WO2016190208A1 - Agent d'impression à base de pigments et matière textile utilisant celui-ci - Google Patents

Agent d'impression à base de pigments et matière textile utilisant celui-ci Download PDF

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Publication number
WO2016190208A1
WO2016190208A1 PCT/JP2016/064853 JP2016064853W WO2016190208A1 WO 2016190208 A1 WO2016190208 A1 WO 2016190208A1 JP 2016064853 W JP2016064853 W JP 2016064853W WO 2016190208 A1 WO2016190208 A1 WO 2016190208A1
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WO
WIPO (PCT)
Prior art keywords
printing agent
pigment
pigment printing
polymerizable monomer
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2016/064853
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English (en)
Japanese (ja)
Inventor
芳郎 山口
俊介 河中
賢志 橋本
正浩 梶川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DIC Corp
Original Assignee
DIC Corp
Dainippon Ink and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DIC Corp, Dainippon Ink and Chemicals Co Ltd filed Critical DIC Corp
Priority to CN201680029069.4A priority Critical patent/CN107614786B/zh
Priority to JP2017520660A priority patent/JP6222404B2/ja
Publication of WO2016190208A1 publication Critical patent/WO2016190208A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00—Making patterns or designs on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form

Definitions

  • the present invention can impart an excellent texture to a printed fabric without generating harmful formaldehyde, can impart high washing resistance and friction resistance to the printed portion, and further overlays a dye printing agent on the fabric.
  • the present invention relates to a pigment printing agent capable of imparting high washing resistance to a printed part and a fabric using the same.
  • a binder resin of a pigment printing agent is a heavy resin that uses a polymerizable monomer having a reactive functional group such as N-methylol (meth) acrylamide to impart washing resistance, friction resistance, and the like. Coalescence was used. Since this polymer has a reactive functional group, high crosslinking resistance and friction resistance can be imparted by the crosslinking reaction of the functional group, but there is a problem that harmful formaldehyde is generated during the crosslinking reaction. there were.
  • the problem to be solved by the present invention is that a printed fabric can be given an excellent texture without generating harmful formaldehyde, high washing resistance and friction resistance can be given to the printed portion, and further, It is an object to provide a pigment printing agent that can impart high washability to the color portion, and a fabric using the pigment printing agent.
  • the present inventors polymerized a polymerizable monomer including a polymerizable monomer having a carboxyl group and a polymerizable monomer having a hydrolyzable silyl group. It was found that the above-mentioned problems can be solved by using the polymer obtained in the above-mentioned manner and setting the film elongation rate and 1,000% modulus of the polymer alone within a specific range, thereby completing the present invention.
  • the present invention relates to a polymer obtained by polymerizing a polymerizable monomer containing a polymerizable monomer (a1) having a carboxyl group and a polymerizable monomer (a2) having a hydrolyzable silyl group.
  • the present invention provides a pigment printing agent characterized in that is 0.1 MPa or more and a fabric using the same.
  • the pigment printing agent of the present invention is excellent in washing resistance, friction resistance, etc. of the printed part without damaging the original texture of the fabric, even if it contains titanium oxide as a pigment or is printed on the fabric. Since it is excellent in the washing resistance of the dye heavy color portion, it is possible to obtain a printed fabric with a natural texture and suppressed color fading during washing or the like.
  • the pigment printing agent of the present invention can be used in combination with a dye printing agent to print various designs on a fabric without being restricted by the design.
  • the pigment printing agent of the present invention was obtained by polymerizing a polymerizable monomer containing a polymerizable monomer (a1) having a carboxyl group and a polymerizable monomer (a2) having a hydrolyzable silyl group.
  • a pigment printing agent comprising a polymer (A) and titanium oxide (B), wherein the elongation percentage of the polymer (A) alone film is in the range of 1,200 to 5,000%, 1,000 % Modulus is 0.1 MPa or more.
  • the polymerizable monomer (a1) is a polymerizable monomer having a carboxyl group, and examples thereof include (meth) acrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic anhydride, and citraconic acid. It is done.
  • the polymerizable monomer (a2) is a polymerizable monomer having a hydrolyzable silyl group, and examples thereof include vinylmethyldimethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy).
  • Vinylsilane compounds such as silane; 3- (meth) acryloyloxypropyltrimethoxysilane, 3- (meth) acryloyloxypropylmethyldimethoxysilane, 3- (meth) acryloyloxypropyltriethoxysilane, 3- (meth) acryloyloxy Examples include (meth) acryloyloxyalkylsilane compounds such as propylmethyldiethoxysilane.
  • the above polymerizable monomers (a1) and (a2) can be used alone or in combination of two or more.
  • (meth) acrylic acid refers to one or both of methacrylic acid and acrylic acid
  • (meth) acrylate refers to one or both of methacrylate and acrylate
  • (meta) “) Acryloyl” refers to one or both of methacryloyl and acryloyl.
  • polymerizable monomers that can be used as raw materials for the polymer (A) other than the polymerizable monomer (a1) having a carboxyl group and the polymerizable monomer (a2) having a hydrolyzable silyl group.
  • the monomer (a3) include methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, sec-butyl (meth) acrylate, t-butyl (meth) acrylate, and isopropyl (meth).
  • Alkyl (meth) acrylates such as acrylate, isobutyl (meth) acrylate, 2-ethylhexyl (meth) acrylate; aromatic (meth) acrylates such as benzyl (meth) acrylate; silanes such as trimethylsiloxyethyl (meth) acrylate (meta ) Acrylate; methoxypolyethylene glycol mono ( ) Acrylate, alkylpolyalkylene glycol mono (meth) acrylate such as methoxypolypropylene glycol mono (meth) acrylate; fluorine-based (meth) acrylate such as perfluoroalkylethyl (meth) acrylate; styrene, styrene derivative (p-dimethylsilyl) Styrene, (p-vinylphenyl) methylsulfide, p-hexynylstyrene, p-methoxyst
