segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera pra., Spodoptera pra.
  • Stomopteryx subsecivella Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Tuta absoluta, Vira from the order of the Orthoptera or Saltatoria, for example Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; from the order of the Phthiraptera, for example Damalinia spp., Haematopinus spp., Linognathus spp.,
  • Pests from the Mollusca tribe especially from the Bivalvia class, e.g. Dreissena spp., As well as from the gastropoda class e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;
  • the Bivalvia class e.g. Dreissena spp.
  • gastropoda class e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;
  • Animal parasites from the strains of Plathelminthes and Nematoda e.g. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakispp., Anisakispp., Anisakispp., Anisakispp., Anisakispp., Anisakispp., Anisakispp., Anisakispp.pp.
  • Baylisascaris spp. Brugia malayi, Brugia timori, Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulusotylidiumiphidium, diphyidium spp., Dirofilaria spp., Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Eucoleus spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Filaroides spp., Gongylonppact.
  • Necator spp. Nematodirus spp., Nippostrongylus spp., Oesophagostomum spp., Ollulanus spp., Onchocerca volvulus, Opisthorchis spp., Oslerus spp.,, Ostertagia spp., Oxyuris spp., Paracapillaria spp., Parafilaria spp., Paragonphalus spp., Parppimphalus spp ., Parascaris spp., Passalurus spp., Protostrongylus spp., Schistosom spp., Setaria spp., Spirocerca spp., Stephanofilaria spp., Stephanurus spp., Strongyloides fuelleborni, Strongyloides stercoralis, Strongylus spp., Syngamus sppata., Taenia , Taenia
  • Plant pests from the Nematoda tribe i.e. plant-parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichoderic spp., Dolichoderic spp ., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchichus s
  • Pratylenchus spp. Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., Tylenchulus ., Xiphinema spp .;
  • Pests from the Aphididae family can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the Pemphigidae family can be controlled with particular preference using the active compound combinations according to the invention.
  • pests from the Phylloxeridae family root lice
  • pests from the Psyllidae family leaf fleas
  • pests from the Coccidae family can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the family of the Diaspididae can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the Ortheziidae family can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the family of the Pseudococcidae can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the family of the Aleyrodidae can be controlled particularly preferably with the active compound combinations according to the invention. It is also particularly preferred to use the inventive Combination of active substances to fight pests from the family Thripidae (thrips).
  • pests from the Cicadellidae family can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the Delphacidae family can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the family of the Pentatomidae can be controlled particularly preferably with the active compound combinations according to the invention.
  • pests from the family Chrysomelidae can be controlled particularly preferably with the active compound combinations according to the invention.
  • the present invention further relates to formulations and use forms prepared therefrom as crop protection agents and / or pesticides, such as. B. drench, drip and spray broths, comprising at least one of the active compounds according to the invention.
  • the forms of use contain further crop protection agents and / or pesticides and / or adjuvants which improve the action, such as penetration promoters, for.
  • vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetative fatty acids such as rapeseed oil or soybean methyl or alkanol alkoxylates and / or spreading agents such as alkylsiloxanes and / or salts z.
  • vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetative fatty acids such as rapeseed oil or soybean methyl or alkanol alkoxylates and / or spreading agents such as alkylsiloxanes
  • organic or inorganic ammonium or phosphomium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or the retention-promoting agents such.
  • B. glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizers.
  • Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS) ; these and other possible types of formulations are described, for example, by Crop Life International and in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576.
  • the formulations may contain, in addition to one or more active substances according to the invention, further agrochemical active substances.
  • auxiliaries such as, for example, extenders, solvents, promoters of spontaneity, carriers, emulsifiers, dispersants, antifreezes, biocides, thickeners and / or other auxiliaries, such as, for example, adjuvants.
  • An adjuvant in this context is a component that improves the biological effect of the formulation without the component itself having a biological effect.
  • Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface or penetration.
  • These formulations are prepared in a known manner, for example by mixing the active ingredients with auxiliaries such as extenders, solvents and / or solid carriers and / or other auxiliaries such as surface-active substances. The formulations are either produced in suitable plants or before or during use.
  • Auxiliaries which can be used are substances which are suitable for imparting special properties, such as certain physical, technical and / or biological properties, to the formulation of the active ingredient or to the use forms prepared from these formulations (such as usable crop protection agents such as spray liquors or seed dressings).
  • Suitable extenders are e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalines, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone) , Esters (also fats and oils) and (poly) ethers, the simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, the sulfones and sulfoxides (such as dimethyl sulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalines, chlorobenzenes
  • alcohols and polyols which may also be substituted, etherified
  • organic solvents can also be used as auxiliary solvents.
