WO2017153237A1 - Catalyseur en nid d'abeille à base de matériau fibreux non tissé - Google Patents

Catalyseur en nid d'abeille à base de matériau fibreux non tissé Download PDF

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Publication number
WO2017153237A1
WO2017153237A1 PCT/EP2017/054881 EP2017054881W WO2017153237A1 WO 2017153237 A1 WO2017153237 A1 WO 2017153237A1 EP 2017054881 W EP2017054881 W EP 2017054881W WO 2017153237 A1 WO2017153237 A1 WO 2017153237A1
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WO
WIPO (PCT)
Prior art keywords
honeycomb catalyst
coat
substrate
honeycomb
catalytically active
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2017/054881
Other languages
English (en)
Inventor
Claus S. JØRGENSEN
Jakob Weiland HØJ
Keld Johansen
Karsten Pedersen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Publication of WO2017153237A1 publication Critical patent/WO2017153237A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/88—Handling or mounting catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • B01J35/57—Honeycombs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite

Definitions

  • the present invention relates to a honeycomb shaped cata ⁇ lyst formed of a corrugated substrate composed of a non- woven fibrous material.
  • the invention provides an improved honeycomb shaped catalyst prepared from corrugated sheets of a non- woven fibrous material, preferably provided with a flat liner.
  • a stable honeycomb shaped catalyst can be made of non-woven fibrous material, for instance E-glass fibers as starting material, when coating the material with a first coat layer prior to corrugating and forming the fibrous material into a corrugated sheet.
  • the first coat lay ⁇ er is applied as an aqueous suspension of ceramic material.
  • this invention provides a honeycomb catalyst with a plurality of flow through chan- nels, wherein the honeycomb catalyst comprises a corrugated substrate and optionally a liner applied on the corrugated substrate, the substrate and the optional liner are com- posed of non-woven fibrous material with a first coat of a ceramic material in an amount to result in total weight of the substrate and first coat of between 60-100 g/m 2 and a washcoat layer applied on the first coat, the wash coat contains or is impregnated with one or more catalytically active compounds.
  • the first coat ceramic material comprises preferably tita- nia, silica and/or kaolin.
  • the first coat can be applied on the substrate sheet in form of an aqueous slurry, having a total solid content of 15 - 25 wt%, on one side of the sheet or on both sides of the sheet.
  • the slurry penetrates the sheet.
  • a honeycomb body is formed by stacking up a plurality of the coated and corrugated sheets, or by rolling-up a single coated and corrugated sheet, preferably lined with a flat liner, into a rectangular or cylindrical honeycomb body.
  • the formed honeycomb body has a plurality of par ⁇ allel flow through channels formed by waves of the corru ⁇ gated sheet (s) and the optional liner applied on the corru ⁇ gated sheet ( s ) .
  • the honey ⁇ comb body pre-coated with the first coat is formed by stacking up or rolling up the coated corrugated sheet (s) and the coated liner if present, and is subsequently coated with the washcoat.
  • the washcoat acts as a carrier for the catalytic materials and is used to disperse the materials over a large surface area.
  • Alumina, titania, silica, or mixtures thereof can be used.
  • the washcoat consists of titania.
  • Washcoating of the honeycomb body is usually performed by slurry pickup in the honeycomb body pre-coated with the first coat by pouring the washcoat slurry into the channels of the honeycomb body, or by dipping the body at one side into the washcoat slurry and optionally applying vacuum at the opposite side.
  • the washcoat contains the catalytic active material.
  • the pre-coated and washcoated honey ⁇ comb body is finally impregnated with an aqueous solution containing one or more precursors of the desired catalyti- cally active material, followed by drying and calcination.
  • a honeycomb catalyst according to the invention can be prepared by a method comprising the steps of
  • step e) impregnating the washcoated body with a solution of catalytic active components or precursors thereof, if not contained in the washcoat of step e) ;
  • step (fl) drying and calcining the body of step (el) to obtain the final honeycomb catalyst.
  • Honeycomb catalysts are typically employed in the cleaning of engine exhaust gas.
  • the honeycomb cata ⁇ lyst is shaped as a cylindrical body and canned in a metal housing with a mat between the honeycomb catalyst body and the metallic housing.
  • the cylindrical honeycomb body is radially compressed in order to pro ⁇ vide sufficient friction between the mat and the body and between the mat and the metallic housing.
  • Radially compres- sion typically causes cracks in the coated and calcined body.
  • a further advantage of the first coat provided on the substrate is that the canning process causes a much reduced cracking of the honeycomb body.
  • the canned honeycomb catalyst is as mentioned above typi ⁇ cally used in the catalytically removal of noxious com ⁇ pounds in the exhaust gas, including nitrogen oxides, un- burnt engine fuel and carbon monoxide.
  • the catalytically active com ⁇ pounds of the honeycomb catalyst are active in the removal of noxious compounds in engine exhaust gas.
  • Catalyst compounds active in engine exhaust gas cleaning are per se known in the art.
  • typically em ⁇ ployed catalysts are vanadium oxide, tungsten oxide, palla- dium and platinum, and zeolitic material either used alone or as mixtures thereof.
  • the nitrogen oxides are converted to free nitrogen with a re ⁇ ducing agent, typically ammonia, in the presence of an SCR catalyst by selective, catalytic reduction:
  • Fig. 1 of the drawings is a sectional view of a honeycomb catalyst according to the invention.
  • the substrate 1 of a honeycomb catalyst according to the invention is composed of a corrugated sheet 2 of non-woven fibrous material substrate, optionally provided with a liner (not shown) .
  • Substrate 1 can be rolled-up to a cylindrical body.
  • a first coat layer 3 made of ceramic material is coated on sheet 2.
  • the first coat material can also diffuse through the fibrous material of sheet 2 and forms a first coat lay- er on both sides of sheet 2and within the fibrous material, as shown in Fig.l.
  • a washcoat layer 4 is coated on the first coat layer 3. Washcoat layer 4 contains catalyst par ⁇ ticles 5.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un catalyseur en nid d'abeille avec une pluralité de canaux traversants d'écoulement, le catalyseur en nid d'abeille comprenant un substrat ondulé et facultativement une gaine appliquée sur le substrat ondulé, le substrat et la gaine facultative étant composés d'un matériau fibreux non tissé, tel que des fibres de verre, avec un premier revêtement d'un matériau céramique et une couche d'enduit appliquée sur le premier matériau céramique de revêtement, l'enduit contenant un ou plusieurs métaux à action catalytique et/ou oxydes métalliques, tels que l'oxyde de vanadium, l'oxyde de tungstène, un matériau zéolitique, du platine et/ou du palladium.
PCT/EP2017/054881 2016-03-09 2017-03-02 Catalyseur en nid d'abeille à base de matériau fibreux non tissé Ceased WO2017153237A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201600145 2016-03-09
DKPA201600145 2016-03-09