  • the elongation percentage of the polymer (A) alone film is in the range of 1,200 to 5,000%, and the 1,000% modulus is 0.1 MPa or more. Therefore, it is preferable to use a polymerizable monomer having a glass transition temperature (Tg) of a homopolymer such as 2-ethylhexyl acrylate, n-butyl acrylate and ethyl acrylate of ⁇ 20 ° C. or lower.
  • Tg glass transition temperature
  • the ratio of the polymerizable monomer (a1) in the total amount of the polymerizable monomers (a1) to (a3) used as the raw material of the polymer (A) is determined by adding the pigment printing agent of the present invention to water.
  • a range of 0.1 to 10% by mass is preferable, and a range of 0.5 to 8% by mass is more preferable because better dispersibility can be imparted and high washing resistance and friction resistance can be imparted to the printed part.
  • the range of 1 to 6% by mass is more preferable.
  • the ratio of the polymerizable monomer (a2) in the total amount of the polymerizable monomers (a1) to (a3) as the raw material of the polymer (A) is marked with the pigment printing agent of the present invention.
  • the range of 0.1 to 5% by mass is preferable, since an excellent texture can be imparted to the printed fabric, and high washing resistance and friction resistance can be imparted to the printed part. Is more preferable, and the range of 0.5 to 2.5% by mass is more preferable.
  • a method for producing the polymer (A) for example, a known emulsion polymerization method can be used.
  • the elongation percentage of the polymer (A) alone is in the range of 1,200 to 5,000%, but since it can impart high washing resistance and friction resistance to the printed part, 1,500 to A range of 4,000% is preferred.
  • the 1,000% modulus of the film is 0.1 MPa or more, and the upper limit is preferably 3 MPa because the printing part can impart high washing resistance and friction resistance with a soft texture. Is more preferable.
  • the elongation rate and 1,000% modulus of the polymer (A) alone are values obtained by preparing a film with the polymer (A) alone and measuring with a tensile tester.
  • a tensile tester for example, “Tensilon” manufactured by Orientec Co., Ltd., “Autograph” manufactured by Shimadzu Corporation, etc. can be used.
  • the said polymer (A) of the quantity used as the film thickness of about 0.5 mm is poured into a glass-made type
  • the pigment printing agent of the present invention contains titanium oxide (B).
  • the titanium oxide (B) is used for coloring the pigment printing agent of the present invention in white, and there are anatase type (tetragonal), rutile type (tetragonal) and brookite type (orthorhombic). In addition to the rutile type having low activity and excellent thermal stability, an anatase type can also be used.
  • the titanium oxide (B) may be added directly to the polymer (A) and mixed uniformly. However, the titanium oxide (B) is previously dispersed in water together with a surfactant and a pigment dispersant. After preparing the liquid, it is preferable to use a method in which the dispersion is added to the polymer (A) and mixed uniformly to improve concealability and miscibility.
  • an extender pigment (C) such as silica, alumina silicate, calcium carbonate, precipitated barium sulfate is blended for the purpose of enhancing the hiding property. Also good.
  • the extender pigment (C) may be added directly to the polymer (A) and mixed uniformly.
  • the extender pigment (C) is dispersed in water together with a surfactant and a pigment dispersant in advance. After preparing the liquid, it is preferable to use a method in which the dispersion is added to the polymer (A) and mixed uniformly to improve concealability and miscibility.
  • a pigment (D) other than the titanium oxide (B) may be blended in order to obtain a desired hue.
  • An organic pigment and an inorganic pigment can be used.
  • the organic pigment include lake red, permanent red, brilliant carmine, calcium lake, naphthol AS red, benzimidazolone yellow, disazo yellow HR, pyrazolone red, condensed azo yellow, condensed azo red, condensed azo brown, nickel azo yellow.
  • Phthalocyanine pigments such as phthalocyanine blue, chlorinated phthalocyanine green, brominated phthalocyanine green; anthraquinone yellow, dianthraquinonyl red, indanthrene blue, thioindigo Bordeaux, perinone orange, perylene scarlet, perylene orange Perylene red, perylene maroon, quinacridone red, quinacridone magenta, quinacridone scarlet, dioxazine violet, Isoindolinone yellow, quinophthalone yellow, isoindoline yellow, etc. condensed polycyclic pigments such as diketopyrrolopyrrole red and the like.
  • the inorganic pigment examples include metal oxide pigments such as zinc white, petal, iron black, and chromium oxide; titanium yellow, zinc-iron brown, titanium cobalt green, cobalt green, cobalt blue, and copper-chromium black.
  • Metal complex oxide pigments such as copper-iron black; Chromic acid pigments such as yellow lead and molybdate orange; Ferrocyanide pigments such as bitumen; Sulfide pigments such as cadmium yellow, cadmium red, zinc sulfide, and barium sulfide; Examples include ultramarine blue, calcium carbonate, cobalt violet, yellow iron oxide, and carbon black.
  • the other pigment (D) may be directly added to the polymer (A) and mixed uniformly.
  • the pigment (D) may be added in advance to a surfactant or a pigment. It is preferable to use a method of preparing a dispersion dispersed in water together with a dispersant, and then adding the dispersion to the polymer (A) and mixing them uniformly, because the saturation and miscibility are improved.
  • the blending amount of the titanium oxide (B), the extender pigment (C) and the other pigment (D) in the pigment printing agent of the present invention varies depending on the desired hue, but usually the pigment printing agent of the present invention.
  • the total of the titanium oxide (B), the extender pigment (C) and the other pigment (D) is preferably in the range of 5 to 40% by mass.
  • a printing paste or the like can be blended to impart suitability such as viscosity according to the printing method.
  • Printing paste is a material that thickens pigment printing agents and imparts printability to screen printing, such as sodium carboxymethylcellulose, hydroxyethylcellulose, propioxycellulose, sodium alginate, alginate, polycarboxylate, etc. The thing melt
  • distributed to water is mentioned.
