WO2012074419A2 - Procédé de fabrication de matériaux barrière textiles - Google Patents

Procédé de fabrication de matériaux barrière textiles Download PDF

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Publication number
WO2012074419A2
WO2012074419A2 PCT/PL2011/000120 PL2011000120W WO2012074419A2 WO 2012074419 A2 WO2012074419 A2 WO 2012074419A2 PL 2011000120 W PL2011000120 W PL 2011000120W WO 2012074419 A2 WO2012074419 A2 WO 2012074419A2
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WIPO (PCT)
Prior art keywords
modified
anatase
amount
titanium dioxide
oxide composite
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Ceased
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PCT/PL2011/000120
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English (en)
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WO2012074419A4 (fr
WO2012074419A3 (fr
Inventor
Jadwiga SÓJKA-LEDAKOWICZ
Joanna Olczyk
Anetta Walawska
Teofil Jesionowski
Katarzyna SIWIŃSKA-STEFAŃSKA
Agnieszka Przbylska
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Instytut Wlokiennictwa
Politechnika Poznanska
Inst Wlokiennictwa
Original Assignee
Instytut Wlokiennictwa
Politechnika Poznanska
Inst Wlokiennictwa
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Priority to GB1307313.5A priority Critical patent/GB2500125B/en
Priority to BR112013012019-3A priority patent/BR112013012019B1/pt
Publication of WO2012074419A2 publication Critical patent/WO2012074419A2/fr
Publication of WO2012074419A3 publication Critical patent/WO2012074419A3/fr
Publication of WO2012074419A4 publication Critical patent/WO2012074419A4/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, e.g. by ultrasonic waves, corona discharge, irradiation, electric currents or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Sonic or ultrasonic waves; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08—Processes in which the treating agent is applied in powder or granular form

