WO2019094052A1 - Soc avec des dispositifs au nitrure du groupe iv et du groupe iii sur des substrats soi - Google Patents
Soc avec des dispositifs au nitrure du groupe iv et du groupe iii sur des substrats soi Download PDFInfo
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Definitions
- III-N Group Ill-Nitride
- PMJCs power management ICs
- RF radio frequency
- HFETs III-N heterostructure field effect transistors
- HEMTs high electron mobility transistors
- MOS metal oxide semiconductor
- III-N HFET devices benefit from a relatively wide bandgap ( ⁇ 3.4eV), enabling higher breakdown voltages than Si-based MOSFETs, as well as high carrier mobility.
- the III-N material system is also useful for photonics (e.g., LEDs) and piezoelectric sensors, one or more of which may be useful to integrate with Si-based FETs into an electronic device platform.
- Forming devices utilizing the wurtzite material system on large format silicon substrates is a challenge due to a large lattice mismatch (e.g., -41% between GaN and Si) and a large thermal expansion coefficient mismatch (e.g., ⁇ 116% between Si and GaN).
- a large lattice mismatch e.g., -41% between GaN and Si
- a large thermal expansion coefficient mismatch e.g., ⁇ 116% between Si and GaN.
- III-N transistors into the silicon device fabrication infrastructure to take advantage of the economies of scale brought by 300mm/450mm wafer processing as well as achieve the higher device performance possible with integrated system-on-chip (SOC) architectures.
- FIG. 1 is a flow diagram illustrating methods of integrating III-N HFET circuitry and Si-based FET circuitry, in accordance with some embodiments
- FIG. 2A is a plan view of illustrating regions on a semiconductor-on-insulator (SOI) substrate suitable for III-N HFET circuitry and surround regions suitable for Group IV-based FET circuitry, in accordance with some embodiments;
- SOI semiconductor-on-insulator
- FIG. 2B is a cross-sectional view illustrating the semiconductor-on-insulator (SOI) substrate shown in FIG. 2A, in accordance with some embodiments;
- FIG. 3 is a cross-sectional view illustrating a definition of first and second regions of a SOI substrate, in accordance with some embodiments
- FIG. 4 and 5 are cross-sectional views illustrating delineation of an amorphous growth mask, in accordance with some embodiments
- FIG. 6 is a cross-sectional view illustrating epitaxial growth of III-N material within a region of a SOI substrate, in accordance with some embodiments
- FIG. 7 and FIG. 8 are cross-sectional views illustrating deposition of an interlayer dielectric (ILD) material and formation of a III-N polarization layer, in accordance with some embodiments;
- ILD interlayer dielectric
- FIG. 9 is a cross-sectional view illustrating formation of a plurality of HFET terminals coupled to III-N material in one region of a SOI substrate, in accordance with some embodiments.
- FIG. 10 is a cross-sectional view illustrating formation of a plurality of MOSFET terminals coupled to substrate material in another region of a SOI substrate, in accordance with some embodiments
- FIG. 11 is a cross-section view illustrating a plurality of metallization levels interconnecting MOSFETs into CMOS circuitry, and III-N-based HFETs into HFET circuitry, in accordance with some embodiments;
- FIG. 12 is a schematic illustrating a mobile computing platform and a data server machine employing an SoC including both III-N HFET circuitry and Si-based CMOS circuitry, in accordance with some embodiments.
- FIG. 13 is a functional block diagram illustrating an electronic computing device, in accordance with some embodiments.
- Coupled may be used to indicated that two or more elements are in either direct or indirect (with other intervening elements between them) physical or electrical contact with each other, and/or that the two or more elements co-operate or interact with each other (e.g., as in a cause an effect relationship).
- one material over or under another may be directly in contact or may have one or more intervening materials.
- One material “over” a second material has a footprint that overlaps at least a portion of the second material's footprint.
- One material “above” a second material is higher within a stack of materials, but footprints of the materials need not overlap.
- one material between two materials may be directly in contact with the two layers or may have one or more intervening layers.
- a first material "on” a second material is in direct contact with that second material/material. Similar distinctions are to be made in the context of component assemblies.
- SOC structures including a semiconductor-on-insulator (SOI) substrate that has a (111) crystalline substrate layer advantageous for seeding an epitaxial III- N material with which III-N devices may be integrated into the SOC structures.
- the SOI substrate may further include another crystalline substrate layer that has a different crystal orientation than the other crystalline substrate layer.
- the SOI substrate may include a (100) or (110) crystal that is advantageous for integrating Group IV devices, such as Si MOSFETs, into the SOC structures. Regions of the SOI substrate may be patterned to remove the (100) or (110) crystal and expose the underlying (111) crystal.
- an amorphous material may be deposited over a sidewall of the (100) or (110) crystal layer that is exposed at a perimeter of the patterned region.
- III-N heteroepitaxy may proceed from the (111) crystal within an opening of the amorphous material with the amorphous material serving as a growth mask preventing competitive III-N heteroepitaxial fronts from forming on the sidewall of the (100) or (110) crystal.
- an SOI substrate layer employed as an epitaxial platform includes a (111) silicon layer.
- the (111) silicon layer may be recessed as needed to accommodate 1-5 microns of III-N buffer thickness while maintaining planarity between the HFET and MOSFET regions of an SOC.
- the (111) crystal layer may have high electrical resistivity, for example to reduce parasitic losses between MOSFET circuitry formed on the (100) or (110) crystal layer and other regions of the SOC.
- the (100) or (110) crystal layer may also include silicon (e.g., a silicon or silicon alloy layer) advantageous for forming Group IV logic devices (e.g., Si FETs).
- the (100) or (110) crystal layer may have higher conductivity than the (111) crystal layer, which may for example, mitigate fabrication issues associated with highly resistive substrates and/or facilitate CMOS multi-well architectures. FIG.
- FIG. 1 is a flow diagram illustrating methods 101 for fabricating an SOC that includes both Group IV MOSFET circuitry and III-N HFET circuitry, in accordance with some embodiments.
- methods 101 are described in the context of exemplary HFET embodiments, it will be appreciated that similar integration may be applied to other III-N based transistor architectures (e.g., any HEMT architecture), as well as other III-N based devices, such as, but not limited to, bipolar transistors and (light emitting) diodes.
- Methods 101 begin with receiving a SOI substrate at operation 105.
