WO2013108384A1 - Dentifrices en forme de film - Google Patents

Dentifrices en forme de film Download PDF

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Publication number
WO2013108384A1
WO2013108384A1 PCT/JP2012/051003 JP2012051003W WO2013108384A1 WO 2013108384 A1 WO2013108384 A1 WO 2013108384A1 JP 2012051003 W JP2012051003 W JP 2012051003W WO 2013108384 A1 WO2013108384 A1 WO 2013108384A1
Authority
WO
WIPO (PCT)
Prior art keywords
film
dentifrice
pigment
present
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2012/051003
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English (en)
Japanese (ja)
Inventor
月岡忠夫
西村美佐夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tsukioka Co Ltd
Original Assignee
Tsukioka Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tsukioka Co Ltd filed Critical Tsukioka Co Ltd
Priority to PCT/JP2012/051003 priority Critical patent/WO2013108384A1/fr
Publication of WO2013108384A1 publication Critical patent/WO2013108384A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

Definitions

  • the present invention relates to a film-like dentifrice, and more particularly to a film-like dentifrice having good foaming, excellent detergency, can be easily attached to a toothbrush, and has excellent usability and usability.
  • the inventors of the present invention include a water-soluble polymer and a detergent composition containing at least a foaming detergent as a component, and the content of the foaming detergent is 15 to 45% by weight in the whole in Patent Document 1.
  • a film-like dentifrice is proposed as a dentifrice. Since the film-like dentifrice contains a foaming detergent at a high concentration, the film-like dentifrice has excellent detergency even in the form of a film having a small mass.
  • an object of the present invention is to provide a film-like dentifrice which has good foaming, excellent cleaning power, can be easily attached to a toothbrush, and has excellent usability and usability.
  • a film-like dentifrice prepared by mixing a water-soluble edible polymer and an effervescent detergent component, characterized in that voids exist in 20 to 60% of the total volume of the film-like dentifrice. Film dentifrice. 2.
  • the film-like dentifrice of the present invention can be used in a fixed amount every time it is used, has good foaming, is excellent in cleaning power, can be easily attached to a toothbrush, and has excellent usability and usability.
  • FIG. 1 is a perspective view showing an embodiment of the film-like dentifrice of the present invention.
  • 2 is a cross-sectional view taken along line II-II in FIG.
  • FIG. 3 is a perspective view schematically showing a part of a continuous body of the film-like dentifrice of the present invention.
  • FIG. 4 is a perspective view showing how the continuum shown in FIG. 3 is used.
  • FIG. 5 is a cross-sectional view (corresponding to FIG. 2) showing another embodiment of the film-like dentifrice of the present invention.
  • the film-like dentifrice 1 of this embodiment shown in FIG. 1 has a rectangular shape, and comprises a film body 10 and a coating layer 20 that covers the front surfaces of both the front and back surfaces.
  • a plurality of linear recesses 30 formed by embossing are provided on the surface of one side of the film-like dentifrice 1.
  • the recess 30 is provided along the longitudinal direction of the film-like dentifrice.
  • the recess 30 can easily bite into the tip of the toothbrush, and the film strength is improved, so that the film-like dentifrice can be easily inserted into the toothbrush, and the usability can be particularly improved.
  • the taper part 40 is formed in the edge part by the side with the recessed part 30 of a film-form dentifrice, and it is formed so that it can insert in between the hairs of a toothbrush more.
  • the surface on the opposite side to the surface in which the recessed part 30 is provided is not provided with the recessed part 30, but is made into a flat surface.
  • the size of the film-like dentifrice of the present invention can be arbitrarily set within a range of 1 to 3 cm on one side and 1 to 3 cm on the other side, and this embodiment is also in a rectangular shape selected within that range.
  • one side is 1 to 2 cm and the other side is 1.5 to 2.5 cm.
  • the shape is rectangular.
  • the shape is not particularly limited, such as various shapes such as a square, a circle, a triangle, and an ellipse, and various character shapes.
