WO2013154392A1 - 개선된 사용감을 가지는 발포 폼 - Google Patents

개선된 사용감을 가지는 발포 폼 Download PDF

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Publication number
WO2013154392A1
WO2013154392A1 PCT/KR2013/003101 KR2013003101W WO2013154392A1 WO 2013154392 A1 WO2013154392 A1 WO 2013154392A1 KR 2013003101 W KR2013003101 W KR 2013003101W WO 2013154392 A1 WO2013154392 A1 WO 2013154392A1
Authority
WO
WIPO (PCT)
Prior art keywords
foam
cosmetic composition
foamed
cotton
styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2013/003101
Other languages
English (en)
French (fr)
Inventor
정하진
김경남
최정선
최경호
최영진
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
Original Assignee
Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US14/391,088 priority Critical patent/US9844496B2/en
Priority to CN201380030894.2A priority patent/CN104379646B/zh
Priority to JP2015505648A priority patent/JP6523949B2/ja
Priority to US16/721,053 priority patent/USRE48906E1/en
Priority to EP13775492.5A priority patent/EP2837652B1/en
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Publication of WO2013154392A1 publication Critical patent/WO2013154392A1/ko
Anticipated expiration legal-status Critical
Priority to US15/213,961 priority patent/US10105291B2/en
Priority to US16/110,444 priority patent/US10646411B2/en
Priority to US16/722,222 priority patent/USRE49062E1/en
Priority to US16/841,014 priority patent/US11141358B2/en
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8123—Compositions of homopolymers or copolymers of compounds having one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers, e.g. PVC, PTFE
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8194—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/40—Impregnation
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00—Details not otherwise provided for in A45D
    • A45D2200/10—Details of applicators
    • A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1018—Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00—Details not otherwise provided for in A45D
    • A45D2200/10—Details of applicators
    • A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1036—Applicators comprising a pad, tissue, sponge, or the like containing a cosmetic substance, e.g. impregnated with liquid or containing a soluble solid substance
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/036—Use of an organic, non-polymeric compound to impregnate, bind or coat a foam, e.g. fatty acid ester
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00—Characterised by the use of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2331/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
    • C08J2331/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
    • C08J2331/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers

Definitions

  • the present invention relates to a foamed article of a specific material having excellent properties and a product containing the same.
  • the cosmetic composition has been layered, distributed and stored mainly in a vacuum container, a pump container or a glass container.
  • a disadvantage that the containers are inconvenient to carry.
  • a cosmetic composition that is convenient to carry, as the necessity of cosmetic preparation or correction is increased easily even when going out.
  • a fact type container can be conceived. In order to contain a liquid cosmetic composition in a fact type container, it is necessary to determine whether it is a cosmetic composition carrier which can be used in the container, whether the cosmetic composition can be well impregnated into the carrier, whether the carrier can homogeneously carry the cosmetic composition for a long period And whether or not an appropriate amount is discharged when taking the cosmetic composition from the carrier.
  • ⁇ 4> The inventors of the present invention have confirmed that a foamed product of a specific material has excellent skin adhesion, finish, thinning, softness, durability, smoothness, smoothness, skin texture correction or silky feeling and completes the present invention .
  • foam foam of a specific material has excellent skin adhesion feeling, skin irregularity reduction, skin texture correction or improved wettability.
  • a cosmetic composition is applied to a specific foamed article by comparing the case where the cosmetic composition is impregnated into a specific foamed article and then the appropriate amount is manually applied to the face and the case where the cosmetic composition is applied to the face, The impregnation was found to be excellent in feeling, and the present invention was completed. It is an object of the present invention to provide a foamed article having an enhanced feeling of use and cosmetics containing the same.
  • the present invention provides a method for producing an acrylonitrile-butadiene
  • the present invention provides a foamed foam for enhancing the skin adhesion feeling and a cosmetic comprising the same, which is made of a material containing at least one selected from the group consisting of SBR (Styrene Butadiene Rubber) and NR (Natural Rubber).
  • the present invention also relates to polyvinyl chloride, polyethylene and EVA (Ethylene Vinyl
  • the cosmetic composition comprises at least one material selected from the group consisting of acetic acid and acetic acid, and cosmetics containing the same.
  • the present invention can be applied to a method of manufacturing a semiconductor device
  • a cosmetic composition comprising at least one material selected from the group consisting of styrene, SEBS (Styrene Ethylene Butylene ene Styrene), PVA (Polyvinyl Alcohol), silicone elastomer, nitrile, butyl, And a cosmetic product containing the same.