- the SOI substrate includes at least two crystalline material layers. At least the top crystal layer is patterned to expose the underlying crystal layer within predetermined regions of the substrate. Within these regions, III-N material is to be heteroepitaxially grown from the lower crystal layer. This III-N material is to host one or more III-N devices. Regions where the top crystal layer is retained are to host one or more Group IV devices. Interconnect metallization formed during back-end-of-line (BEOL) processing then couples the III-N devices and Group IV devices into a function integrated circuit (e.g., an SOC that includes both Group IV and III-N devices). Notably, methods 101 may be practiced over a range of substrate areas.
- BEOL back-end-of-line
- the area of a SOI substrate of a given size (e.g., 300 mm diameter) that is apportioned to a III-N device region or to a Group IV device region may also vary with implementation.
- FIG. 2A is a plan view illustrating a semiconductor-on-insulator (SOI) substrate portion 201 suitable for III-N devices within substrate regions 207 and Group IV-based devices within the surrounding regions 206, in accordance with some embodiments.
- Substrate portion 201 may correspond to a single SOC, a portion thereof, or multiple SOCs may be singulated from substrate portion 201.
- One or more island of III-N material is to be heteroepitaxially grown within each substrate region 207.
- a continuous III-N material layer is formed within each substrate region 207.
- III-N material growth may be confined to one or more smaller regions (e.g., through pinholes in a growth mask) within each substrate region 207 so that many discrete islands or mesas of III-N material may span the area of one substrate region 207.
- Each substrate region 207 may have lateral dimensions (e.g., x-y axes) ranging from a few microns on a side to many hundreds of microns.
- substrate regions 207 may be any arbitrary polygon.
- Substrate regions 207 are surrounded by substrate region 206 that is to be substantially free of III -N material. Portions of a crystal layer present within substrate 206 may be employed as channel material in a MOSFET, for example.
- An SOC that includes the substrate regions 206 and 207 may implement any integrated circuitry.
- MOSFETs in substrate region 206 implement a plurality of LED driver circuits, individual ones of which are coupled to one or more light emitters (e.g., LEDs) arrayed over one or more of the substrate regions 207.
- a FET in substrate region 206 implements CMOS logic circuitry coupled to a RF power amplifier (PA) implemented in one or more of the substrate regions 207.
- PA RF power amplifier
- FETs in substrate regions 206 implement CMOS logic circuitry coupled to one or more high voltage (e.g., > 100V) switches implemented in one or more of the substrate regions 207.
- the substrate received at operation 105 includes a top crystal layer that has a crystal orientation other than that of an underlying crystal layer.
- FIG. 2B is a cross-sectional view further illustrating the semiconductor-on-insulator (SOI) substrate shown in FIG. 2A along the A-A' line, in accordance with some embodiments.
- SOI substrate portion 201 includes a top substrate layer 215 over bottom substrate layer 205 with an intervening dielectric material 210 between crystalline substrate layers 205 and 215.
- substrate layer 215 has (100) or (110) cubic crystal orientation.
- a top surface of substrate layer 215 may therefore be a (100) or (110) crystal plane of a group IV material having cubic crystallinity (e.g., Si, Ge, or SiGe alloy), which is well suited to the fabrication of silicon CMOS circuitry.
- substrate layer 215 is monocrystalline (100) silicon.
- Substrate layer 215 may have a wide range of thicknesses. In some embodiments, substrate layer 215 may have a thickness that is on the order of a predetermined height of a fin that is to be formed into substrate layer 215 (e.g., substrate layer 215 may be 100 nm, or less).
- substrate layer 215 may have a thickness that is much greater than a predetermined height of a fin that is to be formed into substrate layer 215 (e.g., substrate layer 215 may be 1-2 ⁇ , or more). As described further below, greater thicknesses may be leveraged to maintain planarity between substrate regions 206 and 207 following subsequent processing.
- Substrate layer 215 may have any impurity doping that is suitable for hosting complementary MOS (CMOS) transistors.
- substrate layer 215 may include donor or acceptor impurities that impart n-type or p-type conductivity.
- CMOS complementary MOS
- Exemplary impurities include phosphorus, arsenic (n-type dopants of silicon) and boron (p-type dopant of silicon).
- any known dopant species may be selected depending on the semiconductor material system.
- substrate layer 215 is Si
- substrate layer 215 includes a background level of acceptor impurities such that substrate layer 215 is p-type with a resistivity that is less than 500 ohm-cm, and may be less than 100 ohm-cm.
- these lower resistivities may be beneficial because high-resistivity substrates can cause complications during the IC fabrication process. For example, plasma etching and plasma enhanced chemical vapor deposition (PECVD), for example, may induce a local build-up of electrical charges.
- PECVD plasma enhanced chemical vapor deposition
- a lower resistivity (higher conductivity) of substrate layer 205 may be leveraged to mitigate such issues.
- substrate layer 205 has a resistivity below 500 ohm-cm, and advantageously less than 100 ohm-cm.
- Substrate layer 215 may further comprise regions (e.g., wells) having a conductivity type that is complementary to the background (e.g., n-type wells). Substrate layer 215 may have any of the attributes described above and may have all of the attributes described above. For example, in some embodiments substrate layer 215 is (100) silicon, with a thickness of at least 100 nm, and a resistivity less than 500 ohm-cm.
- substrate layer 205 is a portion of a "handle" wafer.
- substrate layer 205 has (111) crystal orientation.
- a top surface of the layer may therefore be a (111) crystal plane of a group IV material (e.g., Si, Ge, or SiGe alloy) having cubic crystallinity.
- a (111) surface of a group IV material e.g., Silicon or SiGe having cubic crystallinity offers a larger lattice spacing than other first order cubic crystal planes, such as (100) and (110).
- substrate layer 205 may however also have other crystallographic orientations.
- a (111) silicon crystal surface may be miscut or offcut, for example 2-10° toward [110] or [100], exposing higher order planes.
- substrate layer 215 is monocrystalline silicon.
- substrate layer 205 has a higher electrical resistivity than substrate layer 215.
- high frequency (e.g., GHz band) devices e.g., RFICs
- electrical resistance of the substrate material upon which an IC is fabricated is often important. As an IC's operating frequency increases, parasitic losses associated with the substrate become more substantial unless the resistivity of the substrate material is increased.
- substrate layer 205 is silicon
- the silicon is substantially undoped and has a resistivity over 500 ohm-cm, advantageously at least 1000 ohm-cm, and potentially 5000 ohm-cm, or higher.
- Substrate layer 205 is generally thicker than substrate layer 215.
- substrate layer 205 is a bulk crystalline handle wafer of a bi-layer SOI wafer.