  • auxiliary solvents e.g. organic solvents
  • aromatics such as xylene, toluene or alkylnaphthalenes
  • chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride
  • aliphatic hydrocarbons such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol as well as their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl formamide and dimethyl sulfoxide, and water.
  • Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons such as e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, e.g. Methanol, ethanol, iso-propanol, butanol or glycol as well as their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide and water.
  • aromatic hydrocarbons e.g. Xylene, toluene or alkylnaphthalenes
  • chlorinated aromatic or aliphatic hydrocarbons
  • Carrier materials in particular come into question: for example ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used.
  • Carriers for granules are possible: e.g.
  • broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.
  • Liquefied gaseous extenders or solvents can also be used.
  • Particularly suitable extenders or carriers are those which are gaseous at normal temperature and pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
  • Examples of emulsifiers and / or foam-generating agents, dispersants or wetting agents with ionic or nonionic properties or mixtures of these surface-active substances are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, for example Alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates
  • dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are present.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are present.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other agents which improve chemical and / or physical stability can also be present. Foam-producing agents or defoamers can also be contained.
  • formulations and use forms derived therefrom can also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids.
  • adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids.
  • Other auxiliary substances can be mineral and vegetable oils.
  • auxiliaries can be contained in the formulations and the use forms derived therefrom.
  • additives are, for example, fragrances, protective Colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestering agents, complexing agents, humectans, spreading agents.
  • the active ingredients can be combined with any solid or liquid additive which is usually used for formulation purposes.
  • penetration promoters include all those substances that are usually used to improve the penetration of agrochemical active substances into plants.
  • Penetration promoters are defined in this context by the fact that they penetrate the cuticle of the plant from the (usually aqueous) application broth and / or from the spray coating and can thereby increase the mobility of the active substances in the cuticle.
  • the method described in the literature can be used to determine this property.
  • Examples include alcohol alkoxylates such as coconut fat ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil methyl esters, fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • alcohol alkoxylates such as coconut fat ethoxylate (10) or isotridecyl ethoxylate (12)
  • fatty acid esters such as rapeseed oil or soybean oil methyl esters
  • fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • plants and parts of plants can be treated.
  • Plants are understood here to mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants).
  • Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
  • the plants which can be treated with the active compound combinations according to the invention include, for. B.
  • turf, vines, cereals for example wheat, barley, rye, oats, rice, corn and millet, triticale
  • Beets for example sugar beets and fodder beets
  • Fruits for example pome fruit, stone fruit and soft fruit, for example apples, pears, plums, peaches, almonds, cherries and berries, e.g. B.
  • Legumes for example beans, lentils, peas and soybeans;
  • Oil crops for example rapeseed, mustard, poppy seeds, olives, sunflowers, coconut, castor oil plants, cocoa beans and peanuts;
  • Cucumber plants for example pumpkin, cucumber and melons;
  • Fiber plants for example cotton, flax, hemp and jute;
  • Citrus fruits for example oranges, lemons, grapefruits and mandarins;
  • Vegetables for example spinach, (head) salad, asparagus, cabbage, carrots, onions, tomatoes, potatoes and peppers;
  • Laurel plants for example avocado, cinnamomum, camphor, or plants such as tobacco, nuts, coffee, eggplant, sugar cane, tea, pepper, grapevines, hops, bananas, natural rubber plants and ornamental plants, for example flowers, shrubs, deciduous trees and conifers such as conifers. This list is not a limitation.
  • Plant parts are to be understood to mean all above-ground and underground parts and organs of the plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes .
  • the plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.
  • the treatment of the plants and parts of plants according to the invention with the active compound combinations is carried out directly or by acting on their surroundings, living space or storage space according to the customary treatment methods, e.g. by dipping, (spraying) spraying, (spraying) spraying, sprinkling, evaporating, atomizing, pouring on, atomizing, (scattering) scattering, foaming, brushing on spreading, injecting, watering (drenching), drip irrigation and on propagation material, in particular in the case of seeds, also by means of dry pickling, wet pickling, slurry pickling, incrustation, single or multi-layer coating.
  • a preferred direct treatment for the plants is leaf application, i.e. the active compound combinations according to the invention are applied to the foliage, the treatment frequency and the application rate being adapted to the infestation pressure of the respective pest.
  • the active compound combinations according to the invention reach the plants via the root system.