  • the foamed product of the present invention contains a variety of materials and has impregnated with the cosmetic composition as well as enhancing skin adhesion, skin irregularity, skin texture correction or improved wetting. It is easy to use with stability in formulation and portability. Particularly, since each of the foamed articles has a different purpose, it is useful because it can feel an optimal feeling of use in the use of cosmetics containing foamed foam.
  • &quot foamed article " refers to a foam in which the polymer is foamed by dry or wet foaming
  • Flocking &quot in the present specification means a processing method in which very short fibers (flocs) are fixed to a foam or the like.
  • a resin composition comprising: NBR (acrylonitrile-butadiene rubber); SBR (styrene
  • Butadiene rubber NR (natural rubber), polyvinyl chloride, polyethylene, EVA (Ethylene Vinyl Acetate), latex silicone, film type, SIS (Styrene Isoprene Styrene), SEBS (Styrene Ethylene Butylene ene Styrene) ), A silicone elastomer, a nitrile, a butyl, a polyether, and a neoprene. And at least one selected from the group consisting of the above-mentioned materials.
  • the foamed foam may be selected from the group consisting of cotton, cotton / acrylic, cotton / acrylic / polyester, cotton / rayon, acrylic, polyamide, nylon, polyester, nylon / polyester Or may be flocked to silk.
  • rubber for example, NBR (acrylonitrile-NBR)
  • the present invention relates to a foamed article for enhancing the skin feel of a cosmetic composition.
  • Improvement of skin adhesion feeling 1 &quot means that when the cosmetic composition impregnated on the foamed foam is applied to the skin, the cosmetic does not look on the skin and is attached to the surface of the skin.
  • the foam can be brought into close contact with the skin, allowing the cosmetic material to be thinly applied, applying the cosmetic material evenly to the skin, and thus being able to express smoothly silky skin.
  • the present invention relates to a foamed foam, And a cosmetic composition impregnated in the foamed article.
  • a cosmetic composition comprising at least one material selected from the group consisting of vinyl (vinyl), for example, polyvinyl chloride polyethylene and EVA (Ethylene Vinyl Acetate)
  • vinyl for example, polyvinyl chloride polyethylene
  • EVA Ethylene Vinyl Acetate
  • the phrase " for skin irregularity reduction " means that when the cosmetic composition impregnated in the foamed foam is applied to the skin, fine irregularities of the skin are cleared and planarized.
  • the irregularities of the skin may be caused by scars or pores caused by scars such as acne, but are not limited thereto.
  • a foamed article And a cosmetic material impregnated in the foamed foam ≪ / RTI >
  • a process for producing a silicone elastomer composition which comprises the steps of mixing a silicone such as latex, silicone, coating type, SIS (Styrene Isoprene Styrene), SEBS (Styrene Ethylene Butylene Styrene), PVA , Nitrile, butyl, polyether, and neoprene.
  • SIS Styrene Isoprene Styrene
  • SEBS Styrene Ethylene Butylene Styrene
  • PVA Nitrile, butyl, polyether, and neoprene.
  • For skin texture correction &quot means to constantly correct skin tone or to smooth skin texture when the skin tone is not constant due to internal or external factors or the skin texture is poor.
  • the skin tone may have uneven color due to pigmentation due to a wound, exposure to aging ultraviolet rays, and the like, but is not limited thereto.
  • the present invention relates to a foamed foam, And a cosmetic composition impregnated in the foamed foam.
  • the foamed foam may be selected from the group consisting of cotton, cotton / acrylic, cotton / acrylic / polyester, cotton / rayon, acrylic, polyamide, nylon, polyester, nylon / polyester Or flocked to silk, or may be a foamed product for improving skin texture of a cosmetic composition.
  • &Lt For enhancing skin-spreading ability " means that a cosmetic material is adsorbed on skin and can be spread thinly without being pushed or lifted.
  • a cosmetic comprising at least one foamed product, wherein the foamed product is impregnated with a cosmetic composition.
  • the cosmetic composition includes a liquid or solid phase, and may specifically include a solution, an emulsion, a gel, a cream or a suspension.
  • the cosmetic composition includes an aqueous dispersion type, an oil dispersion type, a waxy water (W / 0) type or an oil-in-water type (0 / W) type.
  • the cosmetic composition When the cosmetic composition is in a liquid state, it tends to be difficult to carry and store when it is in a solid state. However, when a cosmetic composition containing a foamed foam according to one aspect of the present invention is used, the liquid and cream cosmetic compositions are also stably and safely stored And can be carried.