- substrate layer 205 may have any thickness ranging from tens to many hundreds of micrometers (e.g., 800 ⁇ ).
- substrate layer 205 may have any and all of the attributes described above.
- substrate layer 205 is (111) silicon, with a thickness over 100 ⁇ , and a resistivity over 500 ohm-cm.
- Substrate dielectric material 210 may be any suitable dielectric material, such as a buried silicon dioxide (BOX) layer.
- Substrate dielectric material 210 may have any ratio of oxygen and silicon constituents, for example.
- Other dielectric material compositions are also possible, such as, but not limited to materials having a relative permittivity below 3.5, and even below 3.0.
- the thickness (z-dimension in FIG. 2B) of the layer of substrate dielectric material 210 may vary with implementation. The thickness may be targeted, for example, based on device performance parameters, such as a level electrical isolation between circuitry formed over substrate layer 215 and substrate layer 205.
- the layer of substrate dielectric material 210 may be thin (50-200 nm).
- the layer of substrate dielectric material 210 may be thick (e.g., 1-2 ⁇ , or more) to provide better noise isolation at higher frequencies (e.g., > 2GHZ).
- the thickness of the layer of substrate dielectric material 210 may also be designed to minimize non-planarity between substrate regions 206 and 207. Hence, even where not necessary for electrical isolation, the thickness of substrate dielectric material 210 may be multiple microns.
- methods 101 continue at operation 110 where portions of the SOI in which III-N devices are to be fabricated are defined.
- operation 110 at least the top crystalline substrate layer is removed from within a first substrate region where the III-N material is to be subsequently grown.
- Operation 110 may be staged anywhere within a frontend MOS transistor fabrication process.
- operation 110 may be performed before or after, or integrated into, any known shallow trench isolation (STI) process.
- the top crystalline substrate layer may be removed with any suitable masked etch.
- the underlying substrate dielectric may be similarly removed to expose the underlying crystalline substrate layer.
- an amorphous material is formed over at least the sidewall of the substrate layer(s) etched at operation 110.
- FIG. 3 is a cross-sectional view of a structure 301 illustrating first and second regions of a SOI substrate along the A-A' line following a selective removal of substrate layer 215, in accordance with some embodiments.
- device structures have been fabricated within substrate region 206.
- STI processing has been performed to define fins 318 surrounded by STI material 316.
- STI material 316 may include one or more layers of any suitable dielectric material, such as, but not limited to, S1O2 or S13N4. Where substrate layer 215 has a thickness on the order of a desired total fin height, STI material 316 may extend through the entire thickness of substrate layer 215, as denoted by dashed lines 317.
- STI material 316 may only extend into a portion of substrate layer 215 such that fin 318 resides in an upper portion of substrate layer 215.
- structure 301 further includes a sacrificial gate mandrel 321 extending over a channel portion of fin 318.
- a hard mask 322 is over substrate layer 215 and may also be over gate mandrel 321.
- Hard mask 322 may be a dielectric material, such as, but not limited to, a compound of silicon and oxygen, such as S1O2. In other examples, hard mask 322 is SiON, SiOC(H).
- substrate layer 215 and substrate dielectric material 210 have been removed, forming recess 330. Any etch process known to be suitable for the compositions of substrate layer 215 and substrate dielectric material 210 may be enlisted to form recess 330. Substrate layer 215 and substrate dielectric material 210 remain only within substrate region 206. In the illustrated embodiment, a (111) surface of substrate layer 205 is exposed within recess 330. Substrate layer sidewall 320 is also exposed along a perimeter of recess 330. The etch process employed to remove substrate layer 215 and dielectric material 210 may stop at any depth within substrate layer 205, as denoted in FIG. 3 by dashed line 350.
- Recess 330 may therefore have any depth (e.g., z-axis) relative to a top surface of substrate layer 215.
- recess 330 extends into substrate layer 250 by a micron, or more.
- the depth of recess 330 may be predetermined, for example, to accommodate a predetermined thickness of III-N material within recess 330 in a manner that improves planarity between a substrate regions 206 and 207.
- a top surface of substrate layer 215 is covered with a hard mask 322, which may be any dielectric material, such as, but not limited to, SiOx, SiN x , SiON, or SiOC(H).
- a layer of amorphous material 324 is deposited over both substrate regions 206 and 207, for example covering hard mask 322 and covering the (111) surface of substrate layer 205 that would otherwise be exposed within recess 330.
- Amorphous material 324 also covers substrate layer sidewall 320.
- amorphous material 324 is a substantially conformal layer having a thickness over substrate layer sidewall 320 that is at least 80% of its average thickness over substrate layer 205.
- Amorphous material 324 is to be retained over at least substrate layer sidewall 320 and may be of any material known to be suitable for blocking, masking or otherwise precluding growth of III-N material.
- amorphous material 324 is a nitride.
- amorphous material 324 includes one or more layers of a compound including predominantly silicon and nitrogen, such as S13N4.
- amorphous material 324 includes one or more layers of a compound including silicon, oxygen, and nitrogen, such as silicon oxynitride (SiON).
- SiON silicon oxynitride
- amorphous material 324 includes one or more layers of a compound of predominantly silicon and oxygen (e.g., S1O2).
- amorphous material 324 may be a metallic compound or metal oxide.
- Amorphous material 324 may be deposited with any conformal deposition technique known to be suitable for the desired material composition, such as, but not limited to chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), or atomic layer deposition (ALD).
- CVD chemical vapor deposition
- PECVD plasma enhanced CVD
- ALD atomic layer deposition
- Amorphous material 324 may have any thickness sufficient to preclude subsequent material growth over substrate layer sidewall 320.
- Amorphous material 324 may then be patterned with either a self-aligned technique (e.g., with an anisotropic spacer etch) or with a masked patterning technique.
- spacers of amorphous material 324 are retained only along the perimeter of substrate region 207. The resulting spacers may then protect a sidewall of substrate layer 215. Where a significant portion of substrate layer 205 is also recessed, the spacers of amorphous material may also protect a sidewall of substrate layer 205, which may also otherwise present an undesirable seeding surface during subsequent III-N material growth.
- amorphous material 324 is masked, and openings or windows are defined through amorphous material 324.
- recess 330 is backfilled with a sacrificial masking material 410.
- a top surface of masking material 410 is then planarized (e.g., within a few tens of nanometers) with a top surface of substrate region 206.
- masking material 410 has been planarized with hard mask 322, for example with a polish that removed amorphous material 324 from substrate region 206.
