WO2022060253A1 - Alliage d'aluminium de coulée - Google Patents
Alliage d'aluminium de coulée Download PDFInfo
- Publication number
- WO2022060253A1 WO2022060253A1 PCT/RU2021/050295 RU2021050295W WO2022060253A1 WO 2022060253 A1 WO2022060253 A1 WO 2022060253A1 RU 2021050295 W RU2021050295 W RU 2021050295W WO 2022060253 A1 WO2022060253 A1 WO 2022060253A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- casting
- alloy
- calcium
- zinc
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/003—Alloys based on aluminium containing at least 2.6% of one or more of the elements: tin, lead, antimony, bismuth, cadmium, and titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/02—Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
- B22D21/04—Casting aluminium or magnesium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
Definitions
- the invention relates to the field of metallurgy, in particular to aluminum-based alloys characterized by high corrosion resistance.
- the alloy can be used to obtain thin-walled castings of complex shape by casting into a metal mold.
- Industrial non-hardened alloys of the A-Si system for example, A413.2 or AK12pch (GOST 1583), are characterized by high manufacturability during casting and a relatively low level of strength properties, in particular, the yield strength usually does not exceed 60-80 MPa, depending on casting thickness.
- a higher level of strength properties of castings already in the cast state is provided by the addition of copper, in particular, alloys of the AA383.1 or AK12M2 type are known.
- the increase in mechanical properties in this case is accompanied by a significant decrease in relative elongation and deterioration in corrosion resistance.
- alloys based on a solid solution based on the Al-Mg system are known, for example, AMgbl, AMg5K, AMg5Mts (GOST 1583), Magsimal®59 (Rheinfelden Alloys), etc., characterized by satisfactory processability during casting, good corrosion resistance , a good level of strength properties and relative elongation.
- the disadvantages of the alloys of this system one should single out a high linear shrinkage and insufficiently good tightness of thin-walled castings.
- the combination of a high level of strength properties, relative to elongation and corrosion resistance is realized in alloys of the Al-Si system with the addition of 0.2-0.5 wt.
- % magnesium in particular, alloys such as AK9 (GOST1583), Silafont®36 (Rheinfelden Alloys), trimal®37 (Trimet), etc. are known. quenching in water), change in overall dimensions and the appearance of cracks.
- alloys such as AK9 (GOST1583), Silafont®36 (Rheinfelden Alloys), trimal®37 (Trimet), etc. are known. quenching in water), change in overall dimensions and the appearance of cracks.
- NUST MISiS An invention of NUST MISiS is known, disclosed in patent RU2660492.
- the material for use in the cast state contains (wt.%): 5.4-6.4% calcium, 0.3-0.6% silicon and 0.8-1.2% iron.
- the disadvantages of the proposed invention one should highlight the low relative elongation, which did not exceed 2.6%, which limits the use of the material in critical cast parts.
- a casting alloy of the Al-Ni-Mn system is known, intended for the production of structural components for automotive and aerospace applications, which is an alternative to branded silumins, developed by Alcoa and disclosed in patent US6783730B2 (published on August 31, 2004). It is possible to obtain castings from this alloy with a good combination of casting and mechanical properties with a content (wt.%) of 2-6% Ni, 1-3% p, 1% Fe, less than 1% silicon, and also with the content of other unavoidable impurities.
- a high level of casting and mechanical properties is ensured by the use of aluminum grades of high purity and with a high nickel content, which significantly increases the cost of the obtained castings.
- the proposed material is thermally non-hardening in the entire concentration range, which limits its use.
- the corrosion resistance of castings is significantly reduced.
- cast aluminum alloys based on Al-Ni and A1-Ni-Mn systems and a method for producing cast parts from them which are described in the invention of Alcoa US8349462B2 (publ. 08.01.2013) and application EP201 1055318 of Rheinfelden Alloys GmbH & Co. kg.
- the invention provides alloy compositions for use in the as-cast state.
- the common thing in the proposed inventions is a high nickel content of 1-6%, which determines the main disadvantage - a significant decrease in corrosion resistance. With a relatively low content of nickel and manganese, casting alloys have a low level of strength characteristics.
- the objective of the invention is to create a new cast aluminum alloy designed to produce thin-walled castings by various methods of casting into a metal mold, in particular, gravity, high-pressure casting, low-pressure casting, liquid stamping, but not limited to, satisfying the specified requirements for a set of technological and corrosion characteristics.
- the technical result of the invention is to provide a given combination of technological characteristics during casting and corrosion resistance.
- Silicon up to 1.0 optional, at least one element selected from the group
- calcium and zinc in the structure are presented mainly in the form of eutectic particles.