  • the cosmetic composition When the cosmetic composition is in a solid phase, it is possible to reduce instantaneous changes in properties of the solid phase due to external stiffness, such as heat or layering, by supporting the carrier on a carrier, and when the cosmetic composition is used, the carrier serves to fix the contents, There is an advantage of payoff.
  • Water and may be specifically water-in-oil (W / 0) type or oil-in-water (0 / W) type composition dispersed composition, specifically, the organic dispersion or dispersion composition.
  • the cosmetic composition which can be applied to cosmetics which is one aspect of the present invention includes, for example, a makeup plasticizer, a makeup base, a liquid or solid foundation, a concealer, a lipstick, a lip gloss, a powder, a lip liner, , A blusher, a root cake, a sunblock, a lotion, a cream or an essence, but the present invention is not limited thereto.
  • Each of the foamed products of Examples 1 to 5 was impregnated with a cosmetic composition (common emulsifying makeup cosmetic composition) having the composition shown in Table 1.
  • the cosmetic composition was impregnated into a foamed product of NBR (AcryloNitrile-Butadiene Rubber) having a diameter of 48 mm and a thickness of 50 mm, and the cosmetic composition was expected to be stabilized in appearance. Two hours later, after the formulation was stabilized, 0.5 g of the amount of the foaming product, which was once contacted with the hand, was applied to the face.
  • NBR AcryloNitrile-Butadiene Rubber
  • the cosmetic composition was impregnated with foamed polyvinyl chloride foam having a diameter of 48 mm and a thickness of 50 mm at room temperature, and then the cosmetic composition was visually waited for stabilization. Two hours later, after the formulation was stabilized, 0.5 g of the amount of the foaming product, which was once contacted with the hand, was applied to the face.
  • the cosmetic composition was impregnated with foamed latex foam having a memory capacity of 48 letters and a diameter of 50 at room temperature and waited for the cosmetic formulation to be apparently stabilized. Two hours later, after the formulation was stabilized, 0.5 g of the amount of the foaming agent was applied to the face by pressing the foaming article with one touch.
  • the polyether foamed product having a diameter of 48 ⁇ and a thickness of 50 ⁇ at room temperature was flocked to polyester and the cosmetic composition was impregnated and the cosmetic composition was visually waited for stabilization. After the formulation was stabilized after 2 hours, 0.5 g of the amount of the foaming foam was applied to the face by pressing the foaming foam by hand and touching with the hand.
  • the cosmetic composition was impregnated into polyether foamed articles having a diameter of 48 ⁇ and a thickness of 50 thighs at room temperature, and then the cosmetic composition was visually waited for stabilization. Two hours later, after the formulation was stabilized, 0.5 g of the amount of foaming was applied to the face by pressing the foam with one hand, which was applied to the face.
  • ⁇ 8i> The subjects were 24-35 year-old male and female with at least 2 years of experience in cosmetic makeup. Five professional panelists, who were used at least five times a week, Very poor, 2 points: poor, 3 points: normal, 4 points: good, 5 points: very good). The results are shown in the following table.
  • ⁇ S2>'Adhesion' is an index of skin adhesion effect
  • 'finish 1 ' is an index of residual feeling such as stickiness after skin application
  • 'thin filming' is an index of skin makeup after application.
  • smooth spreadability 1 is an index of skin spreadability effect
  • one persistence is an indicator of the sheet screen after the coating continuity
  • "uniformity” is the indicators makeup does partially mungchiji as after application
  • 1 smooth ' is the supple supple implications indicators, such as baby's skin after application, one smoothness "can be seen as an indicator of skin roughness reduction.
  • 'Skin Tone Correction 1 is to fix the skin tone or to smooth skin texture when the skin tone is not constant due to internal or external factors or if the skin texture is unstable and the' silky ' It is an index of slipperiness.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Cosmetics (AREA)

Abstract

본 발명은 우수한 성질을 가지는 특정 재질의 발포 폼 및 이를 포함하는 화장품에 관한 것이다.

Description

【명세서】
【발명의 명칭】
개선된 사용감을 가지는 발포 품
【기술분야】
<1> 본 발명은 우수한 성질을 가지는 특정 재질의 발포 품 및 이를 포함하는 화 장품에 관한 것이다.