- masking material 410 may be planarized with top surface of amorphous material 324.
- An opening 415 is then defined in a masking material 410, which may be a photodefinable material, or may be any suitable hardmask. Opening 415 is then translated with one or more process (e.g., dry develop and/or anisotropic etch) through masking material 410, and through amorphous material 324.
- Exemplary structure 501 shown in FIG. 5 includes a patterned amorphous growth mask 524 within substrate region 207 that is suitable for templating a III-N epitaxial growth from the (11 1) surface of substrate 205 exposed within opening 515 without competitive growths on a substrate layer sidewall 320.
- III-N material growth over the top surface of substrate layer 215 within substrate region 206 may also be prevented by growth mask 524 if retained over substrate region 206, or prevented by an underlying amorphous material (e.g., hard mask 322) that is retained within substrate region 206.
- methods 101 continue at operation 125 where one or more layers of III-N material are heteroepitaxially grown over the substrate layer having (1 1 1) orientation.
- the heteroepitaxial growth process may form III-N material over an entire SOI substrate wherever the (11 1) substrate layer is exposed.
- the growth mask covering at least the sidewalls at the perimeter of the III-N device region may further limit the formation of III-N material to only the (111) surface. Any number of layers of III-N material may be grown to any suitable thickness during operation 125.
- III-N material composition including binary alloys (e.g., GaN, InN), ternary alloys (e.g., Al x Ini- x N, In x Gai- x N, or ALGai- xN), and quaternary alloys (e.g., In x Ga y Ali- x - y N) may be grown at operation 125.
- the III-N semiconductor material grown at operation 125 is a III-N
- III-N heteroepitaxial growth process may be employed at operation 125, such as, but not limited to, molecular beam epitaxy (MBE), metal-organic chemical vapor deposition (MOCVD), vapor phase epitaxy (VPE), or any other technique known to be suitable for III-N material growth.
- MBE molecular beam epitaxy
- MOCVD metal-organic chemical vapor deposition
- VPE vapor phase epitaxy
- elevated temperatures of 900 °C, or more are employed to epitaxially grow a GaN crystalline structure over the buffer.
- the growth process includes growth of intrinsic GaN material (having no intentional donor or acceptor impurity doping).
- oxygen impurity concentration may be less than lel7/cm 3 (e.g., Iel5-lel6/cm 3 ).
- III-N material 620 is grown within substrate region 207, wherever growth mask 524 is absent.
- III-N material 330 is monocrystalline with the hexagonal/wurzite oaxis substantially orthogonal to the (111) plane of silicon substrate layer 205.
- the c-plane of the III-N material is no more than 10° from parallel to the (111) plane of silicon substrate layer 205.
- III-N material 620 includes a buffer layer grown directly on exposed regions of substrate layer 205.
- examples include an A1N and/or AlGaN nucleation layer directly on the (111) silicon surface, with one or more AlGaN and/or GaN layers on the nucleation layer.
- a buffer of III-N material e.g., GaN
- first epitaxial growth conditions e.g., a first growth pressure, a first growth temperature, and a first V/III growth precursor ratio.
- growth conditions may be changed to a second growth temperature, and/or second growth pressure, and/or a second V/III growth precursor ratio favoring lateral epitaxial overgrowth (LEO) of III-N material (e.g., GaN) to extend III-N material 620 over growth mask portion 622.
- LEO lateral epitaxial overgrowth
- III-N material e.g., GaN
- the LEO process employed favors formation of inclined sidewall facets. Overgrowth at rates that favor wurtzite crystal facets non-parallel and non-normal (e.g., -60°) to the c-plane have been found to bend defects away from the c-plane and toward the sidewalls such that the quality of a top surface of the III-N crystalline structure can improve with overgrowth time.
- III-N material 330 Upon termination of the growth operation, III-N material 330 has a trapezoidal profile, the dimensions of which depend on growth time.
- III-N material 620 is grown to a z-thickness of 1-3 ⁇ , or more, over the interface with substrate layer 205. This thickness may be selected to arrive at a desirable crystal quality (e.g., defect density below le9/cm 2 ).
- thicknesses of substrate layer 215 and dielectric material layer 210, along with a depth of a recess into substrate layer 205 may be predetermined so that a desired thickness of III-N material 620 results in planarity of III-N material top surface 621 and a top surface 615 of substrate layer 215.
- a polish may be performed following III-N material growth to planarize III- N material top surface 621 with top surface 615.
- methods 101 continue at operation 130 where another amorphous material is formed over sidewalls of the III-N material grown at operation 125.
- This amorphous material may serve as another growth mask confining further epitaxial growth to portions of the III-N material.
- the amorphous material may be deposited over non-polar and/or semi-polar surfaces of the III-N material grown at operation 125. Any amorphous material known to be suitable for such purposes may be deposited by any technique known to be suitable for the material.
- the amorphous material deposited at operation 130 has the same composition as the amorphous material deposited at operation 120.
- Amorphous material formed at operation 125 may be deposited with any deposition technique known to be suitable for the desired material composition, such as, but not limited to, CVD, PECVD, or ALD.
- an amorphous material 725 is deposited over III-N material 620 and over amorphous growth mask 524.
- Amorphous material 725 backfills the recess within substrate region 207.
- Amorphous material 725 may include multiple material layers, for example including a substantially conformal layer having a thickness over a sidewall of III-N material 620 that is at least 80% of its average thickness over adjacent portions of growth mask 524.
- Amorphous material 725 may further include one or more gap-filling material layers over any conformal layer(s).
- Amorphous material 725 is to be retained over at least a sidewall of III-N material 620.
- amorphous material 725 includes a nitride layer in contact with III- N material 620.
- the nitride layer is a compound including predominantly silicon and nitrogen, such as S13N4.
- amorphous material 725 includes a layer of a compound including silicon, oxygen, and nitrogen, such as silicon oxynitride (SiON), in contact with III-N material 620.
- SiON silicon oxynitride
- amorphous material 725 includes a layer of a compound of predominantly silicon and oxygen (e.g., S1O2) in contact with III-N material 620.
- amorphous material 725 includes a layer of metal oxide in contact with III-N material 620.
- amorphous material 725 further includes a gap filling material, such as any flowable oxide known to be suitable for such applications. Following deposition of amorphous material 725, growth mask 524 and amorphous material 725 (e.g. in the x- dimension) occupy space between III-N material 620 and a sidewall of substrate layer 215.