Definitions

  • the present invention relates to a process of manufacturing textile barrier materials from polyester fibers or their blends containing other fibers by sulfate and/or emulsion precipitation method as opposed to well-known hydrolysis and condensation of organic precursors (the so-called sol-gel method).
  • These materials demonstrate an exceptional resistance to UV radiation and microorganisms as well as photocatalytic properties thanks to introducing into the structure of the textile material the anatase type of titanium dioxide or its oxygen composite Ti0 2 -Si0 2 the size of nano- and micrometric particles.
  • the barrier properties of the textiles against UV radiation may result from the dense textile texture, as described in the patent EP644820B 1. They can also be effectively improved by, among other things, the use of UV absorbers, which are colorless substances that absorb radiation in the wavelength range of 290-400 nm. Depending on the mechanism of action, the UV absorbers can be divided into two groups:
  • Inorganic absorbers or so-called physical blockers, which reflect and scatter UV radiation.
  • the most commonly used blockers are zinc oxide (ZnO) and titanium dioxide (Ti0 2 ).
  • Nano- Ti0 2 with highly developed surface of contact has the ability to block UV radiation and possesses self-cleaning (photocatalytic) properties. For this reason, it is readily applied to textiles. Due to its high capacity for UV absorption, as well as reflection and scattering of UV radiation, titanium dioxide is used as a physical blocker of UV radiation, increasing the barrier capacity of the textiles it modifies.
  • the patent application JP 2006321087 (A) describes the barrier material based on polyester containing metal oxides such as silicon, titanium, tin, zinc, aluminum, indium.
  • the anatase type titanium dioxide for modification of polyester textile material is also described in the following JP patent applications: 08-276397, 08-281715, 07-206059, 06- 142167, 01-115764, 01-014066.
  • Ti0 2 -Si0 2 oxide composite One functional material with special useful properties is the Ti0 2 -Si0 2 oxide composite.
  • the degree of dispersion of titanium dioxide is much greater, and its activity is higher. This also contributes to the transformation from anatase to rutile form, which prevents the growth of titanium dioxide particles during thermal treatment.
  • silica increases the specific surface area of titanium dioxide and contributes to the formation of ⁇ Ti-O-Si ⁇ bonds. All of this increases photocatalytic activity of the Ti0 2 - Si0 2 composite [Ren S., Zhao X., Zhao L., Yuan M., Yu Y., Guo Y., Wang Z., Journal of Solid State Chemistry.
  • Silica-coated titanium dioxide shows a higher thermal and mechanical stability, at the same time a reduced tendency for agglomeration of the particles and an increase the surface activity of the final product are observed.
  • the nature of the invention is the method for obtaining textile barrier material against UV radiation and microbes, while using titanium dioxide particles of the anatase type which are micronized by means of alkoxysilanes or its Ti0 2 -Si0 2 oxide composite introduced into the structure of textile material.
  • the process is performed in two stages.
  • the first stage consists in proper preparation of the textile material in order to increase its adhesive properties.
  • the surface of the polyester fibers is modified by low temperature plasma treatment (non-equilibrium) in the atmosphere of various gases, preferably carbon dioxide or argon.
  • Another way to modify the surface is a controlled treatment of the textile product in a solution of sodium hydroxide at a temperature above 90° C.
  • micronized particles of titanium dioxide of the anatase type or its oxide composites are introduced into the structure of the textile material in the amount that is not less than 0.5 wt%. and not more than 10% by weight.
  • Polyester fiber products are padded with aqueous dispersion containing micronized particles of functionalized Ti0 2, a wetting agent, and a thickening agent.
  • the dispersion is subjected to intense homogenization by means of a homogenizer at the proper time and speed. Once the padding has been completed in a two-roller padding machine, the excess of dispersion is removed from the samples in order to obtain an adequate level of deposition. Then, the samples are dried and heated up in a heat coating machine.
  • aqueous dispersion with 1-5 wt.% of the modified Ti0 2 preparation, a wetting agent - polyethylene glycol (PEG) in the amount of 5-15 wt%. and hydroxyethyl cellulose thickener (HEC) - in the amount of 1-5 wt%.
  • PEG polyethylene glycol
  • HEC hydroxyethyl cellulose thickener
  • Another way of incorporating Ti0 2 particles into the structure of the textile product is coating.
  • a properly prepared paste on the basis of acrylic resin and containing the modified titanium dioxide of nano- and micrometric size, a thickening agent, and a wetting agent are applied to a textile carrier using a special kit for application of nanostructured film coatings.
  • the film's thickness is controlled by adjusting the feeding slot/gap between the coating blade and the textile material being coated.
  • the product with the applied coating is dried and heated up.
  • paste containing 1-3 wt.% of modified Ti0 2, a wetting agent - polyethylene glycol (PEG) in the amount of 5-15 wt.%, styrene-acrylic resin with no more than 20 wt.%, acrylic thickening agent of 3-10 wt.%.
  • PEG polyethylene glycol
  • An anatase sample was placed in a reactor with the capacity of 500 cm 3 and sprayed with the 3-Methacryloxypropyltrimethoxysilane solution by means of a special spray system (atomizer).
  • the solution contained a binding silane compound in the amount of 0.5 wt. parts of silane per 100 wt. parts of anatase.
  • the binding silane compound was hydrolyzed in a mixture of methanol and water at the volume ratio of 4: 1. Then, the system was stirred for 1 hour in order to perfectly homogenize the anatase sample with the solution of the modifying compound and the solvent was distilled off.
  • the modified sample was dried at the temperature of 105°C in a stationary dryer for 2 hours.