【배경기술】
<2> 종래 화장료 조성물은 주로 진공 용기， 펌프 용기 또는 유리 용기 등에 층진 되어 유통 및 보관되었다. 하지만 상기 용기들은 휴대가 불편하다는 단점이 있다. 최근， 외출시에도 간편하게 화장올 하거나 수정할 필요성이 증가함에 따라， 휴대가 편리한 화장료 조성물에 대한 요구가 있다.
<3> 화장료 조성물을 간편하게 휴대할 수 있는 용기로는 팩트 타입의 용기를 생 각할 수 있다. 팩트 타입의 용기에 액상 화장료 조성물을 담기 위해서는, 그 용기 에 사용하는 것이 가능한 화장료 조성물 담체인지 여부, 그 담체에 화장료 조성물 이 잘 함침될 수 있는지 여부， 담체가 화장료 조성물을 장기간 균질하게 담지할 수 있는지 여부 및 담체로부터 화장료 조성물을 취하고자 할 때 적당량이 배출되는지 여부 등을 고려하여야 할 것이다.
<4> 본 발명자들은 특정 재질의 발포 품이 우수한 피부 밀착감， 마무리감， 얇은 발림， 부드러움 발림성， 지속성, 균일함 보송함， 매끈함， 피부결 보정 또는 실키 함을 가지는 것을 확인하고, 본 발명을 완성하게 되었다.
<5> 보다 구체적으로는 특정 재질의 발포 폼이 우수한 피부 밀착감, 피부 요철 감소, 피부결 보정 또는 개선된 발림성을 가지는 것을 확인하고， 본 발명을 완성하 게 되었다.
【발명의 상세한 설명】
【기술적 과제】
<6> 본 발명에서는 특정 발포 품에 화장료 조성물을 함침한 후 적정량을 손으로 취하여 얼굴에 도포한 경우와 함침되지 않은 화장료 조성물 자체를 얼굴에 도포한 경우를 비교하여， 특정 발포 품에 화장료 조성물을 함침시킨 경우가 사용감이 월등 히 우수함을 발견하고 본 발명을 완성하게 되었다. 본 발명의 목적은 증진된 사용 감을 가지는 발포 품 및 이를 포함하는 화장품을 제공하는 데 있다.
【기술적 해결방법】
<v> 상기 목적을 달성하기 위하여 본 발명은 NBR(AcryloNitrile-Butadiene Rubber), SBR( Styrene Butadiene Rubber) 및 NR(Natural Rubber)으로 구성된 군에 서 선택되는 하나 이상을 포함하는 재질로 이루어진， 화장료 조성물의 피부 밀착감 증진용 발포 폼 및 이를 포함하는 화장품을 제공한다.
<8> 본 발명은 또한， 폴리염화 비닐， 폴리에틸렌 및 EVA(Ethylene Vinyl
Acetate)으로 구성된 군에서 선택되는 하나 이상을 포함하는 재질로 이루어진, 화 장료 조성물의 피부 요철 감소용 발포 품 및 이를 포함하는 화장품을 제공한다.
<9> 아울러 본 발명은 라텍스， 실리콘， 피막 타입， SIS(Styrene Isoprene
Styrene) , SEBS( Styrene Ethylene Butyl ene Styrene) , PVA(PolyVinyl Alcohol ) , 실 리콘제 엘라스토머, 니트릴, 부틸, 플리에테르 및 네오프렌으로 구성된 군에서 선 택되는 하나 이상을 포함하는 재질로 이루어진， 화장료 조성물의 피부결 보정용 발 포 품 및 이를 포함하는 화장품을 제공한다.
【유리한 효과】
<ιο> 본 발명의 발포 품은 다양한 재질을 함유하여， 피부 밀착감 증진， 피부 요철 감소， 피부결 보정 또는 개선된 발림성을 가질 뿐 아니라, 상기 화장료 조성물을 함침하고 있어서，. 제형안정성， 휴대성을 가지고 간편하게 사용할 수 있다. 특히, 각각의 발포 품이 별도의 용도를 가짐에 따라， 발포 폼을 포함하는 화장품의 사용 에 있어서, 최적의 사용감을 느낄 수 있어서 유용하다.
【발명의 실시를 위한 최선의 형태】
<ι ι> 본 명세서에서， "발포 품''은 폴리머를 건식 혹은 습식의 발포 방식으로 폼을
' 형성한 것을 의미한다.
<12>
<13> 본 명세서에서 "플로킹 (flocking)"은 발포체 등에 극히 짧은 섬유 (플록)를 고착시키는 가공법을 의미한다.