- the alloy is made in the form of castings.
- the proposed alloy is characterized by a narrow crystallization interval, which, in combination with a large amount of the eutectic phase, provides a good level of casting characteristics, and due to elements that dissolve in the aluminum solid solution, a satisfactory level of strength properties in the cast state.
- corrosion resistance is maintained at a good level.
- the main criterion for the acceptable choice of alloying elements was the formation of the desired structure, excluding the presence of coarse primary crystals and/or coarsening of the eutectic phase; the rationale for the concentration range is given below.
- the concentration (wt.%) of calcium in the range of 1.5-5.1% and zinc in the range of 0.1-1.8% provide good casting properties due to the fact that calcium and zinc mainly form a sufficient amount of the eutectic phase.
- the main effect of the joint introduction of calcium and zinc is the formation of a joint eutectic phase A14(Ca,Zn), where the zinc atom replaces the calcium atom.
- the level of strength properties is further increased. If the calcium content is less than the declared level, it will lead to a decrease in casting characteristics. When zinc is reduced below the stated level, there will be no significant increase in strength properties.
- the content of calcium and zinc above the stated level will lead to the formation of a rough structure and a significant decrease in mechanical properties.
- the content of iron and silicon is primarily determined by the purity of the aluminum used in the preparation of the alloy.
- iron and silicon can also be used as alloying elements, due to the fact that silicon in an amount of up to 1.0 wt.% is redistributed between the solid solution and the eutectic, which, on the one hand, provides an increase in strength properties due to additional solid solution hardening in the cast state, and on the other hand, it positively affects the casting characteristics of the alloy due to an increase in the amount of eutectic. With a higher content of silicon, the morphology of the eutectic phase worsens, which generally reduces the strength characteristics.
- Iron in an amount of up to 0.5 wt.% predominantly forms phases of eutectic origin, which positively affects the casting characteristics of the alloy due to an increase in the amount of eutectic. With an increase in the concentration of iron above 0.5 wt.%, coarsening of the eutectic phase is possible and, as a result, a decrease in mechanical properties.
- Manganese in an amount of up to 2.5 wt % is necessary to improve the strength properties, primarily in the cast state, by providing solid solution strengthening.
- the manganese content is above 2.5 wt.% in the structure, primary crystals of the Alb(Te, Mn) phase can be formed, which can lead to a decrease in mechanical characteristics.
- the content of manganese is less than 0.2 wt.% will not lead to significant solid-solution hardening and, as a consequence, a weak increase in strength characteristics.
- Zirconium and chromium within the stated limits (wt.%) 0.05-0.14% and 0.05-0.15%, respectively, are necessary to ensure solid solution strengthening. At lower concentrations of these elements, a significant increase in strength characteristics in the cast state is not achieved. For large quantities, it will be necessary to increase the casting temperature above the typical level, which will reduce the durability of the casting molds, otherwise, there will be a high probability of the formation of primary crystals of the AlCr and AlsZr phase, which will not lead to an increase in the level of mechanical properties from the introduction of these elements.
- Titanium in the amount of 0.005-0.1 wt.% is necessary for modifying the aluminum solid solution. With a higher content of titanium in structure, the appearance of primary crystals is possible, which will reduce the overall level of mechanical properties, and at a lower level, the positive effect of the influence of this element will not be realized. Titanium can be introduced in the form of a multicomponent alloy, such as Al-Ti-B and/or Al-Ti-C, so in this case, the presence of boron and carbon in compounds with titanium is possible in the alloy, in amounts proportional to the content of the corresponding alloy. Boron and carbon, as independent elements, did not have a significant effect on the mechanical and casting properties in relation to the range under consideration. In addition, in the presence of titanium, in some cases, a decrease in the tendency to form hot cracks during casting is noted.
- alloys For the preparation of alloys, the following charge materials were used (wt.%): A99 and A8 grade aluminum, TsO grade zinc, calcium in the form of calcium metal and A1-6Ca master alloys, manganese in the form of A1-10% Mn master alloy, Al-10% Zr master alloy , Al-10%Cr, Al-5%Ti.
- Table 1 Chemical composition of experimental alloys (wt.%) The content of other elements typically did not exceed 0.05 wt.%.
- the chemical composition of the alloy was chosen from the condition of obtaining a structure consisting of an aluminum solid solution and a eutectic component. Casting of samples was carried out by gravity method in a metal mold "Separately cast sample". Form temperature - could fluctuate in the range of 20 -60 °C. The casting was a tensile specimen with a diameter of 10 mm and a calculated length of 50 mm, which was tested for tension (with the determination of the yield limit, tensile strength, and relative elongation) immediately after casting without machining. The structure of the samples was evaluated from the sample heads.