  • the thickness of the film-like dentifrice of the present invention is preferably from 100 to 2,000 ⁇ m, more preferably from 200 to 500 ⁇ m.
  • the width of the recess 30 is preferably 0.3 to 1 mm, and the interval between the recesses 30 is preferably 0.5 to 3 mm in order to realize a desired effect by providing the recess.
  • the film-like dentifrice 1 of the present embodiment is formed into a film by mixing a water-soluble edible polymer and a foaming detergent component, and is 20 to 60%, preferably 25 to 40% of the total volume. It is characterized in that there are voids 11 in the surface. When the gap 11 is less than 20% of the total volume of the film-like dentifrice, foaming occurs and the feeling of use is poor.
  • the void 11 has a substantially spherical shape, and its size (average diameter) is preferably 20 to 100 ⁇ m from the viewpoint of sufficiently achieving the desired effect of the present invention, and more preferably 30 to 80 ⁇ m. .
  • the optimal form in the present invention is a form in which a large number of substantially spherical fine voids are formed in the film, and the total volume of the voids is within the above-mentioned range with respect to the volume of the entire film. Further, the formation of the concave portion 30 compensates for the decrease in film strength due to the provision of a large number of spherical fine voids, and the film-like dentifrice is cracked or broken at the start of use before use. It can prevent and can exhibit a favorable usability.
  • the size of the gap can be measured by, for example, observing a surface of the film dentifrice or a cross section obtained by cutting the film dentifrice at a predetermined position with a 400 times microscope.
  • the film-like dentifrice of this embodiment is formed by mixing arbitrary components in addition to the following essential components.
  • the water-soluble edible polymer is a component that forms the matrix of the film-like dentifrice of the present invention.
  • cellulose derivatives such as hydroxypropylmethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, Pullulan, pectin, arabinoxylan, soybean polysaccharide, polyvinylpyrrolidone, polyvinyl alcohol, sodium alginate, polyethylene glycol, tragacanth gum, guar gum, locust bean gum, xanthan gum, glucomannan, gum arabic, polyacrylic acid, methyl methacrylate copolymer, carboxyvinyl polymer , Hydroxypropylated starch, carboxymethylated starch, octenyl succinic acid starch, dextst Emissions, chitin, chitosan, levan, elsinan, mention may be made of collagen, gelatin, gluten, soy protein, casein, albumin and the like, may be used alone or in mixtures thereof in use.
  • polyvinyl alcohol partially saponified product
  • polyethylene glycol 400 polyethylene glycol 400
  • cellulose derivative are preferably used as the cellulose derivative, particularly hydroxypropylmethylcellulose or carboxymethylcellulose. be able to.
  • the foaming detergent as the foaming detergent component is a component for exerting the cleaning ability as a dentifrice, and specifically includes, for example, sodium lauryl sulfate, lauryldimethylaminoacetic acid betaine, lauryltrimethylammonium chloride, polyoxyethylene Sodium lauryl ether sulfate, PEG-2 hydrogenated castor oil, sodium cocoamphoacetate, potassium stearate, sucrose fatty acid ester, polyglycerin fatty acid ester, sodium stearoyl glutamate, N-stearoyl-N- Examples include methyl taurine sodium, polyoxyethylene alkyl ether, benzalkonium chloride, polysorbate 80, coconut oil fatty acid sodium, saponin, lecithin and the like, and when used, a single compound or a mixture of two or more thereof may be used. it can.
  • the blending ratio of each of the above components is preferably 50 to 90 parts by weight of foaming detergent with respect to 100 parts by weight of the water-soluble edible polymer, and more preferably 60 to 80 parts by weight of foaming detergent. preferable.