<14>
<15> 본 명세서에서 "함침' '되어 있다는 것은 발포 폼에 화장료 조성물이 함유되어 있음을 의미한다 . "
<16>
<17> 본 발명은 일 관점에서， NBR(AcryloNitrile-Butadiene Rubber), SBR(Styrene
Butadiene Rubber), NR(Natural Rubber), 폴리염화 비닐, 폴리에틸렌， EVA(Ethylene Vinyl Acetate), 라텍스ᅳ 실리콘， 피막 타입， SIS(Styrene Isoprene Styrene) , SEBS( Styrene Ethylene Butyl ene Styrene) , PVA(PolyVinyl Alcohol), 실 리콘제 엘라스토머， 니트릴， 부틸， 폴리에테르 및 네오프렌으로 구성된 군에서 선 택되는 하나 이상을 포함하는 재질로 이루어진， 화장료 조성물 함침용 발포 폼에 관한 것이다.
<18>
<19> 본 발명의 일 관점인 발포 폼에 있어서， 상기 발포 폼은 코튼， 코튼 /아크릴， 코튼 /아크릴 /폴리에스테르， 코튼 /레이온， 아크릴， 폴리아미드， 나일론， 폴리에스테 르， 나일론 /폴리에스테르 또는 실크로 플로킹 (flocking)되어 있올 수 있다.
<20>
<21> 본 발명은 일 관점에서 , 러버 (고무)류， 예를 들어 NBR(AcryloNitrile-
Butadiene Rubber), SBR(Styrene Butadiene Rubber) 및 NR(Natural Rubber)으로 구 성된 군에서 선택되는 하나 이상을 포함하는 재질로 이루어진， 화장료 조성물의 피 부 밀착감 증진용 발포 품에 관한 것이다.
<22>
<23> "피부 밀착감 증진1 '은 상기 발포 폼에 함침되어 있는 화장료 조성물을 피부 에 적용시키는 경우， 화장료가 피부 상에서 들뜨지 않고， 피부 표면에 빈틈없이 달 라붙는 것을 의미하는 것이다. 본 발명의 발포 폼은 피부에 밀착하여, 화장료가 얇 게 발리도록 할 수 있고， 피부에 화장료를 고르게 적용시킬 수 있으며 이에 따라 매끈하게 실키한 피부를 표현할 수 있다는 장점이 있다.
<24>
<25> 본 발명은 다른 관점에서， 상기 발포 폼; 및 상기 발포 품에 함침된 화장료 조성물을 포함하는 화장품에 관한 것이다.
<26>
<27> 본 발명은 또 다른 관점에서， 비닐 (바이닐류), 예를 들어 폴리염화 비닐 폴 리에틸렌 및 EVA(Ethylene Vinyl Acetate)으로 구성된 군에서 선택되는 하나 이상 을 포함하는 재질로 이루어진， 화장료 조성물의 피부 요철 감소용 발포 품에 관한 것이다.
<28>
<29> "피부 요철 감소용 "은 상기 발포 폼에 함침되어 있는 화장료 조성물을 피부 에 적용시키는 경우， 피부의 미세한 요철을 틈틈아메꾸어 주어 평탄화시키는 것을 의미하는 것이다. 피부의 요철은 여드름 등의 상처에 따른 흉터 또는 모공에 의해 생길 수 있으나， 이에 제한되는 것은 아니다.
<30>
<31> 본 발명은 다른 관점에서， 상기 발포 품; 및 상기 발포 폼에 함침된 화장료 조성물을 포함하는， 화장품에 관한 것이다.
<32> .
<33> 본 발명은 또 다른 관점에서, 실리콘류, 예를 들어 라텍스, 실리콘， 피막 타 입， SIS(Styrene Isoprene Styrene) , SEBS(Styrene Ethylene Butyl ene Styrene) , PVA(PolyVinyl Alcohol), 실리콘제 엘라스토머, 니트릴， 부틸, 폴리에테르 및 네오 프렌으로 구성된 군에서 선택되는 하나 이상을 포함하는 재질로 이루어진， 화장료 조성물의 피부결 보정용 발포 폼에 관한 것이다.
<34>
<35> "피부결 보정용 "은 내부적 또는 외부적 요인에 의해 피부톤이 일정하지 못하 거나 피부결이 울통불통한 경우, 피부톤을 일정하게 수정하거나 또는 피부결을 매 끈하게 만들어 주는 것을 의미한다. 상기 피부톤은 상처에 따른 색소 침착， 노화 자외선으로의 노출 등에 의해 불균일한 색상을 가질 수 있으나， 이에 제한되는 것 은 아니다.