- a gap filling material such as any flowable oxide known to be suitable for such applications.
- III-N material 620 that is to host a III-N device is then further processed. For example, returning to FIG. 1 , methods 101 continue at operation 135 where a III-N FET is fabricated in one substrate region. Any III-N FET may be fabricated at operation 135 according to any suitable techniques. In some embodiments, a III-N HFET including a gate electrode, a source, and a drain is fabricated at operation 135. For the exemplary structure
- HFET fabrication begins with forming a polarization layer 850 over a polar plane (e.g., oplane) of III-N material 620.
- Polarization layer 850 may be epitaxially grown on exposed surface of III-N material 620 using any suitable growth technique, such as any of those employed to form III-N material 620.
- any suitable growth technique such as any of those employed to form III-N material 620.
- portions of III-N material 620 are protected from III-N material overgrowth by amorphous material 725.
- Polarization layer 850 may include any binary, ternary, or quaternary III-N alloy that has a spontaneous polarization and/or piezoelectric polarization suitable for inducing a charge carrier sheet (e.g., electron gas or hole gas) within a channel portion of the underlying III-N material 620.
- polarization charge layer 850 includes a material such as, but not limited to, Al z Gai- z N (e.g., where Z ranges from 0.2-0.3), or Al w Ini- w N (e.g., where W ranges from 0.7-0.85), or A1N.
- polarization layer 850 includes a layer of Al z Gai- z N.
- the thickness of the polarization layer 850 may vary with material composition.
- a layer of Al z Gai- z N can have a thickness between 5nm-30nm with the thickness varying inversely with the Al concentration. For example, for Z between 20 and 50 atomic percent, the thickness may vary between 30nm and 5nm, respectively.
- the thickness of polarization layer 850 is approximately 25nm (e.g., +/- 20%).
- polarization layer 850 includes is Al w Ini- w N
- the thickness is between 10nm-20nm depending on the Al concentration.
- the thickness may again vary inversely with the Al concentration.
- the Al w Ini- w N layer thickness may vary between 20nm and l Onm, respectively.
- Such an intermediate layer may help to improve mobility of the charge carriers induced by polarization layer 850.
- a mobility enhancement layer may have a thickness of lnm, or less, for example.
- a mobility enhancement layer may be a binary alloy. In one such embodiment where III-N material 620 includes binary GaN nearest to polarization layer 850, a layer of A1N may function as a mobility enhancement layer.
- III-N devices that may be fabricated at operation 135 include, but are not limited to, diodes, light emitting diodes (LEDs), transistors, lasers, and piezoelectric sensors.
- the III-N devices fabricated include transistors, and more specifically heteroj unction field effect transistors.
- the transistors fabricated at operation 135 may have any architecture known to be suitable for an RFIC, power (high-voltage) IC, or a logic IC.
- an ILD material 965 is deposited over substrate regions 206 and 207.
- ILD material 965 may be any dielectric material composition known to be suitable for ICs.
- ILD material 965 may be planarized with any suitable planarization process (e.g., polish).
- ILD material 965 may be patterned and III-N epitaxial growth or deposition processes may be practiced as needed to fabricate a given device structure.
- impurity (e.g., donor) doped III-N material may be selectively grown as source and drain terminals according to any suitable technique.
- impurity doped III-N material may be selectively grown as source and drain terminals according to any suitable technique.
- source and drain terminals 971 are coupled to a device layer (e.g., 2DEG within a top portion of III-N material 360) on opposite sides of a gate electrode stack that includes a gate electrode 981 separated from the device layer by a gate dielectric 975.
- Gate electrode 981, along with source and drain terminals 971 on opposite sides of gate electrode 981, are operable as a first transistor based on electric field modulation of the 2DEG.
- methods 101 continue at operation 140, where Group IV -based devices are fabricated within another substrate region.
- Exemplary devices that may be fabricated at operation 140 include, but are not limited to, diodes, light emitting diodes (LEDs), photovoltaics, transistors, and optical sensors.
- the devices include silicon-based transistors, and more specifically n-type and p-type MOSFETs that may form any desired CMOS circuitry.
- the transistors fabricated at operation 140 may have any architecture known to be suitable for a logic IC, for example. Notably, the sequence of operations 135 and 140 may be reversed from that illustrated.
- fabrication of the III-N device includes an epitaxial growth of III-N material, for example to form semiconductor device terminals, it may be advantageous to perform such III-N growths prior to fabrication of Group IV transistors (e.g., for the sake of accommodating the thermal budget of a MOSFET).
- a gate stack including a gate electrode 1082 and a gate dielectric 1083 is over one or more fin 318.
- a gate stack may be formed according to any known finFET fabrication technique.
- the gate mandrel 321 may be replaced with a permanent gate stack according to any "gate-last" technique.
- FinFET transistors include double-gate transistors and tri-gate transistors, and wrap-around or "gate all-around" transistors, such as nanoribbon and nanowire transistors.
- MOSFETs fabricated within region 206 may also be planar transistors, or a combination of both planar and non-planar transistors.
- a source and drain terminals 1071 are formed on opposite sides of gate electrode 1082.
- Gate electrode 1082 and source and drain terminals 1081 are operable as a transistor based on electric field modulation of conductivity with a channel portion of fin 318. With substrate regions 206 and 207 substantially planar, transistor fabrication processes within each substrate region 206, 207 may be performed concurrently in some advantageous embodiments.
- the gate dielectric layers 1075 and 1083 may each include one layer or a stack of layers.
- the one or more layers may include silicon oxide, silicon dioxide (S1O2) and/or a high-k dielectric material.
- the high-k dielectric material may include elements such as hafnium, silicon, oxygen, titanium, tantalum, lanthanum, aluminum, zirconium, barium, strontium, yttrium, lead, scandium, niobium, and zinc.
- high- k materials that may be used in the gate dielectric layer include, but are not limited to, hafnium oxide, hafnium silicon oxide, lanthanum oxide, lanthanum aluminum oxide, zirconium oxide, zirconium silicon oxide, tantalum oxide, titanium oxide, barium strontium titanium oxide, barium titanium oxide, strontium titanium oxide, yttrium oxide, aluminum oxide, lead scandium tantalum oxide, and lead zinc niobate.
- the gate electrodes 981 and 1082 may include at least one P-type work function metal or N-type work function metal, depending on conductivity type of the transistor channel.
- substrate region 206 includes NMOS transistors with N-type work function metal and PMOS transistors with P-type work function metal.