  • an aqueous dispersion was made containing 3 wt%. of this sample, a wetting agent - polyethylene glycol in the amount of 10 wt%., and a thickening agent - hydroxyethyl cellulose in the amount of 1 wt%., with which the polyester fabric was padded after having been subjected to alkaline pre- treatment process.
  • the dispersion was subjected to intense homogenization using a homogenizer for the duration of 60 s with the assumed speed of 20000 r / min. After the padding in a two-roller padding machine and removing the excess dispersion, the samples were dried for 3 minutes at the temperature of 100°C in a heating unit and heated up at the same temperature for 10 minutes.
  • the alkaline pre-treatment of polyester fabric was conducted in a laboratory dyeing apparatus at bath ratio 10:1, in a bath composed of sodium hydroxide, 38° BE - 1.8 g/dm3, sodium carbonate - 4.1 g/dm3, sequestering and wetting agent - 1,0 g/dm3.
  • the process was carried out at the temperature of 98°C for the duration of 60 minutes.
  • the fabric was rinsed for 10 minutes in a water bath at the temperature of 80 ° C, and then under running water.
  • Example I using 1 wt. part of silane per 100 wt. parts of anatase.
  • the process of modifying titanium dioxide was carried out in the same way as in Example I using 3 wt. parts of silane per 100 wt. parts of anatase.
  • the modification process was carried out in the same way as in Example I.
  • Vinyltrimethoxysilane was used as a silane.
  • an aqueous dispersion was made containing 3 wt% of the sample, a wetting agent - polyethylene glycol in the amount of 10 wt%. and a thickening agent - hydroxyethyl cellulose in the amount of 1 wt%. It was then padded onto the polyester nonwoven fabric which had previously been subjected to plasma pre-treatment.
  • the dispersion was subjected to intense homogenization by means of a homogenizer for the duration of 60 s with the assumed speed of 20 000 r/min.
  • the samples were dried for 3 minutes at the temperature of 100°C in a heating unit and heated up at the same temperature for 10 minutes.
  • the plasma treatment of the polyester nonwoven fabric was carried out at RF discharge (13.56 MHz frequency). Plasma was generated in argon. The duration of the treatment was 15 s.
  • N-2-(aminoethyl)-3-aminopropyltrimethoxysilane was used as silane.
  • a coating paste was obtained on the basis of acrylic resin in the amount of 10 wt.% containing 3 wt.% of anatase preparation, a thickening agent of 4.5 wt.%, and a wetting agent (polyethylene glycol) of 10 wt.% with uniform dispersion and viscosity of 68 dPas which was applied to a polyester fabric previously subjected to alkaline pre-treatment process.
  • polyester fabric was performed using a special kit for application of nanostructured coatings.
  • the film's thickness was controlled by adjusting the feeding slot/gap between the coating blade and the textile material being coated - 0.05 mm.
  • the samples were dried (heated up) at the temperature of 120°C for the duration of 6 minutes.
  • the alkaline pre-treatment of polyester fabric was conducted in a laboratory dyeing apparatus at 10: 1 bath ratio, in a bath composed of sodium hydroxide, 38° BE - 1.8 g/dm3, sodium carbonate - 4.1 g/dm3, sequestering and wetting agent - 1,0 g/dm3.
  • the process was carried out at the temperature of 98°C for the duration of 60 minutes.
  • the fabric was rinsed for 10 minutes in a water bath at the temperature of 80° C, and then under running water.
  • a suspension of titanium sulfate was centrifuged for 30 minutes at the speed of 2500 rpm/min, until a clear solution was obtained.
  • two emulsions were prepared.
  • the E2 emulsion was formed, which consisted of cyclohexane, titanium sulfate, and nonionic surfactants. The components of this emulsion were homogenized.
  • the El emulsion was prepared consisting of cyclohexane, 20% solution of sodium silicate and hydrophobizing agents. The El emulsion was also homogenized.
  • the process of coating polyester nonwoven fabric was performed using a special kit for application of nanostructured coatings. The film's thickness was controlled by adjusting the feeding slot/gap between the coating blade and the textile material being coated - 0.05 mm.
  • the samples were dried (heated up) at the temperature of 120°C for the duration of 6 minutes.
  • the plasma treatment of the polyester nonwoven fabric was carried out at RF discharge (13.56 MHz frequency). Plasma was generated in carbon dioxide. The duration of the treatment was 15 s.
  • the barrier properties of the modified textiles for UV radiation were determined based on the measurements of the transmittance of UV radiation of fabric by means of the spectrophotometric method.
  • the photooxidative activity was assessed based on the possibility of removing organic pollutant - formaldehyde, from the air in a closed system in which a sample of a textile product with titanium dioxide was placed - photocatalysing decomposition reactions of simple inorganic compounds.
  • a product is obtained with barrier properties for UV radiation expressed by a reduced value of spectral transmittance in the whole UV range (increasing of absorption) and by the value of the coefficient UPF>50 determined in accordance to the standard EN 13758-1. It is characterized by a very good photooxidative activity (the decomposition efficiency of formaldehyde is 90-98%) and the inhibitory action of microorganisms like Bacillus subtilis, Micrococcus fla s, Pseudomonas aureginosa, Escherichia coli (Table 1).
  • the antimicrobial properties of the modified textile product containing Ti0 2 of the anatase type in its structure were assessed by a screening method according to the standard EN ISO 20645 (agar plate diffusion test), based on the presence and size of the inhibition zone inhibiting the growth of the tested microorganisms around the examined sample and the growth, or lack thereof, in the contact zone of the sample with the culture medium.
  • the resulting protective effect against UV radiation and the development of microorganisms is stable and maintained even after 10 laundry cycles.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Catalysts (AREA)
  • Artificial Filaments (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

