WO2024254474A3 - Block copolymers with polyester moieties and applications thereof - Google Patents

Block copolymers with polyester moieties and applications thereof Download PDF

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Publication number
WO2024254474A3
WO2024254474A3 PCT/US2024/033044 US2024033044W WO2024254474A3 WO 2024254474 A3 WO2024254474 A3 WO 2024254474A3 US 2024033044 W US2024033044 W US 2024033044W WO 2024254474 A3 WO2024254474 A3 WO 2024254474A3
Authority
WO
WIPO (PCT)
Prior art keywords
block copolymers
applications
polyester
active ingredient
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2024/033044
Other languages
French (fr)
Other versions
WO2024254474A2 (en
Inventor
Osama M. Musa
Matthew Adam Henry FARMER
Steven Peter Armes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISP Investments LLC
Original Assignee
ISP Investments LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ISP Investments LLC filed Critical ISP Investments LLC
Publication of WO2024254474A2 publication Critical patent/WO2024254474A2/en
Publication of WO2024254474A3 publication Critical patent/WO2024254474A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6882Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from hydroxy carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/664Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6852Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from hydroxy carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides block copolymers comprising polyester linkages. These copolymers are obtained by the reaction of polyester forming precursors, RAFT agents, and radically polymerizable monomers. The invention further provides compositions comprising the block copolymers and applications thereof in various industrial areas. The invention furthermore provides a method for reducing the particle size of an active ingredient by obtaining a composition that comprises colloidal particles of the block copolymers and the active ingredient and subjecting the composition to a suitable size reduction operation. Each a, b, and R11 is described herein.
PCT/US2024/033044 2023-06-08 2024-06-07 Block copolymers with polyester moieties and applications thereof Ceased WO2024254474A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US202363507007P 2023-06-08 2023-06-08
US63/507,007 2023-06-08
US202363583897P 2023-09-20 2023-09-20
US63/583,897 2023-09-20

Publications (2)

Publication Number Publication Date
WO2024254474A2 WO2024254474A2 (en) 2024-12-12
WO2024254474A3 true WO2024254474A3 (en) 2025-04-17

Family

ID=93794618

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2024/033044 Ceased WO2024254474A2 (en) 2023-06-08 2024-06-07 Block copolymers with polyester moieties and applications thereof

Country Status (1)

Country Link
WO (1) WO2024254474A2 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10207919B2 (en) * 2015-06-12 2019-02-19 Rhodia Operations Hybrid nanoparticles containing dendrons, methods of producing such hybrid nanoparticles, and uses thereof
US10660970B2 (en) * 2013-07-30 2020-05-26 Genevant Sciences Gmbh Nucleic acid constructs and methods of using the same
US20220025088A1 (en) * 2018-12-20 2022-01-27 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride polymer dispersion
US20240117103A1 (en) * 2022-09-15 2024-04-11 Seoul National University R&Db Foundation Polymer, method of preparing same, and polyurethane prepared by using same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10660970B2 (en) * 2013-07-30 2020-05-26 Genevant Sciences Gmbh Nucleic acid constructs and methods of using the same
US10207919B2 (en) * 2015-06-12 2019-02-19 Rhodia Operations Hybrid nanoparticles containing dendrons, methods of producing such hybrid nanoparticles, and uses thereof
US20220025088A1 (en) * 2018-12-20 2022-01-27 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride polymer dispersion
US20240117103A1 (en) * 2022-09-15 2024-04-11 Seoul National University R&Db Foundation Polymer, method of preparing same, and polyurethane prepared by using same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE PUBCHEM COMPOUND 30 November 2018 (2018-11-30), ANONYMOUS: "1-Butylsulfanylcarbothioylsulfanyldodecane1,3,5,7,9,11-hexacarboxylic acid", XP093306784, Database accession no. 135005649 *
LAI, J.T. ET AL.: "Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents", MACROMOLECULES, vol. 35, no. 18, 1 January 2002 (2002-01-01), US , pages 6754 - 6756, XP002313952, ISSN: 0024-9297, DOI: 10.1021/ma020362m *

Also Published As

Publication number Publication date
WO2024254474A2 (en) 2024-12-12

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