  • the plants are then treated by the action of the active compound combinations according to the invention on the plant's habitat.
  • This can be, for example, by drenching, mixing into the soil or the nutrient solution, i.e. the location of the plant (e.g. soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations according to the invention, or by the soil application, i.e. the active compound combinations according to the invention are introduced in solid form (e.g. in the form of granules) into the location of the plants.
  • this can also be done by metering the invention into a solid application form (e.g. as granules) in a flooded rice field.
  • the present invention therefore also relates in particular to a method for protecting seed and germinating plants from attack by pests by treating the seed with the active compound combinations according to the invention.
  • the method according to the invention for protecting seeds and germinating plants from attack by pests comprises a method in which the seeds are treated simultaneously with the active ingredient of the formula (I) and mixing partners in one operation. It also includes a process in which the seed is mixed with the at different times Active ingredient of formula (I) and mixed partners is treated.
  • the invention also relates to the use of the active compound combinations according to the invention for the treatment of seed to protect the seed and the plant resulting therefrom from animal pests.
  • the invention relates to seeds which have been treated with the active compound combinations according to the invention for protection against animal pests.
  • the invention also relates to seeds which were treated at the same time with the active ingredient of the formula (I) and mixing partner.
  • the invention further relates to seeds which have been treated at different times with the active ingredient of the formula (I) and mixing partner.
  • the individual active ingredients of the agent according to the invention can be present in different layers on the seed.
  • the layers which contain the active ingredient of the formula (I) and mixing partners can, if appropriate, be separated by an intermediate layer.
  • the invention also relates to seeds in which the active ingredient of the formula (I) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.
  • the invention also relates to seeds which, after treatment with the active compound combinations according to the invention, are subjected to a film coating process in order to avoid dust abrasion on the seeds.
  • One of the advantages of the present invention is that, because of the special systemic properties of the agents according to the invention, the treatment of the seeds with these agents not only protects the seeds themselves, but also the plants resulting therefrom after emergence from animal pests. In this way, the immediate treatment of the crop at the time of sowing or shortly thereafter can be omitted.
  • active ingredient combinations according to the invention can also be used in particular with transgenic seeds.
  • plants and their parts can be treated according to the invention.
  • plant species and plant cultivars and their parts occurring wildly or obtained by conventional organic breeding methods, such as crossing or protoplast fusion are treated.
  • the traditional propagation and breeding methods can by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or supported or supplemented by bioengineering methods and genetic engineering methods.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated.
  • heterologous gene essentially means a gene that is provided or assembled outside of the plant or plant cell and that, when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, gives the transformed plant new or improved agronomic or other characteristics imparts by expressing a protein or polypeptide of interest or by down-regulating or switching off another gene that is present in the plant or other genes that are present in the plant (e.g. by means of antisense technology, cosuppression technology , RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)).
  • RNAi technology RNA interference technology
  • miRNA technology microRNA technology
  • a heterologous gene that has been integrated into the genome is also called a transgene.
  • a transgene that has been integrated into the plant genome is called a transformation event or transgenic event.
  • Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.
  • the treatment according to the invention can also cause superadditive (“synergistic") effects.
  • superadditive for example, reduced application rates and / or widening of the spectrum of action and / or an increase in the action of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance , easier harvesting, acceleration of ripening, higher crop yields, larger fruits, higher plant height, more intense green color, of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruit, higher storability and / or workability of the Harvest products possible that go beyond the expected effects.
  • the preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which have received genetic material through the genetic engineering modification, which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or against water or soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or workability of the harvested products.
  • transgenic plants are the important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted.
  • the traits are particularly emphasized as the increased defense of the plants against insects by toxins which arise in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF as well as their combinations) are produced in the plants (hereinafter "Bt plants”).
  • the properties (“traits”) which are particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example “PAT” gene).
  • the genes imparting the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants.
  • Examples of "Bt plants” are corn varieties, cotton varieties, soy varieties and potato varieties that are sold under the trade names YIELD GARD ® (e.g. corn, cotton, soy), KnockOut ® (e.g. corn), StarLink ® (e.g.
  • herbicide-tolerant plants are maize varieties, cotton varieties and soy varieties which are marketed under the trade names Roundup Ready ® (tolerance to glyphosate e.g. corn, cotton, soybeans), Liberty Link ® (tolerance to phosphinotricin, e.g. rapeseed), IMI ® (tolerance to Imidazolinone) and STS ® (tolerance to sulfonylureas such as maize).