- the gate electrodes 981 and 1082 include a stack of two or more metal layers, where one or more metal layers are work function metal layers and at least one metal layer is a conductive fill layer.
- metals that may be used for the gate electrode 1082 include, but are not limited to, ruthenium, palladium, platinum, cobalt, nickel, and conductive metal oxides (e.g., ruthenium oxide).
- metals that may be used for the gate electrode layer 1082 include, but are not limited to, hafnium, zirconium, titanium, tantalum, aluminum, alloys of these metals, and carbides of these metals such as hafnium carbide, zirconium carbide, titanium carbide, tantalum carbide, and aluminum carbide. These same gate metals may be employed for gate electrodes 981. Alternatively, different gate metals (e.g., titanium nitride, etc.) may be employed for gate electrodes 981.
- a pair of sidewall spacers may be formed on opposing sides of the gate stacks.
- the sidewall spacers may separate the gate stack from the source and drain terminals.
- the sidewall spacers may be formed from a material such as silicon nitride, silicon oxide, silicon carbide, silicon nitride doped with carbon, and silicon oxynitride. Processes for forming sidewall spacers are well known in the art and generally include deposition and etching process operations.
- Source and drain terminals 1071 may be formed using either an
- the source and drain terminals 1071 are a silicon alloy such as silicon germanium or silicon carbide.
- methods 101 continue at operation 145 where the optional Group IV device (low voltage/frequency CMOS) circuitry is interconnected to III-N device (e.g., high voltage/frequency HFET) circuitry.
- III-N device e.g., high voltage/frequency HFET
- metallization levels and intervening ILD is fabricated over both device regions 206, 207, interconnecting all devices on the SOC concurrently.
- the number of metallization levels disposed over substrate region 206 differs from the number of metallization levels disposed over substrate region 207. For example, within substrate region 207 there may less than half the metallization layers than are present in substrate region 206.
- metallization levels may be disposed over substrate region 206
- only 1-5 metallization levels may be disposed over substrate region 207.
- a reduced metallization level count within the III-N device region may be associated with metallization levels that have significantly greater z-thicknesses than the levels employed in the Group IV device region.
- HFET device density is much lower than that of the Si FETs. While a larger and/or lower transistor count within the HFET region of the substrate can be interconnected by fewer metallization levels, a higher interconnect power rating, and/or inductance may be beneficial to high-voltage (HV) circuitry of an integrated SOC.
- HV high-voltage
- the III-N HFET circuitry within substrate region 207 comprises one or more RF power amplifier transistors
- at least one thick metallization (e.g., >1.5 ⁇ ) level and/or thick ILD is routed within substrate region 207.
- HFET circuitry disposed over the HFET region of the substrate includes an inductor.
- the inductor may be fabricated in at least one thick metallization level with any known technique.
- Use of the thick metallization may enable an inductor of advantageous quality factor (Q) to be fabricated over the HFET region within the same z-thickness occupied by the more numerous, but thinner metallization levels disposed over the Si FET region. This high-Q inductor may further benefit from high resistance of substrate layer 205.
- a plurality of interconnect metallization levels 1172 interconnect MOS transistor terminals into CMOS circuitry, formed in accordance with some embodiments.
- a plurality of metallization levels 1165 and intervening ILD 1166 is formed over substrate region 206.
- thick metallization levels 1167 are formed.
- the ILD levels 1166 are present in both substrate regions 206, 207.
- formation of thick metallization levels 1167 within III-N HFET regions of the substrate involves etching a pattern through multiple ILD levels and backfilling the etched pattern in one plating operation.
- thick metallization level 367 may implement an inductor having a z- thickness of at least 1.5 ⁇ and disposed only over substrate region 207.
- Multiple ILD levels 1166 corresponding to a least two metallization levels within substrate region 206 are patterned and backfilled to form thick metallization level 367.
- thick metallization level 367 lands on an underlying metallization level 365, further increasing the effective III-N HFET metallization level thickness by forming a metallization stack including at least one Si FET metallization level.
- structure 1101 may be portion of a monolithic SOC that includes any and/or all of the device structures and properties described above.
- the SOC includes III-N (GaN) HFETs within high voltage circuitry of a power management integrated circuit, while Si FETs implement logic and/or controller functions in low voltage circuitry of the PMIC.
- the SOC includes III-N (GaN) HFETs within high voltage power amplifier circuitry of an RF transceiver, while Si FETs implement logic and/or controller functions in low voltage circuitry of the RF transceiver.
- FIG. 12 illustrates a system 1200 in which a mobile computing platform 1205 and/or a data server machine 1206 employs a monolithically integrated SOC including both III-N HFET circuitry and Si CMOS circuitry, for example in accordance with one or more embodiments described above.
- the server machine 1206 may be any commercial server, for example including any number of high-performance computing platforms disposed within a rack and networked together for electronic data processing, which in the exemplary embodiment includes a packaged device 1250.
- the mobile computing platform 1205 may be any portable device configured for each of electronic data display, electronic data processing, wireless electronic data transmission, or the like.
- the mobile computing platform 1205 may be any of a tablet, a smart phone, laptop computer, etc., and may include a display screen (e.g., a capacitive, inductive, resistive, or optical touchscreen), a chip-level or package-level integrated system 1210, and a battery 1215.
- SOC 1260 includes at least III-N HFET circuitry and Si-based CMOS(FET) circuitry.
- SOC 1260 may further include a memory circuitry and/or a processor circuitry 1240 (e.g., RAM, a microprocessor, a multi-core microprocessor, graphics processor, etc.).
- III-N HFET and Si- FET circuitry may implement high and low voltage portions, respectively, of one or more of PMIC 1230, or RF (radio frequency) integrated circuitry (RFIC) 1225 including a wideband RF transmitter and/or receiver (TX/RX).
- SoC 1260 includes a digital baseband and an analog front end module further comprising a power amplifier on a transmit path and a low noise amplifier on a receive path), and a controller 1235.
- PMIC 1230 may perform battery power regulation, DC-to-DC conversion, etc., and so has an input coupled to battery 1215, and an output providing a current supply to other functional modules.
- RFIC 1225 has an output coupled to an antenna (not shown) to implement any of a number of wireless standards or protocols, including but not limited to Wi-Fi (IEEE 802.11 family), WiMAX (IEEE 802.16 family), IEEE 802.20, long term evolution (LTE), Ev-DO, HSPA+, HSDPA+, HSUPA+, EDGE, GSM, GPRS, CDMA, TDMA, DECT,
- each of these SoC modules may be integrated onto separate ICs coupled to a package substrate, interposer, or board.