  • the pigment printing agent of the present invention includes a pH adjuster such as ammonia water, petroleum solvents such as mineral spirits, emulsifiers, thickeners, crosslinking agents, antioxidants, ultraviolet absorbers, dispersants, Additives such as water repellents, leveling agents, antifoaming agents, bactericides, and preservatives can be blended.
  • a pH adjuster such as ammonia water
  • petroleum solvents such as mineral spirits, emulsifiers, thickeners, crosslinking agents, antioxidants, ultraviolet absorbers, dispersants
  • Additives such as water repellents, leveling agents, antifoaming agents, bactericides, and preservatives can be blended.
  • Examples of a method for printing the pigment printing agent of the present invention on a fabric include a screen printing method using a roller printing machine, a flat screen, a rotary screen printing machine or the like with a squeegee such as rubber or urethane resin.
  • the screen used for screen printing is usually 60 to 300 mesh.
  • a drying and heat treatment process is performed at 100 to 150 ° C. for 1 to 5 minutes to fix the pigment printing agent to the fabric.
  • the pigment printing agent of the present invention is printed on the fabric and then dried once to print the dye printing agent.
  • the method (wet-on-dry method) or the method of printing the pigment printing agent of the present invention on a fabric and then printing the dye-printing agent without drying may be used.
  • various printing methods such as gravure coating, roll coating, comma coating, air knife coating, kiss coating, wire bar coating, and flow coating can also be used as a method for printing the pigment printing agent of the present invention on a fabric. Can do.
  • the pigment printing agent of this invention can also be apply
  • Synthesis Example 1 Synthesis of polymer (A-1)) 8 parts by mass of acrylic acid (hereinafter abbreviated as “AA”), 12 parts by mass of maleic anhydride (hereinafter abbreviated as “MAH”), vinyltriethoxysilane (hereinafter abbreviated as “VSi”) 2 parts by mass, 2-ethylhexyl acrylate (hereinafter abbreviated as “2EHA”) 277 parts by mass, styrene (hereinafter abbreviated as “St”) 100 parts by mass, water 200 parts by mass and a nonionic emulsifier (No.
  • the mixture was further reacted at 60 ° C. for 1 hour to obtain a polymer (A-1). Thereafter, the mixture was cooled to room temperature, neutralized by adding 9 parts by mass of 25% by mass of aqueous ammonia, water was added so that the non-volatile content was 36% by mass, and the mixture was uniformly mixed. An aqueous resin emulsion was obtained.
  • Example 1 Preparation of pigment printing agent (1)
  • 30 parts by mass of an aqueous acrylic resin emulsion of the polymer (A-1) obtained in Synthesis Example 1 3 parts by mass of ethylene glycol, 4.5 parts by mass of water, and a white pigment dispersion (“WHITE 70 BASE” manufactured by DIC Corporation) , 60 mass parts of pigment content) was uniformly mixed using a dispersion stirrer.
  • 1.5 parts by mass of a thickener (“RYUDYE-W NT CONC 117” manufactured by DIC Corporation) and 1 part by mass of 25% by mass ammonia water are added, and mixed uniformly using a dispersion stirrer to produce a pigment printing agent. (1) was obtained.
  • Examples 2 to 4 Preparation of pigment printing agents (2) to (4)
  • the aqueous resin emulsion of polymer (A-1) used in Example 1 instead of the aqueous resin emulsion of polymer (A-1) used in Example 1, the aqueous resin emulsions of polymers (A-2) to (A-4) obtained in Synthesis Examples 2 to 4 were used respectively. Except that, pigment printing agents (2) to (4) were obtained in the same manner as in Example 1.
  • Friction resistance was evaluated by judging grades from grades 1 to 5 according to visual criteria using a gray scale for fading. The grade 1 has the lowest wear resistance (large fading), and the grade 5 has higher wear resistance (less fading).
  • Preparation Example 1 Preparation of emulsion paste
  • 5 parts by mass of an emulsifying thickener (“RYUDYE-W REDUCER CONC 720ENF” manufactured by DIC Corporation)
  • 45 parts by mass of water were mixed together to produce a homogenizer
  • special Emulsion paste was obtained by emulsification using “TK Homomixer” manufactured by Meika Kogyo Co., Ltd.
  • Preparation Example 2 Preparation of dye printing agent 10 parts by weight of water, 20 parts by weight of 4% by weight aqueous sodium alginate solution, 20 parts by weight of 6% by weight aqueous carboxymethylcellulose solution, 40 parts by weight of the emulsion paste obtained in Preparation Example 1, 2 parts by weight of sodium bicarbonate, 10 parts by weight of urea, Dye printing using 5 parts by weight of dye (“Kayacion Red P-BN Liquid 33” or “Kayacion Blue P-NFB Liquid 50”, manufactured by Nippon Kayaku Co., Ltd.) using a dispersion stirrer and mixing them uniformly An agent was obtained.
  • dye printing agent 10 parts by weight of water, 20 parts by weight of 4% by weight aqueous sodium alginate solution, 20 parts by weight of 6% by weight aqueous carboxymethylcellulose solution, 40 parts by weight of the emulsion paste obtained in Preparation Example 1, 2 parts by weight of sodium bicarbonate, 10 parts by weight of urea
  • Table 2 shows the evaluation results using the pigment printing agents (1) to (4), (R1) and (R2) obtained in Examples 1 to 4 and Comparative Examples 1 and 2.
  • the fabric printed with the pigment printing agent of the present invention (Examples 1 to 4) has excellent washing resistance and friction resistance without impairing the original texture of the fabric. It was confirmed that there was no problem with the water resistance of the portion (dye heavy color portion) printed with the printing agent.
  • Comparative Example 1 is an example in which a polymer that did not use the polymerizable monomer (a2) having a hydrolyzable silyl group was used, and the 1,000% modulus of the polymer film was less than 0.1 MPa. However, as compared with the pigment printing agent of the present invention, it was confirmed that it was inferior in washing resistance, wet friction resistance and washing resistance of the dye-heavy color part.
  • Comparative Example 2 is an example in which the elongation percentage of the polymer alone used in the pigment printing agent is less than 1,200%. However, compared with the pigment printing agent of the present invention, the original texture of the fabric is impaired, and It was confirmed that the washability, the wet rub resistance, and the washability of the dye heavy color portion were inferior.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