Publications (1)

Publication Number Publication Date
WO2017153237A1 true WO2017153237A1 (fr) 2017-09-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2017/054881 Ceased WO2017153237A1 (fr) 2016-03-09 2017-03-02 Catalyseur en nid d'abeille à base de matériau fibreux non tissé

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11987914B2 (en) 2018-04-04 2024-05-21 Unifrax I Llc Activated porous fibers and products including same

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4416800A (en) * 1978-09-12 1983-11-22 Sakai Chemical Industry Co., Ltd. Method for producing a catalyst and a carrier therefor including heat-resistant fibers
US5194414A (en) * 1991-01-21 1993-03-16 Toshimi Kuma Method of manufacturing a gas absorbing element or a catalyst carrier having a honeycomb structure
EP1195196A1 (fr) * 2000-10-06 2002-04-10 Akzo Nobel N.V. Support pour un catalyseur comprenant un papier à fibres imprégné avec des micro-fibres, procédé pour sa production et ses utilisations
US20090025553A1 (en) * 2001-01-05 2009-01-29 Questair Technologies Inc. Adsorbent coating compositions, laminates and adsorber elements comprising such compositions and methods for their manufacture and use
EP2373405A1 (fr) * 2008-12-08 2011-10-12 Haldor Topsøe A/S Procédé et catalyseur pour extraction d oxydes d azote dans un gaz de combustion
US20150151293A1 (en) * 2012-06-06 2015-06-04 Haldor Topsøe A/S Scr catalyst and method of preparation thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4416800A (en) * 1978-09-12 1983-11-22 Sakai Chemical Industry Co., Ltd. Method for producing a catalyst and a carrier therefor including heat-resistant fibers
US5194414A (en) * 1991-01-21 1993-03-16 Toshimi Kuma Method of manufacturing a gas absorbing element or a catalyst carrier having a honeycomb structure
EP1195196A1 (fr) * 2000-10-06 2002-04-10 Akzo Nobel N.V. Support pour un catalyseur comprenant un papier à fibres imprégné avec des micro-fibres, procédé pour sa production et ses utilisations
US20090025553A1 (en) * 2001-01-05 2009-01-29 Questair Technologies Inc. Adsorbent coating compositions, laminates and adsorber elements comprising such compositions and methods for their manufacture and use
EP2373405A1 (fr) * 2008-12-08 2011-10-12 Haldor Topsøe A/S Procédé et catalyseur pour extraction d oxydes d azote dans un gaz de combustion
US20150151293A1 (en) * 2012-06-06 2015-06-04 Haldor Topsøe A/S Scr catalyst and method of preparation thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11987914B2 (en) 2018-04-04 2024-05-21 Unifrax I Llc Activated porous fibers and products including same

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