- FIG. 13 is a functional block diagram of a computing device 1300, arranged in accordance with at least some implementations of the present disclosure.
- Computing device 1300 may be found inside platform 1205 or server machine 1206, for example.
- Device 1300 further includes a motherboard 1302 hosting a number of components, such as, but not limited to, a processor 1304 (e.g., an applications processor), which may further incorporate III-N HFET circuitry interconnected with Si FET circuitry, in accordance with embodiments of the present invention.
- Processor 1304 may for example include power management integrated circuitry (PMIC) that includes III-N HFET circuitry interconnected with Si FET circuitry.
- PMIC power management integrated circuitry
- Processor 1304 may be physically and/or electrically coupled to motherboard 1302.
- processor 1304 includes an integrated circuit die packaged within the processor 1304.
- processor or “microprocessor” may refer to any device or portion of a device that processes electronic data from registers and/or memory to transform that electronic data into other electronic data that may be further stored in registers and/or memory.
- one or more communication chips 1306 may also be physically and/or electrically coupled to the motherboard 1302. In further implementations,
- computing device 1300 may include other components that may or may not be physically and electrically coupled to motherboard 1302. These other components include, but are not limited to, volatile memory (e.g., MRAM 1330, DRAM 1332), non-volatile memory (e.g., ROM 1335), flash memory, a graphics processor 1322, a digital signal processor, a crypto processor, a chipset, an antenna 1325, touchscreen display 1315, touchscreen controller 1375, battery 1310, audio codec, video codec, power amplifier 1321, global positioning system (GPS) device 1340, compass 1345, accelerometer, gyroscope, audio speaker 1320, camera 1341, and mass storage device (such as hard disk drive, solid-state drive (SSD), compact disk (CD), digital versatile disk (DVD), and so forth), or the like.
- volatile memory e.g., MRAM 1330, DRAM 1332
- non-volatile memory e.g., ROM 1335
- flash memory e.g., NAND 1345
- Communication chips 1306 may enable wireless communications for the transfer of data to and from the computing device 1300.
- the term "wireless” and its derivatives may be used to describe circuits, devices, systems, methods, techniques, communications channels, etc., that may communicate data through the use of modulated electromagnetic radiation through a non-solid medium. The term does not imply that the associated devices do not contain any wires, although in some embodiments they might not.
- Communication chips 1306 may implement any of a number of wireless standards or protocols, including but not limited to those described elsewhere herein.
- computing device 1300 may include a plurality of communication chips 1306. For example, a first communication chip may be dedicated to shorter-range wireless communications, such as Wi-Fi and Bluetooth, and a second communication chip may be dedicated to longer-range wireless
- an integrated circuit (IC) structure includes a first device region comprising a first substrate layer over a second substrate layer with a layer of intervening dielectric material therebetween, wherein the first substrate layer comprises silicon and has (100) or (110) crystallinity, and wherein the second substrate layer comprises silicon and has (111) crystallinity.
- the IC structure includes a second device region lacking the first substrate layer, and comprising a Group Ill-Nitride (III-N) material and an amorphous material, wherein the amorphous material is over a sidewall of the first substrate layer, and wherein the III-N material is over the second substrate layer with a portion of the III-N material within an opening in the amorphous material.
- III-N Group Ill-Nitride
- the amorphous material defines a perimeter enclosing the second device region.
- the amorphous material comprises one or more layer of dielectric material.
- the intervening dielectric material comprises silicon and oxygen
- the amorphous material comprises silicon and nitrogen.
- the III-N material comprises a buffer with one or more III-N alloy layers, the buffer contacting the second substrate layer.
- the III-N material comprises a polarization layer over the buffer, wherein the polarization layer comprises a first III-N alloy that induces a two-dimensional charge sheet within a second III-N alloy that is below the polarization layer.
- the polarization layer is on a oplane of the buffer, the buffer has a thickness of at least 1 ⁇ , and a top surface of the buffer is planar with a top surface of the first substrate layer.
- the IC structure further includes a first transistor within the first device region, wherein the first transistor includes a first source coupled to a first drain through at least a portion of the first substrate layer.
- the IC structure further includes a second transistor within the second device region, wherein the second transistor includes a second source coupled to a second drain through at least a portion of the III-N material.
- the IC structure further includes one or more metallization levels electrically interconnecting the first transistor to the second transistor.
- the IC structure includes an interlay er dielectric (ILD) over the amorphous material and over a sidewall of the III-N material, wherein a portion of the second source and the second drain is within an opening in the ILD.
- ILD interlay er dielectric
- the amorphous material is in direct contact with the sidewall of the first substrate layer, and in direct contact with the second substrate layer. A portion of the III-N material extends laterally over the amorphous material.
- the ILD is in direct contact with the amorphous material and the portion of the III-N material that extends laterally over the amorphous material.
- the first transistor comprises a metal-oxide-semiconductor (MOS)FET that further includes a first gate electrode separated from the first substrate layer by a first gate dielectric.
- the second transistor comprises a III-N heterostructure field effect transistor (HFET) that further includes a gate electrode separated from the III-N material by a second gate dielectric.
- MOS metal-oxide-semiconductor
- HFET III-N heterostructure field effect transistor
- the first substrate layer has a thickness greater than 100 nm
- the second substrate layer has a lower electrical resistivity than the first substrate layer
- the layer of substrate dielectric material has a thickness greater than that of the first layer.
- a system-on-chip comprises processor circuitry coupled to the RF transceiver circuitry, wherein the processor circuitry comprises a first transistor within the first device region of any of the first through sixth examples.
- RF circuitry comprising a second transistor is within the second device region of any of the first through sixth examples.
- a system-on-chip includes processor circuitry.
- the processor circuitry comprises metal-oxide-semiconductor field effect transistors (MOSFETs) including a portion of a (100) or (110) crystalline substrate layer within a first region of the SOC, the (100) or (110) crystalline substrate layer separated from a (111) crystalline substrate layer by an intervening dielectric material.
- MOSFETs metal-oxide-semiconductor field effect transistors
- the SOC includes RF circuitry coupled to the processor circuitry.
- the RF circuitry comprises one or more heterostructure field effect transistors (HFETs) including a Group Ill-Nitride (III-N) material within a second region of the SOC that lacks the (100) or (110) crystalline substrate layer.
- HFETs heterostructure field effect transistors
- III-N Group Ill-Nitride
- a portion of the III-N material that is within an opening in an amorphous material is in contact with the (111) crystalline substrate layer.