  • Coating agent Materials for forming the coating layer include cellulose derivatives such as hydroxypropylmethylcellulose (HPMC), carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, pullulan, pectin, arabinoxylan, soybean polysaccharide, polyvinylpyrrolidone, polyvinyl alcohol, sodium alginate , Polyethylene glycol, tragacanth gum, guar gum, locust bean gum, xanthan gum, glucomannan, gum arabic, polyacrylic acid, methyl methacrylate copolymer, carboxyvinyl polymer, hydroxypropylated starch, carboxymethylated starch, octenyl succinic acid starch, dextrin, chitin , Chitosan, levan, erucinan, collagen Gelatin, zein, gluten, soy protein, casein, can as albumin or the like can be used alone or in combination is in use.
  • the film-like dentifrice of the present invention can be formed into a film by adding and mixing sugar alcohol.
  • Sugar alcohol is a component having a caries-preventing action, and specific examples include, for example, xylitol, sorbitol, erythritol and the like, and can be used alone or as a mixture of two or more thereof.
  • the amount of sugar alcohol used is preferably 5 to 15 parts by weight, more preferably 7 to 13 parts by weight, based on 100 parts by weight of the water-soluble edible polymer.
  • components such as an anti-adhesive agent, a plasticizer, a fragrance, a sweetener, a medicinal component, an abrasive, a saliva promoter, a colorant and the like can be added without departing from the spirit of the present invention.
  • the adhesion preventing agent crystalline cellulose that is insoluble in water can be suitably used.
  • the adhesion preventing agent is contained to prevent adhesion between the film-like dentifrices, and is effective when the coating layer is not formed.
  • the content is preferably 0.5 to 10% by weight, particularly 1 to 4% by weight, based on the whole film dentifrice.
  • Perfumes include mint flavors such as peppermint and spearmint; spice flavors such as cinnamon and ginger; citrus flavors such as orange, lemon, grapefruit, citrus and lime; blueberries, apple, strawberry, melon, grape, banana, Examples thereof include fruit flavors such as peach and pineapple, and can be used alone or in admixture of two or more.
  • sweeteners examples include saccharin sodium, aspartame, acesulfame potassium, sucralose, thaumatin, disodium glycyrrhizinate, stevia extract, licorice extract, D-xylose, erythritol, sorbitol, maltitol, xylitol and the like. Can be used alone or in admixture of two or more.
  • Medicinal ingredients include d- ⁇ -tocopherol preparation, dipotassium glycyrrhizinate, chlorhexidine hydrochloride, cetylpyridium chloride, allantoin, polyethylene glycol, triclosan, malic acid, tocopherol acetate, ⁇ -lipoic acid, flavonoids, vitamin C, coenzyme Q10, vitamin A, l-menthol, essential oils, catechin, eucalyptus extract, rosemary extract, methyl paraoxybenzoate, xylitol, CPP-ACP, hydroxyapatite, fukuronori extract, potassium fluoride, chamomile extract, buckwheat extract, nettle Extract, Latania tincture, myrrh tincture, licorice extract, gardenia extract, stearyl glycyrrhetinate, dextranase, sodium fluoride, sodium monofluorophosphate Um, water-soluble collagen, various amino acids,
  • a saliva promoter is a component that facilitates the dissolution of the film by promoting the secretion of saliva when a film-like dentifrice is included in the mouth.
  • the content is preferably 1 to 10% by weight.
  • saliva promoters include organic acids such as citric acid, malic acid, fumaric acid, tartaric acid, lactic acid, ascorbic acid, and gluconic acid, and l-menthol. Can be used.
  • coloring agents food red No. 2 and its aluminum lake, food red No. 3 and its aluminum lake, food red No.
  • food red No. 102 food red No. 104, food red No. 105, food red 106 No., purple potato pigment, gardenia red pigment, elderberry pigment, perilla pigment, purple corn pigment, grape juice pigment, beet red, cochineal pigment (neutral), lac pigment (neutral), safflower red pigment, red beetle pigment, boysen Berry dye, Akane dye, Food yellow No. 4 and its aluminum lake, Food yellow No.