  • Herbicide-resistant plants (bred conventionally for herbicide tolerance) plants also sold under the name Clearfield ® varieties (eg maize) are mentioned. Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").
  • the plants listed can be treated particularly advantageously according to the invention with the active compound mixtures according to the invention.
  • the preferred ranges given above for the active ingredient combinations also apply to the treatment of these plants.
  • Plant treatment with the active ingredient combinations specifically listed in the present text should be particularly emphasized.
  • Formula for the degree of killing of a combination of two active substances The expected effect for a given combination of two active substances can, according to S.R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, 20-22, 1967) can be calculated as follows:
  • Active ingredient A in an application rate of m g / ha or in a concentration of m ppm means
  • the combination is superadditive in its kill, i.e. there is a synergistic effect.
  • active compound 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by dilution with water containing emulsifier.
  • Chinese cabbage leaf slices (Brassica pekinensis) are sprayed with an active ingredient preparation of the desired concentration and, after drying, are populated with larvae of the horseradish leaf beetle (Phaedon cochleariae).
  • the effect is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined killing values are calculated using the Colby formula.
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by dilution with water containing emulsifier.
  • Corn leaf disks (Zea mays) are sprayed with an active ingredient preparation of the desired concentration and, after drying, are covered with caterpillars of the army worm (Spodoptera frugiperda).
  • the effect is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillar has been killed.
  • the determined killing values are calculated using the Colby formula.
  • Emulsifier alkylary polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by dilution with water containing emulsifier.
  • Emulsifier alkylaryl polyglycol ether
  • the kill is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed.
  • the determined killing values are calculated using the Colby formula. In this test, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:
  • Table D-2 Aphis gossypii spray test
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. To prepare further test concentrations, dilute with water containing emulsifier.
  • Rice plants (Oryza sativa) are sprayed with the active ingredient preparation of the desired concentration and then infected with the brown-backed leafhopper (Nilaparvata lugens).
  • the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed.
  • the determined killing values are calculated using the Colby formula.

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  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Insects & Arthropods (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne des associations de principes actifs contenant, d'une part, des composés connus représentés par la formule (I) et, d'autre part, un ou plusieurs autres principes actifs, lesdites association de principes actifs étant appropriées à la lutte contre des animaux nuisibles.
PCT/EP2019/077567 2018-10-16 2019-10-11 Associations de principes actifs Ceased WO2020078839A1 (fr)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022268815A1 (fr) 2021-06-24 2022-12-29 Syngenta Crop Protection Ag Lutte contre les insectes, les acariens et les nématodes nuisibles

Citations (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003106457A1 (fr) 2002-06-14 2003-12-24 Syngenta Limited Derives de spiroindolinepiperidine
WO2004099160A1 (fr) 2003-05-12 2004-11-18 Sumitomo Chemical Company, Limited Composes de pyrimidine et compostion de lutte contre les animaux nuisibles contenant ces composes
WO2006003494A2 (fr) 2004-06-28 2006-01-12 Syngenta Participations Ag Composes chimiques
