WO2012173413A3 - 일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합 - Google Patents

일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합 Download PDF

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Publication number
WO2012173413A3
WO2012173413A3 PCT/KR2012/004708 KR2012004708W WO2012173413A3 WO 2012173413 A3 WO2012173413 A3 WO 2012173413A3 KR 2012004708 W KR2012004708 W KR 2012004708W WO 2012173413 A3 WO2012173413 A3 WO 2012173413A3
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WO
WIPO (PCT)
Prior art keywords
carbon monoxide
catalyst
olefin
same
suspension polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/KR2012/004708
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English (en)
French (fr)
Other versions
WO2012173413A2 (ko
Inventor
이분열
박지혜
오경환
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Ajou University Industry Academic Cooperation Foundation
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Ajou University Industry Academic Cooperation Foundation
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Filing date
Publication date
Application filed by Ajou University Industry Academic Cooperation Foundation filed Critical Ajou University Industry Academic Cooperation Foundation
Publication of WO2012173413A2 publication Critical patent/WO2012173413A2/ko
Publication of WO2012173413A3 publication Critical patent/WO2012173413A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Polyethers (AREA)

Abstract

본 발명은 일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합 제조 공정에 관한 것으로서, 보다 구체적으로는 하이드로포빅한 그룹을 가진 알킬 또는 아릴 설포네이트 음이온(RSO3 -)을 포함하는 화학식 1로 표시되는 화합물, 상기 화합물을 이용한 일산화탄소/올레핀 공중합 촉매 및 상기 촉매를 이용하여 폴리케톤을 제조하는 방법에 관한 것이다. 상기 촉매를 이용하는 경우 일산화탄소/올레핀 현탁중합을 구현할 수 있으며, 구형 또는 과립형으로 입자 모양이 조절되고, 벌크덴서티가 높은 폴리머 입자를 제조할 수 있어 대량 생산에 용이하다.
PCT/KR2012/004708 2011-06-16 2012-06-14 일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합 Ceased WO2012173413A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110058756A KR101145176B1 (ko) 2011-06-16 2011-06-16 일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합
KR10-2011-0058756 2011-06-16

Publications (2)

Publication Number Publication Date
WO2012173413A2 WO2012173413A2 (ko) 2012-12-20
WO2012173413A3 true WO2012173413A3 (ko) 2013-03-28

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PCT/KR2012/004708 Ceased WO2012173413A2 (ko) 2011-06-16 2012-06-14 일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합

Country Status (2)

Country Link
KR (1) KR101145176B1 (ko)
WO (1) WO2012173413A2 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113912836B (zh) * 2021-12-03 2023-05-12 黄河三角洲京博化工研究院有限公司 一种有效提升聚酮产品热稳定性的方法
CN116622062B (zh) * 2022-02-11 2025-09-09 黄河三角洲京博化工研究院有限公司 一种连续溶液聚合法制备脂肪族聚酮的方法及脂肪族聚酮
CN117164641A (zh) * 2023-08-24 2023-12-05 大连理工大学 一种合成聚酮树脂的镍配合物、制备方法及应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4877860A (en) * 1987-07-30 1989-10-31 Shell Oil Company Catalytic copolymerization of carbon monoxide/olefin with ketone/alcohol diluent
US4880900A (en) * 1987-07-23 1989-11-14 Shell Oil Company Carbon monoxide/olefin polymerization process with bis (diaryl phosphino) 2-silapropane containing catalyst
EP0743336A2 (en) * 1995-05-18 1996-11-20 Shell Internationale Researchmaatschappij B.V. A process for the preparation of a linear alternating copolymer of carbon monoxide with ethene and another olefinically unsaturated compound

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0074333A1 (de) * 1981-08-25 1983-03-16 M. Schaerer A.G. Hydraulischer Antrieb für den Arbeitskolben einer Kaffeemaschine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4880900A (en) * 1987-07-23 1989-11-14 Shell Oil Company Carbon monoxide/olefin polymerization process with bis (diaryl phosphino) 2-silapropane containing catalyst
US4877860A (en) * 1987-07-30 1989-10-31 Shell Oil Company Catalytic copolymerization of carbon monoxide/olefin with ketone/alcohol diluent
EP0743336A2 (en) * 1995-05-18 1996-11-20 Shell Internationale Researchmaatschappij B.V. A process for the preparation of a linear alternating copolymer of carbon monoxide with ethene and another olefinically unsaturated compound

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DRENT, E. ET AL.: "Palladium-Catalyzed Alternating Copolymerization of Alkenes and Carbon Monoxide.", CHEM. REV., vol. 96, 1996, pages 663 - 681 *

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KR101145176B1 (ko) 2012-05-14
WO2012173413A2 (ko) 2012-12-20

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