  • Anato dye Water-soluble Anato, Cochineal dye (acidic), Lac dye (acidic), Pepper dye, Turmeric dye, Orange Pigment, gardenia yellow, corn Koshi pigment, carrot carotene, ⁇ -carotene, safflower yellow, riboflavin (vitamin B2), edible green 3 and its aluminum lake, chlorophyllin, chlorophyll, copper chlorophyllin sodium, iron chlorophyllin sodium, edible blue 1 and its aluminum lake, Food blue No. 2 and its aluminum lake, gardenia blue pigment, spirulina pigment, cacao pigment, onion pigment, caramel pigment, cucumber pigment, tamarind pigment, etc. can be mentioned, and when used, one or a mixture of two or more be able to.
  • egg yolk powder containing IgY (egg yolk antibody) as a glucosyltransferase activity inhibitor may be included.
  • the film-like dentifrice of this embodiment first dissolves a water-soluble edible polymer, a detergent component, and the above-described optional components in a solvent, and obtains a mixture coating solution of film raw materials.
  • the obtained coating liquid is stirred using a homogenizer, an in-line stirrer (in-line mixer), etc. to generate a large number of fine bubbles inside the coating liquid, and the fine-bubble-containing coating liquid is prepared to obtain the fine
  • the bubble-containing coating solution is applied onto a base material made of a synthetic resin film such as a polyethylene film or a polypropylene film.
  • the coating can be performed by using various coater machines such as a comma coater machine and a knife coater machine, using gravure printing, silk printing, and other well-known printing methods, or by brushing, spraying, or the like.
  • various coater machines such as a comma coater machine and a knife coater machine, using gravure printing, silk printing, and other well-known printing methods, or by brushing, spraying, or the like.
  • an in-line homomixer it is preferable to treat at 30 to 70 Hz for the generation of bubbles.
  • a homomixer it is 1 to 10 minutes at 5000 to 10000 revolutions, and in the case of a propeller type stirrer, 1000 to 2000 revolutions. Stirring is preferably performed for 10 to 40 minutes.
  • the applied coating solution is dried with warm air or far infrared rays.
  • a forming material liquid for forming a coating layer is applied to the surface of the obtained film main body 10 to a desired thickness, and dried to obtain a long film-like dentifrice. Furthermore, after embossing the surface of the obtained elongate thing, it peels off from a base material, winds up, and the film-form dentifrice 1 is obtained by cutting to a fixed magnitude
  • embossing can be performed according to the following conditions.
  • Line width 0.5-3mm Interval: 1 to 3mm Temperature: 40-200 ° C
  • Linear pressure 1 to 10 kP
  • the solvent that can be used at this time the following can be used.
  • ethanol water, ethyl acetate or a combination of these solvents (for example, ethanol-water mixture, ethanol-ethyl acetate mixture) can be most preferably used.
  • the film-like dentifrice 1 of the present embodiment is attached by inserting the film vertically on the toothbrush bristle part with the finger between the fingers or by placing the film on the upper surface of the toothbrush bristle, watering, and film-like toothpaste in the mouth.
  • the film-like dentifrice 1 is quickly dissolved in a similar manner to the paste-like dentifrice after 2 to 3 seconds by saliva and water, and foams and teeth can be brushed.
  • the concave portion can be adjusted so as to be along the long axis direction of the toothbrush bristle.
  • the product form at the time of use can be as follows.
  • the film-form dentifrice of this invention can also be used for use as a film-form dentifrice continuum shown in FIG. That is, the film-like dentifrice continuum 100 shown in FIG. 3 includes a base sheet 101 made of a long synthetic resin film, and a long film dentifrice 1 placed on the surface of the base sheet 101.
  • the film-like dentifrice is the above-described film-like dentifrice of the present invention, and a separating portion 102 for separating the elongated film-like dentifrice at a predetermined position is provided.
  • the concave portions are omitted for easy understanding of the main part as a continuous body.