WO2006043635A1 (fr) 2004-10-20 2006-04-27 Kumiai Chemical Industry Co., Ltd. Dérivé de 3-triazolylphénylsulfide et insecticide/acaricide/nématicide incluant ledit dérivé au titre de principe actif
WO2007040282A1 (fr) 2005-10-06 2007-04-12 Nippon Soda Co., Ltd. Compose d'amine cyclique et agent pesticide
CN101337937A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具有杀虫活性的n-苯基-3-取代氨基吡唑类化合物
CN101337940A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具杀虫活性的含氮杂环二氯烯丙醚类化合物
JP2010018586A (ja) 2008-07-14 2010-01-28 Meiji Seika Kaisha Ltd Ｐｆ１３６４物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤
WO2010051926A2 (fr) 2008-11-05 2010-05-14 Bayer Cropscience Aktiengesellschaft Nouveaux composés substitués par halogène
WO2010052161A2 (fr) 2008-11-06 2010-05-14 Syngenta Participations Ag Compositions herbicides
CN101715774A (zh) 2008-10-09 2010-06-02 浙江化工科技集团有限公司 一个具有杀虫活性化合物制备及用途
WO2010066780A1 (fr) 2008-12-12 2010-06-17 Syngenta Participations Ag N-oxypipéridines spirohétérocycliques utilisées comme pesticides
WO2011067272A1 (fr) 2009-12-01 2011-06-09 Syngenta Participations Ag Composés insecticides à base de dérivés isoxazoline
WO2011085575A1 (fr) 2010-01-15 2011-07-21 江苏省农药研究所股份有限公司 Composés de formanilide hétérocyclique, leurs procédés de synthèse et leur utilisation
WO2011151146A1 (fr) 2010-05-31 2011-12-08 Syngenta Participations Ag Procédé d'amélioration du rendement d'un produit cultivé
WO2012034403A1 (fr) 2010-09-14 2012-03-22 中化蓝天集团有限公司 Composés de fluorométhoxypyrazole et d'anthranilamide, leurs procédés de synthèse et leurs utilisations
CN102391261A (zh) 2011-10-14 2012-03-28 上海交通大学 一种n-取代噁二嗪类化合物及其制备方法和应用
WO2013050317A1 (fr) 2011-10-03 2013-04-11 Syngenta Limited Formes polymorphes d'un dérivé d'isoxazoline
WO2013050302A1 (fr) 2011-10-03 2013-04-11 Syngenta Participations Ag Dérivés d'isoxazoline utilisés comme composés insecticides
CN103109816A (zh) 2013-01-25 2013-05-22 青岛科技大学 硫代苯甲酰胺类化合物及其应用
CN103232431A (zh) 2013-01-25 2013-08-07 青岛科技大学 一种二卤代吡唑酰胺类化合物及其应用
WO2013115391A1 (fr) 2012-02-01 2013-08-08 日本農薬株式会社 Dérivé d'arylalkyloxy pyrimidine, pesticide à usage agricole et horticole contenant le dérivé d'arylalkyloxy pyrimidine comme ingrédient actif, et son utilisation
CN103265527A (zh) 2013-06-07 2013-08-28 江苏省农用激素工程技术研究中心有限公司 邻氨基苯甲酰胺化合物及其制备方法和应用
WO2013144213A1 (fr) 2012-03-30 2013-10-03 Basf Se Composés de pyridylidène n-substitués et dérivés destinés à lutter contre les animaux nuisibles
EP2647626A1 (fr) 2012-04-03 2013-10-09 Syngenta Participations AG. Dérivés de 1-aza-spiro[4.5]déc-3-ène and 1,8-diaza-spiro[4.5]déc-3-ène en tant que pesticides
WO2013162715A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
CN103524422A (zh) 2013-10-11 2014-01-22 中国农业科学院植物保护研究所 苯并咪唑衍生物及其制备方法和用途
US20140213448A1 (en) 2012-04-27 2014-07-31 Dow Agrosciences Llc Pesticidal compositions and processes related thereto
US20140275503A1 (en) 2013-03-13 2014-09-18 Dow Agrosciences Llc Process for the preparation of certain triaryl rhamnose carbamates
WO2014187846A1 (fr) 2013-05-23 2014-11-27 Syngenta Participations Ag Formulations de mélange en cuve
WO2015058028A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de composés pesticides
WO2015058021A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de de composés pesticides
WO2018011111A1 (fr) 2016-07-12 2018-01-18 Bayer Cropscience Aktiengesellschaft Composés bicycliques utilisés comme pesticides

Patent Citations (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003106457A1 (fr) 2002-06-14 2003-12-24 Syngenta Limited Derives de spiroindolinepiperidine
WO2004099160A1 (fr) 2003-05-12 2004-11-18 Sumitomo Chemical Company, Limited Composes de pyrimidine et compostion de lutte contre les animaux nuisibles contenant ces composes
WO2006003494A2 (fr) 2004-06-28 2006-01-12 Syngenta Participations Ag Composes chimiques
WO2006043635A1 (fr) 2004-10-20 2006-04-27 Kumiai Chemical Industry Co., Ltd. Dérivé de 3-triazolylphénylsulfide et insecticide/acaricide/nématicide incluant ledit dérivé au titre de principe actif
WO2007040282A1 (fr) 2005-10-06 2007-04-12 Nippon Soda Co., Ltd. Compose d'amine cyclique et agent pesticide