La présente invention concerne un agent d'impression à base de pigments comprenant un polymère (A) produit par polymérisation d'un constituant monomère polymérisable comprenant un monomère polymérisable ayant un groupe carboxyle (a1) et un monomère polymérisable ayant un groupe silyle hydrolysable (a2) et de l'oxyde de titane (B), ledit agent d'impression à base de pigments présentant une propriété telle qu'un film fabriqué uniquement à partir du polymère (A) présente un pourcentage d'allongement compris entre 1 200 et 5 000 % et un module à 1 000 % supérieur ou égal à 0,1 MPa. L'agent d'impression à base de pigments ne subit pas de production du composé nocif qu'est le formaldéhyde, peut conférer une excellente texture à une matière textile sur laquelle est imprimé l'agent d'impression à base de pigments, peut conférer des propriétés élevées de résistance au lavage et de résistance au frottement à une partie sur laquelle est imprimé l'agent d'impression à base de pigments, et peut également conférer une lavabilité élevée à une partie sur laquelle sont imprimés de multiples pigments.
PCT/JP2016/064853 2015-05-28 2016-05-19 Agent d'impression à base de pigments et matière textile utilisant celui-ci Ceased WO2016190208A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201680029069.4A CN107614786B (zh) 2015-05-28 2016-05-19 颜料印染剂和使用其的布帛
JP2017520660A JP6222404B2 (ja) 2015-05-28 2016-05-19 顔料捺染剤及びそれを用いた布帛