  • the film-like dentifrice continuum 100 of this embodiment can wind up an elongate continuous body as shown in FIG. 4, and can use it for a roll form, and it is a film from the base sheet 101 at the time of use.
  • the film-like dentifrice 1 ' can be cut off at the detaching portion 102 while the tooth-like dentifrice 1' is peeled off and used as individual film-like dentifrice 1 '.
  • the continuous film-like dentifrice continuous body according to the present embodiment is slit to a width of 1 to 3 cm while the long product finally obtained in the above-described manufacturing method is attached to the base material, and the length of 1 to Half-cut every 3 cm (by inserting a blade from the film-like dentifrice side and cutting from about one-third to one-half of the base material to completely cut only the film and leave the base material in roll form. It can be manufactured by adding a method.
  • the continuous film-like dentifrice continuum wound in a roll can be used by being attached to a film-like dentifrice dispenser (not shown).
  • the dispenser can be configured so that the film-like dentifrice cut one by one can be automatically discharged while reading the sensor mark by pulling the base material with a motor, and can be used more easily.
  • the film-like dentifrice 1 of the present embodiment has the above-mentioned voids, it is rapidly dissolved in the mouth, is easy to foam, has an excellent feeling of use, and has an excellent detergency even though it is in the form of a small film.
  • an appropriate amount can be used at any time without worrying about the amount used during use. Mobile is also convenient.
  • the film-form dentifrice of this invention is not restrict
  • it can print on the surface of a film dentifrice.
  • Printing can be done by using edible inks by universal printing methods such as offset printing, flexographic printing, gravure printing, letterpress printing, and foil stamping.
  • commercial printing can be used as an inexpensive commercial medium.
  • the film-like dentifrice of the present invention not only brushes teeth with a toothbrush as described above, but also cleans the mouth by putting the film-like dentifrice into the mouth without water and chewing like a gum. And brushing teeth.
  • Unlike gum if you chew it in your mouth for about 1 to 3 minutes, everything in the form of a gum will dissolve, and the ingredients are all edible, so you can swallow the dissolved one.
  • exhale to exhale using tissue paper. There is an advantage that there is nothing left in the shape like gum, so there is no waste.
  • the film-like dentifrice of the present invention which is edible and completely dissolves, cleans the oral cavity just by putting it in the mouth and chewing it even without water. And if you can't go to the washroom, you can swallow it or vomit it to a nearby place while lying down, and you can maintain good oral hygiene.
  • the muscle strength in the oral cavity decreases due to aging and the tongue cannot be moved, the effect of oral gymnastics can be expected by chewing with a gum-like toothpaste.
  • Example 1 Each component was mixed with the composition shown in Table 1 to produce a coating solution. At the time of adjusting the coating liquid, using a homogenizer, a time treatment was performed at 8000 rpm for 5 minutes to generate a large number of fine bubbles in the coating liquid.
  • the surface of the exposed surface side is coated using hydroxypropyl methylcellulose (HPMC).
  • a coating layer having a thickness of 3 ⁇ m was formed to obtain a film body. Embossing was performed by pressurizing the obtained film main body at a temperature of 50 ° C., and recesses having a width of 0.5 mm and a depth of 0.1 mm were formed at an interval of 1 mm. Furthermore, it cut into the magnitude
  • Example 2 A film-like dentifrice was obtained in the same manner as in Example 1 except that the components shown in Table 1 were used in the amounts shown in Table 1. The obtained film-like dentifrice had good usability as in the case of the dentifrice of Example 1, and was excellent in storage stability.
  • Example 3 A film-like dentifrice was obtained in the same manner as in Example 1 except that the components shown in Table 1 were used in the amounts shown in Table 1. The obtained film-like dentifrice had good usability as in the case of the dentifrice of Example 1, and was excellent in storage stability.