- the amorphous material extends over a sidewall of the (100) or (110) crystalline substrate layer along a perimeter of the second region.
- the HFETs further comprise a gate electrode disposed over a (0001) surface of the III-N material.
- the (111) crystalline substrate layer has a higher electrical resistivity than the (100) or (110) crystalline substrate layer.
- the amorphous material comprises silicon and nitrogen and has a thickness less than 1 ⁇ .
- the HFETs further comprise a source and a drain disposed over a (0001) surface of the III-N material.
- the SOC further comprises an interlay er dielectric (ILD) over the amorphous material and over a sidewall of the III-N material, wherein a portion of the second source and the second drain is within an opening in the ILD.
- ILD interlay er dielectric
- a method of fabricating a system-on-chip includes receiving a substrate comprising a first substrate layer over a second substrate layer with a layer of intervening dielectric material therebetween, wherein the first substrate layer comprises silicon and has (100) or (110) crystallinity, and wherein the second substrate layer comprises silicon and has (111) crystallinity.
- the method includes exposing the second substrate layer within a first region of the substrate by removing the first substrate layer and the intervening dielectric material from the first region selectively to a second region where the first substrate layer is retained.
- the method includes depositing an amorphous material over a sidewall of the first substrate layer along a perimeter of the first region.
- the method includes epitaxially growing a Group Ill-Nitride (III-N) material over the second substrate layer within the first region, forming one or more heterostructure field effect transistors (HFETs) comprising the III-N material, and forming one or more metal-oxide-semiconductor FETs (MOSFETs) comprising the first substrate layer.
- III-N Group Ill-Nitride
- HFETs heterostructure field effect transistors
- MOSFETs metal-oxide-semiconductor FETs
- depositing the amorphous material further comprises depositing a dielectric material over the sidewall of the first substrate layer and over an exposed surface of the second substrate layer
- the method further includes forming an opening in the dielectric material that exposes the second substrate layer
- epitaxially growing the III-N material further comprises growing the III-N material within the opening in the dielectric material.
- epitaxially growing the III-N material further comprises laterally over-growing the III-N material layer over a surface of the dielectric material.
- the method includes planarizing a top surface of the III-N material with a top surface of the second substrate layer.
- the method includes depositing an interlay er dielectric (ILD) material over a sidewall of the III-N material and over the amorphous material, forming an opening in the ILD material that exposes a portion of the III-N material, and epitaxially growing source and drain material on the exposed portion of the III-N material.
- ILD interlay er dielectric
- the MOSFETs comprise (100) silicon
- the method further comprises interconnecting the HFETs with the MOSFETs.
- exposing the second substrate layer within a first region further comprises recess etching the second substrate layer by a predetermined amount.
- growing the III-N material further comprises growing a polarization layer from at least a (0001) surface of an underlying III-N layer, the polarization layer having a composition that induces a 2D electron gas (2DEG) in the underlying III-N layer.
- Forming the one or more HFETs further comprises forming first gate electrodes and first source and drain terminals that are coupled to the 2DEG.
- Forming the one or more MOSFETs further comprises forming second gate electrodes and second source and drain terminals that are coupled to a portion of the first substrate layer.
- the second substrate layer and has an electrical resistivity that is higher than that of the first substrate layer.
- the method further comprises forming one or more metallization levels, wherein forming the one or more metallization levels further comprises forming first metallization over first gate electrodes and first source and drain terminals within the first region of the SOC, forming second metallization over second gate electrodes and second source and drain terminals within the second region of the SOC, and forming a third metallization over both the first metallization and the second metallization, the third metallization level interconnecting the first metallization with the second metallization.
- the above embodiments are not limited in this regard and, in various implementations, the above embodiments may include the undertaking only a subset of such features, undertaking a different order of such features, undertaking a different combination of such features, and/or undertaking additional features than those features explicitly listed.
- the scope of the invention should, therefore, be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled.
Landscapes
- Thin Film Transistor (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
Abstract
Un substrat semi-conducteur sur isolant (SOI) comprend une couche de substrat cristallin (111) avantageuse pour l'ensemencement d'un empilement d'un matériau III-N épitaxial sur lequel peuvent être formés des dispositifs III-N. Le substrat SOI peut en outre comprendre une autre couche de substrat cristallin qui peut avoir une résistivité électrique inférieure et/ou une orientation cristalline différente par rapport à la couche de substrat cristallin. Un substrat SOI peut comprendre un cristal (100) ou (110) avantageux pour intégrer des dispositifs du groupe IV tels que des MOSFET, par exemple. Des régions du substrat SOI peuvent être conçues pour éliminer le cristal (100) ou (110) et pour exposer le cristal sous-jacent (111) en vue d'une hétéroépitaxie III-N ultérieure. Un matériau amorphe peut être déposé sur une paroi latérale du cristal (100) ou (110) exposé au niveau d'un périmètre de la région configurée. L'hétéroépitaxie III-N peut se faire à partir du cristal (111) à l'intérieur d'une ouverture du matériau amorphe.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2017/061360 WO2019094052A1 (fr) | 2017-11-13 | 2017-11-13 | Soc avec des dispositifs au nitrure du groupe iv et du groupe iii sur des substrats soi |
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| Application Number | Priority Date | Filing Date | Title |
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| PCT/US2017/061360 WO2019094052A1 (fr) | 2017-11-13 | 2017-11-13 | Soc avec des dispositifs au nitrure du groupe iv et du groupe iii sur des substrats soi |
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| WO2019094052A1 true WO2019094052A1 (fr) | 2019-05-16 |
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| PCT/US2017/061360 Ceased WO2019094052A1 (fr) | 2017-11-13 | 2017-11-13 | Soc avec des dispositifs au nitrure du groupe iv et du groupe iii sur des substrats soi |
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| GB2588015A (en) * | 2019-05-13 | 2021-04-14 | X Fab France Sas | Transfer printing for RF applications |
| EP3940763A1 (fr) * | 2020-07-14 | 2022-01-19 | IMEC vzw | Procédé de fabrication d'une structure semiconductrice |
| GB2605668A (en) * | 2020-11-05 | 2022-10-12 | Ibm | Confined Gallium nitride epitaxial layers |
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| GB2588015A (en) * | 2019-05-13 | 2021-04-14 | X Fab France Sas | Transfer printing for RF applications |
| GB2588015B (en) * | 2019-05-13 | 2021-10-13 | X Fab France Sas | Transfer printing for RF applications |
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