<36> '
<37> 본 발명은 다른 관점에서 , 상기 발포 폼; 및 상기 발포 폼에 함침된 화장료 조성물을 포함하는， 화장품에 관한 것이다.
<38>
<39> 본 발명의 일 관점인 발포 폼에 있어서， 상기 발포 폼은 코튼, 코튼 /아크릴， 코튼 /아크릴 /폴리에스테르， 코튼 /레이온 , 아크릴 , 폴리아미드， 나일론， 폴리에스테 르， 나일론 /폴리에스테르 또는 실크로 플로킹 (flocking)되어 있는， 화장료 조성물 의 피부 발림성 증진용 발포 품일 수 있다.
<40>
<41> "피부 발림성 증진용' '은 화장료를 피부에 흡착시켜 밀리거나 들뜨지 않고 얇 게 펴 바를 수 있어서， 자연스러운 사용감을 가짐을 의미하는 것이다.
<42>
<43> 본 발명은 또 다른 관점에서 상기 발포 품을 하나 이상 포함하는 화장품으로 서, 상기 발포 품은 화장료 조성물이 함침된, 화장품에 관한 것이다.
<44>
<45> 본 발명의 일 관점인 화장품에 있어서， 상기 화장료 조성물은 액상 또는 고 상을 포함하고, 구체적으로， 용액， 에멀견, 젤, 크림 또는 현탁액을 포함할 수 있 다. <47> 본 발명의 일 관점인 화장품에 있어서， 상기 화장료 조성물은 수분산형， 유 분산형，유중수 (W/0)형 또는 수중유 (0/W)형을 포함한다.
<48>
<49> 화장료 조성물이 고상인 경우보다 액상인 경우 휴대 및 보관이 곤란한 경향 이 높으나， 본 발명의 일관점에 따른 발포 폼을 포함하는 화장품을 이용하는 경우， 액상, 크림상의 화장료 조성물도 안정하고 안전하게 보관 및 휴대할 수 있다는 점 에서 바람직할 수 있다. 화장료 조성물이 고상인 경우， 담체에 담지함으로 해서 열 또는 층적 등의 외부의 층격에 의한 고상의 순간적인 물성 변화를 줄여 즐 수 있으 며 , 화장료 사용시 담체가 내용물을 고정시키는 역할을 하여 적정량의 내용물만을 페이오프할수 있는 장점이 있다.
<50>
<51> 본 발명의 일 관점인 화장품에 적용될 수 있는 화장료 조성물은 유화형 조성
' 물, 구체적으로 유중수 (W/0)형 또는 수중유 (0/W)형 조성물 분산형 조성물, 구체적 으로는 유분산 또는 수분산 조성물 일 수 있다.
<52>
<53> 본 발명의 일 관점인 화장품에 적용될 수 있는 화장료 조성물은 예를 들면， 메이크업 프라아머， 메이크업 베이스， 액상 또는 고상 파운데이션, 컨실러, 립스 틱， 립글로스, 파우더， 립 라이너， 아이브로우, 아이새도우， 블러셔 (blusher), 트 원 케익, 자외선 차단제， 로션, 크림 또는 에센스 등으로 제형화될 수 있으나, 이 에 한정되는 것은 아니다.
<54>
<55> 이하， 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시 예는 오로지 본 발명을 예시하기 위한 것으로， 본 발명의 범위가 이들 실시예에 의 해 제한되는 것으로 해석되지 않는 것은 당업계에서 통상의 지식을 가진 자에게 있 어서 자명할 것이다.
<56>
<57> [제조예]
<58> 하기 각각의 실시예 1 내지 5의 발포품에 표 1의 조성을 가지는 화장료 조성 물 (일반 유화 메이크업 화장료 조성물)을 함침시켰다.
<59>
<60> 【표 1】
Figure imgf000007_0001
<61>
<62> [비교예]
<63> 상온에서 상기 화장료 조성물 0.5g을 손으로 취하고， 얼굴에 도포하였다. <64>
<65> [실시예 1]
<66> 상은에서 지름 48隱, 두께 50腿의 NBR(AcryloNitrile-Butadiene Rubber) 재 질의 발포 품에 상기 화장료 조성물을 함침시킨 후 외관상 제형이 안정화되기를 기 다렸다. 2시간 뒤에 제형이 안정화된 후 손으로 발포 품을 눌러서 1회 접촉하여 손 에 묻어나오는 양 0.5g을 취하고， 얼굴에 도포하였다.