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Application Number Priority Date Filing Date Title
JP2015108678 2015-05-28
JP2015-108678 2015-05-28

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WO2016190208A1 true WO2016190208A1 (fr) 2016-12-01

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JP (1) JP6222404B2 (fr)
CN (1) CN107614786B (fr)
WO (1) WO2016190208A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018221235A1 (fr) * 2017-05-30 2018-12-06 Dic株式会社 Encre, article imprimé et procédé de fabrication d'un article imprimé
KR102212265B1 (ko) * 2019-08-30 2021-02-04 (주)대성티앤씨 섬유 날염용 백색 페이스트 및 이의 제조방법

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52147654A (en) * 1976-06-03 1977-12-08 Dynamit Nobel Ag Aqueous solution comprising organoosilicon compound and process for production thereof
JPS61151259A (ja) * 1984-12-26 1986-07-09 Nippon Shokubai Kagaku Kogyo Co Ltd 水性樹脂組成物
JPS61155474A (ja) * 1984-12-28 1986-07-15 Kansai Paint Co Ltd 水性被覆用組成物
JPS62156362A (ja) * 1985-12-26 1987-07-11 株式会社日本触媒 繊維用処理剤
JPH02284950A (ja) * 1989-04-26 1990-11-22 Nippon Synthetic Chem Ind Co Ltd:The 安定化された塗料用組成物
JPH02305871A (ja) * 1989-05-22 1990-12-19 Dainichiseika Color & Chem Mfg Co Ltd 塗料組成物
JPH08291474A (ja) * 1995-02-20 1996-11-05 Kuraray Co Ltd 樹脂加工布及び加工方法
JPH09250086A (ja) * 1996-03-12 1997-09-22 Kuraray Co Ltd 防炎性樹脂加工布
JPH11293195A (ja) * 1998-04-07 1999-10-26 Jsr Corp 硬化体
JP2000119587A (ja) * 1998-10-20 2000-04-25 Clariant Polymer Kk コーティング組成物
JP2002180386A (ja) * 2000-09-18 2002-06-26 Hiraoka & Co Ltd プリント用複合メッシュシー卜
JP2002309489A (ja) * 2001-04-17 2002-10-23 Komatsu Seiren Co Ltd 印刷用シート
JP2007231459A (ja) * 2006-03-01 2007-09-13 Basu Corporation:Kk 着色加工用半製品、染料により着色加工した製品およびそれらの製造方法
JP2013245333A (ja) * 2012-05-29 2013-12-09 Kansai Paint Co Ltd 無機建材用水性シーラー組成物