WO2007040280A1 (fr) 2005-10-06 2007-04-12 Nippon Soda Co., Ltd. Cyclic amine compound and pest control agent
JP2010018586A (ja) 2008-07-14 2010-01-28 Meiji Seika Kaisha Ltd Ｐｆ１３６４物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤
CN101337940A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具杀虫活性的含氮杂环二氯烯丙醚类化合物
CN101337937A (zh) 2008-08-12 2009-01-07 国家农药创制工程技术研究中心 具有杀虫活性的n-苯基-3-取代氨基吡唑类化合物
CN101715774A (zh) 2008-10-09 2010-06-02 浙江化工科技集团有限公司 一个具有杀虫活性化合物制备及用途
WO2010051926A2 (fr) 2008-11-05 2010-05-14 Bayer Cropscience Aktiengesellschaft Nouveaux composés substitués par halogène
WO2010052161A2 (fr) 2008-11-06 2010-05-14 Syngenta Participations Ag Compositions herbicides
WO2010066780A1 (fr) 2008-12-12 2010-06-17 Syngenta Participations Ag N-oxypipéridines spirohétérocycliques utilisées comme pesticides
WO2011067272A1 (fr) 2009-12-01 2011-06-09 Syngenta Participations Ag Composés insecticides à base de dérivés isoxazoline
WO2011085575A1 (fr) 2010-01-15 2011-07-21 江苏省农药研究所股份有限公司 Composés de formanilide hétérocyclique, leurs procédés de synthèse et leur utilisation
WO2011151146A1 (fr) 2010-05-31 2011-12-08 Syngenta Participations Ag Procédé d'amélioration du rendement d'un produit cultivé
WO2012034403A1 (fr) 2010-09-14 2012-03-22 中化蓝天集团有限公司 Composés de fluorométhoxypyrazole et d'anthranilamide, leurs procédés de synthèse et leurs utilisations
WO2013050317A1 (fr) 2011-10-03 2013-04-11 Syngenta Limited Formes polymorphes d'un dérivé d'isoxazoline
WO2013050302A1 (fr) 2011-10-03 2013-04-11 Syngenta Participations Ag Dérivés d'isoxazoline utilisés comme composés insecticides
CN102391261A (zh) 2011-10-14 2012-03-28 上海交通大学 一种n-取代噁二嗪类化合物及其制备方法和应用
WO2013115391A1 (fr) 2012-02-01 2013-08-08 日本農薬株式会社 Dérivé d'arylalkyloxy pyrimidine, pesticide à usage agricole et horticole contenant le dérivé d'arylalkyloxy pyrimidine comme ingrédient actif, et son utilisation
WO2013144213A1 (fr) 2012-03-30 2013-10-03 Basf Se Composés de pyridylidène n-substitués et dérivés destinés à lutter contre les animaux nuisibles
EP2647626A1 (fr) 2012-04-03 2013-10-09 Syngenta Participations AG. Dérivés de 1-aza-spiro[4.5]déc-3-ène and 1,8-diaza-spiro[4.5]déc-3-ène en tant que pesticides
US20140213448A1 (en) 2012-04-27 2014-07-31 Dow Agrosciences Llc Pesticidal compositions and processes related thereto
WO2013162715A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
WO2013162716A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
CN103232431A (zh) 2013-01-25 2013-08-07 青岛科技大学 一种二卤代吡唑酰胺类化合物及其应用
CN103109816A (zh) 2013-01-25 2013-05-22 青岛科技大学 硫代苯甲酰胺类化合物及其应用
US20140275503A1 (en) 2013-03-13 2014-09-18 Dow Agrosciences Llc Process for the preparation of certain triaryl rhamnose carbamates
WO2014187846A1 (fr) 2013-05-23 2014-11-27 Syngenta Participations Ag Formulations de mélange en cuve
CN103265527A (zh) 2013-06-07 2013-08-28 江苏省农用激素工程技术研究中心有限公司 邻氨基苯甲酰胺化合物及其制备方法和应用
CN103524422A (zh) 2013-10-11 2014-01-22 中国农业科学院植物保护研究所 苯并咪唑衍生物及其制备方法和用途
WO2015058028A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de composés pesticides
WO2015058021A1 (fr) 2013-10-17 2015-04-23 Dow Agrosciences Llc Procédés de préparation de de composés pesticides
WO2018011111A1 (fr) 2016-07-12 2018-01-18 Bayer Cropscience Aktiengesellschaft Composés bicycliques utilisés comme pesticides

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
"FAO Plant Production and Protection Papers", vol. 173, 2004, article "Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides"
"The Pesticide Manual", 2006, BRITISH CROP PROTECTION COUNCIL
BAUR ET AL., PESTICIDE SCIENCE, vol. 51, 1997, pages 131 - 152
CHEMICAL ABSTRACTS, Columbus, Ohio, US; abstract no. 1370358-69- 2
S.R. COLBY: "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", WEEDS, vol. 15, 1967, pages 20 - 22, XP001112961

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022268815A1 (fr) 2021-06-24 2022-12-29 Syngenta Crop Protection Ag Lutte contre les insectes, les acariens et les nématodes nuisibles

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