[실시예 2]
상온에서 지름 48醒， 두께 50瞧의 폴리염화비닐 재질의 발포 폼에 상기 화장 료 조성물을 함침시킨 후 외관상 제형이 안정화되기를 기다렸다. 2시간 뒤에 제형 이 안정화된 후 손으로 발포 품을 눌러서 1회 접촉하여 손에 묻어나오는 양 0.5g을 취하고， 얼굴에 도포하였다.
[실시예 3]
상온에서 지름 48誦， 두께 50画의 라텍스 재질의 발포 폼에 상기 화장료 조 성물을 함침시킨 후 외관상 제형이 안정화되기를 기다렸다. 2시간 뒤에 제형이 안 정화된 후 손으로 발포 품을 눌러서 1회 접촉하여 손에 묻어나오는 양 0.5g을 취하 고， 얼굴에 도포하였다. <74> [실시예 4]
<75> 상온에서 지름 48誦, 두께 50隱의 폴리에테르 재질의 발포 품을 폴리에스테 르로 플로킹하였고， 상기 화장료 조성물을 함침시킨 후 외관상 제형이 안정화되기 를 기다렸다. 2시간 뒤에 제형이 안정화된 후 손으로 발포 폼을 눌러서 1회 접촉하 여 손에 묻어나오는 양 0.5g을 취하고， 얼굴에 도포하였다.
<76>
<77> [실시예 5]
<78> 상온에서 지름 48誦, 두께 50腿의 폴리에테르 재질의 발포 품에 상기 화장료 조성물을 함침시킨 후 외관상 제형이 안정화되기를 기다렸다. 2시간 뒤에 제형이 안정화된 후 손으로 발포 품을 눌러서 1회 접촉하여 손에 묻어나오는 양 0.5g을 취 하고， 얼굴에 도포하였다.
<79>
<80> [실험예]
<8i> 평가 대상은 24~35세 미흔 및 기흔 여성으로서 화장 경력이 최소 2년 이상이 며， 일주일에 최소 5회 이상 지속적으로 사용하는 여성인 전문 패널 5명이 항목별 5점 척도 (1점 ： 아주 나쁨, 2점 ： 나쁨， 3점: 보통, 4점 ： 좋음， 5점: 아주 좋음) 으로 비교 평가하였다. 그 결과를 하기 표에 나타내었다.
<S2> '밀착성'은 피부 밀착감 효과의 지표이고, '마무리감1은 피부 도호 후 끈적 이는 등 잔여감의 지표이며， '얇은 발림'은 도포 후 피부의 화장이 두터움의 지표 . 이며 , '부드러운 발림성1은 피부 발림성 효과의 지표이고, 1지속성 '은 도포 후 화 장지속성에 대한 지표이고， '균일함'은 도포 후 화장이 부분적으로 뭉치지 않는 지 표이며, 1보송함 '은 도포 후 아기피부와 같이 보들보들함의 지표이며， 1매끈함 '은 피부 요철 감소 효과의 지표로 볼 수 있다. '피부결 보정1은 내부적 또는 외부적 요인에 의해 피부톤이 일정하지 못하거나 피부결이 울통불통한 경우， 피부톤을 일 정하게 수정하거나 또는 피부결을 매끈하게 만들어 주는 것이고 '실키함'은 피부 도포시 미끄러지는 발림성의 지표이다.
<83>
<84> 【표 2】
Figure imgf000009_0001
이상으로 본 발명 내용의 특정한 부분을 상세히 기술하였는바， 당업계의 통 상의 지식을 가진 자에게 있어서 이러한 구체적 기술은 단지 바람직한 실시태양일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것ᅳ이 아닌 점은 명백할 것이다. 따 라서, 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의하여 정 의된다고 할 것이다.

Claims

【청구의 범위】
【청구항 1】
NBR(AcryloNitri le-Butadiene Rubber ) , SBR( Styrene Butadiene Rubber ) , NRCNatural Rubber), 폴리염화 비닐， 폴리에틸렌， EVA(Ethylene Vinyl Acetate), 라텍스， 실리콘, 피막 타입， SIS(Styrene Isoprene Styrene), SEBS(Styrene Ethylene Butyl ene Styrene) , PVA(PolyVinyl Alcohol), 실리콘제 엘라스토머， 니트 릴， 부틸， 폴리에테르 및 네오프렌으로 구성된 군에서 선택되는 하나 이상을 포함 하는 재질로 이루어진, 화장료 조성물 함침용 발포 폼.