La présente invention concerne un procédé de fabrication de matériaux barrière textiles à partir de fibres polyester par la méthode de précipitation de sulfate et/ou d'émulsion, qui constitue des matériaux barrière contre le rayonnement UV et des micro-organismes, mettant en œuvre un support textile modifié avec des alcoxysilanes, du dioxyde de titane anatase ou le composite d'oxyde de Ti02-Si02.
PCT/PL2011/000120 2010-11-29 2011-11-28 Procédé de fabrication de matériaux barrière textiles Ceased WO2012074419A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB1307313.5A GB2500125B (en) 2010-11-29 2011-11-28 Process of manufacturing textile barrier materials
BR112013012019-3A BR112013012019B1 (pt) 2010-11-29 2011-11-28 processo de fabricação de materiais de barreira de tecido

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PLP-393076 2010-11-29
PL393076A PL219301B1 (pl) 2010-11-29 2010-11-29 Sposób wytwarzania barierowych materiałów włókienniczych

Publications (3)

Publication Number Publication Date
WO2012074419A2 true WO2012074419A2 (fr) 2012-06-07
WO2012074419A3 WO2012074419A3 (fr) 2012-08-02
WO2012074419A4 WO2012074419A4 (fr) 2012-11-01

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BR (1) BR112013012019B1 (fr)
GB (1) GB2500125B (fr)
PL (1) PL219301B1 (fr)
WO (1) WO2012074419A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015011725A2 (fr) 2013-07-22 2015-01-29 Reliance Industries Limited Fibre pouvant être utilisée pour le conditionnement et le stockage de produits agricoles végétaux
CN110102352A (zh) * 2019-06-11 2019-08-09 河北燕园众欣石墨烯科技有限公司 一种负载型TiO2/纤维复合光催化剂的制备方法
CN111139550A (zh) * 2019-12-30 2020-05-12 江苏众恒可来比家具有限公司 一种床品填充用自清洁聚酯纤维及其制备方法
CN112552061A (zh) * 2020-12-28 2021-03-26 海鹰空天材料研究院(苏州)有限责任公司 一种陶瓷纤维板的制备方法
CN114875659A (zh) * 2022-06-13 2022-08-09 安徽元琛环保科技股份有限公司 一种超疏水滤料及其制备方法

Citations (16)

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Publication number Priority date Publication date Assignee Title
US4176089A (en) 1978-08-03 1979-11-27 Exxon Research & Engineering Co. Process for the preparation of silica-titania and catalysts comprising the same
US4410501A (en) 1979-12-21 1983-10-18 Snamprogetti S.P.A. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
US4547557A (en) 1984-07-09 1985-10-15 Phillips Petroleum Company Silica-titania cogel from two-step hydrolysis
JPS6414066A (en) 1987-07-08 1989-01-18 Nec Corp Printing head cooling system
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US5162283A (en) 1991-01-22 1992-11-10 Mobil Oil Corporation Highly porous amorphous titania and titania/silica phases
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JPH07206059A (ja) 1994-01-24 1995-08-08 Toutsuu Haisou Service Kk 絵画用コンテナー
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