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60224852A (ja) * 1984-04-13 1985-11-09 大日本インキ化学工業株式会社 不織布
IT1320087B1 (it) * 2000-11-21 2003-11-18 Atofina Dispersioni acquose di polimeri acrilici.
CN1978575A (zh) * 2005-11-30 2007-06-13 东莞奥美医疗用品有限公司 一种水性粘合剂
JP5057690B2 (ja) * 2006-04-21 2012-10-24 日本合成化学工業株式会社 合成樹脂エマルジョン、該エマルジョンを含有する不織布用バインダーおよび加工不織布
CA2689190A1 (fr) * 2008-12-29 2010-06-29 Alistair John Mclennan Resines liantes a base de copolymere d'acetate de vinyle et de 2-ethylhexanoate de vinyle
JP5630644B2 (ja) * 2010-10-15 2014-11-26 株式会社ミマキエンジニアリング 捺染方法及び捺染物
WO2013035777A1 (fr) * 2011-09-09 2013-03-14 Dic株式会社 Pigment composite et procédé pour sa production
CN103526599A (zh) * 2013-10-25 2014-01-22 合肥聚合辐化技术有限公司 一种高鲜艳度印花粘合剂及其制备方法

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52147654A (en) * 1976-06-03 1977-12-08 Dynamit Nobel Ag Aqueous solution comprising organoosilicon compound and process for production thereof
JPS61151259A (ja) * 1984-12-26 1986-07-09 Nippon Shokubai Kagaku Kogyo Co Ltd 水性樹脂組成物
JPS61155474A (ja) * 1984-12-28 1986-07-15 Kansai Paint Co Ltd 水性被覆用組成物
JPS62156362A (ja) * 1985-12-26 1987-07-11 株式会社日本触媒 繊維用処理剤
JPH02284950A (ja) * 1989-04-26 1990-11-22 Nippon Synthetic Chem Ind Co Ltd:The 安定化された塗料用組成物
JPH02305871A (ja) * 1989-05-22 1990-12-19 Dainichiseika Color & Chem Mfg Co Ltd 塗料組成物
JPH08291474A (ja) * 1995-02-20 1996-11-05 Kuraray Co Ltd 樹脂加工布及び加工方法
JPH09250086A (ja) * 1996-03-12 1997-09-22 Kuraray Co Ltd 防炎性樹脂加工布
JPH11293195A (ja) * 1998-04-07 1999-10-26 Jsr Corp 硬化体
JP2000119587A (ja) * 1998-10-20 2000-04-25 Clariant Polymer Kk コーティング組成物
JP2002180386A (ja) * 2000-09-18 2002-06-26 Hiraoka & Co Ltd プリント用複合メッシュシー卜
JP2002309489A (ja) * 2001-04-17 2002-10-23 Komatsu Seiren Co Ltd 印刷用シート
JP2007231459A (ja) * 2006-03-01 2007-09-13 Basu Corporation:Kk 着色加工用半製品、染料により着色加工した製品およびそれらの製造方法
JP2013245333A (ja) * 2012-05-29 2013-12-09 Kansai Paint Co Ltd 無機建材用水性シーラー組成物

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018221235A1 (fr) * 2017-05-30 2018-12-06 Dic株式会社 Encre, article imprimé et procédé de fabrication d'un article imprimé
JPWO2018221235A1 (ja) * 2017-05-30 2019-06-27 Dic株式会社 インク、印刷物及び印刷物の製造方法
US12091560B2 (en) 2017-05-30 2024-09-17 Dic Corporation Ink, printed article, and method of manufacturing printed article
KR102212265B1 (ko) * 2019-08-30 2021-02-04 (주)대성티앤씨 섬유 날염용 백색 페이스트 및 이의 제조방법

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