- compositions 2, 5 and 12 are most preferred due to the good yield strength to elongation ratio.
- the most desirable structure of the alloy, on the example of composition 5 (table 1), is shown in Fig.1.
- Casting characteristics were evaluated in terms of hot brittleness (HB) using "casting harp", where the best indicator is to obtain a casting with the maximum length of the "rod” (figure 2).
- the hot cracking susceptibility was assessed using the example of alloys 2, 4 and 12 (Table 1).
- an alloy of the type AD6 As a comparison, an alloy of the type AD6.
- the absence of cracks in alloys 2, 4 and 12 (Table 1) is shown, which is a good indicator at the level of most alloys of the Al-Si system, in contrast to the ADC6 alloy, in the casting from which about 40% of the cores were destroyed, starting from the maximum length.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Continuous Casting (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020237012282A KR20230069152A (ko) | 2020-09-16 | 2021-09-15 | 알루미늄 주조 합금 |
| EP21869849.6A EP4215634A4 (fr) | 2020-09-16 | 2021-09-15 | Alliage d'aluminium de coulée |
| JP2023517279A JP7693797B2 (ja) | 2020-09-16 | 2021-09-15 | アルミニウム鋳造合金 |
| CN202180063010.8A CN116057193B (zh) | 2020-09-16 | 2021-09-15 | 铝铸造合金 |
| CA3195581A CA3195581A1 (fr) | 2020-09-16 | 2021-09-15 | Alliage d'aluminium de coulee |
| MX2023003144A MX2023003144A (es) | 2020-09-16 | 2021-09-15 | Aleación de aluminio fundido. |
| US18/121,825 US20230212717A1 (en) | 2020-09-16 | 2023-03-15 | Aluminum casting alloy |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2020130578A RU2745595C1 (ru) | 2020-09-16 | 2020-09-16 | Литейный алюминиевый сплав |
| RU2020130578 | 2020-09-16 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US18/121,825 Continuation US20230212717A1 (en) | 2020-09-16 | 2023-03-15 | Aluminum casting alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2022060253A1 true WO2022060253A1 (fr) | 2022-03-24 |
Family
ID=75353198
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/RU2021/050295 Ceased WO2022060253A1 (fr) | 2020-09-16 | 2021-09-15 | Alliage d'aluminium de coulée |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20230212717A1 (fr) |
| EP (1) | EP4215634A4 (fr) |
| JP (1) | JP7693797B2 (fr) |
| KR (1) | KR20230069152A (fr) |
| CN (1) | CN116057193B (fr) |
| CA (1) | CA3195581A1 (fr) |
| MX (1) | MX2023003144A (fr) |
| RU (1) | RU2745595C1 (fr) |
| WO (1) | WO2022060253A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025171296A1 (fr) | 2024-02-09 | 2025-08-14 | Revolution Medicines, Inc. | Inhibiteurs de ras |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4339316A4 (fr) * | 2021-05-14 | 2025-04-23 | LG Electronics Inc. | Alliage d'aluminium, son procédé de fabrication et pièces l'utilisant |
| KR20250076581A (ko) * | 2022-09-28 | 2025-05-29 | 옵쉬체스트보 에스 오그라니첸노쉬 오트베트스트벤노스트유 “인스티튜트 렉키크 마테리알로브 아이 테크놀로지쉬” | 알루미늄 주조 합금 |
| KR20240171365A (ko) | 2023-05-30 | 2024-12-09 | 현대모비스 주식회사 | 차량용 조명장치 |
| DE102024207364A1 (de) | 2024-08-02 | 2026-02-05 | Zf Friedrichshafen Ag | Aluminiumlegierung |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB546899A (en) * | 1941-10-23 | 1942-08-04 | Nat Smelting Co | Improvements in or relating to aluminium base alloys |
| US5573606A (en) * | 1995-02-16 | 1996-11-12 | Gibbs Die Casting Aluminum Corporation | Aluminum alloy and method for making die cast products |
| US6783730B2 (en) | 2001-12-21 | 2004-08-31 | Alcoa Inc. | Al-Ni-Mn casting alloy for automotive and aerospace structural components |
| US8349462B2 (en) | 2009-01-16 | 2013-01-08 | Alcoa Inc. | Aluminum alloys, aluminum alloy products and methods for making the same |
| RU2478131C2 (ru) | 2010-10-29 | 2013-03-27 | Федеральное государственное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Термостойкий литейный алюминиевый сплав |