【청구항 2]
제 1항에 있어서, 상기 발포 폼은 코튼， 코튼 /아크릴， 코튼 /아크릴 /폴리에스 테르， 코튼 /레이온， 아크릴， 폴리아미드, 나일론， 폴리에스테르， 나일론 /폴리에스 테르 또는 실크로 플로킹 (flocking)되어 있는， 화장료 조성물 함침용 발포 폼.
【청구항 3]
NBR(AcryloNitri le-Butadiene Rubber), SBR( Styrene Butadiene Rubber) 및 NR(Natural Rubber)으로 구성된 군에서 선택되는 하나 이상을 포함하는 재질로 이 루어진, 화장료 조성물의 피부 밀착감 증진용 발포 품.
【청구항 4]
제 3항에 따른 발포 품 하나 이상; 및 상기 발포 품에 함침된 화장료 조성물 을 포함하는， 화장품.
【청구항 5]
폴리염화 비닐, 폴리에틸렌 및 EVA(Ethylene Vinyl Acetate)으로 구성된 군 에서 선택되는 하나 이상을 포함하는 재질로 이루어진， 화장료 조성물의 피부 요철 감소용 발포 폼.
【청구항 6】
거 15항에 따른 발포 폼 하나 이상; 및 상기 발포 폼에 함침된 화장료 조성물 을 포함하는， 화장품.
【청구항 7】
라텍스， 실리콘， 피막 타입， SIS(Styrene Isoprene Styrene), SEBSCStyrene Ethylene Butyl ene Styrene), PVA(PolyVinyl Alcohol), 실리콘제 엘라스토머， 니트 릴， 부틸， 폴리에테르 및 네오프렌으로 구성된 군에서 선택되는 하나 이상을 포함 하는 재질로 이루어진， 화장료 조성물의 피부결 보정용 발포 품.
【청구항 8】 저 ]7항에 따른 발포 폼 하나 이상; 및 상기 발포 품에 함침된 화장료 조성물 을 포함하는, 화장품.
【청구항 9]
제 3항， 게 5항 또는 제 7항 중 어느 한 항에 있어서, 상기 발포 품은 코튼， 코 튼 /아크릴, 코튼 /아크릴 /폴리에스테르， 코튼 /레이온, 아크릴, 폴리아미드， 나일론， 폴리에스테르， 나일론 /폴리에스테르 또는 실크로 플로킹 (flocking)되어 있는， 화장 료 조성물의 피부 발림성 증진용 발포 폼.
【청구항 10]
제 9항에 따른 발포 폼 하나 이상; 및 상기 발포 폼에 함침된 화장료 조성물 을 포함하는, 화장품.
【청구항 11】
제 4항, 제 6항 또는 제 8항 중 어느 한 항에 있어서， 상기 화장료 조성물은 액 상 또는 고상인 , 화장품.
【청구항 12]
제 10항에 있어서， 상기 화장료 조성물은 액상 또는 고상인， 화장품.
【청구항 13】
제 11항에 있어서， 상기 화장료 조성물은 수분산형, 유분산형, 유중수 (W/0)형 또는 수중유 (0/W)형인, 화장품.
【청구항 14】
제 12항에 있어서， 상기 화장료 조성물은 수분산형， 유분산형， 유중수 (W/0)형 또는 수중유 (0/W)형인, 화장품.
PCT/KR2013/003101 2012-04-12 2013-04-12 개선된 사용감을 가지는 발포 폼 Ceased WO2013154392A1 (ko)

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US14/391,088 US9844496B2 (en) 2012-04-12 2013-04-12 Foam having improved feeling during use
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JP2015505648A JP6523949B2 (ja) 2012-04-12 2013-04-12 改善された使用感を有する発泡フォームを備える化粧品
US16/721,053 USRE48906E1 (en) 2012-04-12 2013-04-12 Foam having improved feeling during use
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US15/213,961 US10105291B2 (en) 2012-04-12 2016-07-19 Foam having improved feeling during use
US16/110,444 US10646411B2 (en) 2012-04-12 2018-08-23 Foam having improved feeling during use
US16/722,222 USRE49062E1 (en) 2012-04-12 2019-12-20 Foam having improved feeling during use
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US10646411B2 (en) 2020-05-12
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US9844496B2 (en) 2017-12-19
US20180360699A1 (en) 2018-12-20
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