  • Example 4 A film-like dentifrice was obtained in the same manner as in Example 1 except that the components shown in Table 1 were used in the amounts shown in Table 1. The obtained film-like dentifrice had good usability as in the case of the dentifrice of Example 1, and was excellent in storage stability.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Cosmetics (AREA)
PCT/JP2012/051003 2012-01-19 2012-01-19 Dentifrices en forme de film Ceased WO2013108384A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/JP2012/051003 WO2013108384A1 (fr) 2012-01-19 2012-01-19 Dentifrices en forme de film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2012/051003 WO2013108384A1 (fr) 2012-01-19 2012-01-19 Dentifrices en forme de film

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016503022A (ja) * 2012-12-14 2016-02-01 コルゲート・パーモリブ・カンパニーＣｏｌｇａｔｅ−Ｐａｌｍｏｌｉｖｅ Ｃｏｍｐａｎｙ オーラル・ケアに使用するための摩耗性フィルム
WO2022004598A1 (fr) * 2020-06-29 2022-01-06 株式会社サンギ Patch dentaire
CN114007584A (zh) * 2019-06-13 2022-02-01 宝洁公司 包括单位剂量口腔护理组合物的套盒
JP2023010444A (ja) * 2021-07-09 2023-01-20 花王株式会社 口腔用貼付シート

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5815600A (ja) * 1981-07-15 1983-01-28 「ゆ」　炳彦 セルロ−スフイルムを有する発泡薄膜洗剤およびその製法
JPH04502332A (ja) * 1989-10-14 1992-04-23 エルテーエス　ローマン　テラピー―ズュステーメ　ゲーエムベーハー 口内及び歯の清浄化剤
JP2005538202A (ja) * 2002-09-07 2005-12-15 エスシーエス・スキン・ケア・システムズ・ゲーエムベーハー 空気気泡を含むセッケン調製物
JP2007197540A (ja) * 2006-01-25 2007-08-09 Tsukioka:Kk 水溶性洗浄用フィルム

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5815600A (ja) * 1981-07-15 1983-01-28 「ゆ」　炳彦 セルロ−スフイルムを有する発泡薄膜洗剤およびその製法
JPH04502332A (ja) * 1989-10-14 1992-04-23 エルテーエス　ローマン　テラピー―ズュステーメ　ゲーエムベーハー 口内及び歯の清浄化剤
JP2005538202A (ja) * 2002-09-07 2005-12-15 エスシーエス・スキン・ケア・システムズ・ゲーエムベーハー 空気気泡を含むセッケン調製物
JP2007197540A (ja) * 2006-01-25 2007-08-09 Tsukioka:Kk 水溶性洗浄用フィルム

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016503022A (ja) * 2012-12-14 2016-02-01 コルゲート・パーモリブ・カンパニーＣｏｌｇａｔｅ−Ｐａｌｍｏｌｉｖｅ Ｃｏｍｐａｎｙ オーラル・ケアに使用するための摩耗性フィルム
US9498418B2 (en) 2012-12-14 2016-11-22 Colgate-Palmolive Company Abradable films for use in oral care
CN114007584A (zh) * 2019-06-13 2022-02-01 宝洁公司 包括单位剂量口腔护理组合物的套盒
JP2022535928A (ja) * 2019-06-13 2022-08-10 ザ プロクター アンド ギャンブル カンパニー 単位用量口腔ケア組成物を含むキット
JP7420837B2 (ja) 2019-06-13 2024-01-23 ザ プロクター アンド ギャンブル カンパニー 単位用量口腔ケア組成物を含むキット
US12251460B2 (en) 2019-06-13 2025-03-18 The Procter And Gamble Company Kits comprising unit-dose oral care compositions
WO2022004598A1 (fr) * 2020-06-29 2022-01-06 株式会社サンギ Patch dentaire
JP2023010444A (ja) * 2021-07-09 2023-01-20 花王株式会社 口腔用貼付シート
JP7492943B2 (ja) 2021-07-09 2024-05-30 花王株式会社 口腔用貼付シート

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