| RU2660492C1 (ru) | 2017-11-03 | 2018-07-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Литейный алюминиево-кальциевый сплав |
| RU2672653C1 (ru) * | 2017-11-16 | 2018-11-16 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Коррозионностойкий литейный алюминиевый сплав |
| RU2683399C1 (ru) * | 2017-06-21 | 2019-03-28 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Сплав на основе алюминия |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US4126448A (en) * | 1977-03-31 | 1978-11-21 | Alcan Research And Development Limited | Superplastic aluminum alloy products and method of preparation |
| GB2055895A (en) * | 1979-07-20 | 1981-03-11 | British Aluminium Co Ltd | Aluminium-calcium alloys |
| JPH11302765A (ja) * | 1998-04-20 | 1999-11-02 | Shinko Kosen Kogyo Kk | 衝撃吸収性に優れた発泡金属 |
| JP4523529B2 (ja) | 2005-09-16 | 2010-08-11 | 株式会社神戸製鋼所 | アルミニウム合金発泡体およびその製造方法 |
| JP5305067B2 (ja) | 2007-09-14 | 2013-10-02 | 日産自動車株式会社 | アルミニウム合金からなる応力緩衝材料 |
| KR101402896B1 (ko) * | 2011-05-20 | 2014-06-02 | 한국생산기술연구원 | 알루미늄 합금 및 그 제조방법 |
| CN104775054B (zh) | 2015-03-29 | 2017-06-30 | 深圳市欣茂鑫实业有限公司 | 一种铝合金制品及其制备方法 |
| CN108070746A (zh) | 2016-11-14 | 2018-05-25 | 镇江市润州金山金属粉末厂 | 一种铝合金压铸件 |
| RU2673593C1 (ru) | 2017-05-30 | 2018-11-28 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Высокопрочный сплав на основе алюминия |
| RU2714564C1 (ru) | 2019-08-15 | 2020-02-18 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Литейный алюминиевый сплав |
-
2020
- 2020-09-16 RU RU2020130578A patent/RU2745595C1/ru active
-
2021
- 2021-09-15 WO PCT/RU2021/050295 patent/WO2022060253A1/fr not_active Ceased
- 2021-09-15 CA CA3195581A patent/CA3195581A1/fr active Pending
- 2021-09-15 EP EP21869849.6A patent/EP4215634A4/fr active Pending
- 2021-09-15 CN CN202180063010.8A patent/CN116057193B/zh active Active
- 2021-09-15 JP JP2023517279A patent/JP7693797B2/ja active Active
- 2021-09-15 KR KR1020237012282A patent/KR20230069152A/ko active Pending
- 2021-09-15 MX MX2023003144A patent/MX2023003144A/es unknown
-
2023
- 2023-03-15 US US18/121,825 patent/US20230212717A1/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB546899A (en) * | 1941-10-23 | 1942-08-04 | Nat Smelting Co | Improvements in or relating to aluminium base alloys |
| US5573606A (en) * | 1995-02-16 | 1996-11-12 | Gibbs Die Casting Aluminum Corporation | Aluminum alloy and method for making die cast products |
| US6783730B2 (en) | 2001-12-21 | 2004-08-31 | Alcoa Inc. | Al-Ni-Mn casting alloy for automotive and aerospace structural components |
| US8349462B2 (en) | 2009-01-16 | 2013-01-08 | Alcoa Inc. | Aluminum alloys, aluminum alloy products and methods for making the same |
| RU2478131C2 (ru) | 2010-10-29 | 2013-03-27 | Федеральное государственное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Термостойкий литейный алюминиевый сплав |
| RU2683399C1 (ru) * | 2017-06-21 | 2019-03-28 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Сплав на основе алюминия |
| RU2660492C1 (ru) | 2017-11-03 | 2018-07-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Литейный алюминиево-кальциевый сплав |
| RU2672653C1 (ru) * | 2017-11-16 | 2018-11-16 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Коррозионностойкий литейный алюминиевый сплав |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP4215634A4 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025171296A1 (fr) | 2024-02-09 | 2025-08-14 | Revolution Medicines, Inc. | Inhibiteurs de ras |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2745595C1 (ru) | 2021-03-29 |
| JP7693797B2 (ja) | 2025-06-17 |
| JP2023542129A (ja) | 2023-10-05 |
| CA3195581A1 (fr) | 2022-03-24 |
| CN116057193A (zh) | 2023-05-02 |
| EP4215634A4 (fr) | 2024-10-09 |
| US20230212717A1 (en) | 2023-07-06 |
| MX2023003144A (es) | 2023-06-16 |
| CN116057193B (zh) | 2025-04-18 |
| KR20230069152A (ko) | 2023-05-18 |
| EP4215634A1 (fr) | 2023-07-26 |
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