WO2017155307A3 - 유기 아연 촉매, 이의 제조 방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법 - Google Patents

유기 아연 촉매, 이의 제조 방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법 Download PDF

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Publication number
WO2017155307A3
WO2017155307A3 PCT/KR2017/002522 KR2017002522W WO2017155307A3 WO 2017155307 A3 WO2017155307 A3 WO 2017155307A3 KR 2017002522 W KR2017002522 W KR 2017002522W WO 2017155307 A3 WO2017155307 A3 WO 2017155307A3
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WO
WIPO (PCT)
Prior art keywords
catalyst
organic zinc
carbonate resin
polyalkylene carbonate
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2017/002522
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English (en)
French (fr)
Other versions
WO2017155307A2 (ko
Inventor
김성경
박승영
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LG Chem Ltd
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LG Chem Ltd
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Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Priority to JP2018515659A priority Critical patent/JP6571278B2/ja
Priority to CN201780003772.2A priority patent/CN108602063B/zh
Priority to EP17763568.7A priority patent/EP3415234A4/en
Priority to US15/761,323 priority patent/US10633488B2/en
Publication of WO2017155307A2 publication Critical patent/WO2017155307A2/ko
Publication of WO2017155307A3 publication Critical patent/WO2017155307A3/ko
Anticipated expiration legal-status Critical
Priority to US16/823,496 priority patent/US10836860B2/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/068—Polyalkylene glycols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/123—Organometallic polymers, e.g. comprising C-Si bonds in the main chain or in subunits grafted to the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 폴리알킬렌 카보네이트 수지의 제조를 위한 중합 과정에서 기존 유기아연 촉매보다 향상된 촉매활성을 나타내고 반응 과정에서 응집 현상을 방지할 수 있는 유기 아연 촉매와 이의 제조 방법, 그리고 상기 유기아연 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법에 관한 것이다. 상기 유기 아연 촉매의 제조 방법은 폴리에테르 유도체의 존재 하에 아연 전구체와 디카르복실산을 반응시켜 아연 디카르복실레이트계 촉매를 형성하는 단계를 포함하여 진행된다.
PCT/KR2017/002522 2016-03-09 2017-03-08 유기 아연 촉매, 이의 제조 방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법 Ceased WO2017155307A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2018515659A JP6571278B2 (ja) 2016-03-09 2017-03-08 有機亜鉛触媒、その製造方法および前記触媒を利用したポリアルキレンカーボネート樹脂の製造方法
CN201780003772.2A CN108602063B (zh) 2016-03-09 2017-03-08 有机锌催化剂，其制备方法，以及使用该催化剂制备聚碳酸亚烷基酯树脂的方法
EP17763568.7A EP3415234A4 (en) 2016-03-09 2017-03-08 ORGANIC ZINC CATALYST, PRODUCTION PROCESS AND METHOD FOR PRODUCING A POLYALKYLENE CARBONATE RESIN WITH THIS CATALYST
US15/761,323 US10633488B2 (en) 2016-03-09 2017-03-08 Organic zinc catalyst, preparation method thereof, and method for preparing polyalkylene carbonate resin using the catalyst
US16/823,496 US10836860B2 (en) 2016-03-09 2020-03-19 Organic zinc catalyst, preparation method thereof, and method for preparing polyalkylene carbonate resin using the catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20160028458 2016-03-09
KR10-2016-0028458 2016-03-09

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US15/761,323 A-371-Of-International US10633488B2 (en) 2016-03-09 2017-03-08 Organic zinc catalyst, preparation method thereof, and method for preparing polyalkylene carbonate resin using the catalyst
US16/823,496 Division US10836860B2 (en) 2016-03-09 2020-03-19 Organic zinc catalyst, preparation method thereof, and method for preparing polyalkylene carbonate resin using the catalyst

Publications (2)

Publication Number Publication Date
WO2017155307A2 WO2017155307A2 (ko) 2017-09-14
WO2017155307A3 true WO2017155307A3 (ko) 2018-08-02

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PCT/KR2017/002522 Ceased WO2017155307A2 (ko) 2016-03-09 2017-03-08 유기 아연 촉매, 이의 제조 방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법

Country Status (6)

Country Link
US (2) US10633488B2 (ko)
EP (1) EP3415234A4 (ko)
JP (1) JP6571278B2 (ko)
KR (1) KR102109788B1 (ko)
CN (1) CN108602063B (ko)
WO (1) WO2017155307A2 (ko)

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KR20190037440A (ko) 2017-09-29 2019-04-08 원영식 챔버 잔류가스 배기장치
JP7128965B2 (ja) 2018-12-21 2022-08-31 エルジー・ケム・リミテッド 表面改質処理による廃有機亜鉛触媒の再生方法
WO2021140870A1 (ja) * 2020-01-08 2021-07-15 住友精化株式会社 有機亜鉛触媒組成物の製造方法
KR102576776B1 (ko) * 2022-10-28 2023-09-07 아주대학교산학협력단 이산화탄소-에폭사이드 반응 촉매, 이의 제조 방법 및 이를 이용한 폴리머 합성 방법
KR102705225B1 (ko) * 2023-05-15 2024-09-11 국립공주대학교 산학협력단 고활성 유기 아연 촉매의 제조 방법 및 이로부터 제조된 촉매를 이용한 폴리알킬렌 카보네이트의 제조 방법

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Also Published As

Publication number Publication date
JP6571278B2 (ja) 2019-09-04
US20180265632A1 (en) 2018-09-20
US10633488B2 (en) 2020-04-28
WO2017155307A2 (ko) 2017-09-14
EP3415234A4 (en) 2019-04-17
CN108602063A (zh) 2018-09-28
KR20170105435A (ko) 2017-09-19
JP2018530651A (ja) 2018-10-18
EP3415234A2 (en) 2018-12-19
US10836860B2 (en) 2020-11-17
US20200216612A1 (en) 2020-07-09
KR102109788B1 (ko) 2020-05-12
CN108602063B (zh) 2020-12-08

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